CN1043339A - Color flame candles - Google Patents
Color flame candles Download PDFInfo
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- CN1043339A CN1043339A CN 88108610 CN88108610A CN1043339A CN 1043339 A CN1043339 A CN 1043339A CN 88108610 CN88108610 CN 88108610 CN 88108610 A CN88108610 A CN 88108610A CN 1043339 A CN1043339 A CN 1043339A
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- weight
- chromogenic reagent
- paraffin
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- color flame
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Abstract
A kind of color flame candles, formulated by components such as wax material, chromogenic reagent, solvent, dispersion agent, exciting agents.Wax material is paraffin and ceresine or paraffin and poly mixture.Chromogenic reagent is multiple metal and nonmetallic inorganic or organic compound.Solvent is an alcohols.Dispersion agent is the acid amides and the polyoxyethylene glycol of high carbon number.Exciting agent is a muriate.Match is handled with ignition dope in advance.When lighting this color flame candles, flame presents multiple chromatic colour, has increased the happy atmosphere when lighting.The match sufficient combustion is not smoldered, noncoking, not carbon deposit.
Description
The present invention is a kind of candle of Chromatic color flame, and it belongs to the candle class.Color flame candles of the present invention is formulated by components such as wax material, chromogenic reagent, solvent, dispersion agent, exciting agents.
Color flame candles is when lighting, and candle wick and wax material burned flame have pleasing shades of colour.In red-letter day and celebrating party, especially in the party of congratulating the birthday, light the color flame candles on the birthday cake, more can increase happy atmosphere.About the manufacturing and the technical recipe of color flame candles, many patent documentation reports are arranged all both at home and abroad.As USP 3,468,815, DE(OS) 1945120, special public clear 50-8268, special public clear 50-22828, spy open clear 53-30176, special public clear 49-46362, the spy opens clear 61-16996, CN86105053B, CN87212896U etc.How these patented technologies are with wax material, chromogenic reagent then adopt inorganic salt or the organic salts that wax material incendiary high temperature excite under can make flame present the multiple metal of different colours of paraffin as the burning main ingredient, as copper, barium, strontium, indium, lithium, boron etc. more.Because the solubleness of metal-salt in wax material is very little, the colour of candle flame is very shallow.In order to increase solubleness and the dispersity of metal-salt in wax material, existing patented technology has proposed various terms of settlement.As the public clear 50-22828 of spy with the higher alcohols fatty acid ester of eight carbon to two, ten carbon as solvent.It is wax material with paraffin and palm wax that the spy opens clear 61-16996, is solvent with monohydroxy-alcohol or polyvalent alcohol, and other adds stearic acid, and the ester that acid, alcohol reaction generate makes chromogenic reagent be subjected to the dispersive effect in wax material.In addition, owing to the yellow flame brightness that the wax material based on paraffin presents when burning is stronger, covered chromogenic reagent to a large extent and be subjected to exciting the coloured flame that presents.Therefore, the spy opens clear 54-160068 and CN85105053B uses urethane (urethanum) that " gold-tinted " is more shallow when burning to replace paraffin commonly used as wax material, so just can make the coloured flame of chromogenic reagent outstanding.Yet the price of urethane has increased the cost of raw material far beyond the paraffin costliness.Therefore, with common paraffin is main wax material, add a little auxiliary to improve the content of chromogenic reagent in the color flame candles component, improve the performance of color flame candles when lighting, overcome problems such as " do branch ", the carbon deposit of smoldering, flowing the gutterings of a candle, wax core, coking, all be reflected in the different technologies measure in the disclosed patent documentation.
Purpose of the present invention is exactly in order to solve the above problems, a suitable prescription that contains components such as wax material, chromogenic reagent, solvent and auxiliary agent is proposed, improve the content of chromogenic reagent, make the chromogenic reagent in the color flame candles behind the stripping forming can dissolve equably, be dispersed in the wax material, coloured flame is bright, bright-coloured, stable when lighting, and the candle wick burning fully.
The invention is characterized in:
1. select a kind of in paraffin and ceresine or paraffin and the poly two kinds of mixtures for use, make the candle after the moulding that intensity and toughness preferably be arranged as compound wax material.
2. improve metallic element and the mineral compound of non-metallic element and the content of chromogenic reagent in color flame candles of organic compound, reach as high as 45%(weight).
3. adding acid amides and polyoxyethylene glycol mixture is composite dispersing agent, improves the dispersity of chromogenic reagent in the candle component.
4. be exciting agent with chlorine compound, make the colored enriching of flame.
5. match lights candle wick through the processing of giving of muriate, ethanol and the urethane solution of perchlorate ignition dope, chromogenic reagent element easily, burning fully, noncoking, not carbon deposit.
Wax material is the incendiary material of color flame candles, and as mentioned above, how existing colour candle is wax material with paraffin.The weak point of single paraffin is easily deliquescing, distortion in the storage of the low paraffin of melting point when summer, and the paraffin that melting point is high then became fragile in winter, and the candle after the moulding is fractureed easily.In addition, only making wax material with paraffin flows " gutterings of a candle " easily when lighting.In order to improve the performance of this respect, can add stearic acid, beeswax or macromolecular organic compound such as polyvinyl acetate etc.The used wax material of color flame candles of the present invention is compound wax material, promptly chooses any one kind of them in paraffin and ceresine or paraffin and poly two kinds of mixtures.If during with paraffin and cereous compound wax material, paraffin and cereous weight ratio can be in 1: 1.8～3 scopes, and be better with 1: 2～2.3.If during with the compound wax material of paraffin and polyethylene (molecular weight is about 2000), paraffin and poly weight ratio are in 1: 0.3～0.05 scope.The compound wax material content of color flame candles of the present invention is in 15～50%(weight) in the scope, better with 25～35%.
The present invention is a chromogenic reagent with multiple element compounds such as strontium, potassium, lithium, boron, copper, barium, indiums.According to the multiple colored requirement of candle flame, use the inorganic or organic compound of following element, all obtain satisfied effect:
Green flame chromogenic reagent-mainly use boron compound, as boric acid (H
3BO
3), boron oxide (B
2O
3), boric acid ester ((RO)
3B, R are the alkyl of carbonic acid 2～14) etc.
Rose-colored flame chromogenic material-mainly use lithium compound, as lithium chloride (LiCl), lithiumbromide (LiBr), Lithium Oxide 98min (Li
2O), Lithium Acetate (LiOOC CH
3), naphthenic acid lithium (LiOOC C
nH
2n-1), oleic acid lithium (LiOOC C
17H
33) etc.
Carmetta flame chromogenic material-mainly use strontium compound, as strontium chloride SrCl
2, strontium oxide (SrO), strontium acetate (Sr(CH
3COO)
2), strontium stearate (Sr(C
17H
35COO)
2) etc.
Sky blue flame chromogenic material-mainly use copper compound, as cuprous chloride (CuCl), cupric chloride (CuCl
2), copper carbonate (CuCO
3), the organic complex of copper etc.
Blackish green flame chromogenic material-mainly use the organic salt compound of copper, as neutralized verdigris (Cu(CH
3COO)
2), lipid acid copper (Cu(RCOO)
2, R is the alkyl of carbon number 8～10) etc.
The content of tinting material is 10～45%(weight in color flame candles of the present invention), better with 20～30%.Because the present invention uses suitable solvent and composite dispersing agent, though the content of chromogenic reagent may be up to 45%(weight in color flame candles of the present invention), but still can be dissolved in the wax material and be evenly distributed and can not separate out the coloured flame distinctness with solid state.
In existing technology, the solvent of dissolving chromogenic reagent uses alcohol compound more, comprise monohydroxy-alcohol (as ethanol, higher alcohols, polyvinyl alcohol etc.), dibasic alcohol (as ethylene glycol, polyoxyethylene glycol, glycol ether), polyvalent alcohol (as glycerol) etc., spent glycol of the present invention is a solvent, and its content is 5～30%(weight), better with 10～25%.
The effect of dispersion agent be improve chromogenic reagent in wax material solubleness and it is scatter equably, candle flame therefore colored and stablizing.Existing color flame candles scarcely uses dispersion agent, and the fatty acid ester of the useful higher alcohols of discrete patent documentation or the fatty acid ester of polyvalent alcohol are the report of dispersing auxiliary.The present invention has used the composite dispersing agent that contains acid amides and polyoxyethylene glycol in order further to improve the degree of scatter of chromogenic reagent in wax material.Acid amides is the high-carbon fatty acid amide, and carbon number can be at C
10To C
20Scope, with C
12Acid amides (laurylamide, C
11H
23CONH
2) to C
18Acid amides (stearylamide C
17H
35CONH
2) better.The molecular weight of polyoxyethylene glycol is between 10,000 to 20,000, and the weight ratio of acid amides and polyoxyethylene glycol is 1.5～3: 1, and is better with 2: 1.The content of dispersion agent in color flame candles of the present invention is 10～40%(weight), better with 20～30%.
Another feature of the present invention is that the adding clorafin is the exciting agent of color flame candles.With reference to USP3, the method of 468,615 intensification combustion flame color, one of them is to fix a thin slice cylinder made of copper on the top of match, in the wax material of candle, add the haloid element compound and make exciting agent, can strengthen the blue light that the copper sheet cylinder is sent out under the high temperature that candle is lighted.The present invention directly adds clorafin (chloride about 30%, weight) in the mixture of the color flame candles that contains wax material, solvent, chromogenic reagent and dispersion agent as exciting agent.The degree that the introducing of exciting agent is stimulated the metallic element in the tinting material improves, and has deepened the colour of candle flame.When using boride,, can not add exciting agent because of excitation temperature is low as chromogenic reagent.Except that adding clorafin, can with the muriate of metal chromogenic reagent also.When adding clorafin, its add-on is 0.5～5%(weight of color flame candles).
The pre-treatment of match also is one of important improvement content of many relevant patented technologies, though because of candle wick without pre-treatment, deal with or treated but cooperate the incorrect gutterings of a candle of smoldering, flow can both cause color flame candles to light the time bad phenomenon such as candle wick " is done branch ", coking or carbon deposit improperly with ratio between wax material, solvent, auxiliary agent.Be candle wick is soaked with the potassium chlorate solution and to use the solution-treated identical to the pretreatment process of candle wick among the present invention with chromogenic reagent.Concrete step is to prepare 2～20% the Potcrate aqueous solution earlier, the cotton thread candle wick is soaked wherein, about about 10 minutes of soak time, put into muriatic ethanol such as the boron identical, lithium, strontium, copper, barium and urethane after the taking-up again (1: 1 with chromogenic reagent, weight ratio) mixing solutions (chloride 20～60%, weight) soaked 10～15 minutes in, then in 80～90 ℃ infrared lamp loft drier or the natural air drying drying.
The making method and the prior art of color flame candles of the present invention are roughly the same, promptly earlier with chromogenic reagent and solvent, heated and stirred is to dissolving, add dispersion agent, all just add wax material after the fusing, continue heated and stirred up to evenly, inject the system wax machine that has been equipped with through pretreated match while hot, be color flame candles after the cooling forming demoulding.
Color flame candles of the present invention is lighted easily, flame color distinctness when lighting owing to chromogenic reagent content height, and flame stabilization is not smoldered, and does not flow the gutterings of a candle, and the candle wick sufficient combustion does not have phenomenons such as " doing branch ", coking or carbon deposit, indeformable, not brittle failure when storing.
Embodiment 1
Getting boric acid 5 grams joins in ethylene glycol 5 grams, be heated to 110 ℃ and constantly stirring, after treating whole boric acid dissolvings, add polyoxyethylene glycol (molecular weight 20,000) 2 grams again, heated and stirred is continued in stearylamide 4 gram backs, all add Chinese wax 5 grams after the fusing No. 60, polyethylene (molecular weight 2000) 0.5 gram, heated and stirred is to even.Take advantage of heat to inject the system wax machine that the wax core has been housed, be the candle of green flame after cooling forming takes out.
Embodiment 2
Get lithium chloride 6 grams and join in ethylene glycol 6 grams, be heated to 100 ° ± 10 ℃, after constantly whole lithium chlorides dissolvings are treated in stirring, add polyoxyethylene glycol 3 grams again, stearylamide 6 grams continue heated and stirred, all add Chinese wax 4 grams after the fusing again No. 60, polyethylene 0.3 gram, heated and stirred is extremely evenly.Be the rose flame candle behind the cooling forming.
Embodiment 3
Compound method such as embodiment 1,2, but the preparation component is Lithium Acetate 8 grams, ethylene glycol 3 grams, laurylamide 3 grams, polyoxyethylene glycol 1 gram, clorafin (cl content 30%) 0.1 gram, No. 56 Chinese wax 2 grams, ceresine 5 grams.It after the moulding rose-colored flame candle.
Embodiment 4
Compound method such as embodiment 1,2, preparation component are oleic acid lithium 4 grams, ethylene glycol 1 gram, and stearylamide 3 grams, polyoxyethylene glycol 1 gram, clorafin 0.5 gram, No. 60 Chinese wax 5 grams, polyethylene 0.5 gram is rose-colored flame candle after the moulding.
Embodiment 5
Compound method such as embodiment 1,2, preparation component are strontium chloride 4 grams, ethylene glycol 2 grams, stearylamide 2 grams, polyoxyethylene glycol 1 gram, No. 60 Chinese wax 4 grams, polyethylene 1 gram.It after the moulding carmetta flame candle.
Embodiment 6
Compound method such as embodiment 1,2, preparation component are strontium acetate 8 grams, ethylene glycol 2 grams, and clorafin 0.3 gram, stearylamide 2 grams, polyoxyethylene glycol 1 gram, No. 60 Chinese wax 5 grams, polyethylene 0.5 gram is the carmetta flame candle after the moulding.
Embodiment 7
Compound method such as embodiment 1,2, preparation component are cupric chloride 3 grams, ventilation breather 3 grams, ethylene glycol 2 grams, stearic acid 5 grams, stearylamide 2 grams, polyoxyethylene glycol 1 gram, No. 75 ceresine 3.5 grams, No. 56 Chinese wax 1.5 grams, clorafin 0.2 gram is the sky blue flame candle after the moulding.Because the solubleness and the dispersity of ventilation breather are relatively poor, have added the performance of stearic acid with further improvement this respect.
Embodiment 8
Compound method such as embodiment 1,2, preparation component are cupric chloride 4 grams, ethylene glycol 2 grams, and stearylamide 2 grams, polyoxyethylene glycol 1 gram, No. 60 Chinese wax 5 grams, polyethylene 0.5 gram is the sky blue flame candle after the moulding.
Embodiment 9
Compound method such as embodiment 1,2, preparation component are neutralized verdigris 2 grams, ethylene glycol 2 grams, and stearylamide 2 grams, polyoxyethylene glycol 1 gram, clorafin 0.1 gram, 75 gram ceresine, 5 grams, No. 56 Chinese wax 2 grams are blackish green flame candle after the moulding.
Embodiment 10
Compound method such as embodiment 1,2, preparation component are capric acid copper 4 grams, ethylene glycol 2 grams, and ethylene glycol 2 grams, stearic acid 2 grams, stearylamide 2 grams, polyoxyethylene glycol 1 gram, clorafin 0.1 gram, No. 60 Chinese wax 5 grams, polyethylene 0.5 gram is blackish green flame candle after the moulding.Add stearic effect such as embodiment 7.
Embodiment 11
Compound method such as embodiment 1,2, preparation component are boron oxide 5 grams, ethylene glycol 6 grams, and stearylamide 4 grams, polyoxyethylene glycol 2 grams, No. 60 Chinese wax 5 grams, polyethylene 0.5 gram is the green flame candle after the moulding.
Claims (6)
1, a kind of color flame candles contains wax material, chromogenic reagent, solvent component, forms by shaping and demoulding, the invention is characterized in:
1. select a kind of for compound wax material in paraffin and ceresine or paraffin and the poly two kinds of mixtures for use, the content of compound wax material is 15～50% (weight), and is better with 25～35%;
2. mineral compound and the organic compound with metallic element and non-metallic element is chromogenic reagent, and the content of chromogenic reagent is 10～45% (weight), and is better with 20～30%;
3. be the solvent of chromogenic reagent with ethylene glycol, the content of solvent is 5～30% (weight), and is better with 10～25%;
4. the mixture that adds acid amides and polyoxyethylene glycol is a composite dispersing agent, and the content of dispersion agent is 10～40% (weight), and is better with 20～30%;
5. be exciting agent with the clorafin, the content of exciting agent is 0.5～5% (weight);
6. match is in advance through the processing of potassium perchlorate, chromogenic reagent element muriate, ethanol and urethane solution.
2, according to the said color flame candles of claim 1, it is characterized in that paraffin and the cereous weight ratio in the compound wax material is 1: 1.8～3, better with 1: 2～2.3; Paraffin and poly weight ratio are 1: 0.3～1: 0.05.
3,, it is characterized in that chromogenic reagent can be selected from a kind of in boron, lithium, strontium, copper mineral compound and the organic compound according to the said color flame candles of claim 1.
4, according to the said color flame candles of claim 1, it is characterized in that the acid amides that dispersion agent is used and the weight ratio of polyoxyethylene glycol are 1.5～3: 1, better with 2: 1; Acid amides is the high-carbon fatty acid amide, and carbonatoms is at C
10～C
20In the scope, with C
12～C
18Better; The molecular weight of polyoxyethylene glycol is 10,000～20, in 000 scope.
5, according to the said color flame candles of claim 1, it is characterized in that being used as that the clorafin of exciting agent is chloride is 30%(weight); When the muriate that uses metal during, can not add exciting agent as chromogenic reagent.
6, according to the said color flame candles of claim 1, it is characterized in that used match is in advance with containing 2～20%(weight) aqueous solution soaking of Potcrate 10 minutes, and then put into muriate 20～60%(weight with the chromogenic reagent same metal) ethanol and urethane (1: 1, weight ratio) soak 10～15 minutes in the mixing solutions, the exsiccant method is handled then.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 88108610 CN1043339A (en) | 1988-12-17 | 1988-12-17 | Color flame candles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 88108610 CN1043339A (en) | 1988-12-17 | 1988-12-17 | Color flame candles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1043339A true CN1043339A (en) | 1990-06-27 |
Family
ID=4835133
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 88108610 Pending CN1043339A (en) | 1988-12-17 | 1988-12-17 | Color flame candles |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1043339A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1051336C (en) * | 1994-08-15 | 2000-04-12 | 西安能源水处理新技术开发公司 | Producing method for liquid colour-light candle and candlewick |
| CN1098238C (en) * | 1998-12-28 | 2003-01-08 | 罗永年 | Application of chlorinated paraffin in fireworks |
| CN103484259A (en) * | 2013-09-30 | 2014-01-01 | 昆山市巴城镇顺拓工程机械配件厂 | Candle |
| CN108865323A (en) * | 2018-07-03 | 2018-11-23 | 罗德尼.尼尔.卡梅隆 | A kind of blue flame colorant |
-
1988
- 1988-12-17 CN CN 88108610 patent/CN1043339A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1051336C (en) * | 1994-08-15 | 2000-04-12 | 西安能源水处理新技术开发公司 | Producing method for liquid colour-light candle and candlewick |
| CN1098238C (en) * | 1998-12-28 | 2003-01-08 | 罗永年 | Application of chlorinated paraffin in fireworks |
| CN103484259A (en) * | 2013-09-30 | 2014-01-01 | 昆山市巴城镇顺拓工程机械配件厂 | Candle |
| CN108865323A (en) * | 2018-07-03 | 2018-11-23 | 罗德尼.尼尔.卡梅隆 | A kind of blue flame colorant |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |