CN104264181B - Improve the device that electrolysis ozone generator manufactures the hydroxyl radical free radical of Ozone Water - Google Patents
Improve the device that electrolysis ozone generator manufactures the hydroxyl radical free radical of Ozone Water Download PDFInfo
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- CN104264181B CN104264181B CN201410560683.6A CN201410560683A CN104264181B CN 104264181 B CN104264181 B CN 104264181B CN 201410560683 A CN201410560683 A CN 201410560683A CN 104264181 B CN104264181 B CN 104264181B
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- tempering tank
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/13—Ozone
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
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- Chemical Kinetics & Catalysis (AREA)
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- Materials Engineering (AREA)
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- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Physical Water Treatments (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
The invention discloses the device improving the hydroxyl radical free radical that electrolysis ozone generator manufactures Ozone Water, it includes pure water water replanishing device (1), pure water cylinder (2), electrolysis ozone generator (6), Ozone Water tempering tank (9), reduction carbon bucket (4), it is characterized in that the outlet of Ozone Water tempering tank (9) is by check valve (10) coupled reaction bucket (17), reaction container (17) connects outlet (18), reaction container (17) is provided with uviol lamp (19), uviol lamp (19), entering water electromagnetic valve (7) and generator (6) are all connected with electric control unit (3), present configuration is simple and practical, add the ratio producing OH in Ozone Water, improve sterilization and decomposing organic matter ability.
Description
Technical field:
The present invention relates to improve the device of the hydroxyl radical free radical that electrolysis ozone generator manufactures Ozone Water, belong to ozone technology
And application.
Background technology:
Ozone Water is sterilized and decomposing pollutant by two kinds of approach: the nascent oxygen that direct reaction ozone decomposed produces
Atom directly acts on antibacterial or pollutant；Indirect reaction forms the hydroxyl radical free radical with strong oxidation in water
(OH) antibacterial or pollutant are acted on.Direct reaction is selective, and speed is slow；Indirect reaction non-selectivity, OH(E0=
2.8V) current potential is high, and respond is strong, and speed is fast, can cause chain reaction.Current existing ozone water apparatus simply simply by water with
Ozone gas mixes, and therefore the content of its hydroxyl radical free radical (OH) converted is low, its bactericidal effect and the energy of decomposing pollutant
Power is restricted.
Summary of the invention:
It is an object of the invention to overcome the deficiency of above-mentioned prior art to provide a kind of simple and practical, raising sterilization
With decomposing organic matter ability, improve the device that electrolysis ozone generator manufactures the hydroxyl radical free radical of Ozone Water.
The purpose of the present invention can be reached by following measure: improves electrolysis ozone generator and manufactures the hydroxyl of Ozone Water
The device of free radical, it includes pure water water replanishing device, and pure water water replanishing device connects pure water cylinder, the outlet of pure water cylinder be electrolysed smelly
The anode water inlet of Oxygen Generator connects, and the negative electrode drainage QI KOU of electrolysis ozone generator connects sewage draining exit, and electrolysis ozone is sent out
The anode gas outlet of raw device is connected with the air inlet of pure water cylinder, and the gas outlet of pure water cylinder is by check valve and Ozone Water tempering tank
Ozone gas import is connected, and the water inlet on Ozone Water tempering tank is connected with water inlet by check valve, entering water electromagnetic valve, Ozone Water
The aeration opening of tempering tank connects reduction carbon bucket, and the outlet of reduction carbon bucket is connected with sewage draining exit, it is characterised in that Ozone Water tempering tank
Outlet by check valve coupled reaction bucket, reaction container connects outlet, and reaction container is provided with uviol lamp, uviol lamp, water inlet
Electromagnetic valve and generator are all connected with electric control unit.
In order to realize the purpose of the present invention further, described water inlet is by entering water electromagnetic valve, check valve and alkaline water
The water inlet of tempering tank is connected；The outlet of alkaline water tempering tank passes through check valve coupled reaction bucket, sets in alkaline water tempering tank
Having spacetabs type alkali grain thing, entering water electromagnetic valve is connected with electric control unit.
The present invention can produce following good effect compared with the prior art: research finds under the irradiation of ultraviolet light, ozone
Water can produce rapidly hydroxyl radical free radical (OH)；The reaction container of the present invention increases the way of uviol lamp also makes OH in Ozone Water
Formation speed be greatly improved.Research also discovery ozone decomposes the speed of generation OH in water and adds along with the raising of pH value
Hurry up, at pH, < when 4, ozone decomposition in aqueous is negligible, and its reaction mainly dissolved ozone molecule is with processed
The direct reaction of reducing substances in aqueous solution；At pH > 4 time, the decomposition of ozone just be can not ignore, when pH is higher, then ozone
Mainly at OH-Catalytic action under, resolve into through a series of chain reactions and there is the free radical of high reaction activity and to reduction
Property material carries out non-selective oxidation degraded.If pH value improves a unit ozone and forms the fastest 3 times of the speed of OH；This
Invention increases alkaline water tempering tank, produces alkalescence Ozone Water；Substantially increase the formation speed of OH；Improve sterilization, kill
Bacterium effect.Alkaline water also improves deoiling ability simultaneously.Therefore, this product is a kind of rising advanced oxidation
Sterilization, sterilised products.
Accompanying drawing illustrates:
Fig. 1 is the structural representation of the first embodiment of the present invention；
Fig. 2 is the structural representation of the second embodiment of the present invention.
Detailed description of the invention:
Below in conjunction with the accompanying drawings the detailed description of the invention of the present invention is elaborated:
Embodiment 1: improve the device (seeing Fig. 1) that electrolysis ozone generator manufactures the hydroxyl radical free radical of Ozone Water, its bag
Including pure water water replanishing device 1, pure water water replanishing device 1 connects the sun of pure water cylinder 2, the outlet of pure water cylinder 2 and electrolysis ozone generator 6
Pole water inlet connects, and the negative electrode drainage QI KOU of electrolysis ozone generator 6 connects sewage draining exit 5, the anode of electrolysis ozone generator 6
Gas outlet is connected with the air inlet of pure water cylinder 2, and the gas outlet of pure water cylinder 2 is by the ozone gas of check valve 8 with Ozone Water tempering tank 9
Import is connected, and the water inlet on Ozone Water tempering tank 9 is connected with water inlet 12 by check valve 11, entering water electromagnetic valve 7, Ozone Water
The aeration opening of tempering tank 9 connects reduction carbon bucket 4, and the outlet of reduction carbon bucket 4 is connected with sewage draining exit 5, the water outlet of Ozone Water tempering tank 9
Mouth is by check valve 10 coupled reaction bucket 17, and reaction container 17 connects outlet 18, and reaction container 17 is provided with uviol lamp i.e. UV lamp 19；
Uviol lamp 19, entering water electromagnetic valve 7 and generator 6 are all connected with electric control unit 3.
Pure water is added to the raw water in pure water cylinder 2 as electrolysis ozone generator 6, electric-controlled by pure water water replanishing device 1
Unit 3 processed is powered for electrolysis ozone generator 6, and ozone gas produced by electrolysis ozone generator 6 enters pure water cylinder 2；Ozone
Gas is then passed through the air inlet of the gas outlet on pure water cylinder 2, check valve 8 and Ozone Water tempering tank 9 and enters Ozone Water tempering tank
9；Unnecessary gas enters reduction carbon bucket 4 through the aeration opening of Ozone Water tempering tank 9, is discharged by sewage draining exit 5 after carrying out reduction.When needing
During Ozone Water to be used, electric control unit 3 controls entering water electromagnetic valve 7 and opens, water by entering water electromagnetic valve 7 and through check valve 11 and
Water inlet on Ozone Water tempering tank 9 enters Ozone Water tempering tank 9, is mixed into Ozone Water through Ozone Water tempering tank 9 with ozone gas
Outlet and check valve 10 enter reaction container 17, electric control unit 3 controls uviol lamp 19 and opens, the ozone in reaction container 17
Water irradiates to improve to generate the ratio of OH and speed and pass through outlet 18 through ultraviolet and flows out.
Embodiment 2: improve electrolysis ozone generator and manufacture the device (seeing Fig. 2) of hydroxyl radical free radical of Ozone Water, it with
Principle and the structure of embodiment 1 are essentially identical, and its difference is that water inlet 12 is by entering water electromagnetic valve 13, check valve 14 and alkaline water
The water inlet of tempering tank 15 is connected；The outlet of alkaline water tempering tank 15 passes through check valve 16 coupled reaction bucket 17, and alkaline water mixes
It is provided with spacetabs type alkali grain thing 20 in closing bucket 15；Entering water electromagnetic valve 13, entering water electromagnetic valve 7 and generator 6 are all and electrical control
Unit 3 connects.
Pure water is added to the raw water in pure water cylinder 2 as electrolysis ozone generator 6, electric-controlled by pure water water replanishing device 1
Unit 3 processed is powered for electrolysis ozone generator 6, and ozone gas produced by electrolysis ozone generator 6 enters pure water cylinder 2；Ozone
Gas is then passed through the air inlet of the gas outlet on pure water cylinder 2, check valve 8 and Ozone Water tempering tank 9 and enters Ozone Water tempering tank
9；Unnecessary gas enters reduction carbon bucket 4 through the aeration opening of Ozone Water tempering tank 9, is discharged by sewage draining exit 5 after carrying out reduction.When needing
During Ozone Water to be used, electric control unit 3 controls entering water electromagnetic valve 7 and opens, water by entering water electromagnetic valve 7 and through check valve 11 and
Water inlet on Ozone Water tempering tank 9 enters Ozone Water tempering tank 9, is mixed into Ozone Water through Ozone Water tempering tank 9 with ozone gas
Outlet and check valve 10, electric control unit 3 controls uviol lamp 19 and opens, the Ozone Water in reaction container 17 through ultraviolet shine
Ratio and the speed of penetrating raising generation OH are flowed out by outlet 18.When needs alkalescence Ozone Water, electric control unit 3 is controlled
Entering water electromagnetic valve 7 and 13 processed is opened simultaneously, and alkaline water and Ozone Water are mixed into alkalescence Ozone Water also in pipeline and reaction container 17
Irradiate to improve through ultraviolet and generate the ratio of OH and speed and flowed out by outlet 18.
Above embodiment is only to be described the preferred embodiment of the present invention, not enters the scope of the present invention
Row limits, on the premise of designing spirit without departing from the present invention, and this area ordinary skill technical staff technical side to the present invention
Various deformation that case is made and improvement, all should fall in the protection domain that claims of the present invention determines.
Claims (2)
1. improving the device that electrolysis ozone generator manufactures the hydroxyl radical free radical of Ozone Water, it includes pure water water replanishing device (1), pure
Water water replanishing device (1) connects pure water cylinder (2), and the outlet of pure water cylinder (2) connects with the anode water inlet of electrolysis ozone generator (6)
Connecing, the negative electrode drainage QI KOU of electrolysis ozone generator (6) connects sewage draining exit (5), and the anode of electrolysis ozone generator (6) is given vent to anger
Mouthful being connected with the air inlet of pure water cylinder (2), the smelly of check valve (8) and Ozone Water tempering tank (9) is passed through in the gas outlet of pure water cylinder (2)
Oxygen inlet is connected, and the water inlet on Ozone Water tempering tank (9) is by check valve (11), entering water electromagnetic valve (7) and water inlet
(12) being connected, the aeration opening of Ozone Water tempering tank (9) connects reduction carbon bucket (4), the outlet of reduction carbon bucket (4) and sewage draining exit (5)
It is connected, it is characterised in that the outlet of Ozone Water tempering tank (9) passes through check valve (10) coupled reaction bucket (17), reaction container (17)
Connecting outlet (18), reaction container (17) is provided with uviol lamp (19), uviol lamp (19), entering water electromagnetic valve (7) and generator (6)
All it is connected with electric control unit (3).
Raising electrolysis ozone generator the most according to claim 1 manufactures the device of the hydroxyl radical free radical of Ozone Water, and it is special
Levy and be that described water inlet (12) is by entering water electromagnetic valve (13), check valve (14) and the water inlet of alkaline water tempering tank (15)
It is connected；The outlet of alkaline water tempering tank (15) passes through in check valve (16) coupled reaction bucket (17), alkaline water tempering tank (15)
Being provided with spacetabs type alkali grain thing (20), entering water electromagnetic valve (13) is connected with electric control unit (3).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410560683.6A CN104264181B (en) | 2014-10-21 | 2014-10-21 | Improve the device that electrolysis ozone generator manufactures the hydroxyl radical free radical of Ozone Water |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410560683.6A CN104264181B (en) | 2014-10-21 | 2014-10-21 | Improve the device that electrolysis ozone generator manufactures the hydroxyl radical free radical of Ozone Water |
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| Publication Number | Publication Date |
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| CN104264181A CN104264181A (en) | 2015-01-07 |
| CN104264181B true CN104264181B (en) | 2016-08-24 |
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| CN201410560683.6A Active CN104264181B (en) | 2014-10-21 | 2014-10-21 | Improve the device that electrolysis ozone generator manufactures the hydroxyl radical free radical of Ozone Water |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104264180B (en) * | 2014-10-21 | 2016-08-17 | 百特环保科技（烟台）有限公司 | A kind of device of the hydroxyl radical free radical improving electrolysis ozone generator manufacture Ozone Water |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001300561A (en) * | 2000-04-20 | 2001-10-30 | Hiroichi Shioda | Rapid oxidation method and its device |
| CN1334784A (en) * | 1998-12-16 | 2002-02-06 | 林恩技术公司 | Microoganism control of point-of-use potable water sources |
| JP2002166279A (en) * | 2000-12-01 | 2002-06-11 | Core Technology:Kk | Method and device for generating gas by electrolysis |
| CN1399009A (en) * | 2002-08-29 | 2003-02-26 | 太原理工大学 | Prepn of strong oxidant |
| JP2007325981A (en) * | 2006-06-06 | 2007-12-20 | Chlorine Eng Corp Ltd | Circulation-type apparatus for preparing ozone water and method for operating the same |
| CN101448744A (en) * | 2006-05-17 | 2009-06-03 | 奥佐迈克斯公司 | Portable ozone generator and use thereof for purifying water |
| CN101988207A (en) * | 2009-07-30 | 2011-03-23 | 三洋电机株式会社 | Electrode material for electrolysis, electrode for electrolysis, and method for producing same |
| CN104264180A (en) * | 2014-10-21 | 2015-01-07 | 百尔康环保科技有限公司 | Device for increasing hydroxyl radical of ozone water produced by electrolytic ozone generator |
| CN204097574U (en) * | 2014-10-21 | 2015-01-14 | 百尔康环保科技有限公司 | Improve the device that electrolysis ozone generator manufactures the hydroxyl radical free radical of ozone water |
-
2014
- 2014-10-21 CN CN201410560683.6A patent/CN104264181B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1334784A (en) * | 1998-12-16 | 2002-02-06 | 林恩技术公司 | Microoganism control of point-of-use potable water sources |
| JP2001300561A (en) * | 2000-04-20 | 2001-10-30 | Hiroichi Shioda | Rapid oxidation method and its device |
| JP2002166279A (en) * | 2000-12-01 | 2002-06-11 | Core Technology:Kk | Method and device for generating gas by electrolysis |
| CN1399009A (en) * | 2002-08-29 | 2003-02-26 | 太原理工大学 | Prepn of strong oxidant |
| CN101448744A (en) * | 2006-05-17 | 2009-06-03 | 奥佐迈克斯公司 | Portable ozone generator and use thereof for purifying water |
| JP2007325981A (en) * | 2006-06-06 | 2007-12-20 | Chlorine Eng Corp Ltd | Circulation-type apparatus for preparing ozone water and method for operating the same |
| CN101988207A (en) * | 2009-07-30 | 2011-03-23 | 三洋电机株式会社 | Electrode material for electrolysis, electrode for electrolysis, and method for producing same |
| CN104264180A (en) * | 2014-10-21 | 2015-01-07 | 百尔康环保科技有限公司 | Device for increasing hydroxyl radical of ozone water produced by electrolytic ozone generator |
| CN204097574U (en) * | 2014-10-21 | 2015-01-14 | 百尔康环保科技有限公司 | Improve the device that electrolysis ozone generator manufactures the hydroxyl radical free radical of ozone water |
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| CN104264181A (en) | 2015-01-07 |
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Effective date of registration: 20160616 Address after: 264006, building 5, Hua Hua Industrial Park, No. 106, Taishan Road, Yantai Development Zone, Yantai, Shandong Applicant after: Baxter Environmental Technology (Yantai) Co., Ltd. Address before: Chinese Taiwan New Taipei City three District 98 Building No. 5 Hing Road Applicant before: BES GROUP INC |
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