CN106867312A - A kind of nano color paste grinding technics - Google Patents
A kind of nano color paste grinding technics Download PDFInfo
- Publication number
- CN106867312A CN106867312A CN201710144522.2A CN201710144522A CN106867312A CN 106867312 A CN106867312 A CN 106867312A CN 201710144522 A CN201710144522 A CN 201710144522A CN 106867312 A CN106867312 A CN 106867312A
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- China
- Prior art keywords
- mill base
- stage
- grinding
- monomer
- formula
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C25/00—Control arrangements specially adapted for crushing or disintegrating
Abstract
The invention belongs to UV ink-jet ink mill base technical fields and a kind of nano color paste grinding technics is disclosed, be made up of scatter stage 1, scatter stage 2, grinding stage, five stages of scatter stage 3 and filtration stage, step (1)：Scatter stage 1；The scatter stage 1 carries out the 70% of acrylate monomer formula, levelling agent, acrylic resin and dispersant to disperse to obtain mill base 1；Step (2)：Scatter stage 2；The addition toner of mill base described above 1 carries out disperseing to obtain mill base 2；Step (3)：The grinding stage；The mixing zirconium pearl of mill base described above 2 adds grinding thick stick to be ground to obtain mill base 3；Step (4)：Scatter stage 3；Mill base described above 3 adds the remaining acrylic monomers 30% of formula to obtain mill base 4；Step (5)；Filtration stage；Mill base described above 4 is filtrated to get more bright-coloured more smooth finished product.The present invention can be obtained nanoscale mill base, so as to prevent the blocking of printhead, improve the fluency and vividness of ink.
Description
Technical field
The present invention relates to a kind of nano color paste grinding technics, more particularly to a kind of horizontal mill UV photocurings mill base nanometer
Rank grinding preparation process, belongs to UV ink-jet ink mill base technical fields.
Background technology
Now go deimpurity solution relatively simple, backward with UV ink-jet inks, it is impossible to effectively impurity and big grain
Footpath particle removal, impurity and large-size particles are to cause not smooth ink printed, oblique spray, the main cause of plug.
The content of the invention
The technical problem to be solved in the present invention overcomes existing defect, there is provided a kind of nano color paste grinding technics, can be obtained
Nanoscale mill base, so as to prevent the blocking of printhead, improves the fluency and vividness of ink, can effectively solve background technology
In problem.
In order to solve the above-mentioned technical problem, the invention provides following technical scheme：
The present invention provides a kind of nano color paste grinding technics, by scatter stage 1, scatter stage 2, grinding stage, dispersion rank
Five stages of section 3 and filtration stage are constituted, step (1)：Scatter stage 1；Be formulated for acrylate monomer by the scatter stage 1
70%, levelling agent, acrylic resin and dispersant carry out disperseing to obtain mill base 1；Step (2)：Scatter stage 2；In step
The addition toner of the mill base 1 carries out disperseing to obtain mill base 2；Step (3)：The grinding stage；The mixing zirconium of the mill base 2 in step 2
Pearl adds grinding thick stick to be ground to obtain mill base 3；Step (4)：Scatter stage 3；The mill base 3 in step 3 adds formula surplus
Under acrylic monomers 30% mill base 4；Step (5)；Filtration stage；The mill base 4 in step 4 is filtrated to get more
Plus bright-coloured more smooth finished product.
Preferably：Scatter stage described in step (1) (1) by acrylate monomer be formulated 70%, levelling agent, propylene
Acid resin and dispersant are disperseed in dispersion machine, and dispersion obtains mill base 1 in 15-20 minutes；The acrylate monomer is included：
3.3.5- trimethyl cyclohexyl without alkene ester (TAACH), return hydrogenation Kang Quan without olefin(e) acid ester (THFA), 2- benzene oxygen an aromatic plant metioned in ancient books ethyl propylene acid esters
Selected in monomer (PHEA), 1.6- hexanediyl esters monomer (HDDA), propylene glycol diacrylate monomer (DPGDA)
One of which monomer or various of monomer, and above-mentioned all monomer diluting powers are preferably, viscosity is less than 15CPS；The monomer being applicable is needed
The gross weight of 30%-60% is accounted in formula；Levelling agent is included：Polyether-modified dimethyl silicone polymer (BYK-307 and BYK-
333rd, BYK-306, BYK337, BKK-341) it is middle from one or more of which monomer；Selected levelling agent is accounted in formula
The weight of 1%-5%；Acrylic resin is included：Modified poly ester is middle from wherein without olefin(e) acid ester (10-526), (7287), (3364)
One or more；And selected resin has：Wetability, preferably can be combined with toner；Selected resin is accounted in formula
The weight of 5%-10%；Selected dispersant is included：Angstrom hold card A310, (BYK-9151, BYK- of Bick chemical company of the U.S. under the arm
9150th, BYK-9152, BYK-168) one or more of which；Selected dispersant has super wetting, ultra-dispersed, superstability；
Selected dispersant accounts for the weight of the 15%-20% of formula；Selected toner solidity is good, tinting strength, tinting power is good；Selected color
Powder：It is blue：15:1 phthalocyanine blue, 15:2 phthalocyanine blues, 15:3 phthalocyanine blues, 15:4 phthalocyanine blues；Pigment yellow：185、168、183、194；It is red
Color：R122、R121、R120；Black：12400R、M-L、M-E；White：Rutile phthalein white powder；
Preferably：The mill base 1 in step (2) is blended in dispersion machine with the toner disperse 30 minutes
Mill base 2.
Preferably：The mill base 2 and the zirconium pearl in step (3) are added to grinding thick stick and are ground 10-12 hours
Mill base 3.
Preferably：The zirconium pearl in step (3) according to grinding thick stick 1：5 ratio adds a diameter of 0.3-0.5mm zirconiums
Pearl is to grinder.
Preferably：In step (3), mill base 2 is ground in adding grinding thick stick with gas pump cycle formula.
Preferably：The rotating speed of the grinder in step (3) is adjusted to 2800-3500 revs/min, the grinding thick stick temperature
Degree control is below 46 degree.
Preferably：The mill base 3 in step (4) adds the remaining acrylic monomers 30% of formula to enter after being diluted
The mill base 4 of row dispersion 20 minutes.
Preferably：In step (5), the mill base 4 filters to obtain finished product in the filter, and the filter is that filter core is straight
Footpath is the filter of the glass fibre material of 3.0um.
The beneficial effect that is reached of the present invention is：
1. nanoscale mill base can be obtained, so as to prevent the blocking of printhead, the fluency and vividness of ink is improved.
Brief description of the drawings
Accompanying drawing is used for providing a further understanding of the present invention, and constitutes a part for specification, with reality of the invention
Applying example is used to explain the present invention together, is not construed as limiting the invention.
In the accompanying drawings：
Fig. 1 is a kind of nano color paste grinding process flow figure described in the embodiment of the present invention；
Specific embodiment
The preferred embodiments of the present invention are illustrated below in conjunction with accompanying drawing, it will be appreciated that preferred reality described herein
Apply example to be merely to illustrate and explain the present invention, be not intended to limit the present invention.
Embodiment：
Refer to Fig. 1, a kind of nano color paste grinding technics of the invention, by scatter stage 1, scatter stage 2, the grinding stage,
Five stages of scatter stage 3 and filtration stage are constituted：
Step (1)：Scatter stage 1；The scatter stage 1 by acrylate monomer be formulated 70%, levelling agent, propylene
Acid resin and dispersant are disperseed in dispersion machine, and dispersion carries out disperseing to obtain mill base 1 for 15-20 minutes；
Step (2)：Scatter stage (2)；The addition toner of the mill base 1 in step one carries out dispersion 30 in dispersion machine
Minute obtains mill base 2；
Step (3)：The grinding stage；The mill base 2 and the zirconium pearl in step 2 are added to grinding thick stick and are ground
10-12 hours mill base 3, and the mill base 2 with gas pump cycle formula add grinding thick stick in, and the zirconium pearl according to grinding thick stick 1：
5 ratio adds a diameter of 0.3-0.5mm zirconiums pearl to grinder；The rotating speed of the grinder is adjusted to 2800-3500 revs/min,
The grinding thick stick temperature control is below 46 degree；
Step (4)：Scatter stage (3)；The mill base 3 in step 3 adds the remaining propylene of formula after being diluted
Acid monomers 30% carry out dispersion and obtain mill base 4 in 20 minutes；
Step (5)；Filtration stage；The mill base 4 in step 4 is filtered obtain more bright-coloured more smooth in the filter
Finished product, and the filter for a diameter of 3.0um of filter core glass fibre material filter.
The acrylate monomer is included：3.3.5- trimethyl cyclohexyl without alkene ester (TAACH), return hydrogenation Kang Quan without olefin(e) acid
Ester (THFA), 2- benzene oxygen an aromatic plant metioned in ancient books ethyl propylene acid ester monomer (PHEA), 1.6- hexanediyl esters monomer (HDDA), dipropyl two
One of which monomer or various of monomer are selected in alcohol diacrylate monomer (DPGDA), and above-mentioned all monomer diluting powers are preferably,
Viscosity is less than 15CPS；The monomer being applicable need to account for the gross weight of 30%-60% in formula；
Levelling agent is included：Polyether-modified dimethyl silicone polymer (BYK-307 and BYK-333, BYK-306, BYK337,
BKK-341 one or more of which monomer is selected in)；Selected levelling agent accounts for the weight of 1%-5% in formula；
Acrylic resin is included：Modified poly ester without olefin(e) acid ester (10-526), (7287), in (3364) from one of which or
It is various；And selected resin has：Wetability, preferably can be combined with toner；Selected resin accounts for 5%- in formula
10% weight；
Selected dispersant is included：Angstrom hold under the arm card A310, Bick chemical company of the U.S. (BYK-9151, BYK-9150,
BYK-9152, BYK-168) one or more of which；Selected dispersant has super wetting, ultra-dispersed, superstability；It is selected
Dispersant account for formula 15%-20% weight；
Selected toner solidity is good, tinting strength, tinting power is good；Selected toner：
It is blue：15:1 phthalocyanine blue, 15:2 phthalocyanine blues, 15:3 phthalocyanine blues, 15:4 phthalocyanine blues；
Pigment yellow：185、168、183、194；
It is red：R122、R121、R120；
Black：12400R、M-L、M-E；
White：Rutile phthalein white powder；
It is below five kinds of formula tables of color shades of colour grinding, is raw material title English abbreviation+weight；Such as following table institute
State：
The blue unit of table 1：Gram
| Title | Embodiment 1 | Embodiment 2 |
| TMCAA | 55 | 48 |
| BYK-307 | 1.5 | 3 |
| 10-526 | 10 | 15 |
| 9150 | 15 | 14 |
| 15：4 titanium cyanines are blue | 18.5 | 20 |
The black unit of table 2：Gram
| Title | Embodiment 1 | Embodiment 2 |
| THFA | 41 | 40 |
| ADDA | 15 | 10 |
| BYK-306 | 1.5 | 3 |
| EFKA-4310 | 12 | 13 |
| 10-526:3 | 18.5 | 20 |
| M-E | 12 | 14 |
The white powder unit of table 3：Gram
| Title | Embodiment 1 |
| THFA | 33 |
| BYK333 | 2 |
| BYK168 | 12 |
| 7287 | 3 |
| Rutile type titanium white | 50 |
The rouge and powder unit of table 4：Gram
| Title | Embodiment 1 |
| THFA | 34.5 |
| PHEA | 23 |
| BYK-337 | 1.5 |
| BYK-9152 | 16 |
| 3364 | 5 |
| R122 | 20 |
The bloom unit of table 5：Gram
| Title | Embodiment 1 |
| HDDA | 35 |
| DPGDA | 26 |
| BYK-333 | 2 |
| 7287 | 7 |
| BYK-9152 | 5 |
| Pigment yellow 185 | 25 |
Finally it should be noted that：The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention,
Although being described in detail to the present invention with reference to the foregoing embodiments, for a person skilled in the art, it still may be used
Modified with to the technical scheme described in foregoing embodiments, or equivalent is carried out to which part technical characteristic.
All any modification, equivalent substitution and improvements within the spirit and principles in the present invention, made etc., should be included in of the invention
Within protection domain.
Claims (9)
1. a kind of nano color paste grinding technics, by scatter stage 1, scatter stage 2, grinds stage, scatter stage 3 and filtration stage
Five stages are constituted, it is characterised in that：
Step (1)：Scatter stage 1；The scatter stage 1 by acrylate monomer be formulated 70%, levelling agent, acrylic acid tree
Fat and dispersant carry out disperseing to obtain mill base 1；
Step (2)：Scatter stage (2)；The addition toner of the mill base 1 in step one carries out disperseing to obtain mill base 2；
Step (3)：The grinding stage；The mixing zirconium pearl of the mill base 2 in step 2 adds grinding thick stick to be ground to obtain mill base 3；
Step (4)：Scatter stage (3)；The mill base 3 in step 3 adds the remaining acrylic monomers 30% of formula to obtain color
Slurry 4；
Step (5)；Filtration stage；The mill base 4 in step 4 is filtrated to get more bright-coloured more smooth finished product.
2. a kind of nano color paste grinding technics according to claim 1, it is characterised in that：Disperse rank described in step (1)
Section 1 is disperseed the 70% of acrylate monomer formula, levelling agent, acrylic resin and dispersant in dispersion machine, is disperseed
Obtain mill base 1 within 15-20 minutes；
The acrylate monomer is included：3.3.5- trimethyl cyclohexyl without alkene ester (TAACH), return hydrogenation Kang Quan without olefin(e) acid ester
(THFA), 2- benzene oxygen an aromatic plant metioned in ancient books ethyl propylene acid ester monomer (PHEA), 1.6- hexanediyl esters monomer (HDDA), DPG
One of which monomer or various of monomer are selected in diacrylate monomer (DPGDA), and above-mentioned all monomer diluting powers are preferably, glue
Degree is less than 15CPS；The monomer being applicable need to account for the gross weight of 30%-60% in formula；
Levelling agent is included：Polyether-modified dimethyl silicone polymer (BYK-307 and BYK-333, BYK-306, BYK337, BKK-
341) one or more of which monomer is selected in；Selected levelling agent accounts for the weight of 1%-5% in formula；
Acrylic resin is included：Modified poly ester is middle from one of which or many without olefin(e) acid ester (10-526), (7287), (3364)
Kind；And selected resin has：Wetability, preferably can be combined with toner；Selected resin accounts for 5%-10% in formula
Weight；
Selected dispersant is included：Angstrom hold card A310, (BYK-9151, BYK-9150, BYK- of Bick chemical company of the U.S. under the arm
9152nd, BYK-168) one or more of which；Selected dispersant has super wetting, ultra-dispersed, superstability；Selected divides
Powder accounts for the weight of the 15%-20% of formula；
Selected toner solidity is good, tinting strength, tinting power is good；
Selected toner：
It is blue：15:1 phthalocyanine blue, 15:2 phthalocyanine blues, 15:3 phthalocyanine blues, 15:4 phthalocyanine blues；
Pigment yellow：185、168、183、194；
It is red：R122、R121、R120；
Black：12400R、M-L、M-E；
White：Rutile phthalein white powder.
3. a kind of nano color paste grinding technics according to claim 1, it is characterised in that：The mill base in step (2)
1 be blended in dispersion machine with the toner carry out dispersion 30 minutes mill base 2.
4. a kind of nano color paste grinding technics according to claim 1, it is characterised in that：The color in step (3)
Slurry 2 and the zirconium pearl add to grinding thick stick and are ground 10-12 hours to obtain mill base 3.
5. a kind of nano color paste grinding technics according to claim 1, it is characterised in that：The zirconium pearl in step (3)
According to grinding thick stick 1：5 ratio adds a diameter of 0.3-0.5mm zirconiums pearl to grinder.
6. a kind of nano color paste grinding technics according to claim 1, it is characterised in that：In step (3), mill base 2 with
Gas pump cycle formula is ground in adding grinding thick stick.
7. a kind of nano color paste grinding technics according to claim 1, it is characterised in that：The grinding in step (3)
The rotating speed of machine is adjusted to 2800-3500 revs/min, and the grinding thick stick temperature control is below 46 degree.
8. a kind of nano color paste grinding technics according to claim 1, it is characterised in that：The mill base in step (4)
3 be diluted after add the remaining acrylic monomers 30% of formula to carry out the mill base 4 of dispersion 20 minutes.
9. a kind of nano color paste grinding technics according to claim 1, it is characterised in that：In step (5), the color
It is the filter of the glass fibre material of a diameter of 3.0um of filter core that slurry 4 filters to obtain finished product, and the filter in the filter.
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| CN201710144522.2A CN106867312A (en) | 2017-03-13 | 2017-03-13 | A kind of nano color paste grinding technics |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710144522.2A CN106867312A (en) | 2017-03-13 | 2017-03-13 | A kind of nano color paste grinding technics |
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| Publication Number | Publication Date |
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| CN106867312A true CN106867312A (en) | 2017-06-20 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107384029A (en) * | 2017-07-11 | 2017-11-24 | 河北晨阳工贸集团有限公司 | A kind of water nano mill base and preparation method thereof |
| CN109535839A (en) * | 2019-01-18 | 2019-03-29 | 珠海奥维数码科技有限公司 | The UV high speed coding ink and production coding technique of Nano grade |
| CN115608187A (en) * | 2022-11-09 | 2023-01-17 | 珠海奥维数码科技有限公司 | Manufacturing method of UV pigment ink |
| CN115608187B (en) * | 2022-11-09 | 2024-05-14 | 珠海奥维数码科技有限公司 | Manufacturing method of UV pigment ink |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103224734A (en) * | 2012-10-24 | 2013-07-31 | 北京印刷学院 | Cyan UV ink-jet ink for high-speed ink-jet printing and preparation method thereof |
| CN104151938A (en) * | 2014-07-17 | 2014-11-19 | 广东致卓精密金属科技有限公司 | Preparation method of ultraviolet-curing activator based on ink-jet printing technology and process for carrying out activation treatment by using activator |
-
2017
- 2017-03-13 CN CN201710144522.2A patent/CN106867312A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103224734A (en) * | 2012-10-24 | 2013-07-31 | 北京印刷学院 | Cyan UV ink-jet ink for high-speed ink-jet printing and preparation method thereof |
| CN104151938A (en) * | 2014-07-17 | 2014-11-19 | 广东致卓精密金属科技有限公司 | Preparation method of ultraviolet-curing activator based on ink-jet printing technology and process for carrying out activation treatment by using activator |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107384029A (en) * | 2017-07-11 | 2017-11-24 | 河北晨阳工贸集团有限公司 | A kind of water nano mill base and preparation method thereof |
| CN109535839A (en) * | 2019-01-18 | 2019-03-29 | 珠海奥维数码科技有限公司 | The UV high speed coding ink and production coding technique of Nano grade |
| CN115608187A (en) * | 2022-11-09 | 2023-01-17 | 珠海奥维数码科技有限公司 | Manufacturing method of UV pigment ink |
| CN115608187B (en) * | 2022-11-09 | 2024-05-14 | 珠海奥维数码科技有限公司 | Manufacturing method of UV pigment ink |
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Application publication date: 20170620 |