CN104322566B - A kind of for insecticides killing colorado potato bug and preparation method thereof - Google Patents
A kind of for insecticides killing colorado potato bug and preparation method thereof Download PDFInfo
- Publication number
- CN104322566B CN104322566B CN201410658977.2A CN201410658977A CN104322566B CN 104322566 B CN104322566 B CN 104322566B CN 201410658977 A CN201410658977 A CN 201410658977A CN 104322566 B CN104322566 B CN 104322566B
- Authority
- CN
- China
- Prior art keywords
- parts
- insecticides
- colorado potato
- potato bug
- killing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002917 insecticide Substances 0.000 title claims abstract description 41
- 244000061456 Solanum tuberosum Species 0.000 title claims abstract description 31
- 235000002595 Solanum tuberosum Nutrition 0.000 title claims abstract description 31
- 230000002147 killing effect Effects 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims abstract description 57
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims abstract description 40
- 241000238631 Hexapoda Species 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- HVQHXBNMBZJPLK-UHFFFAOYSA-N 1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-5-[(2-methylprop-2-en-1-yl)amino]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound CC(=C)CNC1=C([S+]([O-])C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl HVQHXBNMBZJPLK-UHFFFAOYSA-N 0.000 claims abstract description 20
- 150000001408 amides Chemical class 0.000 claims abstract description 20
- 229930192474 thiophene Natural products 0.000 claims abstract description 20
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 claims abstract description 19
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 claims abstract description 19
- NWWZPOKUUAIXIW-DHZHZOJOSA-N (E)-thiamethoxam Chemical compound [O-][N+](=O)/N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-DHZHZOJOSA-N 0.000 claims abstract description 19
- TVFWYUWNQVRQRG-UHFFFAOYSA-N 2,3,4-tris(2-phenylethenyl)phenol Chemical compound C=1C=CC=CC=1C=CC1=C(C=CC=2C=CC=CC=2)C(O)=CC=C1C=CC1=CC=CC=C1 TVFWYUWNQVRQRG-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000005875 Acetamiprid Substances 0.000 claims abstract description 19
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 19
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000005917 Methoxyfenozide Substances 0.000 claims abstract description 19
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 claims abstract description 19
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims abstract description 19
- QCAWEPFNJXQPAN-UHFFFAOYSA-N methoxyfenozide Chemical compound COC1=CC=CC(C(=O)NN(C(=O)C=2C=C(C)C=C(C)C=2)C(C)(C)C)=C1C QCAWEPFNJXQPAN-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229960002715 nicotine Drugs 0.000 claims abstract description 19
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 claims abstract description 19
- 230000003647 oxidation Effects 0.000 claims abstract description 19
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 19
- 229960005235 piperonyl butoxide Drugs 0.000 claims abstract description 19
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 19
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 19
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 claims abstract description 19
- 101150020633 tbp-1 gene Proteins 0.000 claims abstract description 19
- FJFLPKJHOKJAAS-UHFFFAOYSA-N quinoline;1,3-thiazol-2-amine Chemical compound NC1=NC=CS1.N1=CC=CC2=CC=CC=C21 FJFLPKJHOKJAAS-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000008346 aqueous phase Substances 0.000 claims description 18
- 239000012071 phase Substances 0.000 claims description 18
- 239000000839 emulsion Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 11
- PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 claims description 10
- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 claims description 10
- 229940095100 fulvic acid Drugs 0.000 claims description 10
- 239000002509 fulvic acid Substances 0.000 claims description 10
- -1 Oleum Terebinthinae Chemical compound 0.000 claims description 9
- 239000012467 final product Substances 0.000 claims description 9
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims description 4
- RAIPHJJURHTUIC-UHFFFAOYSA-N 1,3-thiazol-2-amine Chemical compound NC1=NC=CS1 RAIPHJJURHTUIC-UHFFFAOYSA-N 0.000 claims description 2
- 229950003476 aminothiazole Drugs 0.000 claims description 2
- 230000006378 damage Effects 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 241000254173 Coleoptera Species 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- NHOIBRJOQAYBJT-IMGVWCFESA-N nimbin Chemical compound C=1([C@@H]2C[C@H]3O[C@H]4[C@](C3=C2C)(C)[C@@H]([C@]2(C(=O)C=C[C@](C)([C@@H]2[C@H]4OC(C)=O)C(=O)OC)C)CC(=O)OC)C=COC=1 NHOIBRJOQAYBJT-IMGVWCFESA-N 0.000 description 2
- ZQIYJHBQRBBBRZ-UHFFFAOYSA-N nimbin Natural products COC(=O)CC1C2C(C(OC(=O)C)C3OC4CC(C(=C4C13C)C)c5cocc5)C(C)(C=CC2=O)C(=O)OC ZQIYJHBQRBBBRZ-UHFFFAOYSA-N 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- XVVZSEXTAACTPS-UHFFFAOYSA-N 5-[hydroxy-(4-nitrophenoxy)phosphoryl]pentanoic acid Chemical compound OC(=O)CCCCP(O)(=O)OC1=CC=C([N+]([O-])=O)C=C1 XVVZSEXTAACTPS-UHFFFAOYSA-N 0.000 description 1
- 239000005944 Chlorpyrifos Substances 0.000 description 1
- 241001124134 Chrysomelidae Species 0.000 description 1
- 241001498622 Cixius wagneri Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 241000208292 Solanaceae Species 0.000 description 1
- 235000002634 Solanum Nutrition 0.000 description 1
- 241000207763 Solanum Species 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004166 bioassay Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000009637 wintergreen oil Substances 0.000 description 1
Abstract
The present invention relates to a kind of for insecticides killing colorado potato bug and preparation method thereof, belong to technical field of insecticide.Include following component by weight: cyfloxylate 8～12 parts, cholrempenthrin 0.5～1 part, nicotine 0.2～4 parts, Oleum Terebinthinae 0.3～0.6 part, methoxyfenozide 0.3～0.7 part, thiophene insect amide 0.5～1 part, butene-fipronil 0.2～3 parts, Acetamiprid 0.7～1 part, decis 0.2～0.4 part, Diacloden 0.2～0.4 part, aminothiazole quinoline 0.2～0.4 part, oxidation of piperonyl butoxide 0.3～0.5 part, butyl acetate 40～45 parts, dimethylformamide 4～8 parts, tbp 1～3 parts, tristyrylphenol polyoxyethylene ether 0.5～0.7 part, NPE 0.7～0.9 part, dodecylbenzene sodium sulfonate 0.8～1.2 parts, water 100～150 parts.
Description
Technical field
The present invention relates to a kind of for insecticides killing colorado potato bug and preparation method thereof, belong to technical field of insecticide.
Background technology
Colorado potato bug belongs to coleoptera, Chrysomelidae.It it is the crushing quarantine pest insect of world-famous.Originate in the U.S., rear incoming France, Holland, Switzerland, Germany, Spain, Portugal, Italy, Eastern Europe, some countries of America, abroad examine object in being.Host is mainly plant of Solanaceae, and major part is Solanum, and the Rhizoma Solani tuber osi wherein cultivated is the suitableeest host, additionally can cause harm Fructus Lycopersici esculenti, Fructus Solani melongenae, Fructus Capsici, Nicotiana tabacum L. etc..
Colorado potato bug is one and is distributed the widest, Rhizoma Solani tuber osi insect the most very of causing harm.Adult and larva are voracious, usually by the leaf eat everything up of Rhizoma Solani tuber osi.In many countries, cause Rhizoma Solani tuber osi underproduction 30-50%, the even underproduction 90% of the most serious place.(1) is mainly passed through in the route of transmission of this worm is natural propagation, carries propagation including wind, current and air-flow, naturally creeps and migrate.(2) manually propagate, carry propagation including with goods, packaging material and means of transport.From potato block, water fruits and vegetables, log and packaging material and the vehicle in epidemic-stricken area, the most likely carry this worm.
Patent CN102792968A discloses a kind of insecticide preventing and treating colorado potato bug, the component of this insecticide and weight content: cyfloxylate 24～90% and chlopyrifos 10～76%.This invention further simultaneously discloses the cream type insecticide using the insecticide of above-mentioned preventing and treating colorado potato bug to make, and contains the insecticide of the preventing and treating colorado potato bug of 2～60g in every L cream type insecticide.This invention further simultaneously discloses the Water emulsion insecticide using the insecticide of above-mentioned preventing and treating colorado potato bug to make, and contains the insecticide of the preventing and treating colorado potato bug of 2～60g in every L Water emulsion insecticide.CN102084868A discloses a kind of nimbin for preventing and treating colorado potato bug and cyfloxylate compositions, and it is grouped into by the one-tenth of following weight content: the cyfloxylate of 60%～90% and 10%～the nimbin of 40%.But, above-mentioned potato beetle insecticidal agent also exists the problem that deinsectization rate is the highest.
Summary of the invention
It is an object of the invention to: a kind of insecticides colorado potato bug to higher killing effect is provided.
Technical scheme:
nullA kind of insecticides for killing colorado potato bug，Include following component by weight: cyfloxylate 8～12 parts、Cholrempenthrin 0.5～1 part、Nicotine 0.2～4 parts、Oleum Terebinthinae 0.3～0.6 part、Methoxyfenozide 0.3～0.7 part、Thiophene insect amide 0.5～1 part、Butene-fipronil 0.2～3 parts、Acetamiprid 0.7～1 part、Decis 0.2～0.4 part、Diacloden 0.2～0.4 part、Aminothiazole quinoline 0.2～0.4 part、Oxidation of piperonyl butoxide 0.3～0.5 part、Butyl acetate 40～45 parts、Dimethylformamide 4～8 parts、Tbp 1～3 parts、Tristyrylphenol polyoxyethylene ether 0.5～0.7 part、NPE 0.7～0.9 part、Dodecylbenzene sodium sulfonate 0.8～1.2 parts、Water 100～150 parts.
In described compositions, also include fulvic acid 0.5～0.8 part.
The preparation method of described insecticides, comprises the steps:
1st step, by cyfloxylate, cholrempenthrin, nicotine, Oleum Terebinthinae, methoxyfenozide, thiophene insect amide, butene-fipronil, Acetamiprid, decis, Diacloden, aminothiazole quinoline, oxidation of piperonyl butoxide, butyl acetate, dimethylformamide, tbp, tristyrylphenol polyoxyethylene ether, NPE mix homogeneously, obtain oil phase；
2nd step, then after being mixed homogeneously with water by dodecylbenzene sodium sulfonate, obtain aqueous phase；
3rd step, mixes oil phase with aqueous phase the most again, is uniformly dispersed, and makes emulsion, to obtain final product.
In described preparation method, the 1st step also needs to add fulvic acid 0.5～0.8 part.
Beneficial effect
The insecticides that the present invention provides has a good property killed for planthopper, and wintergreen oil and Lignum cinnamomi camphorae oil can play the effect of more preferable Synergistic, it is possible to increase the long-time stability of insecticide and kill performance.
Detailed description of the invention
Embodiment 1
A kind of insecticides for killing colorado potato bug, form as follows: cyfloxylate 8Kg, cholrempenthrin 0.5Kg, nicotine 0.2Kg, Oleum Terebinthinae 0.3Kg, methoxyfenozide 0.3Kg, thiophene insect amide 0.5Kg, butene-fipronil 0.2Kg, Acetamiprid 0.7Kg, decis 0.2Kg, Diacloden 0.2Kg, aminothiazole quinoline 0.2Kg, oxidation of piperonyl butoxide 0.3Kg, butyl acetate 40Kg, dimethylformamide 4Kg, tbp 1Kg, tristyrylphenol polyoxyethylene ether 0.5Kg, NPE 0.7Kg, dodecylbenzene sodium sulfonate 0.8Kg, water 100Kg.
The preparation method of described insecticides, comprises the steps:
1st step, by cyfloxylate, cholrempenthrin, nicotine, Oleum Terebinthinae, methoxyfenozide, thiophene insect amide, butene-fipronil, Acetamiprid, decis, Diacloden, aminothiazole quinoline, oxidation of piperonyl butoxide, butyl acetate, dimethylformamide, tbp, tristyrylphenol polyoxyethylene ether, NPE mix homogeneously, obtain oil phase；
2nd step, then after being mixed homogeneously with water by dodecylbenzene sodium sulfonate, obtain aqueous phase；
3rd step, mixes oil phase with aqueous phase the most again, is uniformly dispersed, and makes emulsion, to obtain final product.
Embodiment 2
A kind of insecticides for killing colorado potato bug, form as follows: cyfloxylate 12Kg, cholrempenthrin 1Kg, nicotine 4Kg, Oleum Terebinthinae 0.6Kg, methoxyfenozide 0.7Kg, thiophene insect amide 1Kg, butene-fipronil 3Kg, Acetamiprid 1Kg, decis 0.4Kg, Diacloden 0.4Kg, aminothiazole quinoline 0.4Kg, oxidation of piperonyl butoxide 0.5Kg, butyl acetate 45Kg, dimethylformamide 8Kg, tbp 3Kg, tristyrylphenol polyoxyethylene ether 0.7Kg, NPE 0.9Kg, dodecylbenzene sodium sulfonate 1.2Kg, water 150Kg.
The preparation method of described insecticides, comprises the steps:
1st step, by cyfloxylate, cholrempenthrin, nicotine, Oleum Terebinthinae, methoxyfenozide, thiophene insect amide, butene-fipronil, Acetamiprid, decis, Diacloden, aminothiazole quinoline, oxidation of piperonyl butoxide, butyl acetate, dimethylformamide, tbp, tristyrylphenol polyoxyethylene ether, NPE mix homogeneously, obtain oil phase；
2nd step, then after being mixed homogeneously with water by dodecylbenzene sodium sulfonate, obtain aqueous phase；
3rd step, mixes oil phase with aqueous phase the most again, is uniformly dispersed, and makes emulsion, to obtain final product.
Embodiment 3
A kind of insecticides for killing colorado potato bug, form as follows: cyfloxylate 10Kg, cholrempenthrin 0.7Kg, nicotine 0.1Kg, Oleum Terebinthinae 0.5Kg, methoxyfenozide 0.5Kg, thiophene insect amide 0.8Kg, butene-fipronil 0.1Kg, Acetamiprid 0.8Kg, decis 0.3Kg, Diacloden 0.3Kg, aminothiazole quinoline 0.3Kg, oxidation of piperonyl butoxide 0.4Kg, butyl acetate 42Kg, dimethylformamide 5Kg, tbp 2Kg, tristyrylphenol polyoxyethylene ether 0.6Kg, NPE 0.8Kg, dodecylbenzene sodium sulfonate 1Kg, water 120Kg.
The preparation method of described insecticides, comprises the steps:
1st step, by cyfloxylate, cholrempenthrin, nicotine, Oleum Terebinthinae, methoxyfenozide, thiophene insect amide, butene-fipronil, Acetamiprid, decis, Diacloden, aminothiazole quinoline, oxidation of piperonyl butoxide, butyl acetate, dimethylformamide, tbp, tristyrylphenol polyoxyethylene ether, NPE mix homogeneously, obtain oil phase；
2nd step, then after being mixed homogeneously with water by dodecylbenzene sodium sulfonate, obtain aqueous phase；
3rd step, mixes oil phase with aqueous phase the most again, is uniformly dispersed, and makes emulsion, to obtain final product.
Embodiment 4
Difference with embodiment 3 is: be additionally added fulvic acid.
A kind of insecticides for killing colorado potato bug, form as follows: cyfloxylate 10Kg, cholrempenthrin 0.7Kg, nicotine 0.1Kg, Oleum Terebinthinae 0.5Kg, methoxyfenozide 0.5Kg, thiophene insect amide 0.8Kg, butene-fipronil 0.1Kg, Acetamiprid 0.8Kg, decis 0.3Kg, Diacloden 0.3Kg, aminothiazole quinoline 0.3Kg, oxidation of piperonyl butoxide 0.4Kg, butyl acetate 42Kg, dimethylformamide 5Kg, tbp 2Kg, tristyrylphenol polyoxyethylene ether 0.6Kg, NPE 0.8Kg, fulvic acid 0.6Kg, dodecylbenzene sodium sulfonate 1Kg, water 120Kg.
The preparation method of described insecticides, comprises the steps:
1st step, by cyfloxylate, cholrempenthrin, nicotine, Oleum Terebinthinae, methoxyfenozide, thiophene insect amide, butene-fipronil, Acetamiprid, decis, Diacloden, aminothiazole quinoline, oxidation of piperonyl butoxide, butyl acetate, dimethylformamide, tbp, tristyrylphenol polyoxyethylene ether, NPE, fulvic acid mix homogeneously, obtain oil phase；
2nd step, then after being mixed homogeneously with water by dodecylbenzene sodium sulfonate, obtain aqueous phase；
3rd step, mixes oil phase with aqueous phase the most again, is uniformly dispersed, and makes emulsion, to obtain final product.
Reference examples 1
Difference with embodiment 3 is: do not add thiophene insect amide.
A kind of insecticides for killing colorado potato bug, form as follows: cyfloxylate 10Kg, cholrempenthrin 0.7Kg, nicotine 0.1Kg, Oleum Terebinthinae 0.5Kg, methoxyfenozide 0.5Kg, butene-fipronil 0.1Kg, Acetamiprid 0.8Kg, decis 0.3Kg, Diacloden 0.3Kg, aminothiazole quinoline 0.3Kg, oxidation of piperonyl butoxide 0.4Kg, butyl acetate 42Kg, dimethylformamide 5Kg, tbp 2Kg, tristyrylphenol polyoxyethylene ether 0.6Kg, NPE 0.8Kg, fulvic acid 0.6Kg, dodecylbenzene sodium sulfonate 1Kg, water 120Kg.
The preparation method of described insecticides, comprises the steps:
1st step, by cyfloxylate, cholrempenthrin, nicotine, Oleum Terebinthinae, methoxyfenozide, butene-fipronil, Acetamiprid, decis, Diacloden, aminothiazole quinoline, oxidation of piperonyl butoxide, butyl acetate, dimethylformamide, tbp, tristyrylphenol polyoxyethylene ether, NPE mix homogeneously, obtain oil phase；
2nd step, then after being mixed homogeneously with water by dodecylbenzene sodium sulfonate, obtain aqueous phase；
3rd step, mixes oil phase with aqueous phase the most again, is uniformly dispersed, and makes emulsion, to obtain final product.
Reference examples 2
Difference with embodiment 3 is: do not add butene-fipronil.
A kind of insecticides for killing colorado potato bug, form as follows: cyfloxylate 10Kg, cholrempenthrin 0.7Kg, nicotine 0.1Kg, Oleum Terebinthinae 0.5Kg, methoxyfenozide 0.5Kg, thiophene insect amide 0.8Kg, Acetamiprid 0.8Kg, decis 0.3Kg, Diacloden 0.3Kg, aminothiazole quinoline 0.3Kg, oxidation of piperonyl butoxide 0.4Kg, butyl acetate 42Kg, dimethylformamide 5Kg, tbp 2Kg, tristyrylphenol polyoxyethylene ether 0.6Kg, NPE 0.8Kg, fulvic acid 0.6Kg, dodecylbenzene sodium sulfonate 1Kg, water 120Kg.
The preparation method of described insecticides, comprises the steps:
1st step, by cyfloxylate, cholrempenthrin, nicotine, Oleum Terebinthinae, methoxyfenozide, thiophene insect amide, Acetamiprid, decis, Diacloden, aminothiazole quinoline, oxidation of piperonyl butoxide, butyl acetate, dimethylformamide, tbp, tristyrylphenol polyoxyethylene ether, NPE mix homogeneously, obtain oil phase；
2nd step, then after being mixed homogeneously with water by dodecylbenzene sodium sulfonate, obtain aqueous phase；
3rd step, mixes oil phase with aqueous phase the most again, is uniformly dispersed, and makes emulsion, to obtain final product.
Reference examples 3
Difference with embodiment 3 is: do not add thiophene insect amide and butene-fipronil.
A kind of insecticides for killing colorado potato bug, forms as follows: cyfloxylate 10Kg, cholrempenthrin 0.7Kg, nicotine 0.1Kg, Oleum Terebinthinae 0.5Kg, methoxyfenozide 0.5Kg, Acetamiprid 0.8Kg, decis 0.3Kg, Diacloden 0.3Kg, aminothiazole quinoline 0.3Kg, oxidation of piperonyl butoxide 0.4Kg, butyl acetate 42Kg, dimethylformamide 5Kg, tbp 2Kg, tristyrylphenol polyoxyethylene ether 0.6Kg, NPE 0.8Kg, dodecylbenzene sodium sulfonate 1Kg, water 120Kg.
The preparation method of described insecticides, comprises the steps:
1st step, by cyfloxylate, cholrempenthrin, nicotine, Oleum Terebinthinae, methoxyfenozide, Acetamiprid, decis, Diacloden, aminothiazole quinoline, oxidation of piperonyl butoxide, butyl acetate, dimethylformamide, tbp, tristyrylphenol polyoxyethylene ether, NPE mix homogeneously, obtain oil phase；
2nd step, then after being mixed homogeneously with water by dodecylbenzene sodium sulfonate, obtain aqueous phase；
3rd step, mixes oil phase with aqueous phase the most again, is uniformly dispersed, and makes emulsion, to obtain final product.
Performance test
Respectively by the emulsion dilute in each embodiment and reference examples, the ratio (volume ratio) of dilution is 1:2000.
Chlorpyrifos ec (prior art) with 2 age colorado potato bug as object, carry out bioassay in indoor.Use the leaf dipping method that international resistance Action Committee (IRAC) proposes, by the medicinal liquid after dilution for using medicament.Fresh potato leaf being cut into the blade bar of 5cm length, soaks 10s respectively in each medicinal liquid to be measured, taking-up is dried, and puts in the culture dish of pad filter paper in advance, and several pieces leaf of potato bars of every ware connect second instar larvae 10.Every concentration repeats for 4 times.After covering ware lid, raise at a temperature of about 25 DEG C, be placed in observation indoor cultivation, and medicine blade and filter paper are soaked in the replacing of variable interval, check examination worm death condition after 48h, calculate mortality rate.
Concrete outcome see table.
| Test group | Mortality rate % |
| Embodiment 1 | 75.5 |
| Embodiment 2 | 76.4 |
| Embodiment 3 | 77.1 |
| Embodiment 4 | 84.2 |
| Reference examples 1 | 65.2 |
| Reference examples 2 | 64.8 |
| Reference examples 3 | 65.4 |
As can be seen from the table, the insecticide that the present invention provides has higher killing rate for colorado potato bug, additionally, can be seen that from reference examples 1～3, reference examples 1 adds thiophene insect amide relative to reference examples 3, reference examples 2 adds butene-fipronil relative to reference examples 3, the most do not produce the increase of obvious drug effect, but owing to being simultaneously introduced thiophene insect amide and butene-fipronil in embodiment 3, make mortality rate be increased 77% significantly by about 65%, while thiophene insect amide and butene-fipronil are described, add the effect creating Synergistic.
The emulsion of embodiment 3 and embodiment 4 carries out long-term stable experiment
The emulsion of embodiment 3 and embodiment 4 is positioned in dark glass container, then is placed in 40 DEG C, deposits 6 months under 80%RH damp condition, after taking-up, repeat above-mentioned dilution, deinsectization test, if as follows:
| Test group | Mortality rate % |
| Embodiment 3 | 70.9 |
| Embodiment 4 | 83.3 |
As can be seen from the table, emulsion in embodiment 3 is after long-term placement, the effect of parasite killing occurs in that significantly decline, illustrate to occur in that the degraded of effective ingredient during depositing, and the emulsion of embodiment 4 can be effectively prevented from degraded destruction owing to adding fulvic acid, killing rate does not occur to decline significantly.
Claims (4)
- null1. the insecticides being used for killing colorado potato bug，It is characterized in that，Include following component by weight: cyfloxylate 8～12 parts、Cholrempenthrin 0.5～1 part、Nicotine 0.2～4 parts、Oleum Terebinthinae 0.3～0.6 part、Methoxyfenozide 0.3～0.7 part、Thiophene insect amide 0.5～1 part、Butene-fipronil 0.2～3 parts、Acetamiprid 0.7～1 part、Decis 0.2～0.4 part、Diacloden 0.2～0.4 part、Aminothiazole quinoline 0.2～0.4 part、Oxidation of piperonyl butoxide 0.3～0.5 part、Butyl acetate 40～45 parts、Dimethylformamide 4～8 parts、Tbp 1～3 parts、Tristyrylphenol polyoxyethylene ether 0.5～0.7 part、NPE 0.7～0.9 part、Dodecylbenzene sodium sulfonate 0.8～1.2 parts、Water 100～150 parts.
- Insecticides for killing colorado potato bug the most according to claim 1, it is characterised in that: also include fulvic acid 0.5～0.8 part.
- 3. the preparation method of the insecticides for killing colorado potato bug described in claim 1, it is characterized in that, comprise the steps: the 1st step, by cyfloxylate, cholrempenthrin, nicotine, Oleum Terebinthinae, methoxyfenozide, thiophene insect amide, butene-fipronil, Acetamiprid, decis, Diacloden, aminothiazole quinoline, oxidation of piperonyl butoxide, butyl acetate, dimethylformamide, tbp, tristyrylphenol polyoxyethylene ether, NPE mix homogeneously, obtain oil phase；2nd step, then after being mixed homogeneously with water by dodecylbenzene sodium sulfonate, obtain aqueous phase；3rd step, mixes oil phase with aqueous phase the most again, is uniformly dispersed, and makes emulsion, to obtain final product.
- The preparation method of the insecticides for killing colorado potato bug the most according to claim 3, it is characterised in that: the 1st step also needs to add fulvic acid 0.5～0.8 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410658977.2A CN104322566B (en) | 2014-11-19 | 2014-11-19 | A kind of for insecticides killing colorado potato bug and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410658977.2A CN104322566B (en) | 2014-11-19 | 2014-11-19 | A kind of for insecticides killing colorado potato bug and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104322566A CN104322566A (en) | 2015-02-04 |
| CN104322566B true CN104322566B (en) | 2016-08-03 |
Family
ID=52397499
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410658977.2A Active CN104322566B (en) | 2014-11-19 | 2014-11-19 | A kind of for insecticides killing colorado potato bug and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104322566B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105918365B (en) * | 2016-06-30 | 2018-10-09 | 西南大学 | Application of the plants essential oil in preventing Paedenus fuscipes Curtis |
| CN106070350A (en) * | 2016-08-23 | 2016-11-09 | 赖丰光 | A kind of Pesticidal combination containing Radix Sophorae Flavescentis |
| CN106857681A (en) * | 2016-12-31 | 2017-06-20 | 新昌县云河虫害防治技术开发有限公司 | Kill insecticide of colorado potato bug and preparation method thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101648906B (en) * | 2004-04-08 | 2012-07-11 | 美国陶氏益农公司 | Insecticidal N-substituted sulfoximines |
| WO2008128355A1 (en) * | 2007-04-24 | 2008-10-30 | The University Of Western Ontario | Pesticidal composition derived from tobacco and pyrolysis process for production thereof |
| CN102450276A (en) * | 2010-11-01 | 2012-05-16 | 海利尔药业集团股份有限公司 | Pesticide composition containing thiazide insect amide and thiamethoxam |
| CN102077838A (en) * | 2011-01-24 | 2011-06-01 | 青岛海利尔药业有限公司 | Insecticidal composition containing clothianidine and pyrethroid compound |
| CN103283769A (en) * | 2013-05-22 | 2013-09-11 | 吴江市德佐日用化学品有限公司 | Insecticidal composition containing dinotefuran, butene-fipronil and clothianidin amide |
-
2014
- 2014-11-19 CN CN201410658977.2A patent/CN104322566B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN104322566A (en) | 2015-02-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103190455B (en) | Plant pesticide | |
| CN104322566B (en) | A kind of for insecticides killing colorado potato bug and preparation method thereof | |
| CN101658178A (en) | Synergistic insecticidal composition | |
| CN103385251B (en) | A kind of Pesticidal combination of pyriproxyfen-containing | |
| CN111165234A (en) | Biological control method for fall webworms | |
| CN101669514A (en) | Synergistic pesticide composition | |
| CN104126617B (en) | A kind of fruit tree fleahopper agent for killing and its preparation method | |
| CN105053020B (en) | Application of the cherry heterorhabditis indica in rice water weevil is prevented | |
| CN104304331B (en) | A kind of for insecticides killing planthopper and preparation method thereof | |
| CN102484994B (en) | Synergy composition of matrine and chlorantraniliprole | |
| CN103210953A (en) | Insecticide composition, insecticide and application of insecticide | |
| CN105815135A (en) | Allelochemicals of plants for parasite expelling and fruit retention to grapholita molesta busck | |
| CN101455204A (en) | Benzoyl urea insecticide and buprofezin compound preparation | |
| CN104397011B (en) | Insect-killing mite-killing agent composition with synergic effect | |
| CN103070186A (en) | Insecticidal composition containing thiamethoxam and application of insecticidal composition | |
| CN103548891B (en) | A kind of botanical pesticide and application thereof preventing and treating cigarette aphid | |
| CN108432810B (en) | Botanical insecticidal composition, preparation and application thereof in preventing and controlling crop pests | |
| CN102907454A (en) | Composite pesticides for controlling rice pests | |
| CN101444215A (en) | Desinsection composite and application thereof | |
| CN105325410B (en) | A kind of sea-buckthorn is around trypetid attractant | |
| CN104488915A (en) | insecticidal composition containing IPP | |
| CN103688986A (en) | Ultra low volume concentrate containing silafluofen and chloronicotinyl insecticide | |
| CN102067846B (en) | Buprofezin-containing pesticide composition | |
| CN102027958A (en) | Insecticidal composition consisting of spinosad and fenobucarb | |
| CN103734172B (en) | Plant insecticide suspending agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Cheng Huanhuan Inventor after: Cheng Lin Inventor after: Cheng Yiming Inventor before: Li Jie |
|
| COR | Change of bibliographic data | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160705 Address after: 231340 Shucheng County, Anhui Province, the town of the town of the village of the village of the town of Applicant after: Cheng Huanhuan Address before: 610000 Sichuan city of Chengdu province Jinjiang District River Qiaojin zhengxinjieyuan C District 7 Building 2 unit 801 Applicant before: Li Jie |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20221214 Address after: 273400 intersection of Yanbin road and yanpo Road, Fei County, Linyi City, Shandong Province Patentee after: Mach Technology (Linyi) Co.,Ltd. Address before: 231340 Chengyuan group, Lanchong village, Hepeng Town, Shucheng County, Lu'an City, Anhui Province Patentee before: Cheng Huanhuan |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20230718 Address after: 321000 east side of floor 3 and 4, building 10, Tangxi town (Jinxi Electromechanical Technology Industrial Park), Wucheng District, Jinhua City, Zhejiang Province Patentee after: Zhejiang shuanghuaiji traditional Chinese Medicine Co.,Ltd. Address before: 273400 intersection of Yanbin road and yanpo Road, Fei County, Linyi City, Shandong Province Patentee before: Mach Technology (Linyi) Co.,Ltd. |