CN104275908A - Method for preparing high-brightness reflective fabric - Google Patents

Method for preparing high-brightness reflective fabric Download PDF

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Publication number
CN104275908A
CN104275908A CN201410500905.5A CN201410500905A CN104275908A CN 104275908 A CN104275908 A CN 104275908A CN 201410500905 A CN201410500905 A CN 201410500905A CN 104275908 A CN104275908 A CN 104275908A
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Prior art keywords
compound
composite
high brightness
reflective fabric
preparation
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CN201410500905.5A
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CN104275908B (en
Inventor
王世杰
查伟强
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Zhejiang Xinghua New Materials Group Co.,Ltd.
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HANGZHOU XINGHUA REFLECTIVE MATERIALS CO Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/02Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/15Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/26Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer which influences the bonding during the lamination process, e.g. release layers or pressure equalising layers
    • B32B2037/268Release layers

Abstract

The invention relates to the field of manufacturing of reflective fabrics and in particular relates to a method for preparing a high-brightness reflective fabric. The method comprises the following process flows: (1) coating a bead embedding adhesive layer on a PET film, and drying through a drying box, thereby obtaining a bead embedding adhesive layer; (2) placing the bead embedding adhesive layer prepared in the step (1) in a glass bead groove for embedding beads, embedding the glass beads into the bead embedding adhesives for realizing bead embedding through the actions of a composite roller and a compression roller; (3) transferring a semi-finished product subjected to bead embedding in the step (2) into coating equipment, turning metals from a solid state into a gaseous state through a resistance heating mode, and desublimating the metals into a metal coating when meeting a bead embedding film; (4) coating a composite adhesive layer on the surface of a base fabric, drying the solvent, compounding a reflective layer, and compounding through blanching; and (5) stripping to remove the PET film and the bead embedding adhesive layer, thereby obtaining the finished product. The key control of the high-brightness reflective fabric refers to raw material selection and blending of the composite adhesive, namely the composite adhesive layer has the effect of adhering the reflective layer and the base fabric, the washing resistance of the composite reflective layer determines the quality of the washed product, the higher the viscosity of the composite adhesive is, the higher the washing resistance is, and the brightness of the washed high-brightness reflective fabric is higher.

Description

A kind of preparation method of high brightness reflective fabric
Technical field
The present invention relates to reflective fabric and manufacture field, particularly, relate to a kind of preparation method of high brightness reflective fabric.
Background technology
Reflection fabric is the closely bound up high-tech product of a kind of wide model is applied to traffic safety equipment, pad pasting, protective garment, work clothes, uniform equal people the security of the lives and property.This Reflection fabric uses the glass microballoon retroreflecting principle of high index of refraction, and made by the advanced technologies of post processing of focusing, distant place direct light line reflection can be postbacked light place by it, no matter just all have good reflex reflection optical property at night or daytime.Especially evening, the high-visibility as daytime can be played, its appearance solves " in sight " and " seeing " this driving at night difficult problem smoothly, use the work clothes that this high-visibility Reflection fabric makes, no matter disturb at light or scattered light, or when remote place, can be found by nighttime driving person with comparalive ease.
In the preparation of Reflection fabric, adhesive is as the function served as bridge such as bonding of bonding glass microballoon, bonded fabric, layer and layer, directly affect the fastness of whole product, the good reflective fabric of its adhesive fastness stands friction more repeatedly and washing when taking with clothes, and service life is just long.Except except glass microballoon and reflecting layer, the glistening intensity to reflectorized material plays a decisive role, the transparency of the adhesive of both connections is also the key factor affecting reflective function.
Along with the development of national economy and the raising of living standards of the people, the safety problem of the ordinary person of transportation work personnel and walking at night is extremely urgent, due to 3M and most domestic reflectorized material producer, to prepare reflective fabric process costs higher, speed of production is slower, under restriction such as many factors such as raw material sources scope narrower grade, need to develop the technique that a kind of cost is lower, speed of production is fast, new and make reflective fabric.
Summary of the invention
The object of this invention is to provide that a kind of production cost is low, speed of production is fast, wash durability is good, the preparation method of the high brightness reflective fabric that brightness is high after washing.
Technical scheme of the present invention is as follows: a kind of preparation method of high brightness reflective fabric, and technological process is: (1) prepares plant glue-line, PET film is coated with one deck and plants pearl glue, namely obtain plant glue-line through oven for drying, (2) glass microballoon is implanted, obtained for step (1) pearl glue-line of planting is placed in glass microballoon groove and carries out planting pearl, by composite roll and pressure roller effect, glass microballoon is nuzzled plant in pearl glue and realize plant, (3) metal cladding, semi-finished product good for plant in step (2) are proceeded in filming equipment, pass through resistance heating manner, metal becomes gaseous state from Solid State Transformation, the coat of metal is sublimated into after meeting beads formed film, namely compound reflecting layer is made, and composite for base fabric (4), one deck composite layer is coated with at scrim surfaces, blanching compound is passed through with compound reflecting layer after dry out solvent, (5) stripping removing PET film and plant glue-line obtain finished product, pearl glue of planting in described step (1) is made up of the raw material of following weight portion: matrix resin 60 parts, curing agent 0-3 part, diluent 0-30 part, the degree of depth that in described step (2), glass microballoon is implanted is 1-50um, compound adhesive in described step (4) is made up of the raw material of following weight portion: matrix resin 60 parts, curing agent 1-9 part, auxiliary agent 0-3 part, diluent 10-30 part, color stuffing 0-5 part, in step (4) compound reflecting layer and composite layer compound tense two-layer between there is air layer, the degree of depth that compound tense glass microballoon implants composite layer is 10-70um.
Further, the matrix resin in described plant glue is the one in water soluble acrylic acid pressure sensitive adhesive, waterborne polyurethane pressure-sensitive adhesives, oiliness acrylate pressure sensitive adhesive, oiliness polyurethane contact adhesive; In described compound adhesive, matrix resin is the one in solvent type acrylic resin, solvent borne polyurethane.
Further, in described plant glue and compound adhesive, curing agent is the one in isocyanate curing agent, aziridine hardener, amino resin curing agents.
Further, in described plant glue, diluent is the one in deionized water, ethyl acetate, toluene, butanone, butyl acetate, dimethylbenzene; In described compound adhesive, diluent is the one in ethyl acetate, toluene, butanone, butyl acetate, dimethylbenzene.
Further, in described compound adhesive, auxiliary agent is one or more in wetting agent, dispersant, coupling agent.
Further, in described compound adhesive, color stuffing is one or more in toner, mill base, calcium carbonate, kaolin, titanium dioxide, silica.
Closer, described compound adhesive allocating technology is:
(1) by after color stuffing Homogeneous phase mixing, add diluent and carry out grinding distribution 20 ~ 60 minutes;
(2) joined by auxiliary agent in the mixed material of step (1) gained, high-speed stirred is after 20 ~ 60 minutes, with 80 ~ 200 mesh screen corase particleses;
(3) matrix resin, curing agent are joined successively in the mixed material of step (2) gained, stir half an hour more than, be compound adhesive finished product.
As preferably, the coat of metal in described step (3) is aluminium metal coating, Titanium coating, metallic zinc coating;
As preferably, in described step (4), base material is the one in TC cloth, chemical fabric, oxford, stretch fabric, leather.
As preferably, the blanching composite steps in described step (4), heat iron temperature is 70-90 DEG C, and blanching pressure is 0.2MPa-0.6MPa.
As preferably, the thickness of described plant glue-line is 10-100um, and the thickness of the described coat of metal is 0.1nm-100nm, and the thickness of described composite layer is 50um-500um.
Compared with prior art, beneficial effect of the present invention is:
(1) compound reflecting layer plays reflection action, realize its under light-illuminating night reflection, reach warning function;
(2) the pass key control of this highlighted reflective fabric is that the raw material of compound adhesive is selected and allotment: the effect of composite layer is used to bond compound reflecting layer and base cloth, and the wash durability of compound reflecting layer, decide the quality after product washing, compound adhesive viscosity is better, wash durability is better, and the brightness after the washing of high brightness reflective fabric is higher;
(3) this production technology plant speed is fast, and speed of production is accelerated, and delivery date shortens, and the cost of raw material reduces, and the product produced can meet guarantee washing and brightness simultaneously.
accompanying drawing illustrates:
Fig. 1 is the semi-finished product structure schematic diagram after a kind of high brightness reflective fabric plant;
Fig. 2 is the semi-finished product structure schematic diagram after a kind of high brightness reflective fabric plating;
Fig. 3 is the structural representation after a kind of high brightness reflective fabric composite steps completes;
Fig. 4 is finished product structure schematic diagram after a kind of high brightness reflective fabric is peeled off;
Wherein, 1.PET film; 2. plant glue; 3. glass microballoon; 4. the coat of metal; 5. compound adhesive; 6. base cloth; 7. air layer.
Detailed description of the invention
A preparation method for high brightness reflective fabric, technological process is: (1) prepares plant glue-line, PET film is coated with one deck and plants pearl glue, namely obtain plant glue-line through oven for drying, (2) glass microballoon is implanted, obtained for step (1) pearl glue-line of planting is placed in glass microballoon groove and carries out planting pearl, by composite roll and pressure roller effect, glass microballoon is nuzzled plant in pearl glue and realize plant, (3) metal cladding, semi-finished product good for plant in step (2) are proceeded in vacuum coating equipment, pass through resistance heating manner, metal becomes gaseous state from Solid State Transformation, the coat of metal is sublimated into after meeting beads formed film, namely compound reflecting layer is made, and composite for base fabric (4), one deck composite layer is coated with at scrim surfaces, blanching compound is passed through with compound reflecting layer after dry out solvent, (5) stripping removing PET film and plant glue-line obtain finished product.
Embodiment 1
Plant glue formula is: water soluble acrylic acid pressure sensitive adhesive 60 parts, isocyanate curing agent 1 part, deionized water 20 parts; The formula of compound adhesive is: solvent type acrylic resin 60 parts, aziridine hardener 1 part, 20 parts, ethyl acetate, toner and mill base totally 5 parts;
The thickness of plant glue-line is 10um, and the thickness of the coat of metal is 100nm, and the thickness of composite layer is 50um, and wherein, base cloth is TC cloth, and the coat of metal is aluminium metal coating, and blanching compound condition is: heat iron temperature 70 DEG C, and blanching pressure is 0.6MPa.
Embodiment 2
Plant glue formula is: waterborne polyurethane pressure-sensitive adhesives 60 parts, 30 parts, ethyl acetate; The formula of compound adhesive is: solvent borne polyurethane 60 parts, amino resin curing agents 8 parts, wetting agent 2 parts, butanone 15 parts; The thickness of plant glue-line is 20um, and the thickness of the coat of metal is 80nm, and the thickness of composite layer is 150um, and wherein, base cloth is leather, and the coat of metal is metallic zinc coating, and blanching compound condition is: heat iron temperature 75 DEG C, and blanching pressure is 0.2MPa.
Embodiment 3
Plant glue formula is: oiliness acrylate pressure sensitive adhesive 60 parts, aziridine hardener 2 parts, toluene 10 parts; The formula of compound adhesive is: solvent type acrylic resin 60 parts, isocyanate curing agent 6 parts, wetting agent 1 part, 10 parts, ethyl acetate, 3 parts, calcium carbonate;
The thickness of plant glue-line is 30um, and the thickness of the coat of metal is 50nm, and the thickness of composite layer is 250um, and wherein, base cloth is chemical fabric, and the coat of metal is Titanium coating, and blanching compound condition is: heat iron temperature 80 DEG C, and blanching pressure is 0.3MPa.
Embodiment 4
Plant glue formula is: oiliness polyurethane contact adhesive 60 parts, aziridine hardener 3 parts; The formula of compound adhesive is: solvent borne polyurethane 60 parts, amino resin curing agents 9 parts, dispersant 1 part, toluene 25 parts, kaolin 5 parts; The thickness of plant glue-line is 80um, and the thickness of the coat of metal is 40nm, and the thickness of composite layer is 200um, and wherein, base cloth is oxford, and the coat of metal is metallic zinc coating, and blanching compound condition is: heat iron temperature 85 DEG C, and blanching pressure is 0.4MPa.
Embodiment 5
Plant glue formula is: water soluble acrylic acid pressure sensitive adhesive 60 parts, amino resin curing agents 3 parts, butyl acetate 25 parts; The formula of compound adhesive is: solvent type acrylic resin 60 parts, isocyanate curing agent 2 parts, coupling agent 2 parts, dimethylbenzene 30 parts, titanium dioxide 4 parts; The thickness of plant glue-line is 100um, and the thickness of the coat of metal is 10nm, and the thickness of composite layer is 300um, and wherein, base cloth is oxford, and the coat of metal is Titanium coating, and blanching compound condition is: heat iron temperature 90 DEG C, and blanching pressure is 0.5MPa.
Embodiment 6
Plant glue formula is: oiliness polyurethane contact adhesive 60 parts, amino resin curing agents 1 part, dimethylbenzene 5 parts; The formula of compound adhesive is: solvent borne polyurethane 60 parts, aziridine hardener 4 parts, coupling agent 3 parts, butyl acetate 20 parts, silica 2 parts; The thickness of plant glue-line is 25um, and the thickness of the coat of metal is 0.1nm, and the thickness of composite layer is 500um, and wherein, base cloth is stretch fabric, and the coat of metal is aluminium metal coating, and blanching compound condition is: heat iron temperature 82 DEG C, and blanching pressure is 0.6MPa.
Technique scheme only embodies the preferred embodiment of the present invention, can not be interpreted as the restriction to authorized range of the present invention, and all distortion of making according to the present invention and improvement, all belong to scope.

Claims (10)

1. a preparation method for high brightness reflective fabric, is characterized in that: technological process is: (1) prepares plant glue-line, PET film is coated with one deck and plants pearl glue, namely obtain plant glue-line through oven for drying, (2) glass microballoon is implanted, obtained for step (1) pearl glue-line of planting is placed in glass microballoon groove and carries out planting pearl, by composite roll and pressure roller effect, glass microballoon is nuzzled plant in pearl glue and realize plant, (3) metal cladding, semi-finished product good for plant in step (2) are proceeded in vacuum coating equipment, pass through resistance heating manner, metal becomes gaseous state from Solid State Transformation, the coat of metal is sublimated into after meeting beads formed film, namely compound reflecting layer is made, and composite for base fabric (4), one deck composite layer is coated with at scrim surfaces, blanching compound is passed through with compound reflecting layer after dry out solvent, (5) stripping removing PET film and plant glue-line obtain finished product, pearl glue of planting in described step (1) is made up of the raw material of following weight portion: matrix resin 60 parts, curing agent 0-3 part, diluent 0-30 part, the degree of depth that in described step (2), glass microballoon is implanted is 1-50um, compound adhesive in described step (4) is made up of the raw material of following weight portion: matrix resin 60 parts, curing agent 1-9 part, auxiliary agent 0-3 part, diluent 10-30 part, color stuffing 0-5 part, in step (4) compound reflecting layer and composite layer compound tense two-layer between there is air layer, the degree of depth that compound tense glass microballoon implants composite layer is 10-70um.
2. the preparation method of a kind of high brightness reflective fabric according to claim 1, it is characterized in that, the matrix resin in described plant glue is the one in water soluble acrylic acid pressure sensitive adhesive, waterborne polyurethane pressure-sensitive adhesives, oiliness acrylate pressure sensitive adhesive, oiliness polyurethane contact adhesive; In described compound adhesive, matrix resin is the one in solvent type acrylic resin, solvent borne polyurethane.
3. the preparation method of a kind of high brightness reflective fabric according to claim 1, is characterized in that, in described plant glue and compound adhesive, curing agent is the one in isocyanate curing agent, aziridine hardener, amino resin curing agents.
4. the preparation method of a kind of high brightness reflective fabric according to claim 1, is characterized in that, in described plant glue, diluent is the one in deionized water, ethyl acetate, toluene, butanone, butyl acetate, dimethylbenzene; In described compound adhesive, diluent is the one in ethyl acetate, toluene, butanone, butyl acetate, dimethylbenzene.
5. the preparation method of a kind of high brightness reflective fabric according to claim 1, is characterized in that, in described compound adhesive, auxiliary agent is one or more in wetting agent, dispersant, coupling agent.
6. the preparation method of a kind of high brightness reflective fabric according to claim 1, is characterized in that, in described compound adhesive, color stuffing is one or more in toner, mill base, calcium carbonate, kaolin, titanium dioxide, silica.
7. the preparation method of a kind of high brightness reflective fabric according to claim 1, is characterized in that, the coat of metal in described step (3) is aluminium metal coating, Titanium coating, metallic zinc coating.
8. the preparation method of a kind of high brightness reflective fabric according to claim 1, is characterized in that, in described step (4), base material is the one in TC cloth, chemical fabric, oxford, stretch fabric, leather.
9. the preparation method of a kind of high brightness reflective fabric according to claim 1, is characterized in that, the blanching composite steps in described step (4), and heat iron temperature is 70-90 DEG C, and blanching pressure is 0.2MPa-0.6MPa.
10. the preparation method of a kind of high brightness reflective fabric according to claim 1, is characterized in that, the thickness of described plant glue-line is 10-100um, and the thickness of the described coat of metal is 0.1nm-100nm, and the thickness of described composite layer is 50um-500um.
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Cited By (13)

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CN105001814A (en) * 2015-07-30 2015-10-28 安徽硕明安全科技有限公司 Bright silver reflective fabric complex adhesive and preparation method thereof
CN107290811A (en) * 2017-08-18 2017-10-24 深圳市联星服装辅料有限公司 A kind of reflective leather label and preparation method thereof
CN107373919A (en) * 2017-08-30 2017-11-24 深圳市联星服装辅料有限公司 A kind of hidden color Reflection zip fastener and preparation method thereof
CN108165185A (en) * 2017-12-28 2018-06-15 振德医疗用品股份有限公司 A kind of double faced adhesive tape composite structure and its complex method
CN108919396A (en) * 2018-08-24 2018-11-30 福建夜光达科技股份有限公司 A kind of changeable reflective fabric of phantom and preparation method thereof
CN109137536A (en) * 2018-08-29 2019-01-04 佛山皖和新能源科技有限公司 A kind of preparation method of high brightness wide angle refecting material
CN111610585A (en) * 2020-06-17 2020-09-01 南阳市新长兴光学科技有限公司 Flexible washable colorful reflective fabric
CN111650679A (en) * 2020-06-17 2020-09-11 南阳市新长兴光学科技有限公司 Processing technology of flexible washable reflective fabric
CN112099120A (en) * 2020-09-15 2020-12-18 浙江夜光明光电科技股份有限公司 Super-soft reflective cloth and preparation method thereof
CN112776434A (en) * 2021-01-20 2021-05-11 南阳市新长兴光学科技有限公司 Manufacturing method of flexible noctilucent cloth
CN114905754A (en) * 2021-07-21 2022-08-16 杭州星华反光材料股份有限公司 Production process and application of high-brightness colorful reflective garment
CN114907795A (en) * 2021-07-22 2022-08-16 杭州星华反光材料股份有限公司 Composite adhesive for highlight chemical fiber material and preparation method thereof
CN114921201A (en) * 2021-07-22 2022-08-19 杭州星华反光材料股份有限公司 Adhesive composition for highlight reflective heat patch and preparation method thereof

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WO1996008737A1 (en) * 1994-09-16 1996-03-21 Minnesota Mining And Manufacturing Company Retroreflective article that has phenolic resin in chemical association with reflective aluminum layer
CN203543247U (en) * 2013-06-04 2014-04-16 杭州星华反光材料有限公司 Water-based adhesive reflective fabric forming structure
CN103529504A (en) * 2013-09-28 2014-01-22 杭州星华反光材料有限公司 Production process of reflective thermal attachment film and special production line thereof
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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105001814A (en) * 2015-07-30 2015-10-28 安徽硕明安全科技有限公司 Bright silver reflective fabric complex adhesive and preparation method thereof
CN107290811A (en) * 2017-08-18 2017-10-24 深圳市联星服装辅料有限公司 A kind of reflective leather label and preparation method thereof
CN107373919A (en) * 2017-08-30 2017-11-24 深圳市联星服装辅料有限公司 A kind of hidden color Reflection zip fastener and preparation method thereof
CN108165185A (en) * 2017-12-28 2018-06-15 振德医疗用品股份有限公司 A kind of double faced adhesive tape composite structure and its complex method
CN108919396A (en) * 2018-08-24 2018-11-30 福建夜光达科技股份有限公司 A kind of changeable reflective fabric of phantom and preparation method thereof
CN109137536A (en) * 2018-08-29 2019-01-04 佛山皖和新能源科技有限公司 A kind of preparation method of high brightness wide angle refecting material
CN111650679B (en) * 2020-06-17 2022-11-15 南阳市新长兴光学科技有限公司 Processing technology of flexible washable reflective fabric
CN111610585A (en) * 2020-06-17 2020-09-01 南阳市新长兴光学科技有限公司 Flexible washable colorful reflective fabric
CN111650679A (en) * 2020-06-17 2020-09-11 南阳市新长兴光学科技有限公司 Processing technology of flexible washable reflective fabric
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