CN104277612B - 一种电熨斗用耐高温涂料及其制备方法 - Google Patents
一种电熨斗用耐高温涂料及其制备方法 Download PDFInfo
- Publication number
- CN104277612B CN104277612B CN201410480652.XA CN201410480652A CN104277612B CN 104277612 B CN104277612 B CN 104277612B CN 201410480652 A CN201410480652 A CN 201410480652A CN 104277612 B CN104277612 B CN 104277612B
- Authority
- CN
- China
- Prior art keywords
- parts
- temperature resistant
- electric iron
- resistant coating
- mix homogeneously
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 239000011248 coating agent Substances 0.000 title claims abstract description 26
- 238000000576 coating method Methods 0.000 title claims abstract description 26
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title abstract description 10
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims abstract description 36
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims abstract description 24
- HXDLWJWIAHWIKI-UHFFFAOYSA-N 2-hydroxyethyl acetate Chemical compound CC(=O)OCCO HXDLWJWIAHWIKI-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004135 Bone phosphate Substances 0.000 claims abstract description 12
- 239000004952 Polyamide Substances 0.000 claims abstract description 12
- 229920006361 Polyflon Polymers 0.000 claims abstract description 12
- IPBVNPXQWQGGJP-UHFFFAOYSA-N acetic acid phenyl ester Natural products CC(=O)OC1=CC=CC=C1 IPBVNPXQWQGGJP-UHFFFAOYSA-N 0.000 claims abstract description 12
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims abstract description 12
- 229910000410 antimony oxide Inorganic materials 0.000 claims abstract description 12
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 claims abstract description 12
- 150000002148 esters Chemical class 0.000 claims abstract description 12
- 235000013312 flour Nutrition 0.000 claims abstract description 12
- 229940070765 laurate Drugs 0.000 claims abstract description 12
- 235000019359 magnesium stearate Nutrition 0.000 claims abstract description 12
- 235000019837 monoammonium phosphate Nutrition 0.000 claims abstract description 12
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229940049953 phenylacetate Drugs 0.000 claims abstract description 12
- WLJVXDMOQOGPHL-UHFFFAOYSA-N phenylacetic acid Chemical compound OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000049 pigment Substances 0.000 claims abstract description 12
- 229920002647 polyamide Polymers 0.000 claims abstract description 12
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 7
- 239000002253 acid Substances 0.000 abstract description 6
- 239000000853 adhesive Substances 0.000 abstract description 6
- 230000001070 adhesive effect Effects 0.000 abstract description 6
- 241000894006 Bacteria Species 0.000 abstract description 2
- 238000010409 ironing Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C09D127/18—Homopolymers or copolymers of tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
本发明提供一种电熨斗用耐高温涂料及其制备方法，该涂料以质量份计含有以下成分：聚四氟乙烯树脂14～22份，氟树脂4～8份，三聚氰胺树脂4～8份，珠光颜料2～6份，石英粉5～10份，三氧化二锑1～3份，硬脂酸镁0.2～0.3份，聚酰胺蜡0.2～0.3份，苯乙酸月桂醇酯0.7～1.2份，磷酸二氢铵0.3～0.8份，二甲基甲酰胺42～53份，乙二醇乙酸酯7～13份，聚醚三元醇4～10份。本发明提供的涂料具有耐高温、耐酸碱、防水、防粘、附着力高、耐磨性好等性能，并且具有良好的抗菌作用，能够有效防止衣物上沾染上细菌。
Description
技术领域
本发明涉及涂料领域，尤其涉及一种电熨斗用耐高温涂料及其制备方法。
背景技术
电熨斗是现代家庭必不可少的电器之一，是平整衣服和布料的工具。电熨斗结构简单，制造容易，使用方便，因而发展迅速。电熨斗的熨板是与衣物直接接触的部件，其表面使用的涂料必须具备耐高温、耐酸碱、强附着力、耐磨等性能。但是，目前使用的熨板涂料的硬度不高，耐磨性能差，并且不具有抗菌作用。
发明内容
解决的技术问题：针对现有电熨斗用涂料硬度不高、耐磨性能差以及不具有抗菌作用的缺点，本发明提供一种电熨斗用耐高温涂料及其制备方法。
技术方案：一种电熨斗用耐高温涂料，以质量份计含有以下成分：聚四氟乙烯树脂14～22份，氟树脂4～8份，三聚氰胺树脂4～8份，珠光颜料2～6份，石英粉5～10份，三氧化二锑1～3份，硬脂酸镁0.2～0.3份，聚酰胺蜡0.2～0.3份，苯乙酸月桂醇酯0.7～1.2份，磷酸二氢铵0.3～0.8份，二甲基甲酰胺42～53份，乙二醇乙酸酯7～13份，聚醚三元醇4～10份。
上述所述的一种电熨斗用耐高温涂料，以质量份计含有以下成分：聚四氟乙烯树脂17～19份，氟树脂5～6份，三聚氰胺树脂6～7份，珠光颜料4～5份，石英粉7～8份，三氧化二锑1.5～2.5份，硬脂酸镁0.23～0.26份，聚酰胺蜡0.25～0.27份，苯乙酸月桂醇酯0.8～1份，磷酸二氢铵0.5～0.6份，二甲基甲酰胺45～50份，乙二醇乙酸酯9～11份，聚醚三元醇6～8份。
上述所述的一种电熨斗用耐高温涂料的制备步骤如下：在反应釜内加入二甲基甲酰胺、乙二醇乙酸酯，混合均匀，再加入氟树脂、三聚氰胺树脂，在温度为50～60℃下搅拌1h，接着加入珠光颜料、石英粉、三氧化二锑、硬脂酸镁、聚酰胺蜡、苯乙酸月桂醇酯，混合均匀后，用球磨罐研磨20h，然后投入搅拌机，再向搅拌机内加入聚四氟乙烯树脂、磷酸二氢铵、聚醚三元醇，混合均匀后过120目筛，即得成品。
有益效果：本发明提供的一种电熨斗用耐高温涂料及其制备方法，该涂料具有耐高温、耐酸碱、防水、防粘、附着力高、耐磨性好等性能，并且具有良好的抗菌作用，能够有效防止衣物上沾染上细菌。
具体实施方式
下面结合具体实施方式对本发明进行详细描述。
实施例1
本实施例提供一种电熨斗用耐高温涂料，以质量份计含有以下成分：聚四氟乙烯树脂14份，氟树脂4份，三聚氰胺树脂4份，珠光颜料2份，石英粉5份，三氧化二锑1份，硬脂酸镁0.2份，聚酰胺蜡0.2份，苯乙酸月桂醇酯0.7份，磷酸二氢铵0.3份，二甲基甲酰胺42份，乙二醇乙酸酯7份，聚醚三元醇4份。
一种电熨斗用耐高温涂料的制备步骤如下：在反应釜内加入二甲基甲酰胺、乙二醇乙酸酯，混合均匀，再加入氟树脂、三聚氰胺树脂，在温度为50℃下搅拌1h，接着加入珠光颜料、石英粉、三氧化二锑、硬脂酸镁、聚酰胺蜡、苯乙酸月桂醇酯，混合均匀后，用球磨罐研磨20h，然后投入搅拌机，再向搅拌机内加入聚四氟乙烯树脂、磷酸二氢铵、聚醚三元醇，混合均匀后过120目筛，即得成品。
本实施例提供的涂料具有耐高温、耐酸碱、防水、防粘、附着力高、耐磨性好等性能，其对细菌的杀灭率达到98.1%。
实施例2
本实施例提供一种电熨斗用耐高温涂料，以质量份计含有以下成分：聚四氟乙烯树脂17份，氟树脂5份，三聚氰胺树脂6份，珠光颜料4份，石英粉7份，三氧化二锑1.5份，硬脂酸镁0.23份，聚酰胺蜡0.25份，苯乙酸月桂醇酯0.8份，磷酸二氢铵0.5份，二甲基甲酰胺45份，乙二醇乙酸酯9份，聚醚三元醇6份。
一种电熨斗用耐高温涂料的制备步骤如下：在反应釜内加入二甲基甲酰胺、乙二醇乙酸酯，混合均匀，再加入氟树脂、三聚氰胺树脂，在温度为60℃下搅拌1h，接着加入珠光颜料、石英粉、三氧化二锑、硬脂酸镁、聚酰胺蜡、苯乙酸月桂醇酯，混合均匀后，用球磨罐研磨20h，然后投入搅拌机，再向搅拌机内加入聚四氟乙烯树脂、磷酸二氢铵、聚醚三元醇，混合均匀后过120目筛，即得成品。
本实施例提供的涂料具有耐高温、耐酸碱、防水、防粘、附着力高、耐磨性好等性能，其对细菌的杀灭率达到97.8%。
实施例3
本实施例提供一种电熨斗用耐高温涂料，以质量份计含有以下成分：聚四氟乙烯树脂19份，氟树脂6份，三聚氰胺树脂7份，珠光颜料5份，石英粉8份，三氧化二锑2.5份，硬脂酸镁0.26份，聚酰胺蜡0.27份，苯乙酸月桂醇酯1份，磷酸二氢铵0.6份，二甲基甲酰胺50份，乙二醇乙酸酯11份，聚醚三元醇8份。
一种电熨斗用耐高温涂料的制备步骤如下：在反应釜内加入二甲基甲酰胺、乙二醇乙酸酯，混合均匀，再加入氟树脂、三聚氰胺树脂，在温度为55℃下搅拌1h，接着加入珠光颜料、石英粉、三氧化二锑、硬脂酸镁、聚酰胺蜡、苯乙酸月桂醇酯，混合均匀后，用球磨罐研磨20h，然后投入搅拌机，再向搅拌机内加入聚四氟乙烯树脂、磷酸二氢铵、聚醚三元醇，混合均匀后过120目筛，即得成品。
本实施例提供的涂料具有耐高温、耐酸碱、防水、防粘、附着力高、耐磨性好等性能，其对细菌的杀灭率达到98.5%。
以上对本发明实施例进行了详细介绍，对于本领域的一般技术人员，依据本发明实施例的思想，在具体实施方式及应用范围上均会有改变之处，综上所述，本说明书内容不应理解为对本发明的限制。
Claims (1)
1.一种电熨斗用耐高温涂料，其特征在于，以质量份计含有以下成分：聚四氟乙烯树脂17～19份，氟树脂5～6份，三聚氰胺树脂6～7份，珠光颜料4～5份，石英粉7～8份，三氧化二锑1.5～2.5份，硬脂酸镁0.23～0.26份，聚酰胺蜡0.25～0.27份，苯乙酸月桂醇酯0.8～1份，磷酸二氢铵0.5～0.6份，二甲基甲酰胺45～50份，乙二醇乙酸酯9～11份，聚醚三元醇6～8份；
所述的一种电熨斗用耐高温涂料通过以下制备方法制备得到：在反应釜内加入二甲基甲酰胺、乙二醇乙酸酯，混合均匀，再加入氟树脂、三聚氰胺树脂，在温度为50～60℃下搅拌1h，接着加入珠光颜料、石英粉、三氧化二锑、硬脂酸镁、聚酰胺蜡、苯乙酸月桂醇酯，混合均匀后，用球磨罐研磨20h，然后投入搅拌机，再向搅拌机内加入聚四氟乙烯树脂、磷酸二氢铵、聚醚三元醇，混合均匀后过120目筛，即得成品。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410480652.XA CN104277612B (zh) | 2014-09-19 | 2014-09-19 | 一种电熨斗用耐高温涂料及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410480652.XA CN104277612B (zh) | 2014-09-19 | 2014-09-19 | 一种电熨斗用耐高温涂料及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104277612A CN104277612A (zh) | 2015-01-14 |
| CN104277612B true CN104277612B (zh) | 2016-07-13 |
Family
ID=52252978
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410480652.XA Expired - Fee Related CN104277612B (zh) | 2014-09-19 | 2014-09-19 | 一种电熨斗用耐高温涂料及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104277612B (zh) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1168403A (zh) * | 1997-05-20 | 1997-12-24 | 吉林大学 | 炊具、家电用高、低温烧结pes防沾涂料的制备 |
| CN103131277A (zh) * | 2011-11-23 | 2013-06-05 | 天津市新丽华色材有限责任公司 | 一种耐高温不脱落的涂料及其制备方法 |
| CN103214897A (zh) * | 2013-03-19 | 2013-07-24 | 宁波墨西新材料有限公司 | 一种石墨烯不粘涂料 |
-
2014
- 2014-09-19 CN CN201410480652.XA patent/CN104277612B/zh not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1168403A (zh) * | 1997-05-20 | 1997-12-24 | 吉林大学 | 炊具、家电用高、低温烧结pes防沾涂料的制备 |
| CN103131277A (zh) * | 2011-11-23 | 2013-06-05 | 天津市新丽华色材有限责任公司 | 一种耐高温不脱落的涂料及其制备方法 |
| CN103214897A (zh) * | 2013-03-19 | 2013-07-24 | 宁波墨西新材料有限公司 | 一种石墨烯不粘涂料 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104277612A (zh) | 2015-01-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104327712B (zh) | 一种高附着力耐磨工程机械防水涂料 | |
| CN104562661A (zh) | 棉麻面料的整理工艺 | |
| CN104532557A (zh) | 服装面料的整理工艺 | |
| CN105274834A (zh) | 针织面料的后整理工艺 | |
| CN104452291A (zh) | 羊毛面料的整理工艺 | |
| CN104606072A (zh) | 一种硅处理绢云母粉的制备方法 | |
| CN104419313A (zh) | 一种用于无粉pvc手套的水性聚氨酯组合物及其制备方法 | |
| CN104562708B (zh) | 一种抗静电涤纶台布的制备方法 | |
| CN105064012A (zh) | 一种服装面料的整理工艺 | |
| CN104452275A (zh) | 家纺面料的整理工艺 | |
| CN104277612B (zh) | 一种电熨斗用耐高温涂料及其制备方法 | |
| CN104480709A (zh) | 上衣面料的整理工艺 | |
| CN103709498A (zh) | 一种吸音棉用含黄麻杆的无纺布材料 | |
| CN103741326A (zh) | 一种耐磨的棉麻面料的制备方法 | |
| CN103710878A (zh) | 一种吸音棉用含硅藻土的无纺布材料 | |
| CN104452289A (zh) | 衬衫面料的整理工艺 | |
| CN104452312A (zh) | 牛仔面料的整理工艺 | |
| CN103087620B (zh) | 一种双组份银色底漆 | |
| CN104386735A (zh) | 氧化锌的制备方法 | |
| CN104562639A (zh) | 床单面料的整理工艺 | |
| CN105484035A (zh) | 化纤面料的后整理工艺 | |
| CN106221352A (zh) | 一种涂料用疏水型纳米二氧化硅的制备方法 | |
| CN105860676A (zh) | 一种电子产品喷涂底漆 | |
| CN103898743A (zh) | 一种衣物柔顺剂 | |
| CN104294611B (zh) | 衣服防水整理方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160713 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |