CN104264180B - A kind of device of the hydroxyl radical free radical improving electrolysis ozone generator manufacture Ozone Water - Google Patents
A kind of device of the hydroxyl radical free radical improving electrolysis ozone generator manufacture Ozone Water Download PDFInfo
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- CN104264180B CN104264180B CN201410560682.1A CN201410560682A CN104264180B CN 104264180 B CN104264180 B CN 104264180B CN 201410560682 A CN201410560682 A CN 201410560682A CN 104264180 B CN104264180 B CN 104264180B
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/13—Ozone
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
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- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
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- Inorganic Chemistry (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Physical Water Treatments (AREA)
Abstract
The invention discloses the device of a kind of hydroxyl radical free radical improving electrolysis ozone generator manufacture Ozone Water, it includes pure water water replanishing device (1), pure water cylinder (2), electrolysis ozone generator (6), Ozone Water tempering tank (9), reduction carbon bucket (4), it is characterized in that the outlet of Ozone Water tempering tank (9) is by check valve (10) coupled reaction bucket (17), reaction container (17) connects outlet (18), and water inlet (12) is connected with the water inlet of alkaline water tempering tank (15) by entering water electromagnetic valve (13), check valve (14)；The outlet of alkaline water tempering tank (15) passes through check valve (16) coupled reaction bucket (17), is provided with spacetabs type alkali grain thing (20) in alkaline water tempering tank (15)；Entering water electromagnetic valve (13), entering water electromagnetic valve (7) and generator (6) are all connected with electric control unit (3), and present configuration is simple and practical, add the ratio producing OH in Ozone Water, improve sterilization and decomposing organic matter ability.
Description
Technical field:
The present invention relates to the device of a kind of hydroxyl radical free radical improving electrolysis ozone generator manufacture Ozone Water, belong to ozone technology and application.
Background technology:
Ozone Water is sterilized and decomposing pollutant by two kinds of approach: the nascent oxygen atom that direct reaction ozone decomposed produces directly acts on antibacterial or pollutant；Indirect reaction is formed in water to be had the hydroxyl radical free radical (OH) of strong oxidation and acts on antibacterial or pollutant.Direct reaction is selective, and speed is slow；Indirect reaction non-selectivity, OH(E0=2.8V) current potential height, respond is strong, and speed is fast, can cause chain reaction.Water is simply simply mixed by current existing ozone water apparatus with ozone gas, and therefore the content of its hydroxyl radical free radical (OH) converted is low, and the ability of its bactericidal effect and decomposing pollutant is restricted.
Summary of the invention:
It is an object of the invention to overcome the deficiency of above-mentioned prior art to provide the device of the hydroxyl radical free radical improving electrolysis ozone generator manufacture Ozone Water of a kind of simple and practical, raising sterilization and decomposing organic matter ability.
nullThe purpose of the present invention can be reached by following measure: the device of a kind of hydroxyl radical free radical improving electrolysis ozone generator manufacture Ozone Water，It includes pure water water replanishing device，Pure water water replanishing device connects pure water cylinder，The outlet of pure water cylinder is connected with the anode water inlet of electrolysis ozone generator，The negative electrode drainage QI KOU of electrolysis ozone generator connects sewage draining exit，The anode gas outlet of electrolysis ozone generator is connected with the air inlet of pure water cylinder，The gas outlet of pure water cylinder is connected with the ozone gas import of Ozone Water tempering tank by check valve，Water inlet on Ozone Water tempering tank passes through check valve、Entering water electromagnetic valve is connected with water inlet，The aeration opening of Ozone Water tempering tank connects reduction carbon bucket，The outlet of reduction carbon bucket is connected with sewage draining exit，It is characterized in that the outlet of Ozone Water tempering tank is by check valve coupled reaction bucket，Reaction container connects outlet，Water inlet passes through entering water electromagnetic valve、Check valve is connected with the water inlet of alkaline water tempering tank；The outlet of alkaline water tempering tank passes through check valve coupled reaction bucket, is provided with spacetabs type alkali grain thing in alkaline water tempering tank；Entering water electromagnetic valve, entering water electromagnetic valve and generator are all connected with electric control unit.
In order to realize the purpose of the present invention further, described reaction container is provided with uviol lamp；Uviol lamp is connected with electric control unit.
The present invention can produce following good effect compared with the prior art: research discovery ozone decomposes the speed of generation OH in water to be accelerated along with the raising of pH value, at pH < when 4, ozone decomposition in aqueous is negligible, and its reaction mainly dissolved ozone molecule is with the direct reaction of reducing substances in processed water solution；At pH > 4 time, the decomposition of ozone just be can not ignore, when pH is higher, then ozone be mainly at OH-Catalytic action under, resolve into through a series of chain reactions and there is the free radical of high reaction activity and reducing substances is carried out non-selective oxidation degraded.If pH value improves a unit ozone and forms the fastest 3 times of the speed of OH；The present invention increases alkaline water tempering tank, produces alkalescence Ozone Water；Substantially increase the formation speed of OH；Research also finds under the irradiation of ultraviolet light, and Ozone Water can produce rapidly hydroxyl radical free radical (OH)；The reaction container of the present invention increases the way of uviol lamp also makes the formation speed of OH in Ozone Water be greatly improved.Improve sterilization, bactericidal effect.Alkaline water also improves deoiling ability simultaneously.Therefore, this product is the sterilization of a kind of rising advanced oxidation, sterilised products.
Accompanying drawing illustrates:
Fig. 1 is the structural representation of the first embodiment of the present invention；
Fig. 2 is the structural representation of the second embodiment of the present invention.
Detailed description of the invention:
Below in conjunction with the accompanying drawings the detailed description of the invention of the present invention is elaborated:
nullEmbodiment 1: the device (seeing Fig. 1) of a kind of hydroxyl radical free radical improving electrolysis ozone generator manufacture Ozone Water，It includes pure water water replanishing device 1，Pure water water replanishing device 1 connects pure water cylinder 2，The outlet of pure water cylinder 2 is connected with the anode water inlet of electrolysis ozone generator 6，The negative electrode drainage QI KOU of electrolysis ozone generator 6 connects sewage draining exit 5，The anode gas outlet of electrolysis ozone generator 6 is connected with the air inlet of pure water cylinder 2，The gas outlet of pure water cylinder 2 is connected with the ozone gas import of Ozone Water tempering tank 9 by check valve 8，Water inlet on Ozone Water tempering tank 9 passes through check valve 11、Entering water electromagnetic valve 7 is connected with water inlet 12，The aeration opening of Ozone Water tempering tank 9 connects reduction carbon bucket 4，The outlet of reduction carbon bucket 4 is connected with sewage draining exit 5，The outlet of Ozone Water tempering tank 9 passes through check valve 10 coupled reaction bucket 17，Reaction container 17 connects outlet 18，Water inlet 12 is by entering water electromagnetic valve 13、Check valve 14 is connected with the water inlet of alkaline water tempering tank 15；The outlet of alkaline water tempering tank 15 passes through check valve 16 coupled reaction bucket 17, is provided with spacetabs type alkali grain thing 20 in alkaline water tempering tank 15；Entering water electromagnetic valve 13, entering water electromagnetic valve 7 and generator 6 are all connected with electric control unit 3.
Pure water is added to the raw water in pure water cylinder 2 as electrolysis ozone generator 6 by pure water water replanishing device 1, and electric control unit 3 is powered for electrolysis ozone generator 6, and ozone gas produced by electrolysis ozone generator 6 enters pure water cylinder 2；Ozone gas is then passed through the air inlet of the gas outlet on pure water cylinder 2, check valve 8 and Ozone Water tempering tank 9 and enters Ozone Water tempering tank 9；Unnecessary gas enters reduction carbon bucket 4 through the aeration opening of Ozone Water tempering tank 9, is discharged by sewage draining exit 5 after carrying out reduction.When needs Ozone Water, electric control unit 3 controls entering water electromagnetic valve 7 and opens, water enters Ozone Water tempering tank 9 by entering water electromagnetic valve 7 water inlet on check valve 11 and Ozone Water tempering tank 9, is mixed into Ozone Water with ozone gas and is flowed out by outlet 18 through reaction container 17 through outlet and the check valve 10 of Ozone Water tempering tank 9；When needs alkalescence Ozone Water, electric control unit 3 controls entering water electromagnetic valve 7 and 13 and opens simultaneously, and alkaline water and Ozone Water are mixed into alkalescence Ozone Water the ratio improving generation OH in pipeline and reaction container 17 and speed is passed through outlet 18 and flowed out.
Embodiment 2: the device (seeing Fig. 2) of a kind of hydroxyl radical free radical improving electrolysis ozone generator manufacture Ozone Water, it is essentially identical with the principle of embodiment 1 and structure, and its difference is that reaction container 17 is provided with uviol lamp (i.e. UV lamp) 19；Uviol lamp 19 is connected with electric control unit 3.
When needs Ozone Water or alkalescence Ozone Water, electric control unit 3 controls uviol lamp 19 and opens, and Ozone Water in reaction container 17 or alkalescence Ozone Water are irradiated to improve to generate the ratio of OH and speed and pass through outlet 18 through ultraviolet and flowed out.
Above embodiment is only to be described the preferred embodiment of the present invention; not the scope of the present invention is defined; on the premise of designing spirit without departing from the present invention; various deformation that technical scheme is made by this area ordinary skill technical staff and improvement, all should fall in the protection domain that claims of the present invention determines.
Claims (1)
- null1. one kind is improved the device that electrolysis ozone generator manufactures the hydroxyl radical free radical of Ozone Water，It includes pure water water replanishing device (1)，Pure water water replanishing device (1) connects pure water cylinder (2)，The outlet of pure water cylinder (2) is connected with the anode water inlet of electrolysis ozone generator (6)，The negative electrode drainage QI KOU of electrolysis ozone generator (6) connects sewage draining exit (5)，The anode gas outlet of electrolysis ozone generator (6) is connected with the air inlet of pure water cylinder (2)，The gas outlet of pure water cylinder (2) is connected with the ozone gas import of Ozone Water tempering tank (9) by check valve (8)，Water inlet on Ozone Water tempering tank (9) passes through check valve (11)、Entering water electromagnetic valve (7) is connected with water inlet (12)，The aeration opening of Ozone Water tempering tank (9) connects reduction carbon bucket (4)，The outlet of reduction carbon bucket (4) is connected with sewage draining exit (5)，It is characterized in that the outlet of Ozone Water tempering tank (9) is by check valve (10) coupled reaction bucket (17)，Reaction container (17) connects outlet (18)，Water inlet (12) passes through entering water electromagnetic valve (13)、Check valve (14) is connected with the water inlet of alkaline water tempering tank (15)；The outlet of alkaline water tempering tank (15) passes through check valve (16) coupled reaction bucket (17), is provided with spacetabs type alkali grain thing (20) in alkaline water tempering tank (15)；Entering water electromagnetic valve (13), entering water electromagnetic valve (7) and generator (6) are all connected with electric control unit (3).
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410560682.1A CN104264180B (en) | 2014-10-21 | 2014-10-21 | A kind of device of the hydroxyl radical free radical improving electrolysis ozone generator manufacture Ozone Water |
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| CN201410560682.1A CN104264180B (en) | 2014-10-21 | 2014-10-21 | A kind of device of the hydroxyl radical free radical improving electrolysis ozone generator manufacture Ozone Water |
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| CN104264180A CN104264180A (en) | 2015-01-07 |
| CN104264180B true CN104264180B (en) | 2016-08-17 |
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| CN104264181B (en) * | 2014-10-21 | 2016-08-24 | 百特环保科技（烟台）有限公司 | Improve the device that electrolysis ozone generator manufactures the hydroxyl radical free radical of Ozone Water |
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| CN2898059Y (en) * | 2006-03-23 | 2007-05-09 | 徐名勇 | Electrolytic ozone water maker with electrical-appliance isolation and ozone generator |
| TW201217584A (en) * | 2010-10-27 | 2012-05-01 | Jing Tian Industry Co Ltd | comprising a hydrogen/oxygen dissociator, an ozone generator and a water gas separator |
| CN103266328A (en) * | 2013-05-09 | 2013-08-28 | 李欣 | Apparatus for producing ozone water and hydrogen water at any time by using ozone electrolysis generator |
| CN103436909A (en) * | 2013-08-13 | 2013-12-11 | 李欣 | Device for supplying sterilized water to ice making machine by utilizing electrolytic ozone generator |
| CN203451627U (en) * | 2013-08-13 | 2014-02-26 | 李欣 | Device for sterilizing ice maker through ozone gas of electrolytic ozone generator |
| JP2014095100A (en) * | 2012-11-07 | 2014-05-22 | Panasonic Corp | Ozone water generator |
| JP2014113549A (en) * | 2012-12-10 | 2014-06-26 | Panasonic Corp | Ozone water generator |
| CN104264181A (en) * | 2014-10-21 | 2015-01-07 | 百尔康环保科技有限公司 | Device for increasing hydroxyl radical content of ozone water produced by electrolytic ozone generator |
| CN204097573U (en) * | 2014-10-21 | 2015-01-14 | 百尔康环保科技有限公司 | A kind of device improving the hydroxyl radical free radical of electrolysis ozone generator manufacture ozone water |
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2014
- 2014-10-21 CN CN201410560682.1A patent/CN104264180B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2898059Y (en) * | 2006-03-23 | 2007-05-09 | 徐名勇 | Electrolytic ozone water maker with electrical-appliance isolation and ozone generator |
| TW201217584A (en) * | 2010-10-27 | 2012-05-01 | Jing Tian Industry Co Ltd | comprising a hydrogen/oxygen dissociator, an ozone generator and a water gas separator |
| JP2014095100A (en) * | 2012-11-07 | 2014-05-22 | Panasonic Corp | Ozone water generator |
| JP2014113549A (en) * | 2012-12-10 | 2014-06-26 | Panasonic Corp | Ozone water generator |
| CN103266328A (en) * | 2013-05-09 | 2013-08-28 | 李欣 | Apparatus for producing ozone water and hydrogen water at any time by using ozone electrolysis generator |
| CN103436909A (en) * | 2013-08-13 | 2013-12-11 | 李欣 | Device for supplying sterilized water to ice making machine by utilizing electrolytic ozone generator |
| CN203451627U (en) * | 2013-08-13 | 2014-02-26 | 李欣 | Device for sterilizing ice maker through ozone gas of electrolytic ozone generator |
| CN104264181A (en) * | 2014-10-21 | 2015-01-07 | 百尔康环保科技有限公司 | Device for increasing hydroxyl radical content of ozone water produced by electrolytic ozone generator |
| CN204097573U (en) * | 2014-10-21 | 2015-01-14 | 百尔康环保科技有限公司 | A kind of device improving the hydroxyl radical free radical of electrolysis ozone generator manufacture ozone water |
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| CN104264180A (en) | 2015-01-07 |
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Effective date of registration: 20160616 Address after: 264006, building 5, Hua Hua Industrial Park, No. 106, Taishan Road, Yantai Development Zone, Yantai, Shandong Applicant after: Baxter Environmental Technology (Yantai) Co., Ltd. Address before: Chinese Taiwan New Taipei City three District 98 Building No. 5 Hing Road Applicant before: BES GROUP INC |
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