CN202936224U - Device capable of eliminating organics in water by collaborative processing of UV-irradiation and sodium hypochlorite - Google Patents
Device capable of eliminating organics in water by collaborative processing of UV-irradiation and sodium hypochlorite Download PDFInfo
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- CN202936224U CN202936224U CN2012205012069U CN201220501206U CN202936224U CN 202936224 U CN202936224 U CN 202936224U CN 2012205012069 U CN2012205012069 U CN 2012205012069U CN 201220501206 U CN201220501206 U CN 201220501206U CN 202936224 U CN202936224 U CN 202936224U
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- clorox
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 79
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 238000012545 processing Methods 0.000 title abstract description 11
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 title abstract description 4
- 239000005708 Sodium hypochlorite Substances 0.000 title abstract 6
- 239000010865 sewage Substances 0.000 claims abstract description 55
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000460 chlorine Substances 0.000 claims abstract description 9
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 9
- 239000007788 liquid Substances 0.000 claims description 18
- 239000010453 quartz Substances 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 230000008030 elimination Effects 0.000 claims description 6
- 238000003379 elimination reaction Methods 0.000 claims description 6
- 238000005070 sampling Methods 0.000 claims description 6
- 239000007844 bleaching agent Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 abstract description 24
- 239000000126 substance Substances 0.000 abstract description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 7
- 239000001301 oxygen Substances 0.000 abstract description 7
- 229910052760 oxygen Inorganic materials 0.000 abstract description 7
- 244000052616 bacterial pathogen Species 0.000 abstract 2
- 239000007787 solid Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 4
- 230000003851 biochemical process Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 230000000968 intestinal effect Effects 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 235000011089 carbon dioxide Nutrition 0.000 description 2
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002957 persistent organic pollutant Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 102000004330 Rhodopsin Human genes 0.000 description 1
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- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
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- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
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- 238000000909 electrodialysis Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000010806 kitchen waste Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 244000000010 microbial pathogen Species 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
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- 239000010802 sludge Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
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Abstract
A device capable of eliminating organics in water by collaborative processing of UV-irradiation and sodium hypochlorite comprises a filter screen, a collection tank, a water pump, a metering pump, a sodium hypochlorite storage tank and an ultraviolet processing tank, wherein the filter screen is arranged at the upper part of the collecting tank; a sewage inlet and an outlet are respectively formed at the top part and the lower part of the collection tank; the outlet is connected with the inlet of the ultraviolet processing tank through the water pump, a flowmeter and a second valve which are connected in series; the inlet of the ultraviolet processing tank is connected with the outlet at the bottom of the sodium hypochlorite storage tank through the metering pump; and an overflow port and a drainage valve are respectively arranged at the upper part and the bottom of the ultraviolet processing tank. The device has innovative characteristics that a method of eliminating organics in water by collaborative processing of UV-irradiation and sodium hypochlorite is adopted, which first introduces aphotochemical method into the field of reducing COD (Chemical Oxygen Demand) and BOD (Biochemical Oxygen Demand) value in the water; harmful germs can be killed while the COD and BOD value is reduced; and when the sodium hypochlorite is adopted to kill harmful germs in the water, the residual chlorine concentration is reduced to zero, and secondary pollution is avoided.
Description
Technical field
The utility model relates to organic device in a kind of ultraviolet lighting and the collaborative elimination of clorox water, belongs to water-treatment technology field, is mainly used in the processing of town domestic sewage and industrial sewage.
Background technology
Along with the growth of population and the fast development of economic society, water resources in china is in short supply will be on the rise.Corresponding with shortage of water resources, another water problems of China is water environment pollution.China's water pollution is mainly from two aspects, and the one, industrial development discharge beyond standards trade effluent, the 2nd, in urbanization, due to town sewage discharging and facility for the central disposal famine, the unprocessed water bodys that directly enter of sanitary sewage cause environmental pollution in a large number.In recent years, the town domestic sewage quantity discharged was with average annual 5% speed increase, and surpassed first the industrial sewage quantity discharged in 1999, accounted for 52.9% of national total amount of sewage discharge.China Environmental State Bulletin statistics in 2003, whole nation industry and urban life wastewater emission amount are 46,000,000,000 tons, wherein discharged volume of industrial waste water is 212.4 hundred million tons, 247.6 hundred million tons of town domestic sewage quantity dischargeds, 1333.6 ten thousand tons of chemical oxygen demand (COD) in waste water (COD) total emission volumns, in town domestic sewage, the COD quantity discharged is 821.7 ten thousand tons.As can be seen from the above data; town domestic sewage has become the first source that water pollutes; its control is directly connected to the protection of water body, water quality and the sustainable use of water resources; it is one of emphasis of China's water prevention and cure of pollution and environment protection; for improving city environmental quality and resident's living environment, promote the Sustainable development tool of society to be of great significance.
Town domestic sewage refers to that mainly the facilities such as city resident family, hotel, institutional settings, school, market due to the sewage that life utilization produces, mainly comprise: flushing supply, life bath water, kitchen waste water etc.These domestic water consumptions are large, often contain the inorganicss such as higher organism (as protein, grease, starch etc.) and nitrogen, phosphorus, in addition, also contain pathogenic micro-organism and more suspended substance.
Pollutent in town domestic sewage generally includes three major types: organism, suspended solids (SS), nutrition (phosphorus and nitrogen), these pollutents are all the removal objects of conventional processing (take qualified discharge as main purpose) and advanced treatment (take regeneration as main purpose).It is main coagulation and take biological treatment as main two stages of second-stage treatment that conventional sewage disposal is divided into again physical removal usually.Wherein, represent organic pollution level in water body with chemical oxygen demand (COD) (COD) and biochemical oxygen demand (BOD) (BOD) numerical value, numerical value is larger, and water body is more serious by the degree of Organic pollutants.COD and BOD value have become the important parameter of many water quality detection standards at present, are one of most important water quality parameters of present sewage treatment area.
Domestic sewage processing method is divided into Physical, physical chemistry and chemical method, biochemical process and electrochemical method.Generally each treatment process is used seldom separately, mostly adopts the form of two kinds or two or more method combinations to carry out sewage disposal.Wherein reduce COD and the BOD value has following several method:
Physical: adopt mechanical means to remove suspended solid magazine in sewage, generally comprise: screen out, the technology such as precipitation, air supporting, filtration and membrane sepn.Its principle is namely to make the organism that is attached to solid particles surface along with solid is separated from water together, thereby reduces COD and BOD value.
Physical chemistry and chemical method: add some chemical substance in sewage, the pollutent by in effect separation, conversion, destruction or the recovery sewage of chemical reaction and medicament mainly comprises coagulating sedimentation, neutralization, redox, absorption electrodialysis etc.Chemical method mainly utilizes the effect of chemical reaction to process pollutent.
Biochemical process: utilize microbiological deterioration, make the organic pollutant in sewage transform, decompose.Biochemical process can be divided into aerobe to be processed and anaerobic biological treatment.Method commonly used has activated sludge process and biomembrance process.
Electrochemical process: utilize after the energising of special battery lead plate by the contacting of pole plate and sewage, the organism in direct oxidation water is decomposed into carbonic acid gas and water with it; Or utilize electrochemical reaction, and produce electric flocculation process, produce colloid in water, suspended substance in absorption sewage, there is or is attached to solid particles surface in partial organic substances with suspended state, can be removed from water body with colloid, thereby reach the effect that reduces COD and BOD.
Make in all sorts of ways reduce water in when COD and BOD value, all have certain limitation: utilize Physical or electro-flucculation process to separate by the organism that insoluble solid in water is entrained from water, for the organism that is dissolved in water, these methods can not play the effect that reduces COD and BOD value; For biochemical process, after organism, reduction COD and BOD value in bacterial degradation water, according to the relevant criterion requirement, also need to throw in addition sterilant (clorox) and kill intestinal bacteria in water, in addition, many standards also have mandatory requirement to the residual concentration of processing clorox in rear water, therefore need to carry out necessary neutralization; Adopt the electrolytic process energy consumption higher than other several methods, in addition, as electrolysis under the fresh water condition, still need add sterilant to process after processing.
Summary of the invention
The utility model aims to provide organic device in a kind of ultraviolet lighting and the collaborative elimination of clorox water, kills simultaneously intestinal bacteria and basically eliminate chlorine residue in water.
the technical solution of the utility model is: organic device in the collaborative elimination of a kind of ultraviolet lighting and clorox water, it is characterized in that, comprise filter screen, holding tank, water pump, volume pump, clorox storage tank and ultraviolet treatment tank, filter screen is located at the top of holding tank, top and bottom at holding tank are respectively equipped with sewage inlet and outlet, this outlet is by the water pump of series connection, under meter be connected the entrance of valve with the ultraviolet treatment tank and be connected, entrance at this ultraviolet treatment tank also is connected by the outlet of volume pump with the clorox tank bottom, top and bottom at this ultraviolet treatment tank are respectively equipped with overflow port and sewage draining valve.
Described holding tank passes through stent support; Be provided with discharge outlet in the bottom of this holding tank and the first valve for blowdown or sampling is housed; Top at this holding tank is provided with sealed tank cap.
The chlorine bleach liquor of flowing out from described clorox storage tank is provided with discharge outlet with the mixed pipeline of sewage that flows out from the second valve and is equipped with for sewage sampling and detects the 3rd valve that mixes rear sewage residual chlorine concentration.
Described ultraviolet treatment tank comprises shell, quartz socket tube and ultraviolet lamp tube, and ultraviolet lamp tube is installed in the enclosure, and the ultraviolet lamp tube outer cover has quartz socket tube that fluorescent tube and sewage are completely cut off; Ultraviolet lamp tube and quartz socket tube are fixed by support.
Upper and lower in described holding tank is respectively equipped with liquid level control switch and lower liquid level control switch, and described upper liquid level control switch, lower liquid level control switch, water pump, under meter, volume pump and ultraviolet lamp tube are controlled by a housing.
The utility model is compared with other treatment technologies, and its innovative point is:
1. first photochemical method is incorporated into the field that reduces COD and BOD value in water;
2. kill harmful germ in water when reducing COD and BOD value;
Utilize clorox kill water in harmful germ, can make that in water, residual chlorine concentration is reduced to 0, non-secondary pollution.
In water after ultraviolet lighting and clorox associated treatment, COD and BOD numerical value have largely and to reduce, and it reduces in degree visual purple external radiation exposure intensity, irradiation time water the factor such as clorox concentration and decides.Adopt separately clorox or ultraviolet lighting to process, COD and BOD value significantly do not change.After passing through associated treatment simultaneously, in water, intestinal bacteria quantity is almost nil, and chlorine residue is eliminated basically.
Description of drawings
Fig. 1 is formation picture of device of the present utility model.
Embodiment
referring to Fig. 1, organic device in the collaborative elimination of a kind of ultraviolet lighting of the utility model and clorox water, comprise filter screen 1, holding tank 2, water pump 6, volume pump 9, clorox storage tank 10 and ultraviolet treatment tank 11, filter screen 1 is located at the top of holding tank 2, top and bottom at holding tank 2 are respectively equipped with sewage inlet 21 and outlet, this outlet is by the water pump 6 of series connection, under meter 7 be connected the entrance of valve 8 with ultraviolet treatment tank 11 and be connected, also be connected with the outlet of clorox storage tank 10 bottoms by volume pump 9 at the entrance of this ultraviolet treatment tank 11, top and bottom at this ultraviolet treatment tank 11 are respectively equipped with overflow port 15 and sewage draining valve 16.
Described holding tank 2 supports by support 17; Be provided with discharge outlet in the bottom of this holding tank 2 and the first valve 18 is housed, be used for blowdown or sampling; Be provided with cover 19 on the top of this holding tank 2.
The chlorine bleach liquor of flowing out from described clorox storage tank 10 be provided with discharge outlet and the 3rd valve 20 be housed from second 8 mixed pipeline of sewage that flows out of valve, be used for sewage sampling, detect mix after residual chlorine concentration in sewage.
In described ultraviolet treatment tank 11, ultraviolet lamp tube 12 is installed, ultraviolet lamp tube 12 outer cover have quartz socket tube 13 that fluorescent tube and sewage are completely cut off; Ultraviolet lamp tube 12 and quartz socket tube 13 are fixing by support 14.
Upper and lower in described holding tank 2 is respectively equipped with liquid level control switch 3 and lower liquid level control switch 4, and described upper liquid level control switch 3, lower liquid level control switch 4, water pump 6, under meter 7, volume pump 9 and ultraviolet lamp tube 12 are controlled by a housing 5.
Working process of the present utility model is: the sewage of introducing from sewage inlet 21 enters holding tank 2 by filter screen 1 through after coarse filtration, be provided with liquid level control switch 3 and lower liquid level control switch 4 in holding tank 2, upper liquid level control switch 3 sends initiating signal startup water pump 6 to housing 5 when sewage level arrives high liquid level point, and sewage is extracted out from holding tank 2; When sewage level arrived low liquid level point, lower liquid level control switch 4 sent to housing 5 work that stop signal stops water pump 6.The discharge of sewage of water pump 6 is controlled by regulated valve 8, simultaneously the under meter 7 monitoring discharges of sewage.When water pump 6 started, volume pump 9 also started simultaneously, and the chlorine bleach liquor in clorox storage tank 10 is extracted out, pumped in pipeline and mixed with sewage.The clorox flow can be regulated by volume pump 9.Mixed sewage enters in ultraviolet treatment tank 11, and sewage flows out from overflow weir 15 after ultraviolet treatment tank 11 stops certain hour.The sewage draining valve 16 of ultraviolet treatment tank 11 bottoms can regularly be discharged the bottom cement admixture.
The utility model is for the organism in various water bodys, adopts organism in the method water of decomposition of ultraviolet lighting and clorox associating, thus COD and BOD value in reduction water.cardinal principle is: sewage advances to filter, after the precipitation pre-treatment, add finite concentration hypochlorous acid (clorox) solution, flow through the container of ultraviolet lamp is installed, under the irradiation of some strength ultraviolet lamp, control the illuminated time of water body by the design of modifier internal structure and water volume flow rate, hypochlorous acid in water (clorox) is under UV-irradiation, the generation photochemistry is decomposed, produce nascent oxygen, this nascent oxygen has very strong oxidation capacity, can be with oxidation operation in water, be decomposed into carbonic acid gas and water, thereby COD and BOD numerical value in reduction water, simultaneously under the acting in conjunction of hypochlorous acid (clorox) and ultraviolet lighting, in water, intestinal bacteria also are killed simultaneously.In addition, hypochlorous acid (clorox) is decomposed under the ultraviolet lighting effect, and is very low without remaining hypochlorous acid (clorox) or residual concentration in last water.Reaction process is as follows:
(1)
When sewage was processed, this treatment process can be used separately or unite to use with additive method and carry out advanced treatment.
Claims (5)
1. a ultraviolet lighting and clorox are collaborative eliminates organic device in water, it is characterized in that, comprise filter screen, holding tank, water pump, volume pump, clorox storage tank and ultraviolet treatment tank, filter screen is located at the top of holding tank, top and bottom at holding tank are respectively equipped with sewage inlet and outlet, this outlet is by the water pump of series connection, under meter be connected the entrance of valve with the ultraviolet treatment tank and be connected, entrance at this ultraviolet treatment tank also is connected by the outlet of volume pump with the clorox tank bottom, top and bottom at this ultraviolet treatment tank are respectively equipped with overflow port and sewage draining valve.
2. organic device in the collaborative elimination of ultraviolet lighting according to claim 1 and clorox water, is characterized in that, described holding tank passes through stent support; Be provided with discharge outlet in the bottom of this holding tank and the first valve for blowdown or sampling is housed; Top at this holding tank is provided with sealed tank cap.
3. ultraviolet lighting according to claim 1 and clorox are worked in coordination with and are eliminated organic device in water, it is characterized in that, the chlorine bleach liquor of flowing out from described clorox storage tank is provided with discharge outlet with the mixed pipeline of sewage that flows out from the second valve and is equipped with for sewage sampling and detects the 3rd valve that mixes rear sewage residual chlorine concentration.
4. ultraviolet lighting according to claim 1 and clorox are worked in coordination with and are eliminated organic device in water, it is characterized in that, described ultraviolet treatment tank comprises shell, quartz socket tube and ultraviolet lamp tube, ultraviolet lamp tube is installed in the enclosure, and the ultraviolet lamp tube outer cover has quartz socket tube that fluorescent tube and sewage are completely cut off; Ultraviolet lamp tube and quartz socket tube are fixed by support.
5. ultraviolet lighting according to claim 1 and clorox are worked in coordination with and are eliminated organic device in water, it is characterized in that, upper and lower in described holding tank is respectively equipped with liquid level control switch and lower liquid level control switch, and described upper liquid level control switch, lower liquid level control switch, water pump, under meter, volume pump and ultraviolet lamp tube are controlled by a housing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012205012069U CN202936224U (en) | 2012-09-27 | 2012-09-27 | Device capable of eliminating organics in water by collaborative processing of UV-irradiation and sodium hypochlorite |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012205012069U CN202936224U (en) | 2012-09-27 | 2012-09-27 | Device capable of eliminating organics in water by collaborative processing of UV-irradiation and sodium hypochlorite |
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| Publication Number | Publication Date |
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| CN202936224U true CN202936224U (en) | 2013-05-15 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2012205012069U Expired - Lifetime CN202936224U (en) | 2012-09-27 | 2012-09-27 | Device capable of eliminating organics in water by collaborative processing of UV-irradiation and sodium hypochlorite |
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| CN (1) | CN202936224U (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104528874A (en) * | 2014-12-31 | 2015-04-22 | 山东圣琪生物有限公司 | Process water sterilization system for fermentation |
| CN109133281A (en) * | 2018-11-01 | 2019-01-04 | 广州新奥环境技术有限公司 | MODS decontamination system |
| CN110282695A (en) * | 2019-07-31 | 2019-09-27 | 上海应用技术大学 | A kind of method that ultraviolet/chlorine group technology removes phenylurea analog herbicide isoproturon in water removal |
-
2012
- 2012-09-27 CN CN2012205012069U patent/CN202936224U/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104528874A (en) * | 2014-12-31 | 2015-04-22 | 山东圣琪生物有限公司 | Process water sterilization system for fermentation |
| CN109133281A (en) * | 2018-11-01 | 2019-01-04 | 广州新奥环境技术有限公司 | MODS decontamination system |
| CN110282695A (en) * | 2019-07-31 | 2019-09-27 | 上海应用技术大学 | A kind of method that ultraviolet/chlorine group technology removes phenylurea analog herbicide isoproturon in water removal |
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