CN104311960A - Impact-resistant nozzle for degreasing and washing - Google Patents
Impact-resistant nozzle for degreasing and washing Download PDFInfo
- Publication number
- CN104311960A CN104311960A CN201410591563.2A CN201410591563A CN104311960A CN 104311960 A CN104311960 A CN 104311960A CN 201410591563 A CN201410591563 A CN 201410591563A CN 104311960 A CN104311960 A CN 104311960A
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- parts
- degreasing
- nano
- raw material
- washing
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/068—Ultra high molecular weight polyethylene
Abstract
The invention discloses an impact-resistant nozzle for degreasing and washing. The nozzle is prepared from the following raw materials in parts by weight: 0.1-0.2 part of 4-dimethylamino-pyridine, 2-3 parts of palm wax, 0.5-1 part of ammonium octamolybdate, 5-7 parts of nano calcium phosphate, 2-3 parts of nano carbon powder, 1-2 parts of sodium dodecyl sulfate, 0.4-1 part of hexafluoro-acetylacetone, 2-3 parts of magnesium sulfate, 1-2 parts of dipropylene glycol, 2-4 parts of tricalcium silicate, 0.6-1 part of silicon gel silicon oil, 0.1-0.2 part of diethylenetriamine, 90-100 parts of ultrahigh molecular weight polyethylene, 5-6 parts of a highly resistant auxiliary and 0.3-1 part of 1, 4-dithiothreitol. By adding the highly resistant auxiliary, esterified butyraldehyde has good flexibility and flexural property and an emulsion adhesive can promote the compatibility of materials and improve the mobility of a melt; by blending and modifying a methyl methacrylate-butadiene-styrene terpolymer which is softened with esterified butyraldehyde and emulsion adhesive, the surface resistance of a finished product is greatly improved.
Description
Technical field
The present invention relates generally to plastic applications, particularly relates to a kind of shock resistance nozzle for degreasing and washing.
Background technology
Nozzle is parts very crucial in the equipment such as a variety of spray, spraying, oil spout, sandblasting, spraying, play an important role, nozzle application in the industry widely, material is from stainless steel, plastics to silicon carbide, polytetrafluoroethylene, PP(engineering plastics), aluminium alloy and wolfram steel etc., range of application is generally commonly used in the industry-by-industries such as automobile, plating, surface treatment, high pressure cleaning, dedusting, cooling, desulfurization, humidification, stirring, gardens.
Summary of the invention
The object of the invention is just to provide a kind of shock resistance nozzle for degreasing and washing.
The present invention is achieved by the following technical solutions:
For a shock resistance nozzle for degreasing and washing, it is characterized in that what it was made up of the raw material of following weight parts:
DMAP 0.1-0.2, palm wax 2-3, ammonium octamolybdate 0.5-1, nano-calcium phosphate 5-7, nano-carbon powder 2-3, sodium laurylsulfonate 1-2, hexafluoroacetylacetone 0.4-1, magnesium sulfate 2-3, dipropylene glycol 1-2, tricalcium silicate 2-4, silica gel silicon oil 0.6-1, Diethylenetriaminee (DETA) 0.1-0.2, ultrahigh molecular weight polyethylene(UHMWPE) 90-100, high resistance auxiliary agent 5-6, Isosorbide-5-Nitrae-dithiothreitol dithio 0.3-1;
Described high resistance auxiliary agent is made up of the raw material of following weight parts:
Neusilin 3-4, MBS terpolymer 30-40, polyvinyl butyral acetal 6-9, Sodium dodecylbenzene sulfonate 1-2, TriMethylolPropane(TMP) 0.4-1, nylon acid methyl esters 2-3, phytinic acid 0.6-1;
Polyvinyl butyral acetal is heated to 60-65 DEG C, adds nylon acid methyl esters, insulated and stirred 6-10 minute, be cooled to normal temperature, obtain esterification butyral;
Sodium dodecylbenzene sulfonate is joined in 8-10 times of water, stir, add neusilin, phytinic acid, be uniformly mixed, obtain emulsion adhesive;
Each raw material after above-mentioned process is mixed with MBS terpolymer, send into reactor, stir, dewatered drying, adds TriMethylolPropane(TMP), at pressure 1.8-1.9MPa, temperature 84-90 DEG C, be uniformly mixed 1-2 hour, cooling discharging, abrasive dust, obtains described high resistance auxiliary agent.
2, as claimed in claim 1 for a preparation method for the shock resistance nozzle of degreasing and washing, it is characterized in that comprising the following steps:
By nano-calcium phosphate, nano-carbon powder mixing, add palm wax, be heated to 80-90 DEG C, add the 5-10% of above-mentioned high-molecular polythene weight after stirring, insulated and stirred mixing 10-20 minute, is cooled to normal temperature, adds DMAP, mix;
Silica gel silicon oil is joined in dipropylene glycol, adds the 5-10% of tricalcium silicate and residue high-molecular polythene weight after stirring, insulated and stirred 10-20 minute at 70-80 DEG C;
Mix with residue each raw material by each raw material after above-mentioned process, send in rubber mixing machine, mixing 2-3 hour at 135-140 DEG C, is placed in injection moulding machine, for the shock resistance nozzle of degreasing and washing described in being processed into.
Advantage of the present invention is:
The high resistance auxiliary agent added in the present invention: wherein esterification butyral has good flexibility and flexibility, emulsion adhesive can promote the consistency of storeroom, and improves the mobility of melt; By softening for MBS terpolymer rear and esterification butyral, emulsion adhesive blending and modifying, greatly improve the surface resistive of finished product;
The nano-calcium phosphate added in nozzle of the present invention, nano-carbon powder not only effectively can promote the consistency of storeroom, hardness and the shock resistance of finished product can also be improved, reduce maintenance rate and breakage rate, nozzle of the present invention is mainly used in degreasing and washing step, can resist the hydraulic shock of high strength.
Embodiment
Embodiment 1
For a shock resistance nozzle for degreasing and washing, it is characterized in that what it was made up of the raw material of following weight parts:
DMAP 0.2, palm wax 2, ammonium octamolybdate 0.5, nano-calcium phosphate 7, nano-carbon powder 3, sodium laurylsulfonate 2, hexafluoroacetylacetone 0.4, magnesium sulfate 3, dipropylene glycol 1, tricalcium silicate 2, silica gel silicon oil 0.6, Diethylenetriaminee (DETA) 0.2, ultrahigh molecular weight polyethylene(UHMWPE) (molecular weight is 3,000,000) 100, high resistance auxiliary agent 6, Isosorbide-5-Nitrae-dithiothreitol dithio 0.3;
Described high resistance auxiliary agent is made up of the raw material of following weight parts:
Neusilin 4, MBS terpolymer 40, polyvinyl butyral acetal 9, Sodium dodecylbenzene sulfonate 2, TriMethylolPropane(TMP) 0.4, nylon acid methyl esters 3, phytinic acid 0.6;
Polyvinyl butyral acetal is heated to 65 DEG C, adds nylon acid methyl esters, insulated and stirred 10 minutes, is cooled to normal temperature, obtains esterification butyral;
Sodium dodecylbenzene sulfonate is joined in 10 times of water, stir, add neusilin, phytinic acid, be uniformly mixed, obtain emulsion adhesive;
Each raw material after above-mentioned process is mixed with MBS terpolymer, send into reactor, stir, dewatered drying, adds TriMethylolPropane(TMP), at pressure 1.9MPa, temperature 90 DEG C, be uniformly mixed 2 hours, cooling discharging, abrasive dust, obtains described high resistance auxiliary agent.
For a preparation method for the shock resistance nozzle of degreasing and washing, it is characterized in that comprising the following steps:
By nano-calcium phosphate, nano-carbon powder mixing, add palm wax after stirring, be heated to 90 DEG C, add 10% of above-mentioned high-molecular polythene weight, insulated and stirred mixes 10 minutes, is cooled to normal temperature, adds DMAP, mixes;
Silica gel silicon oil is joined in dipropylene glycol, to add at tricalcium silicate and residue high-molecular polythene weight 10%, 80 DEG C insulated and stirred after stirring 20 minutes;
Each raw material after above-mentioned process mix with residue each raw material, sends in rubber mixing machine, at 140 DEG C mixing 3 hours, be placed in injection moulding machine, for the shock resistance nozzle of degreasing and washing described in being processed into.
Performance test: tensile strength 30.8MPa.
Claims (2)
1., for a shock resistance nozzle for degreasing and washing, it is characterized in that what it was made up of the raw material of following weight parts:
DMAP 0.1-0.2, palm wax 2-3, ammonium octamolybdate 0.5-1, nano-calcium phosphate 5-7, nano-carbon powder 2-3, sodium laurylsulfonate 1-2, hexafluoroacetylacetone 0.4-1, magnesium sulfate 2-3, dipropylene glycol 1-2, tricalcium silicate 2-4, silica gel silicon oil 0.6-1, Diethylenetriaminee (DETA) 0.1-0.2, ultrahigh molecular weight polyethylene(UHMWPE) 90-100, high resistance auxiliary agent 5-6, Isosorbide-5-Nitrae-dithiothreitol dithio 0.3-1;
Described high resistance auxiliary agent is made up of the raw material of following weight parts:
Neusilin 3-4, MBS terpolymer 30-40, polyvinyl butyral acetal 6-9, Sodium dodecylbenzene sulfonate 1-2, TriMethylolPropane(TMP) 0.4-1, nylon acid methyl esters 2-3, phytinic acid 0.6-1;
Polyvinyl butyral acetal is heated to 60-65 DEG C, adds nylon acid methyl esters, insulated and stirred 6-10 minute, be cooled to normal temperature, obtain esterification butyral;
Sodium dodecylbenzene sulfonate is joined in 8-10 times of water, stir, add neusilin, phytinic acid, be uniformly mixed, obtain emulsion adhesive;
Each raw material after above-mentioned process is mixed with MBS terpolymer, send into reactor, stir, dewatered drying, adds TriMethylolPropane(TMP), at pressure 1.8-1.9MPa, temperature 84-90 DEG C, be uniformly mixed 1-2 hour, cooling discharging, abrasive dust, obtains described high resistance auxiliary agent.
2., as claimed in claim 1 for a preparation method for the shock resistance nozzle of degreasing and washing, it is characterized in that comprising the following steps:
By nano-calcium phosphate, nano-carbon powder mixing, add palm wax, be heated to 80-90 DEG C, add the 5-10% of above-mentioned high-molecular polythene weight after stirring, insulated and stirred mixing 10-20 minute, is cooled to normal temperature, adds DMAP, mix;
Silica gel silicon oil is joined in dipropylene glycol, adds the 5-10% of tricalcium silicate and residue high-molecular polythene weight after stirring, insulated and stirred 10-20 minute at 70-80 DEG C;
Mix with residue each raw material by each raw material after above-mentioned process, send in rubber mixing machine, mixing 2-3 hour at 135-140 DEG C, is placed in injection moulding machine, for the shock resistance nozzle of degreasing and washing described in being processed into.
Priority Applications (1)
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CN201410591563.2A CN104311960A (en) | 2014-10-29 | 2014-10-29 | Impact-resistant nozzle for degreasing and washing |
Applications Claiming Priority (1)
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CN201410591563.2A CN104311960A (en) | 2014-10-29 | 2014-10-29 | Impact-resistant nozzle for degreasing and washing |
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CN104311960A true CN104311960A (en) | 2015-01-28 |
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CN201410591563.2A Pending CN104311960A (en) | 2014-10-29 | 2014-10-29 | Impact-resistant nozzle for degreasing and washing |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101463156A (en) * | 2007-12-19 | 2009-06-24 | 上海化工研究院天地科技发展有限公司 | Superhigh molecular weight polyethylene material and preparation thereof |
CN102127269A (en) * | 2010-01-12 | 2011-07-20 | 盛亚军 | Flame-retarding polymer foam material and preparation method thereof |
CN102276925A (en) * | 2011-06-29 | 2011-12-14 | 广州市聚赛龙工程塑料有限公司 | Special material for automobile bumper produced from recovered polyethylene (PE)/polyamide (PA) composite film material and preparation method thereof |
CN102952317A (en) * | 2012-10-19 | 2013-03-06 | 芜湖太平洋塑胶有限公司 | Plastic-wooden composite tray and preparation method thereof |
CN103483843A (en) * | 2013-09-10 | 2014-01-01 | 九江学院 | Glass fiber reinforcement wheat straw or rice straw composite material and preparation method thereof |
CN104045949A (en) * | 2014-05-29 | 2014-09-17 | 江苏梅兰化工有限公司 | Ultra-low temperature resistant fluororubber mixed rubber and preparation method thereof |
-
2014
- 2014-10-29 CN CN201410591563.2A patent/CN104311960A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101463156A (en) * | 2007-12-19 | 2009-06-24 | 上海化工研究院天地科技发展有限公司 | Superhigh molecular weight polyethylene material and preparation thereof |
CN102127269A (en) * | 2010-01-12 | 2011-07-20 | 盛亚军 | Flame-retarding polymer foam material and preparation method thereof |
CN102276925A (en) * | 2011-06-29 | 2011-12-14 | 广州市聚赛龙工程塑料有限公司 | Special material for automobile bumper produced from recovered polyethylene (PE)/polyamide (PA) composite film material and preparation method thereof |
CN102952317A (en) * | 2012-10-19 | 2013-03-06 | 芜湖太平洋塑胶有限公司 | Plastic-wooden composite tray and preparation method thereof |
CN103483843A (en) * | 2013-09-10 | 2014-01-01 | 九江学院 | Glass fiber reinforcement wheat straw or rice straw composite material and preparation method thereof |
CN104045949A (en) * | 2014-05-29 | 2014-09-17 | 江苏梅兰化工有限公司 | Ultra-low temperature resistant fluororubber mixed rubber and preparation method thereof |
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Application publication date: 20150128 |
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