CN104292591A - Plastic resin composite nozzle - Google Patents
Plastic resin composite nozzle Download PDFInfo
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- CN104292591A CN104292591A CN201410591554.3A CN201410591554A CN104292591A CN 104292591 A CN104292591 A CN 104292591A CN 201410591554 A CN201410591554 A CN 201410591554A CN 104292591 A CN104292591 A CN 104292591A
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- plastic resin
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/068—Ultra high molecular weight polyethylene
Abstract
The invention discloses a plastic resin composite nozzle which is prepared from the following raw materials in parts by weight: 80-100 parts of ultra-high molecular weight polyethylene, 6-10 parts of carbomer resin, 1-2 parts of hexafluoro acetylacetone, 0.6-1 part of potassium titanate, 0.7-1 part of N,N-diethyl aniline, 6-10 parts of wollastonite powder, 3-5 parts of octadecyl methacrylate, 1-2 parts of ammonium molybdate, 0.1-0.2 part of butylmercaptooxo stannane, 0.4-1 part of manganese oxide, 5-8 parts of titanium dioxide, 2-4 parts of calcium carbonate, 0.5-1 part of glycerin, 0.5-1 part of ammonium ferrous sulfate and 5-7 parts of a highly resistant addictive. According to the highly resistant addictive added in the plastic resin composite nozzle, esterified butyral has the excellent softness and flexure property, and emulsion adhesive can promote the compatibility among materials and improve the flowability of a fusant; as the methyl methacrylate-butadiene-styrene terpolymer is softened, and then, is mixed together with the esterified butyral and the emulsion adhesive for modification, the surface resistance of a finished product is greatly improved.
Description
Technical field
The present invention relates generally to plastic applications, particularly relates to a kind of Plastic Resin combining nozzle.
Background technology
Nozzle is parts very crucial in the equipment such as a variety of spray, spraying, oil spout, sandblasting, spraying, play an important role, nozzle application in the industry widely, material is from stainless steel, plastics to silicon carbide, polytetrafluoroethylene, PP(engineering plastics), aluminium alloy and wolfram steel etc., range of application is generally commonly used in the industry-by-industries such as automobile, plating, surface treatment, high pressure cleaning, dedusting, cooling, desulfurization, humidification, stirring, gardens.
Summary of the invention
The object of the invention is just to provide a kind of Plastic Resin combining nozzle.
The present invention is achieved by the following technical solutions:
A kind of Plastic Resin combining nozzle, is characterized in that what it was made up of the raw material of following weight parts:
Ultrahigh molecular weight polyethylene(UHMWPE) 80-100, carbomer 6-10, hexafluoroacetylacetone 1-2, potassium titanate 0.6-1, N, N-Diethyl Aniline 0.7-1, wollastonite powder 6-10, stearyl methacrylate 3-5, ammonium molybdate 1-2, butanethiol tin 0.1-0.2, manganese oxide 0.4-1, titanium dioxide 5-8, calcium carbonate 2-4, glycerine 0.5-1, ferrous ammonium sulphate 0.5-1, high resistance auxiliary agent 5-7;
Described high resistance auxiliary agent is made up of the raw material of following weight parts:
Neusilin 3-4, MBS terpolymer 30-40, polyvinyl butyral acetal 6-9, Sodium dodecylbenzene sulfonate 1-2, TriMethylolPropane(TMP) 0.4-1, nylon acid methyl esters 2-3, phytinic acid 0.6-1;
Polyvinyl butyral acetal is heated to 60-65 DEG C, adds nylon acid methyl esters, insulated and stirred 6-10 minute, be cooled to normal temperature, obtain esterification butyral;
Sodium dodecylbenzene sulfonate is joined in 8-10 times of water, stir, add neusilin, phytinic acid, be uniformly mixed, obtain emulsion adhesive;
Each raw material after above-mentioned process is mixed with MBS terpolymer, send into reactor, stir, dewatered drying, adds TriMethylolPropane(TMP), at pressure 1.8-1.9MPa, temperature 84-90 DEG C, be uniformly mixed 1-2 hour, cooling discharging, abrasive dust, obtains described high resistance auxiliary agent.
A preparation method for Plastic Resin combining nozzle as claimed in claim 1, is characterized in that comprising the following steps:
By manganese oxide, titanium dioxide mixing, add stearyl methacrylate after ball milling is even, at 60-70 DEG C, insulation mixing 5-10 minute, adds glycerine under stirring and adjusting, is stirred to normal temperature, obtain esterification material;
Carbomer is joined in 3-5 times of water, add ferrous ammonium sulphate, wollastonite powder after stirring, be stirred to water at 70-80 DEG C and do, mix with above-mentioned esterification material, add 10-20%, the potassium titanate of above-mentioned ultrahigh molecular weight polyethylene(UHMWPE) weight, insulated and stirred 10-20 minute at 100-105 DEG C;
Mixed with each raw material of residue by each raw material after above-mentioned process, send in rubber mixing machine, mixing 2-3 hour at 135-140 DEG C DEG C, is placed in injection moulding machine, is processed into described Plastic Resin combining nozzle.
Advantage of the present invention is:
The high resistance auxiliary agent added in the present invention: wherein esterification butyral has good flexibility and flexibility, emulsion adhesive can promote the consistency of storeroom, and improves the mobility of melt; By softening for MBS terpolymer rear and esterification butyral, emulsion adhesive blending and modifying, greatly improve the surface resistive of finished product;
Nozzle of the present invention adopts ultrahigh molecular weight polyethylene(UHMWPE) and carbomer to be major ingredient, and the consistency of storeroom is good, and stability is high, and optimum range is wide, and long service life, damage rate is low.
Embodiment
Embodiment 1
A kind of Plastic Resin combining nozzle, is characterized in that what it was made up of the raw material of following weight parts:
Ultrahigh molecular weight polyethylene(UHMWPE) (molecular weight is 3,600,000) 100, carbomer 7, hexafluoroacetylacetone 2, potassium titanate 0.6, N, N-Diethyl Aniline 0.7, wollastonite powder 10, stearyl methacrylate 5, ammonium molybdate 1, butanethiol tin 0.1, manganese oxide 0.4, titanium dioxide 8, calcium carbonate 4, glycerine 0.5, ferrous ammonium sulphate 0.5, high resistance auxiliary agent 7;
Described high resistance auxiliary agent is made up of the raw material of following weight parts:
Neusilin 3, MBS terpolymer 40, polyvinyl butyral acetal 9, Sodium dodecylbenzene sulfonate 2, TriMethylolPropane(TMP) 0.4, nylon acid methyl esters 2, phytinic acid 0.6;
Polyvinyl butyral acetal is heated to 65 DEG C, adds nylon acid methyl esters, insulated and stirred 10 minutes, is cooled to normal temperature, obtains esterification butyral;
Sodium dodecylbenzene sulfonate is joined in 10 times of water, stir, add neusilin, phytinic acid, be uniformly mixed, obtain emulsion adhesive;
Each raw material after above-mentioned process is mixed with MBS terpolymer, send into reactor, stir, dewatered drying, adds TriMethylolPropane(TMP), at pressure 1.8MPa, temperature 84-90 DEG C, be uniformly mixed 1 hour, cooling discharging, abrasive dust, obtains described high resistance auxiliary agent.
A preparation method for Plastic Resin combining nozzle, is characterized in that comprising the following steps:
By manganese oxide, titanium dioxide mixing, add stearyl methacrylate after ball milling is even, at 70 DEG C, insulation mixing 5-10 minute, adds glycerine under stirring and adjusting, is stirred to normal temperature, obtain esterification material;
Carbomer is joined in 5 times of water, after stirring, adds ferrous ammonium sulphate, wollastonite powder, be stirred to water at 80 DEG C and do, mix with above-mentioned esterification material, add 20% of above-mentioned ultrahigh molecular weight polyethylene(UHMWPE) weight, potassium titanate, insulated and stirred 20 minutes at 105 DEG C;
Each raw material after above-mentioned process mix with residue each raw material, in feeding rubber mixing machine, at 140 DEG C mixing 3 hours, is placed in injection moulding machine, is processed into described Plastic Resin combining nozzle.
Performance test: tensile strength 34.6MPa.
Claims (2)
1. a Plastic Resin combining nozzle, is characterized in that what it was made up of the raw material of following weight parts:
Ultrahigh molecular weight polyethylene(UHMWPE) 80-100, carbomer 6-10, hexafluoroacetylacetone 1-2, potassium titanate 0.6-1, N, N-Diethyl Aniline 0.7-1, wollastonite powder 6-10, stearyl methacrylate 3-5, ammonium molybdate 1-2, butanethiol tin 0.1-0.2, manganese oxide 0.4-1, titanium dioxide 5-8, calcium carbonate 2-4, glycerine 0.5-1, ferrous ammonium sulphate 0.5-1, high resistance auxiliary agent 5-7;
Described high resistance auxiliary agent is made up of the raw material of following weight parts:
Neusilin 3-4, MBS terpolymer 30-40, polyvinyl butyral acetal 6-9, Sodium dodecylbenzene sulfonate 1-2, TriMethylolPropane(TMP) 0.4-1, nylon acid methyl esters 2-3, phytinic acid 0.6-1;
Polyvinyl butyral acetal is heated to 60-65 DEG C, adds nylon acid methyl esters, insulated and stirred 6-10 minute, be cooled to normal temperature, obtain esterification butyral;
Sodium dodecylbenzene sulfonate is joined in 8-10 times of water, stir, add neusilin, phytinic acid, be uniformly mixed, obtain emulsion adhesive;
Each raw material after above-mentioned process is mixed with MBS terpolymer, send into reactor, stir, dewatered drying, adds TriMethylolPropane(TMP), at pressure 1.8-1.9MPa, temperature 84-90 DEG C, be uniformly mixed 1-2 hour, cooling discharging, abrasive dust, obtains described high resistance auxiliary agent.
2. a preparation method for Plastic Resin combining nozzle as claimed in claim 1, is characterized in that comprising the following steps:
By manganese oxide, titanium dioxide mixing, add stearyl methacrylate after ball milling is even, at 60-70 DEG C, insulation mixing 5-10 minute, adds glycerine under stirring and adjusting, is stirred to normal temperature, obtain esterification material;
Carbomer is joined in 3-5 times of water, add ferrous ammonium sulphate, wollastonite powder after stirring, be stirred to water at 70-80 DEG C and do, mix with above-mentioned esterification material, add 10-20%, the potassium titanate of above-mentioned ultrahigh molecular weight polyethylene(UHMWPE) weight, insulated and stirred 10-20 minute at 100-105 DEG C;
Mixed with each raw material of residue by each raw material after above-mentioned process, send in rubber mixing machine, mixing 2-3 hour at 135-140 DEG C, is placed in injection moulding machine, is processed into described Plastic Resin combining nozzle.
Priority Applications (1)
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CN201410591554.3A CN104292591A (en) | 2014-10-29 | 2014-10-29 | Plastic resin composite nozzle |
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CN201410591554.3A CN104292591A (en) | 2014-10-29 | 2014-10-29 | Plastic resin composite nozzle |
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CN104292591A true CN104292591A (en) | 2015-01-21 |
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CN201410591554.3A Pending CN104292591A (en) | 2014-10-29 | 2014-10-29 | Plastic resin composite nozzle |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104774379A (en) * | 2015-03-26 | 2015-07-15 | 安徽海纳川塑业科技有限公司 | Nanometer micro-foaming polypropylene composite material |
CN104774385A (en) * | 2015-03-26 | 2015-07-15 | 安徽海纳川塑业科技有限公司 | Fiber reinforced polypropylene composite material |
CN104817655A (en) * | 2015-05-01 | 2015-08-05 | 李亮军 | Production method for heat-insulating flame-resistant material |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1580112A (en) * | 2003-08-07 | 2005-02-16 | 上海化工研究院 | Method for preparing ultrahigh molecular weight polyethylene hopper |
CN101463156A (en) * | 2007-12-19 | 2009-06-24 | 上海化工研究院天地科技发展有限公司 | Superhigh molecular weight polyethylene material and preparation thereof |
CN101585941A (en) * | 2008-05-23 | 2009-11-25 | 乐少兵 | Ultra-high molecular weight polyethylene product |
CN102964659A (en) * | 2012-11-05 | 2013-03-13 | 山西晋龙通达管业有限公司 | Multifunctional polyethylene and stainless steel composite pipe |
CN103724774A (en) * | 2013-12-31 | 2014-04-16 | 佛山佛塑科技集团股份有限公司 | Calendered alloy material and preparation method for alloy material membrane |
CN103937075A (en) * | 2014-05-06 | 2014-07-23 | 康泰塑胶科技集团有限公司 | Polyethylene corrugated pipe and preparation method thereof |
-
2014
- 2014-10-29 CN CN201410591554.3A patent/CN104292591A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1580112A (en) * | 2003-08-07 | 2005-02-16 | 上海化工研究院 | Method for preparing ultrahigh molecular weight polyethylene hopper |
CN101463156A (en) * | 2007-12-19 | 2009-06-24 | 上海化工研究院天地科技发展有限公司 | Superhigh molecular weight polyethylene material and preparation thereof |
CN101585941A (en) * | 2008-05-23 | 2009-11-25 | 乐少兵 | Ultra-high molecular weight polyethylene product |
CN102964659A (en) * | 2012-11-05 | 2013-03-13 | 山西晋龙通达管业有限公司 | Multifunctional polyethylene and stainless steel composite pipe |
CN103724774A (en) * | 2013-12-31 | 2014-04-16 | 佛山佛塑科技集团股份有限公司 | Calendered alloy material and preparation method for alloy material membrane |
CN103937075A (en) * | 2014-05-06 | 2014-07-23 | 康泰塑胶科技集团有限公司 | Polyethylene corrugated pipe and preparation method thereof |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104774379A (en) * | 2015-03-26 | 2015-07-15 | 安徽海纳川塑业科技有限公司 | Nanometer micro-foaming polypropylene composite material |
CN104774385A (en) * | 2015-03-26 | 2015-07-15 | 安徽海纳川塑业科技有限公司 | Fiber reinforced polypropylene composite material |
CN104817655A (en) * | 2015-05-01 | 2015-08-05 | 李亮军 | Production method for heat-insulating flame-resistant material |
CN104817655B (en) * | 2015-05-01 | 2017-01-11 | 金华知产婺源信息技术有限公司 | Production method for heat-insulating flame-resistant material |
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