CN114905754A - Production process and application of high-brightness colorful reflective garment - Google Patents
Production process and application of high-brightness colorful reflective garment Download PDFInfo
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- CN114905754A CN114905754A CN202110825457.6A CN202110825457A CN114905754A CN 114905754 A CN114905754 A CN 114905754A CN 202110825457 A CN202110825457 A CN 202110825457A CN 114905754 A CN114905754 A CN 114905754A
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 20
- 230000001070 adhesive effect Effects 0.000 claims abstract description 70
- 239000000853 adhesive Substances 0.000 claims abstract description 66
- 239000011324 bead Substances 0.000 claims abstract description 38
- 239000002131 composite material Substances 0.000 claims abstract description 29
- 239000004744 fabric Substances 0.000 claims abstract description 20
- 238000002360 preparation method Methods 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 11
- 238000007731 hot pressing Methods 0.000 claims abstract description 9
- 238000005520 cutting process Methods 0.000 claims abstract description 8
- 238000009958 sewing Methods 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 229920002635 polyurethane Polymers 0.000 claims description 13
- 239000004814 polyurethane Substances 0.000 claims description 13
- 150000004696 coordination complex Chemical class 0.000 claims description 9
- 239000003431 cross linking reagent Substances 0.000 claims description 9
- 239000011521 glass Substances 0.000 claims description 8
- 239000004848 polyfunctional curative Substances 0.000 claims description 7
- 239000003522 acrylic cement Substances 0.000 claims description 6
- 239000006184 cosolvent Substances 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000012948 isocyanate Substances 0.000 claims description 5
- 239000005083 Zinc sulfide Substances 0.000 claims description 4
- 229910052984 zinc sulfide Inorganic materials 0.000 claims description 4
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 4
- 150000002513 isocyanates Chemical group 0.000 claims description 3
- 238000007738 vacuum evaporation Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 2
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 40
- 238000003756 stirring Methods 0.000 description 12
- 239000003292 glue Substances 0.000 description 8
- 229920000139 polyethylene terephthalate Polymers 0.000 description 8
- 239000005020 polyethylene terephthalate Substances 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000000835 fiber Substances 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- -1 polyethylene terephthalate Polymers 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000002513 implantation Methods 0.000 description 3
- 239000004005 microsphere Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 230000032798 delamination Effects 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- 239000004971 Cross linker Substances 0.000 description 1
- 206010039203 Road traffic accident Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
- A41D13/01—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches with reflective or luminous safety means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
- B29C65/4805—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
- B29C65/483—Reactive adhesives, e.g. chemically curing adhesives
- B29C65/4835—Heat curing adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/40—General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
- B29C66/41—Joining substantially flat articles ; Making flat seams in tubular or hollow articles
- B29C66/45—Joining of substantially the whole surface of the articles
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06Q—DECORATING TEXTILES
- D06Q1/00—Decorating textiles
- D06Q1/10—Decorating textiles by treatment with, or fixation of, a particulate material, e.g. mica, glass beads
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Physical Education & Sports Medicine (AREA)
- Illuminated Signs And Luminous Advertising (AREA)
- Optical Elements Other Than Lenses (AREA)
Abstract
The invention relates to the field of reflective materials, in particular to a production process and application of a high-brightness colorful reflective garment, wherein the process comprises the following steps: and (3) combining the bead planting film and the base material by hot pressing of an adhesive, stripping the PET layer of the bead planting film, and cutting and sewing to obtain the adhesive. The high-brightness colorful reflective garment prepared by the invention has good reflective and luminous effects at night, the effective distance of reflective and luminous is long, the garment is suitable for people working at night to wear, the adhesive property of the cloth composite adhesive and the hot-stick composite adhesive is good, the garment has excellent waterproofness and water washing resistance, the adhesive effect is still good after multiple washing, the bead planting film and the base material can be kept from falling off and edge warping, the process is simple, the preparation raw materials are simple and easy to obtain, and the application prospect is very wide.
Description
Technical Field
The invention relates to the field of reflective materials, in particular to a production process and application of a high-brightness colorful reflective garment.
Background
The reflective garment is a special garment which reflects a weak light source at night or in a dark environment so as to reduce traffic accidents at night, the effective distance between reflective light and noctilucence can reach 500m, in the prior art, a reflective film or a reflective material is usually adhered to the surface of the garment through an adhesive, and the reflective garment is obtained by further pressing, cutting and shaping. When the reflective garment is operated in severe conditions such as rainstorm, snowstorm, low temperature and high temperature, the adhesive components in the reflective garment are easy to deform, the viscosity is reduced, part of the reflective film is warped and falls off, and the night operation safety is affected, so that the development of the high-brightness colorful reflective garment with high weather resistance has great application significance.
Disclosure of Invention
The invention provides a production process of high-brightness colorful reflective clothes, which comprises the following steps: and (3) combining the bead planting film and the base material by hot pressing of an adhesive, stripping the PET layer of the bead planting film, and cutting and sewing to obtain the adhesive.
As a preferred embodiment, the process comprises: coating an adhesive on the surface of a base material, attaching a bead planting film on the adhesive, carrying out hot-press combination, stripping a PET (polyethylene terephthalate) layer of the bead planting film, and cutting and sewing to obtain the adhesive.
In a preferred embodiment, the base material includes any one of highlight strip colored chemical fiber, highlight magic colored chemical fiber, highlight full colored chemical fiber and highlight strip colored heat paste.
As a preferred embodiment, the adhesive is coated to a thickness of 1 μm to 0.08 mm.
Preferably, the coating thickness of the adhesive is 2 μm to 0.06 mm.
Preferably, the coating thickness of the adhesive is 3 μm to 0.04 mm.
As a preferred embodiment, the temperature of the hot pressing is 40 to 200 ℃.
Preferably, the temperature of the hot pressing is 50 to 150 ℃.
Preferably, the temperature of the hot pressing is 50 to 120 ℃.
As a preferable embodiment, the particle size of the glass microspheres in the bead planting film is 10-100 μm.
Preferably, the particle size of the glass microspheres in the bead planting film is 15-90 μm.
Preferably, the refractive index of the glass microspheres in the bead planting film ranges from 1.91 to 2.22.
Preferably, the implantation depth of the glass beads in the bead planting film is 15-50 μm.
In a preferred embodiment, the adhesive comprises a cloth composite adhesive and a heat-sealing composite adhesive.
As a preferred embodiment, the preparation raw materials of the cloth compound adhesive comprise the following components in parts by weight: 120-200 parts of acrylic adhesive, 1-5 parts of metal complex, 0.5-2 parts of cross-linking agent, 1-3 parts of curing agent and 40-60 parts of solvent.
Preferably, the preparation raw materials of the cloth composite adhesive comprise: 120-180 parts of acrylic adhesive, 2-5 parts of metal complex, 0.5-1.5 parts of cross-linking agent, 1.5-3 parts of curing agent and 45-55 parts of solvent.
Preferably, the preparation raw materials of the cloth composite adhesive comprise: 150 parts of acrylic adhesive, 3 parts of metal complex, 1 part of cross-linking agent, 2.5 parts of curing agent and 50 parts of solvent.
As a preferred embodiment, the acrylic adhesive comprises any one of BX-807, BX-806 and BX-805.
Preferably, the acrylic adhesive is BX-807.
Preferably, the BX-807 has a solid content of 36%.
Preferably, the viscosity of the BX-807 is 4000-6000 mPa.s.
As a preferred embodiment, the metal complex is B-56.
In a preferred embodiment, the crosslinker is of type 2088.
As a preferred embodiment, the curing agent is an isocyanate curing agent.
Preferably, the curing agent is an aromatic isocyanate curing agent.
Preferably, the curing agent comprises any one of Bayer N-75, Bayer N-3390 and Bayer L-75.
Preferably, the curing agent is Bayer L-75.
As a preferred embodiment, the solvent includes any one of ethyl acetate, toluene, butanone, acetone, xylene, cyclohexanone, and water.
Preferably, the solvent is butanone.
As a preferred embodiment, the preparation method of the cloth compound adhesive comprises the following steps: adding 10 parts of butanone into a first reaction kettle, then respectively adding 149 parts of BX-807 and 1 part of cross-linking agent, and stirring; adding 25 parts of butanone and 1 part of BX-807 into a second reaction kettle, adding 3 parts of B-56, and stirring; pouring the mixture in the first reaction kettle into a second reaction kettle, and slowly adding 15 parts of butanone into the first reaction kettle for dilution; and continuously adding 2.5 parts of Bayer L-75 into the second reaction kettle, and stirring to obtain the catalyst.
As a preferred embodiment, the preparation raw materials of the thermal patch composite adhesive comprise, by weight: 2-8 parts of complex dye, 60-90 parts of cosolvent, 10-50 parts of polyurethane adhesive, 100-150 parts of adhesive and 5-10 parts of hardener.
Preferably, the raw materials for preparing the thermal adhesive compound glue comprise: 3-6 parts of complex dye, 70-85 parts of cosolvent, 20-40 parts of polyurethane adhesive, 100-130 parts of adhesive and 5-8 parts of hardener.
Preferably, the raw materials for preparing the thermal adhesive compound glue comprise: 5 parts of complex dye, 75 parts of cosolvent, 30 parts of polyurethane adhesive, 130 parts of adhesive and 7 parts of hardening agent.
As a preferred embodiment, the complex dye is B-56.
As a preferred embodiment, the cosolvent comprises any one of ethyl acetate, toluene, butanone, acetone, xylene, cyclohexanone and water.
Preferably, the cosolvent is butanone.
As a preferred embodiment, the polyurethane adhesive is a one-component polyurethane adhesive, preferably type 606.
As a preferred embodiment, the viscosity of the adhesive is 600-.
Preferably, the binder has a solids content of 33 ± 1%.
Preferably, the type of the adhesive is BX-803.
As a preferred embodiment, the hardener is an isocyanate curing agent.
Preferably, the hardener is an aromatic isocyanate curing agent.
Preferably, the hardener comprises any one of Bayer N-75, Bayer N-3390 and Bayer L-75.
Preferably, the hardener is bayer L-75.
As a preferred embodiment, the preparation method of the thermal patch composite adhesive comprises the following steps: adding 30 parts of butanone into a first reaction kettle, then respectively adding 120 parts of BX-803 and 29 parts of monocomponent polyurethane adhesive, and stirring; adding 25 parts of butanone and 1 part of single-component polyurethane adhesive into a second reaction kettle, adding 5 parts of B-56, and stirring; pouring the mixture in the first reaction kettle into a second reaction kettle, and slowly adding 15 parts of butanone into the first reaction kettle for dilution; and continuously adding 7 parts of Bayer L-75 into the second reaction kettle, and stirring to obtain the catalyst.
In a preferred embodiment, the bead-planted film is vacuum-evaporated with zinc sulfide.
The process comprises the following steps: coating a bead planting adhesive on the PET layer, planting beads to obtain a bead planting film, and performing vacuum evaporation on the bead planting film through zinc sulfide to obtain a reflective bead planting film; respectively preparing cloth composite glue and hot-patch composite glue, respectively coating the cloth composite glue and the hot-patch composite glue on the surface of a substrate, respectively attaching bead planting films to the surfaces of the cloth composite glue and the hot-patch composite glue, carrying out hot-press bonding, stripping off a PET (polyethylene terephthalate) layer of the bead planting films, and cutting and sewing to obtain the cloth highlight colorful reflective garment and the hot-patch highlight colorful reflective garment.
The invention provides an application of a production process of a high-brightness colorful reflective garment in a reflective garment product.
Compared with the prior art, the invention has the following beneficial effects:
1. the high-brightness colorful reflective garment prepared by the invention has good reflective and luminous effects at night, has long effective reflective and luminous distances, and is suitable for people who work at night to wear.
2. The bead-planted film adopts a unique zinc sulfide vacuum evaporation process, and can realize the production of reflective films with different patterns and styles.
3. The adhesive property of the cloth composite adhesive and the hot-stick composite adhesive is good, the waterproof property and the washing resistance are excellent, the adhesive effect is still good after multiple washing, and the bead planting film and the base material can be kept from falling off and warping.
4. The method has the advantages of simple process, simple and easily obtained preparation raw materials and very wide application prospect.
The material information in the present invention is as follows:
the glass beads are purchased from Hangzhou Xinghua reflective material GmbH, and have the model number of 72-82-C9
BX-807 and BX-803 are available from GmbH reflective materials GmbH
The metal complex B-56 and the complex dye B-56 are purchased from Meilino chemical Co., Ltd, Wenzhou
Cross-linking agent 2088 was purchased from Never Germany Co Ltd, Shanghai Li Van
Bayer L-75 available from North Hu east Cao chemical science and technology Ltd
606 type single component polyurethane adhesive purchased from Baize engineering rubber and plastic Limited, Jing county
Detailed Description
Example 1
The first aspect of the present embodiment provides a production process of a high bright colorful reflective garment, the process includes: coating the cloth composite adhesive on the surface of the highlight colored chemical fiber with the thickness of 10 μm, attaching a bead planting film on the cloth composite adhesive, hot-pressing at 90 ℃, stripping the PET layer of the bead planting film, and cutting and sewing to obtain the product.
The particle size of the glass beads of the bead planting film is 40 micrometers, the refractive index range is 2.0, and the implantation depth is 35 micrometers.
The preparation raw materials of the cloth composite adhesive comprise, by weight: 150 parts of BX-807 (with the solid content of 36 percent and the viscosity of 5000mPa.s), 150 parts of metal complex B-563, 20881 parts of cross-linking agent, 50 parts of Bayer L-752.5 parts and butanone.
The preparation method of the cloth composite adhesive comprises the following steps: adding 10 parts of butanone into the first reaction kettle, then respectively adding 149 parts of BX-807 and 1 part of cross-linking agent 2088, and stirring; adding 25 parts of butanone and 1 part of BX-807 into a second reaction kettle, adding 3 parts of metal complex B-56, and stirring; pouring the mixture in the first reaction kettle into a second reaction kettle, and slowly adding 15 parts of butanone into the first reaction kettle for dilution; and continuously adding 2.5 parts of Bayer L-75 into the second reaction kettle, and stirring to obtain the catalyst.
Example 2
The first aspect of the present embodiment provides a production process of a high bright colorful reflective garment, the process includes: coating the hot-patch composite adhesive on the surface of the highlight colored chemical fiber with the thickness of 10 μm, attaching a bead planting film on the hot-patch composite adhesive, hot-pressing at 90 ℃, stripping the PET layer of the bead planting film, and cutting and sewing to obtain the product.
The grain diameter of the glass beads of the bead planting film is 40 mu m, the refractive index range is 2.0, and the implantation depth is 35 mu m.
The preparation raw materials of the heat patch type composite adhesive comprise, by weight: b-565 parts of complex dye, 75 parts of butanone, 30 parts of 606 type single-component polyurethane adhesive, BX-803130 parts and 757 parts of Bayer L.
The preparation method of the heat patch type composite adhesive comprises the following steps: adding 30 parts of butanone into a first reaction kettle, then respectively adding 120 parts of BX-803 and 29 parts of 606-type single-component polyurethane adhesive, and stirring; adding 25 parts of butanone and 1 part of 606 type single-component polyurethane adhesive into a second reaction kettle, adding 5 parts of complexing dye B-56, and stirring; pouring the mixture in the first reaction kettle into a second reaction kettle, and slowly adding 15 parts of butanone into the first reaction kettle for dilution; and continuously adding 7 parts of Bayer L-75 into the second reaction kettle, and stirring to obtain the catalyst.
Comparative example 1
The first aspect of the present comparative example provides a production process of a highlight colorful reflective garment, which is implemented in the same manner as in example 1, except that the preparation raw materials of the cloth composite adhesive comprise, by weight: 80 parts of BX-807 (solid content is 36 percent and viscosity is 5000mPa.s), 560.5 parts of metal complex, 20884 parts of cross-linking agent, Bayer L-755 parts and 80 parts of butanone.
Comparative example 2
The first aspect of the present comparative example provides a production process of a highlight colorful reflective garment, which is implemented in the same manner as in example 2, except that the hot-patch type composite adhesive is prepared from the following raw materials in parts by weight: the adhesive comprises, by weight, B-5610 parts of a complex dye, 100 parts of butanone, 8 parts of 606 type single-component polyurethane adhesive, BX-803200 parts, and Bayer L-7512 parts.
Performance testing
The striped bead-planted film obtained in example was subjected to washing resistance and adhesion test, and the results are as follows.
Wash resistance test method reference: ISO 63304N, 15 times of tests.
Adhesion test method reference: ISO5978 FZ/T01063-2008, clamping the surface layer of the fabric by a frame, putting the fabric into a 70 ℃ oven, and observing the adhesion.
| Water washing resistance | Adhesion test | |
| Example 1 | No delamination and no bead falling in large area | 3h without blocking |
| Example 2 | No delamination and no bead falling in large area | 3h without blocking |
| Comparative example 1 | Layering, the bead falling area is more than 50 percent | Adhesion for 1.5h |
| Comparative example 2 | Layering, the bead falling area is more than 50 percent | Adhesion for 1.5h |
Claims (10)
1. A production process of highlight colorful reflective clothes is characterized by comprising the following steps: and (3) combining the bead planting film and the base material by hot pressing of an adhesive, stripping the PET layer of the bead planting film, and cutting and sewing to obtain the adhesive.
2. The production process of the high-brightness colorful reflective garment according to claim 1, wherein the hot pressing temperature is 40-200 ℃.
3. The production process of the high-brightness colorful reflective garment according to claim 1, wherein the grain size of glass beads in the bead planting film is 10-100 μm.
4. The production process of the high-brightness colorful reflective garment according to claim 1, wherein the adhesive comprises cloth composite adhesive and hot-stick composite adhesive.
5. The production process of the high-brightness colorful reflective garment according to claim 4, wherein the preparation raw materials of the cloth composite adhesive comprise the following components in parts by weight: 120-200 parts of acrylic adhesive, 1-5 parts of metal complex, 0.5-2 parts of cross-linking agent, 1-3 parts of curing agent and 40-60 parts of solvent.
6. The production process of the high-brightness colorful reflective garment according to claim 5, wherein the curing agent is an isocyanate curing agent.
7. The production process of the high-brightness colorful reflective garment according to claim 4, wherein the hot-patch type compound adhesive is prepared from the following raw materials in parts by weight: 2-8 parts of complex dye, 60-90 parts of cosolvent, 10-50 parts of polyurethane adhesive, 100-150 parts of adhesive and 5-10 parts of hardener.
8. The process for producing the high-brightness colorful reflective garment according to claim 7, wherein the viscosity of the adhesive is 600-1200 mPa.s.
9. The production process of the high-brightness colorful reflective garment according to claim 1, wherein the bead planting film is subjected to vacuum evaporation by zinc sulfide.
10. Use of the process for producing a highly bright, dazzling retroreflective garment according to any of claims 1 to 9 in the manufacture of retroreflective garment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110825457.6A CN114905754A (en) | 2021-07-21 | 2021-07-21 | Production process and application of high-brightness colorful reflective garment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110825457.6A CN114905754A (en) | 2021-07-21 | 2021-07-21 | Production process and application of high-brightness colorful reflective garment |
Publications (1)
| Publication Number | Publication Date |
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| CN114905754A true CN114905754A (en) | 2022-08-16 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110825457.6A Pending CN114905754A (en) | 2021-07-21 | 2021-07-21 | Production process and application of high-brightness colorful reflective garment |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104275908A (en) * | 2014-09-26 | 2015-01-14 | 杭州星华反光材料有限公司 | Method for preparing high-brightness reflective fabric |
| CN106707388A (en) * | 2017-03-23 | 2017-05-24 | 浙江海川安全防护用品有限公司 | Colorful high-brightness hot-sticking reflective cloth and manufacturing process |
| CN111610585A (en) * | 2020-06-17 | 2020-09-01 | 南阳市新长兴光学科技有限公司 | Flexible washable colorful reflective fabric |
| CN213633888U (en) * | 2020-10-29 | 2021-07-06 | 浙江星华反光材料有限公司 | Luminous reflective material |
| CN213633889U (en) * | 2020-10-29 | 2021-07-06 | 浙江星华反光材料有限公司 | Color reflective material |
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2021
- 2021-07-21 CN CN202110825457.6A patent/CN114905754A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104275908A (en) * | 2014-09-26 | 2015-01-14 | 杭州星华反光材料有限公司 | Method for preparing high-brightness reflective fabric |
| CN106707388A (en) * | 2017-03-23 | 2017-05-24 | 浙江海川安全防护用品有限公司 | Colorful high-brightness hot-sticking reflective cloth and manufacturing process |
| CN111610585A (en) * | 2020-06-17 | 2020-09-01 | 南阳市新长兴光学科技有限公司 | Flexible washable colorful reflective fabric |
| CN213633888U (en) * | 2020-10-29 | 2021-07-06 | 浙江星华反光材料有限公司 | Luminous reflective material |
| CN213633889U (en) * | 2020-10-29 | 2021-07-06 | 浙江星华反光材料有限公司 | Color reflective material |
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