CN104312640A - Methanol gasoline complexing agent for vehicles and preparation method of methanol gasoline complexing agent - Google Patents

Methanol gasoline complexing agent for vehicles and preparation method of methanol gasoline complexing agent Download PDF

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Publication number
CN104312640A
CN104312640A CN201410574610.2A CN201410574610A CN104312640A CN 104312640 A CN104312640 A CN 104312640A CN 201410574610 A CN201410574610 A CN 201410574610A CN 104312640 A CN104312640 A CN 104312640A
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China
Prior art keywords
methanol gasoline
complexing agent
mixing
preparation
tween
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Pending
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CN201410574610.2A
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Chinese (zh)
Inventor
刘旭光
张发
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SHANXI XINYUAN COAL CHEMICAL FUEL CO Ltd
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SHANXI XINYUAN COAL CHEMICAL FUEL CO Ltd
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Priority to CN201410574610.2A priority Critical patent/CN104312640A/en
Publication of CN104312640A publication Critical patent/CN104312640A/en
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Abstract

The invention relates to a methanol gasoline complexing agent for vehicles and a preparation method of the methanol gasoline complexing agent. The methanol gasoline complexing agent is prepared from the following raw materials in percentage by mass: 4-5% of triethanolamine, 30-35% of liquid paraffin, 3-5% of tween-80, 3.5-6% of oleic acid, 25-28% of butyl alcohol, 12-14% of isoamyl alcohol, 5-8% of acetone, 1-5% of ethylene glycol monobutyl ether, 5-6% of kerosene and 6-10% of benzene. The preparation method comprises the following steps: 1, mixing liquid paraffin, triethanolamine and isoamyl alcohol according to the ratio of 6:5:1:2.4 to 8.75:7:1:3.5 for later use; 2, mixing tween-80, oleic acid and acetone according to the ratio of 1:0.7:1 to 1:2:2.67 for later use; 3, mixing ethylene glycol monobutyl ether and benzene according to the ratio of 1:1:1.2 to 1:6:10 for later use, and mixing the three mixtures, thereby obtaining a finished product. The raw materials needed in the methanol gasoline complexing agent are rich and easy to obtain, no 'three wastes' are generated, the methanol gasoline complexing agent is safe, environmentally friendly and simple in process, and the series of technical problems of a conventional high/low vehicle methanol gasoline finished product are effectively solved.

Description

A kind of Vehicular methanol petrol recombiner and preparation method thereof
Technical field
The present invention relates to Vehicular methanol petrol recombiner and preparation method thereof, belong to technical field of petrochemical industry.
Background technology
Along with the fast development of China's economy; petroleum-based energy crisis and environmental pollution two large problems more and more come into one's own; and energy and environment problem has become the important factor affecting China and even world economy and social development; change oil shortage, with serious pollution unique method; reduce the dependence to oil exactly; developing green high-efficiency cleaning substitute energy, therefore, actively seeks and develops the cardinal task that clean energy has become various countries.
Methyl alcohol is with its clean environment firendly, the advantage such as cheap will as one of the most promising substitute energy, it is the best fuel substitute of oil engine except oil fuel, and the raw materials for production of methyl alcohol are easy to get, technical maturity, cheap, research and development have huge development potentiality, it is the developing direction of alternative motor fuels, but methyl alcohol is different from the polarity of gasoline, the calorific value of methyl alcohol in addition, cold start-up, the intrinsic problems such as corrosion are also the problems can not ignored in alternative Process, so what kind of is well fused and to overcome be exactly the emphasis studied corresponding methyl alcohol and gasoline.
Summary of the invention
The present invention is exactly the technical problem such as dynamic property, mutual solubility, corrodibility, swelling property, gas barrier, carbon deposit existed to solve methanol gasoline finished product, and provides a kind of Vehicular methanol petrol recombiner and preparation method thereof.
The technical solution used in the present invention: a kind of Vehicular methanol petrol recombiner, it is formed by the preparation of raw material of following weight percentage: trolamine: 4%-5%, whiteruss: 30%-35%, tween-80: 3%-5%, oleic acid: 3.5%-6%, butanols: 25%-28%, primary isoamyl alcohol: 12%-14%, acetone: 5%-8%, ethylene glycol monobutyl ether: 1%-5%, kerosene: 5%-6%, benzene: 6%-10%.
A kind of preparation method of Vehicular methanol petrol recombiner: the first step by whiteruss and butanols, trolamine, primary isoamyl alcohol according to the ratio mixing for standby use between 6:5:1:2.4-8.75:7:1:3.5, second step by tween-80 and oleic acid, acetone according to the ratio mixing for standby use between 1:0.7:1-1:2:2.67, ethylene glycol monobutyl ether and kerosene, benzene according to the ratio mixing for standby use between 1:1:1.2-1:6:10, finally utilize static mixer that three kinds of spares mixing are finished product by the 3rd step.
The present invention compared with prior art its beneficial effect is: the interpolation situation changing present methanol gasoline additive, now among methanol gasoline finished product allocation process, often to add several additive and just can play corresponding effect, additive and solubility promoter are split in addition, this just causes interpolation problem in process of production, too increase the production cost of enterprise in addition, and the invention provides a kind of Vehicular methanol petrol recombiner, collection hydrotropy, strengthen power, anticorrosive, anti-swelling, stop vapour lock, remove carbon deposit etc. and act as one, make it that there is good economy and market application foreground.
embodiment
embodiment 1
A kind of embodiment of Vehicular methanol petrol recombiner, first each component is respectively trolamine according to parts by weight: 4%, whiteruss: 30%, tween-80: 3%, oleic acid: 4%, butanols: 27%, primary isoamyl alcohol: 12.5%, acetone: 5%, ethylene glycol monobutyl ether: 2.5%, kerosene: 5%, benzene: 7%, the first step is by whiteruss and butanols, trolamine, primary isoamyl alcohol is according to the ratio mixing for standby use of 7.5:6.75:1:3.13, second step is by tween-80 and oleic acid, acetone is according to 1:1.33:1.67 ratio mixing for standby use, 3rd step is by ethylene glycol monobutyl ether and kerosene, benzene is according to the ratio mixing for standby use between 1:2:3, finally utilize static mixer that three kinds of spares mixing are finished product.
embodiment 2
A kind of embodiment of Vehicular methanol petrol recombiner, first each component is respectively trolamine according to parts by weight: 4.5%, whiteruss: 31%, tween-80: 4%, oleic acid: 3.5%, butanols: 25%, primary isoamyl alcohol: 12%, acetone: 6%, ethylene glycol monobutyl ether: 2%, kerosene: 6%, benzene: 6%, the first step is by whiteruss and butanols, trolamine, primary isoamyl alcohol is according to the ratio mixing for standby use of 6.89:5.56:1:2.67, second step is by tween-80 and oleic acid, acetone is according to the ratio mixing for standby use of 1.14:1:1.71, 3rd step is by ethylene glycol monobutyl ether and kerosene, benzene is according to the ratio mixing for standby use between 1:3:3, finally utilize static mixer that three kinds of spares mixing are finished product.
embodiment 3
A kind of embodiment of Vehicular methanol petrol recombiner, first each component is respectively trolamine according to parts by weight: 4.8%, whiteruss: 33%, tween-80: 4.5%, oleic acid: 5%, butanols: 27.5%, primary isoamyl alcohol: 14%, acetone: 7%, ethylene glycol monobutyl ether: 4%, kerosene: 6%, benzene: 10%, the first step is by whiteruss and butanols, trolamine, primary isoamyl alcohol is according to the ratio mixing for standby use of 6.88:5.73:1:2.92, second step is by tween-80 and oleic acid, acetone is according to the ratio mixing for standby use of 1:1.11:1.56, 3rd step is by ethylene glycol monobutyl ether and kerosene, benzene is according to the ratio mixing for standby use between 1:1.5:2.5, finally utilize static mixer that three kinds of spares mixing are finished product.

Claims (2)

1. a Vehicular methanol petrol recombiner, it is characterized in that being formed by the preparation of raw material of following weight percentage: trolamine: 4%-5%, whiteruss: 30%-35%, tween-80: 3%-5%, oleic acid: 3.5%-6%, butanols: 25%-28%, primary isoamyl alcohol: 12%-14%, acetone: 5%-8%, ethylene glycol monobutyl ether: 1%-5%, kerosene: 5%-6%, benzene: 6%-10%.
2. the preparation method of a Vehicular methanol petrol recombiner, it is characterized in that: each component configures according to mass percent according to claim 1, the first step is by whiteruss and butanols, trolamine, primary isoamyl alcohol is according to the ratio mixing for standby use between 6:5:1:2.4-8.75:7:1:3.5, second is tween-80 and oleic acid, acetone is according to the ratio mixing for standby use between 1:0.7:1-1:2:2.67, 3rd is ethylene glycol monobutyl ether and kerosene, benzene is according to the ratio mixing for standby use between 1:1:1.2-1:6:10, finally utilize static mixer that three kinds of spares mixing are finished product.
CN201410574610.2A 2014-10-24 2014-10-24 Methanol gasoline complexing agent for vehicles and preparation method of methanol gasoline complexing agent Pending CN104312640A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105219451A (en) * 2015-11-04 2016-01-06 山西新源煤化燃料有限公司 A kind of Novel vehicle gasoline of high proportion methanol and preparation method thereof
CN105238456A (en) * 2015-09-29 2016-01-13 山西新源煤化燃料有限公司 Environment-friendly mixed fuel auxiliary agent of vehicle methanol gasoline and preparation method thereof
CN110643400A (en) * 2019-10-11 2020-01-03 山西新源煤化燃料有限公司 Environment-friendly enhancing agent for vehicle and preparation method thereof
CN110862850A (en) * 2019-08-15 2020-03-06 山西新源煤化燃料有限公司 Vehicle alcohol gasoline composite synergist and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1123364B1 (en) * 1998-09-18 2007-01-24 American Energy Group, Inc. Diesel fuel additive composition and method for the treatment of diesel fuels
CN101070501A (en) * 2006-05-08 2007-11-14 马征坤 Energy-saving environment-protective fuel-oil compounding agent
CN101724474A (en) * 2008-10-14 2010-06-09 陈若歆 Mode for preparing M15-M100 complexing methanol petrol and gas normal-temperature liquefaction mixed combustion technology
CN102643689A (en) * 2012-04-20 2012-08-22 西安祺祥能源科技发展有限公司 M85 methanol gasoline additive used for vehicles and preparation method and applications thereof
CN102876398A (en) * 2012-10-29 2013-01-16 孙建国 Technical formula and production technique of alcohol-group gasoline

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1123364B1 (en) * 1998-09-18 2007-01-24 American Energy Group, Inc. Diesel fuel additive composition and method for the treatment of diesel fuels
CN101070501A (en) * 2006-05-08 2007-11-14 马征坤 Energy-saving environment-protective fuel-oil compounding agent
CN101724474A (en) * 2008-10-14 2010-06-09 陈若歆 Mode for preparing M15-M100 complexing methanol petrol and gas normal-temperature liquefaction mixed combustion technology
CN102643689A (en) * 2012-04-20 2012-08-22 西安祺祥能源科技发展有限公司 M85 methanol gasoline additive used for vehicles and preparation method and applications thereof
CN102876398A (en) * 2012-10-29 2013-01-16 孙建国 Technical formula and production technique of alcohol-group gasoline

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105238456A (en) * 2015-09-29 2016-01-13 山西新源煤化燃料有限公司 Environment-friendly mixed fuel auxiliary agent of vehicle methanol gasoline and preparation method thereof
CN105219451A (en) * 2015-11-04 2016-01-06 山西新源煤化燃料有限公司 A kind of Novel vehicle gasoline of high proportion methanol and preparation method thereof
CN110862850A (en) * 2019-08-15 2020-03-06 山西新源煤化燃料有限公司 Vehicle alcohol gasoline composite synergist and preparation method thereof
CN110643400A (en) * 2019-10-11 2020-01-03 山西新源煤化燃料有限公司 Environment-friendly enhancing agent for vehicle and preparation method thereof

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