CN105219451A - A kind of Novel vehicle gasoline of high proportion methanol and preparation method thereof - Google Patents
A kind of Novel vehicle gasoline of high proportion methanol and preparation method thereof Download PDFInfo
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- CN105219451A CN105219451A CN201510739540.6A CN201510739540A CN105219451A CN 105219451 A CN105219451 A CN 105219451A CN 201510739540 A CN201510739540 A CN 201510739540A CN 105219451 A CN105219451 A CN 105219451A
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Abstract
The invention discloses a kind of Novel vehicle gasoline of high proportion methanol and preparation method thereof, it is formulated by the component of following weight content: methyl alcohol, hydrocarbyl ether blending ingredients oil, many carbon alcohol mixture, multipurpose additive; Hydrocarbyl ether blending ingredients oil is made up of straight-run spirit, condensate oil, straight(-run) tops, diisopropyl ether, sherwood oil; Many carbon alcohol mixture is made up of ethanol, Virahol, primary isoamyl alcohol; Multipurpose additive is made up of trolamine, oleic acid, benzene, whiteruss, butanols, tween-80.The present invention bases oneself upon and utilizes superfluous methyl alcohol resource, solves the problem of cold starting performance and the swelling trolley part of corrosion, is intended to produce for the popularization of high-proportion methanol gasoline for vehicle and industrialization add devote every effort to help strength.
Description
Technical field
The invention belongs to a kind of Vehicular methanol petrol and preparation method thereof, be specifically related to a kind of Novel vehicle gasoline of high proportion methanol and preparation method thereof.
Background technology
Along with the fast development of China's economy, the increase year by year of per capita income, by 2014 the end of the year private car quantity close to 100,000,000, exhaust emissions is one of main reason becoming haze already; The few oil of the rich coal of China, Imported oil amount increases year by year along with expanding economy, this drastically influence the energy security of China, therefore seek a kind of environmental protection, energy-conservation vehicle alternative fuel becomes the task of top priority, under this background, methyl alcohol receives much concern with its advantage such as clean, cheap, becomes one of substitute energy of most prospect.
The issuing and implementation of in December, 2009 " Vehicular methanol petrol (M85) " and " fuel methanol " two national standards, produce for high-proportion methanol gasoline for vehicle and provide criterion with detection, but according to the high-proportion methanol gasoline for vehicle that this two standards are produced, existence needs fuel-control unit flexible for installation to use and low-temperature startup performance is poor, corrode the problems such as swelling trolley part, fundamentally governs applying and industrialized development of high-proportion methanol gasoline for vehicle.
Summary of the invention
The invention provides a kind of Novel vehicle gasoline of high proportion methanol and preparation method thereof, for solve gasoline of high proportion methanol low-temperature startup performance poor, corrode the problems such as swelling trolley part.
The present invention is by the following technical solutions: a kind of Novel vehicle gasoline of high proportion methanol, and it is formulated by the component of following weight content: methyl alcohol 83-85 part, hydrocarbyl ether blending ingredients oil 13-15 parts, many carbon alcohol mixture 1-2 part, multipurpose additive 1-2 part; Wherein, described hydrocarbyl ether blending ingredients oil is by 30%(weight part) straight-run spirit, 25%(weight part) condensate oil, 30%(weight part) straight(-run) tops, 10%(weight part) diisopropyl ether, 5%(weight part) the sherwood oil of 30-60 degree form; Described many carbon alcohol mixture is made up of by the volume ratio of 5:3:2 ethanol, Virahol, primary isoamyl alcohol; Multipurpose additive by trolamine, oleic acid, benzene, whiteruss, butanols, tween-80 according to: the volume ratio of 2:0.5:1:4:2:0.5 forms.
A preparation method for Novel vehicle gasoline of high proportion methanol, it comprises following steps:
1. by 30%(weight part) straight-run spirit, 25%(weight part) condensate oil, 30%(weight part) straight(-run) tops, 10%(weight part) diisopropyl ether, 5%(weight part) the sherwood oil of 30-60 degree be mixed into hydrocarbyl ether blending ingredients oil, for subsequent use;
2. ethanol, Virahol, primary isoamyl alcohol are mixed into many carbon alcohol mixture by the volume ratio of 5:3:2, for subsequent use;
3. by trolamine, oleic acid, benzene, whiteruss, butanols, tween-80 according to: the volume ratio of 2:0.5:1:4:2:0.5 is mixed into multipurpose additive, for subsequent use;
4. by step 1. in the hydrocarbyl ether blending ingredients oil that obtains and step 3. in the multipurpose additive that obtains mix, for subsequent use;
5. by methyl alcohol and step 2. in many carbon alcohol mixture of obtaining mix, for subsequent use;
6. by step 4. with step 5. in mixture mix, namely obtain.
The present invention compared with prior art has following beneficial effect: a kind of Novel vehicle gasoline of high proportion methanol provided by the invention and preparation method thereof, takes full advantage of superfluous methyl alcohol resource, has saved petroleum resources; Methanol gasoline of the present invention does not in use need fuel-control unit flexible for installation, heightens the steam pressure value at low temperature environment temperature by the advantage that low-boiling point material gasification latent heat water lighting energy is low, and oil/gas ratio of mixture improves cold starting performance after increasing; The invention solves and use the difficult problem of gasoline of high proportion methanol at extremely frigid zones, in addition multipurpose additive add the problem solving and corrode swelling trolley part.
Embodiment
Embodiment 1
A kind of Novel vehicle gasoline of high proportion methanol, it is formulated by the component of following weight content: methyl alcohol 83 parts, hydrocarbyl ether blending ingredients oil 13 parts, many carbon alcohol mixture 1 part, multipurpose additive 1 part; Wherein, described hydrocarbyl ether blending ingredients oil by weight every part by 30% straight-run spirit, 25% condensate oil, 30% straight(-run) tops, the diisopropyl ether of 10%, 30-60 degree of 5% sherwood oils form; Described many carbon alcohol mixture is made up of by the volume ratio of 5:3:2 ethanol, Virahol, primary isoamyl alcohol; Multipurpose additive by trolamine, oleic acid, benzene, whiteruss, butanols, tween-80 according to: the volume ratio of 2:0.5:1:4:2:0.5 forms.
Embodiment 2
A kind of Novel vehicle gasoline of high proportion methanol, it is formulated by the component of following weight content: methyl alcohol 84 parts, hydrocarbyl ether blending ingredients oil 14 parts, many carbon alcohol mixture 2 parts, multipurpose additive 2 parts; Wherein, described hydrocarbyl ether blending ingredients oil by weight every part by 30% straight-run spirit, 25% condensate oil, 30% straight(-run) tops, the diisopropyl ether of 10%, 30-60 degree of 5% sherwood oils form; Described many carbon alcohol mixture is made up of by the volume ratio of 5:3:2 ethanol, Virahol, primary isoamyl alcohol; Multipurpose additive by trolamine, oleic acid, benzene, whiteruss, butanols, tween-80 according to: the volume ratio of 2:0.5:1:4:2:0.5 forms.
Embodiment 3
A kind of Novel vehicle gasoline of high proportion methanol, it is formulated by the component of following weight content: methyl alcohol 85 parts, hydrocarbyl ether blending ingredients oil 15 parts, many carbon alcohol mixture 2 parts, multipurpose additive 2 parts; Wherein, described hydrocarbyl ether blending ingredients oil by weight every part by 30% straight-run spirit, 25% condensate oil, 30% straight(-run) tops, the diisopropyl ether of 10%, 30-60 degree of 5% sherwood oils form; Described many carbon alcohol mixture is made up of by the volume ratio of 5:3:2 ethanol, Virahol, primary isoamyl alcohol; Multipurpose additive by trolamine, oleic acid, benzene, whiteruss, butanols, tween-80 according to: the volume ratio of 2:0.5:1:4:2:0.5 forms.
The preparation method of above three kinds of embodiments is as follows: a kind of preparation method of Novel vehicle gasoline of high proportion methanol, and at the temperature of-30-35 DEG C, production Reid vapour pressure RVP value is the gasoline of high proportion methanol product of 70-80kpa, and it comprises following steps:
1. by 30%(weight part) straight-run spirit, 25%(weight part) condensate oil, 30%(weight part) straight(-run) tops, 10%(weight part) diisopropyl ether, 5%(weight part) the sherwood oil of 30-60 degree be mixed into hydrocarbyl ether blending ingredients oil, for subsequent use;
2. ethanol, Virahol, primary isoamyl alcohol are mixed into many carbon alcohol mixture by the volume ratio of 5:3:2, for subsequent use;
3. by trolamine, oleic acid, benzene, whiteruss, butanols, tween-80 according to: the volume ratio of 2:0.5:1:4:2:0.5 is mixed into multipurpose additive, for subsequent use;
4. by step 1. in the hydrocarbyl ether blending ingredients oil that obtains and step 3. in the multipurpose additive that obtains mix, for subsequent use;
5. by methyl alcohol and step 2. in many carbon alcohol mixture of obtaining mix, for subsequent use;
6. by step 4. with step 5. in mixture mix, namely obtain.
Claims (2)
1. a Novel vehicle gasoline of high proportion methanol, it is formulated by the component of following weight content: methyl alcohol 83-85 part, hydrocarbyl ether blending ingredients oil 13-15 parts, many carbon alcohol mixture 1-2 part, multipurpose additive 1-2 part; Wherein, described hydrocarbyl ether blending ingredients oil is by 30%(weight part) straight-run spirit, 25%(weight part) condensate oil, 30%(weight part) straight(-run) tops, 10%(weight part) diisopropyl ether, 5%(weight part) the sherwood oil of 30-60 degree form; Described many carbon alcohol mixture is made up of by the volume ratio of 5:3:2 ethanol, Virahol, primary isoamyl alcohol; Multipurpose additive by trolamine, oleic acid, benzene, whiteruss, butanols, tween-80 according to: the volume ratio of 2:0.5:1:4:2:0.5 forms.
2. a preparation method for Novel vehicle gasoline of high proportion methanol as claimed in claim 1, is characterized in that, comprise following steps:
1. by 30%(weight part) straight-run spirit, 25%(weight part) condensate oil, 30%(weight part) straight(-run) tops, 10%(weight part) diisopropyl ether, 5%(weight part) the sherwood oil of 30-60 degree be mixed into hydrocarbyl ether blending ingredients oil, for subsequent use;
2. ethanol, Virahol, primary isoamyl alcohol are mixed into many carbon alcohol mixture by the volume ratio of 5:3:2, for subsequent use;
3. by trolamine, oleic acid, benzene, whiteruss, butanols, tween-80 according to: the volume ratio of 2:0.5:1:4:2:0.5 is mixed into multipurpose additive, for subsequent use;
4. by step 1. in the hydrocarbyl ether blending ingredients oil that obtains and step 3. in the multipurpose additive that obtains mix, for subsequent use;
5. by methyl alcohol and step 2. in many carbon alcohol mixture of obtaining mix, for subsequent use;
6. by step 4. with step 5. in mixture mix, namely obtain.
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101724474A (en) * | 2008-10-14 | 2010-06-09 | 陈若歆 | Mode for preparing M15-M100 complexing methanol petrol and gas normal-temperature liquefaction mixed combustion technology |
CN101892094A (en) * | 2010-07-22 | 2010-11-24 | 山西新源煤化燃料有限公司 | High-proportion methanol gasoline for vehicle and preparation method thereof |
CN104312640A (en) * | 2014-10-24 | 2015-01-28 | 山西新源煤化燃料有限公司 | Methanol gasoline complexing agent for vehicles and preparation method of methanol gasoline complexing agent |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101724474A (en) * | 2008-10-14 | 2010-06-09 | 陈若歆 | Mode for preparing M15-M100 complexing methanol petrol and gas normal-temperature liquefaction mixed combustion technology |
CN101892094A (en) * | 2010-07-22 | 2010-11-24 | 山西新源煤化燃料有限公司 | High-proportion methanol gasoline for vehicle and preparation method thereof |
CN104312640A (en) * | 2014-10-24 | 2015-01-28 | 山西新源煤化燃料有限公司 | Methanol gasoline complexing agent for vehicles and preparation method of methanol gasoline complexing agent |
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