CN104327597B - A kind of Environmental-protection water-based ink and preparation method thereof - Google Patents

A kind of Environmental-protection water-based ink and preparation method thereof Download PDF

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Publication number
CN104327597B
CN104327597B CN201410454560.4A CN201410454560A CN104327597B CN 104327597 B CN104327597 B CN 104327597B CN 201410454560 A CN201410454560 A CN 201410454560A CN 104327597 B CN104327597 B CN 104327597B
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water
environmental
based ink
infusion liquid
chinese medicine
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CN201410454560.4A
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CN104327597A (en
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杨俊波
杨志德
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Changxing Aifeite Plastic Technology Co Ltd
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Changxing Aifeite Plastic Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/08Printing inks based on natural resins

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Medicinal Preparation (AREA)

Abstract

The present invention provides a kind of Environmental-protection water-based ink, is made up of following raw material: water-borne acrylic resin emulsion, ethanol, Traditional medicine infusion liquid, deionized water;Traditional medicine infusion liquid is made up of following raw material: Aqueous starch binder, pigment, Chinese medicine juice.Present invention simultaneously provides the preparation method of a kind of Environmental-protection water-based ink, step is as follows: (1) heating corn starch is Aqueous starch binder with water;(2) cold water soak Chinese medicinal material, heated and boiled, being filtrated to get clear liquid is Chinese medicine juice;(3) Aqueous starch binder, Chinese medicine juice and pigment being mixed in proportion, dispersion, for Traditional medicine infusion liquid;(4) fine grinding;(5) raw material is mixed in proportion stirs, obtain Environmental-protection water-based ink;(6) inspection, packaging.Use the water color ink of the present invention, without Harmful chemicals content, bright-colored do not fade, have natural faint scent pest control and anticorrosion.

Description

A kind of Environmental-protection water-based ink and preparation method thereof
Technical field
The present invention relates to water color ink field, particularly relate to a kind of Environmental-protection water-based ink and preparation method thereof.
Background technology
Solvent type ink, either in its production process, when being also used to printing, all can give out substantial amounts of low concentration VOC.And for the process of low concentration VOC, in addition to exhausted minority ink factory uses such as the processing method of the high costs such as activated carbon adsorption, great majority all high-altitudes are directly discharged into air, and the VOC quantity being directly discharged into environment is the most surprising, serious to air environmental pollution, harm operator's is healthy.Water color ink refers to all or part of using water as a class ink of diluent, is mainly processed through emulsifying, mixed grinding by water-soluble resin, organic pigment, inorganic pigment, hydrophilic fuel, water and related auxiliaries.Due to water color ink mainly with water as diluent, without organic solvent (such as esters, ketone, benzene class etc.), in use substantially free of volatilization and the residual of organic solvent, therefore it is particularly well-suited to the sanitary conditions such as cigarette, wine, food, beverage, medicine, toy for children and requires strict Packaging Printing Product.Along with the enhancing of people's environmental consciousness, sustainable development, the cry of environmental protection is more and more higher, and water color ink is increasingly becoming the main flow of present and following ink industry.Present stage, along with food-safety problem rises to a height, food casing safety problem is also by public attention, and therefore water color ink development increasingly focuses on environmental protection, not cause safety problem as final goal.
Chinese patent CN102093779A discloses a kind of Environmental-protection water-based ink and preparation method thereof, Environmental-protection water-based ink is made by mill base, functional resin, wear-resistant wax slurry, wetting agent, defoamer and deionized water, this water color ink rate of drying is fast, folding is not ftractureed, but wherein dispersion resin environmental-protecting performance is the highest in mill base, and employ the relatively chemicals such as multi-dispersant, wetting agent.Chinese patent CN103992691A discloses a kind of water color ink and preparation method thereof, feature is that different step employs different types of resin, can improve the wearability of water color ink, but technological process is complicated, the highest to ingredient requirement, and preparation process employs a large amount of chemicals.Chinese patent CN102533001A discloses formula of a kind of environment-friendly type high performance wallpaper water color ink and preparation method thereof, employ organic pigment and function additive, harmless, but chemicals content is the highest, it is only used for wallpaper and cannot be used for the place that the safety requirements such as packaging for foodstuff are high.
Summary of the invention
High in order to solve water color ink chemicals content, technological process is complicated, the problem that environmental-protecting performance is low, we have proposed a kind of Environmental-protection water-based ink and preparation method thereof, uses the present invention can reduce chemicals content with simplification of flowsheet, improves environmental-protecting performance.
The present invention is achieved by the following technical solutions:
For achieving the above object, the present invention provides a kind of Environmental-protection water-based ink, comprises the following raw materials by weight percent:
Water-borne acrylic resin emulsion 20 ~ 30%, ethanol 5 ~ 10%, Traditional medicine infusion liquid 35 ~ 55%, deionized water 5 ~ 40%.Using Chinese medicine extract to replace the chemicals such as defoamer, dispersant, effect is obvious, without chemicals content, without volatilizable pollutant.
Preferably, above-mentioned Traditional medicine infusion liquid comprises the following raw materials by weight percent: Aqueous starch binder 75 ~ 85%, pigment 3 ~ 10%, Chinese medicine juice 5 ~ 22%.
Preferably, above-mentioned Chinese medicine juice is made up of the raw material of following weight portion: Bulbus Allii 1 ~ 5, the Cortex Eucommiae 1 ~ 5, lavandula angustifolia 1 ~ 3, Cortex Cinnamomi 3 ~ 10, Resina garciniae 1 ~ 5, Cortex Phellodendri 1 ~ 5, the Pseudobulbus Bletillae (Rhizoma Bletillae) 1 ~ 5.These Chinese medicine ingredients can increase the gorgeous and thick and heavy sense of light of pigment, can condense resin glue, it is to avoid colloid hydrolysis causes pen and ink level smudgy, beneficially fixation, moreover it is possible to gives out a kind of natural flavor, beneficially pest control and anticorrosion.
Preferably, in above-mentioned Aqueous starch binder, the mass ratio of corn starch and water is 1:4 ~ 10.Corn starch is mixed with water, makes Aqueous starch binder, the binder in conventional formulation can be replaced, the denseness of ink can also be controlled by adjusting the ratio of starch and water simultaneously.
Preferably, at least one during above-mentioned pigment is phthalein viridescent, phthalocyanine blue, permanent bordeaux, benzidine yellow, white carbon black, titanium dioxide.Use these ancient prescription pigment to replace organic pigment, greatly reduce chemicals content and volatile contaminant.
The present invention also provides for the preparation method of a kind of Environmental-protection water-based ink, and step is as follows:
(1) corn starch is mixed by 1:4 ~ 10 with water, add to 80 ~ 90 DEG C, be incubated and within 20 ~ 60 minutes, make the abundant gelatinizing of starch, obtain a kind of aqueous paste, be Aqueous starch binder;
(2) by Chinese medicinal material Bulbus Allii, the Cortex Eucommiae, lavandula angustifolia, Cortex Cinnamomi, Resina garciniae, Cortex Phellodendri and Pseudobulbus Bletillae (Rhizoma Bletillae) cold water soak 2 ~ 6 hours, then heated and boiled, boil 1 ~ 3 hour, be filtrated to get clear liquid and be Chinese medicine juice;Chinese medicinal material is dry product mostly, uses cold water soak, can improve effective ingredient decocting rate before boiling;
(3) Aqueous starch binder, Chinese medicine juice and pigment are mixed in proportion, dispersed with stirring in homogenizer, are Traditional medicine infusion liquid;
(4) by sand mill, product in step (3) is carried out fine grinding, to fineness less than 10 microns;
(4) water-borne acrylic resin emulsion, ethanol, Traditional medicine infusion liquid and auxiliary agent are mixed in proportion and stir, obtain Environmental-protection water-based ink;
(5) inspection, packaging.
Compared with prior art, the beneficial effects of the present invention is: without Harmful chemicals content, non-volatility pollutes, and bright-colored does not fades, and has natural faint scent pest control and anticorrosion, with low cost.
Detailed description of the invention
Below in conjunction with embodiment, further illustrate present disclosure.Should be appreciated that the enforcement of the present invention is not limited to the following examples, any pro forma accommodation or the change of being made the present invention both fall within scope;And the method in following embodiment, if no special instructions, it is the conventional method of this area.
Embodiment 1:
A kind of Environmental-protection water-based ink, comprises the following raw materials by weight percent:
Water-borne acrylic resin emulsion 25%, ethanol 10%, Traditional medicine infusion liquid 40%, deionized water 25%.
Above-mentioned Traditional medicine infusion liquid comprises the following raw materials by weight percent: Aqueous starch link stuff 80%, pigment 5%, Chinese medicine juice 15%.
Above-mentioned pigment is at least one in phthalein viridescent, phthalocyanine blue, permanent bordeaux, benzidine yellow, white carbon black, titanium dioxide.
Preparation method step is as follows:
(1) corn starch is mixed by 1:7 with water, be heated to 80 DEG C, be incubated 30 minutes, be Aqueous starch binder, stand-by;
(2) by 2 parts of Chinese medicinal material Bulbus Allii, the Cortex Eucommiae 2 parts, lavandula angustifolia 1 part, Cortex Cinnamomi 5 parts, Resina garciniae 2 parts, Cortex Phellodendri 2 parts and 2 parts of cold water soak of the Pseudobulbus Bletillae (Rhizoma Bletillae) 2 hours, heated and boiled, boil 2 hours, be filtrated to get clear liquid and be Chinese medicine juice, stand-by;
(3) in proportion Aqueous starch binder, Chinese medicine juice and pigment are mixed, dispersed with stirring in homogenizer, be Traditional medicine infusion liquid;
(4) by sand mill, product in step (3) is carried out fine grinding, to fineness less than 10 microns;
(5) water-borne acrylic resin emulsion, ethanol, Traditional medicine infusion liquid and deionized water are mixed in proportion and stir, obtain Environmental-protection water-based ink;
(6) inspection, packaging.
Embodiment 2:
A kind of Environmental-protection water-based ink, comprises the following raw materials by weight percent:
Water-borne acrylic resin emulsion 20%, ethanol 10%, Traditional medicine infusion liquid 60%, deionized water 10%.
Preparation process is substantially the same manner as Example 1.
Embodiment 3:
A kind of Environmental-protection water-based ink, comprises the following raw materials by weight percent:
Water-borne acrylic resin emulsion 20%, Traditional medicine infusion liquid 60%, deionized water 20%.
Preparation process is substantially the same manner as Example 1.

Claims (3)

1. an Environmental-protection water-based ink, it is characterised in that comprise the following raw materials by weight percent:
Water-borne acrylic resin emulsion 20 ~ 30%, ethanol 5 ~ 10%, Traditional medicine infusion liquid 35 ~ 55%, deionized water 5 ~ 40%;
Wherein, described Traditional medicine infusion liquid comprises the following raw materials by weight percent:
Aqueous starch binder 75 ~ 85%, pigment 3 ~ 10%, Chinese medicine juice 5 ~ 22%;
Wherein, described Chinese medicine juice is made up of the raw material of following weight portion:
Bulbus Allii 1 ~ 5, the Cortex Eucommiae 1 ~ 5, lavandula angustifolia 1 ~ 3, Cortex Cinnamomi 3 ~ 10, Resina garciniae 1 ~ 5, Cortex Phellodendri 1 ~ 5, the Pseudobulbus Bletillae (Rhizoma Bletillae) 1 ~ 5;
In described Aqueous starch binder, corn starch is 1:4 ~ 10 with the mass ratio of water.
2. a kind of Environmental-protection water-based ink as claimed in claim 1, it is characterised in that described pigment is at least one in phthalein viridescent, phthalocyanine blue, permanent bordeaux, benzidine yellow, white carbon black, titanium dioxide.
3. the preparation method of an Environmental-protection water-based ink as claimed in claim 1 or 2, it is characterised in that step is as follows:
(1) corn starch is mixed with water 1:4 ~ 10 in mass ratio, be heated to 80 ~ 90 DEG C, be incubated 20 ~ 60 minutes, be Aqueous starch binder;
(2) by Chinese medicinal material Bulbus Allii, the Cortex Eucommiae, lavandula angustifolia, Cortex Cinnamomi, Resina garciniae, Cortex Phellodendri and Pseudobulbus Bletillae (Rhizoma Bletillae) cold water soak 2 ~ 6 hours, heated and boiled, boil 1 ~ 3 hour, be filtrated to get clear liquid and be Chinese medicine juice;
(3) Aqueous starch binder, Chinese medicine juice and pigment are mixed in proportion, dispersed with stirring in homogenizer, are Traditional medicine infusion liquid;
(4) by sand mill, product in step (3) is carried out fine grinding, to fineness less than 10 microns;
(5) water-borne acrylic resin emulsion, ethanol, Traditional medicine infusion liquid and deionized water are mixed in proportion and stir, obtain Environmental-protection water-based ink;
(6) inspection, packaging.
CN201410454560.4A 2014-09-09 2014-09-09 A kind of Environmental-protection water-based ink and preparation method thereof Expired - Fee Related CN104327597B (en)

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Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104987773A (en) * 2015-07-17 2015-10-21 合肥忠豪新材料有限公司 Environment-friendly water-based printing ink and preparation method thereof
CN105153804A (en) * 2015-08-24 2015-12-16 蚌埠市神龙笔业有限公司 Natural waterborne paint ink and preparation method thereof
CN105086618A (en) * 2015-10-08 2015-11-25 苏州市永津彩印包装有限公司 High-quality anti-setoff printing ink
CN105803765A (en) * 2016-03-31 2016-07-27 铜陵东晟生态农业科技有限公司 Environment-friendly additive for mold proofing of wool textiles
CN105755806A (en) * 2016-03-31 2016-07-13 铜陵东晟生态农业科技有限公司 Environment-friendly soaking agent for wool textile insect bite control
CN105780456A (en) * 2016-03-31 2016-07-20 铜陵东晟生态农业科技有限公司 Environment-friendly additive for corrosion prevention of wool textile
CN106147444A (en) * 2016-06-30 2016-11-23 卓达新材料科技集团威海股份有限公司 A kind of natural faint scent environment friendly decoration board and preparation technology thereof
CN106189496A (en) * 2016-08-17 2016-12-07 郑文忠 A kind of preparation method of antibacterial composite joint material water color ink
CN106221371A (en) * 2016-08-17 2016-12-14 郑文忠 A kind of antibacterial composite joint material water color ink
CN108299941A (en) * 2018-01-08 2018-07-20 天长市嘉瑞包装材料有限公司 A kind of ink of packing bag for medical use picture and text printing

Citations (2)

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CN102225649A (en) * 2011-03-29 2011-10-26 常德市金芙蓉实业发展总公司 Environmentally-friendly water-based ink color outer package smoke box paperboard made of light weight coated (LWC) paper
CN102391725A (en) * 2011-08-29 2012-03-28 山西新今鼎文化产业发展有限公司 Antique water-solubility black ink based on corn starch for screen printing and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102225649A (en) * 2011-03-29 2011-10-26 常德市金芙蓉实业发展总公司 Environmentally-friendly water-based ink color outer package smoke box paperboard made of light weight coated (LWC) paper
CN102391725A (en) * 2011-08-29 2012-03-28 山西新今鼎文化产业发展有限公司 Antique water-solubility black ink based on corn starch for screen printing and preparation method thereof

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Denomination of invention: The invention relates to an environment-friendly water-based ink and a preparation method thereof

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