CN104273146A - Water dispersible granule containing liuyangmycin and chlorfluazuron and application - Google Patents
Water dispersible granule containing liuyangmycin and chlorfluazuron and application Download PDFInfo
- Publication number
- CN104273146A CN104273146A CN201410543883.0A CN201410543883A CN104273146A CN 104273146 A CN104273146 A CN 104273146A CN 201410543883 A CN201410543883 A CN 201410543883A CN 104273146 A CN104273146 A CN 104273146A
- Authority
- CN
- China
- Prior art keywords
- macro tetrolide
- sodium salt
- water dispersible
- dispersible granules
- tetrolide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- UISUNVFOGSJSKD-UHFFFAOYSA-N chlorfluazuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC(C=C1Cl)=CC(Cl)=C1OC1=NC=C(C(F)(F)F)C=C1Cl UISUNVFOGSJSKD-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 239000004562 water dispersible granule Substances 0.000 title claims abstract description 23
- 239000003120 macrolide antibiotic agent Substances 0.000 claims description 61
- 244000046052 Phaseolus vulgaris Species 0.000 claims description 17
- -1 Alkyl naphthalene sulfonic acid sodium salt Chemical compound 0.000 claims description 12
- 239000005995 Aluminium silicate Substances 0.000 claims description 11
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims description 11
- 229920006243 acrylic copolymer Polymers 0.000 claims description 11
- 235000012211 aluminium silicate Nutrition 0.000 claims description 11
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 11
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 11
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 11
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 11
- 159000000000 sodium salts Chemical class 0.000 claims description 11
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical class [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 11
- 210000004894 snout Anatomy 0.000 claims description 8
- 241000238631 Hexapoda Species 0.000 claims description 5
- 239000004480 active ingredient Substances 0.000 claims description 5
- 241000500437 Plutella xylostella Species 0.000 claims description 3
- 244000068988 Glycine max Species 0.000 claims description 2
- 235000010469 Glycine max Nutrition 0.000 claims description 2
- 240000004713 Pisum sativum Species 0.000 claims description 2
- 235000010582 Pisum sativum Nutrition 0.000 claims description 2
- 240000006677 Vicia faba Species 0.000 claims description 2
- 235000010749 Vicia faba Nutrition 0.000 claims description 2
- 235000002098 Vicia faba var. major Nutrition 0.000 claims description 2
- 235000010726 Vigna sinensis Nutrition 0.000 claims description 2
- 244000042314 Vigna unguiculata Species 0.000 claims description 2
- 235000005489 dwarf bean Nutrition 0.000 claims description 2
- 235000013311 vegetables Nutrition 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 12
- 241000607479 Yersinia pestis Species 0.000 abstract description 7
- 238000013329 compounding Methods 0.000 abstract 3
- 239000000575 pesticide Substances 0.000 abstract 3
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 230000009044 synergistic interaction Effects 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 14
- 239000002131 composite material Substances 0.000 description 6
- 238000005507 spraying Methods 0.000 description 6
- 230000002195 synergetic effect Effects 0.000 description 6
- 239000002917 insecticide Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000003905 agrochemical Substances 0.000 description 4
- 239000002574 poison Substances 0.000 description 4
- 231100000614 poison Toxicity 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 230000000857 drug effect Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 239000000375 suspending agent Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 241000238876 Acari Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 206010018498 Goitre Diseases 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000187392 Streptomyces griseus Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000000152 carbamate pesticide Substances 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 201000003872 goiter Diseases 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000035772 mutation Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the technical field of pesticide compounding, and in particular relates to a water dispersible granule containing liuyangmycin and chlorfluazuron and an application. The effective components of the composition comprise liuyangmycin and chlorfluazuron in the weight ratio of 1 to (1-15). According to the water dispersible granule, the synergistic interaction is achieved by compounding, the using amount of the pesticide is reduced, and the influence on the environment is reduced; more importantly, because of compounding, the problem of production of pest resistance is effectively solved, the current problem of pesticide resistance of pests is solved to the maximum extent, and the water dispersible granule conforms to the trend of social environment protection in the future.
Description
Technical field
The invention belongs to the technical field that agricultural chemical insecticide is composite, be specially water dispersible granules and the application of a kind of macro tetrolide and UC 62644.
Background technology
macro tetrolide
Be the antibiotic with macrolide structure produced by the mutation of streptomyces griseus Liuyang, for low toxicity, low-residual, can prevent and treat the broad spectrum acaricides of the multiple mite class of various crop, control efficiency is good.Have good action of contace poison to the tetranychid of various crop, without interior absorption, medicament has lipophilicity, if having efficiently one-tenth mite, does not kill and wound Predatory Mites, and evil mite not easily produces resistance, kills mite spectrum comparatively extensively, all effective to tetranychid, goitre mite.With some organic phosphors or carbamate pesticide composite, have significant synergistic effect.To the action of contace poison of evil mite, 7 ~ 14 days lasting periods.
Physicochemical property: the mixture be made up of 5 components, four viable bacteria elements are main active component.Sterling is colourless prism-shaped crystallization, fusing point 112 DEG C ~ 113 DEG C.Be soluble in benzene, ethyl acetate, chloroform, ether, acetone, dissolve in 50% solvent such as ethanol, n-hexane, water insoluble.To ultraviolet-sensitive, in the sun irradiate 2 days, decomposable asymmetric choice net 50% with property through skin LDso >2 000mg/kg.Proterties sterling is colourless prism-shaped crystallization.
uC 62644
Be a kind of New-type wide-spectrum insecticide, based on stomach poison function, have action of contace poison concurrently, without systemic action.High to insect drug effect, but drug effect is comparatively slow, after general 5-7 days, drug effect occurs.The insect agricultural chemicals such as organic phosphor, pyrethroid lipid, carbamic acid lipid being produced to resistance has good preventive effect.
At present, also do not report about macro tetrolide and the composite of UC 62644.
Summary of the invention
The object of the present invention is to provide a kind of water dispersible granules and the application thereof that have macro tetrolide and UC 62644, said composition active ingredient is macro tetrolide and UC 62644, wherein the weight ratio of macro tetrolide and UC 62644 is, macro tetrolide: UC 62644=1:1-1:15, good synergistic function is served by composite, decrease the consumption of agricultural chemicals, also the impact for environment is alleviated, the more important thing is, this compounded combination has effectively resisted the problem that pest resistance produces, farthest alleviate the problem of current pest resistance to insecticide, meet the trend of future society environmental protection.
Technical scheme of the present invention is:
A water dispersible granules for macro tetrolide and UC 62644, active ingredient is macro tetrolide and UC 62644, and wherein the weight ratio of macro tetrolide and UC 62644 is, macro tetrolide: UC 62644=1:1-1:15.
As preferably, the weight ratio of macro tetrolide and UC 62644 is, macro tetrolide: UC 62644=1:6-1:9.
The total weight percentage of described active ingredient is 11-35%.
The water dispersible granules of macro tetrolide of the present invention and UC 62644, it consists of following component by weight percentage:
Macro tetrolide 1-5%,
UC 62644 10-30%,
EDETATE SODIUM salt 4-6%;
Alkyl naphthalene sulfonic acid sodium salt 4-7%;
Acrylic copolymer sodium salt 5-9%;
Ammonium sulfate 6-10%;
Kaolin surplus.
The water dispersible granules of macro tetrolide of the present invention and UC 62644, it consists of following component by weight percentage:
Macro tetrolide 2%,
UC 62644 12%,
EDETATE SODIUM salt 6%;
Alkyl naphthalene sulfonic acid sodium salt 6%;
Acrylic copolymer sodium salt 5%;
Ammonium sulfate 9%;
Kaolin surplus.
The water dispersible granules of macro tetrolide of the present invention and UC 62644, it consists of following component by weight percentage:
Macro tetrolide 3%,
UC 62644 27%,
EDETATE SODIUM salt 6%;
Alkyl naphthalene sulfonic acid sodium salt 7%;
Acrylic copolymer sodium salt 5%;
Ammonium sulfate 6%;
Kaolin surplus.
The water dispersible granules of macro tetrolide of the present invention and UC 62644, it consists of following component by weight percentage:
Macro tetrolide 5%,
UC 62644 15%,
EDETATE SODIUM salt 4%;
Alkyl naphthalene sulfonic acid sodium salt 7%;
Acrylic copolymer sodium salt 8%;
Ammonium sulfate 10%;
Kaolin surplus.
The water dispersible granules of macro tetrolide of the present invention and UC 62644, for preventing and treating insect and the evil mite of vegetables, beans (cowpea, Kidney bean, French beans, kidney bean, pea, broad bean, Fresh edible soybean) crop, as diamond-back moth, the wild snout moth's larva of beans, be particularly useful for the wild snout moth's larva of control beans.
Beneficial effect of the present invention is:
Said composition is compound water dispersible granule composition, significantly enhance effect, delay the generation of pest resistance to insecticide, and expand effective active control spectrum, wherein the weight ratio of macro tetrolide and UC 62644 is, macro tetrolide: UC 62644=1:1-1:15, good synergistic function is served by composite, decrease the consumption of agricultural chemicals, also the impact for environment is alleviated, the more important thing is, this compounded combination has effectively resisted the problem that pest resistance produces, farthest alleviate the problem of current pest resistance to insecticide, meet the trend of future society environmental protection.
Study the compound synergic of composition of the present invention, test adopts the wild snout moth's larva of beans.
Toxicity index and the mixed co-toxicity coefficient (CTC value) of medicament is calculated according to the abundant method of Sun Yun.
Table 1 different ratio relation is to the toxicity test result of the wild snout moth's larva of beans
| Process | Co-toxicity coefficient |
| Macro tetrolide 1: UC 62644 1 | 134.1 |
| Macro tetrolide 1: UC 62644 5 | 140.2 |
| Macro tetrolide 1: UC 62644 6 | 269.8 |
| Macro tetrolide 1: UC 62644 9 | 274.5 |
| Macro tetrolide 1: UC 62644 15 | 133.4 |
| Macro tetrolide | ? |
| UC 62644 | ? |
As can be seen from Table 1, macro tetrolide and UC 62644 composite, has very high synergistic effect, especially macro tetrolide: during UC 62644=1:6-1:9, synergistic effect is more obvious.
Embodiment
Below by specific embodiment, technical scheme of the present invention is described in detail.
embodiment 1
The composition of 14% macro tetrolide and UC 62644
Macro tetrolide 2%,
UC 62644 12%,
EDETATE SODIUM salt 6%;
Alkyl naphthalene sulfonic acid sodium salt 6%;
Acrylic copolymer sodium salt 5%;
Ammonium sulfate 9%;
Kaolin surplus.
Preparation method is the conventional method of this area.
This embodiment medicament is applied to the wild snout moth's larva of control beans:
Co-toxicity coefficient is: 270.1;
Be watered 60 kilograms by every mu of medication amount of formulation and carry out even spraying.
By the spraying of 4000 times of thin ups, after medicine, 7 days control efficiency are that 99.3%, 2% macro tetrolide suspending agent dilutes 200 times and 12% UC 62644 missible oil dilutes 3000 times, and respectively with same method use, after medicine 7 days, control efficiency was respectively 77.4% and 72.5%, significant difference.
embodiment 2
The composition of 30% macro tetrolide and UC 62644
Macro tetrolide 3%,
UC 62644 27%,
EDETATE SODIUM salt 6%;
Alkyl naphthalene sulfonic acid sodium salt 7%;
Acrylic copolymer sodium salt 5%;
Ammonium sulfate 6%;
Kaolin surplus.
Preparation method is the conventional method of this area.
This embodiment medicament is applied to the wild snout moth's larva of control beans:
Co-toxicity coefficient is: 275.0;
Be watered 60 kilograms by every mu of medication amount of formulation and carry out even spraying.
By the spraying of 5000 times of thin ups, after medicine, 7 days control efficiency are that 99.6%, 3% macro tetrolide suspending agent dilutes 200 times and 27% UC 62644 missible oil dilutes 3500 times, and respectively with same method use, after medicine 7 days, control efficiency was respectively 78.2% and 80.2%, significant difference.
embodiment 3
The composition of 20% macro tetrolide and UC 62644
Macro tetrolide 5%,
UC 62644 15%,
EDETATE SODIUM salt 4%;
Alkyl naphthalene sulfonic acid sodium salt 7%;
Acrylic copolymer sodium salt 8%;
Ammonium sulfate 10%;
Kaolin surplus.
Preparation method is the conventional method of this area.
This embodiment medicament is applied to control diamond-back moth:
Co-toxicity coefficient is: 141.7;
Be watered 60 kilograms by every mu of medication amount of formulation and carry out even spraying.
By the spraying of 5000 times of thin ups, after medicine, 7 days control efficiency are that 92.4%, 5% macro tetrolide suspending agent dilutes 150 times and 15% UC 62644 missible oil dilutes 4000 times, and respectively with same method use, after medicine 7 days, control efficiency was respectively 79.3% and 60.4%, significant difference.
Claims (9)
1. a water dispersible granules for macro tetrolide and UC 62644, active ingredient is macro tetrolide and UC 62644, and wherein the weight ratio of macro tetrolide and UC 62644 is, macro tetrolide: UC 62644=1:1-1:15.
2. the water dispersible granules of macro tetrolide according to claim 1 and UC 62644, is characterized in that, the weight ratio of macro tetrolide and UC 62644 is, macro tetrolide: UC 62644=1:6-1:9.
3. the water dispersible granules of macro tetrolide according to claim 2 and UC 62644, is characterized in that, the total weight percentage of described active ingredient is 11-35%.
4. the water dispersible granules of macro tetrolide according to claim 3 and UC 62644, is characterized in that, it consists of following component by weight percentage:
Macro tetrolide 1-5%,
UC 62644 10-30%,
EDETATE SODIUM salt 4-6%;
Alkyl naphthalene sulfonic acid sodium salt 4-7%;
Acrylic copolymer sodium salt 5-9%;
Ammonium sulfate 6-10%;
Kaolin surplus.
5. the water dispersible granules of macro tetrolide according to claim 4 and UC 62644, is characterized in that, it consists of following component by weight percentage:
Macro tetrolide 2%,
UC 62644 12%,
EDETATE SODIUM salt 6%;
Alkyl naphthalene sulfonic acid sodium salt 6%;
Acrylic copolymer sodium salt 5%;
Ammonium sulfate 9%;
Kaolin surplus.
6. the water dispersible granules of macro tetrolide according to claim 4 and UC 62644, is characterized in that, it consists of following component by weight percentage:
Macro tetrolide 3%,
UC 62644 27%,
EDETATE SODIUM salt 6%;
Alkyl naphthalene sulfonic acid sodium salt 7%;
Acrylic copolymer sodium salt 5%;
Ammonium sulfate 6%;
Kaolin surplus.
7. the water dispersible granules of macro tetrolide according to claim 4 and UC 62644, is characterized in that, it consists of following component by weight percentage:
Macro tetrolide 5%,
UC 62644 15%,
EDETATE SODIUM salt 4%;
Alkyl naphthalene sulfonic acid sodium salt 7%;
Acrylic copolymer sodium salt 8%;
Ammonium sulfate 10%;
Kaolin surplus.
8. macro tetrolide according to claim 4 and UC 62644 water dispersible granules for prevent and treat vegetables, beans insect and evil mite, described beans is cowpea, Kidney bean, French beans, kidney bean, pea, broad bean, Fresh edible soybean, and described insect and evil mite are diamond-back moth, the wild snout moth's larva of beans.
9. the water dispersible granules of macro tetrolide according to claim 8 and UC 62644 is for preventing and treating the wild snout moth's larva of beans.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410543883.0A CN104273146B (en) | 2014-10-15 | 2014-10-15 | A kind of macro tetrolide and the water dispersible granules of UC 62644 and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410543883.0A CN104273146B (en) | 2014-10-15 | 2014-10-15 | A kind of macro tetrolide and the water dispersible granules of UC 62644 and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104273146A true CN104273146A (en) | 2015-01-14 |
| CN104273146B CN104273146B (en) | 2016-08-24 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410543883.0A Expired - Fee Related CN104273146B (en) | 2014-10-15 | 2014-10-15 | A kind of macro tetrolide and the water dispersible granules of UC 62644 and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104273146B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0908096A1 (en) * | 1997-10-07 | 1999-04-14 | Sumitomo Chemical Company, Limited | Pesticidal composition |
| CN1475115A (en) * | 2002-08-16 | 2004-02-18 | 张业生 | Pesticide for killing insect and acarid |
| CN102550581A (en) * | 2012-01-13 | 2012-07-11 | 河南金田地农化有限责任公司 | Ultralow-volume concentrate containing chlorfluazuron |
-
2014
- 2014-10-15 CN CN201410543883.0A patent/CN104273146B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0908096A1 (en) * | 1997-10-07 | 1999-04-14 | Sumitomo Chemical Company, Limited | Pesticidal composition |
| CN1475115A (en) * | 2002-08-16 | 2004-02-18 | 张业生 | Pesticide for killing insect and acarid |
| CN102550581A (en) * | 2012-01-13 | 2012-07-11 | 河南金田地农化有限责任公司 | Ultralow-volume concentrate containing chlorfluazuron |
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| Publication number | Publication date |
|---|---|
| CN104273146B (en) | 2016-08-24 |
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