CN104262864A - Conductive PVC (polyvinyl chloride) shoe sole material and manufacturing method thereof - Google Patents
Conductive PVC (polyvinyl chloride) shoe sole material and manufacturing method thereof Download PDFInfo
- Publication number
- CN104262864A CN104262864A CN201410568381.3A CN201410568381A CN104262864A CN 104262864 A CN104262864 A CN 104262864A CN 201410568381 A CN201410568381 A CN 201410568381A CN 104262864 A CN104262864 A CN 104262864A
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- China
- Prior art keywords
- sole material
- conduction
- pvc
- obtains
- conduction pvc
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a conductive PVC shoe sole material. The conductive PVC shoe sole material comprises the following components in parts by weight: 40-60 parts of PVC, 5-15 parts of conductive carbon fibers, 2-10 parts of dispersing agent, 15-30 parts of plasticizer, 1-5 parts of stabilizer, 0.5-1 part of lubricating agent and 0.5-1 part of filler. The invention further discloses a manufacturing method of the conductive PVC shoe sole material. The conductive PVC shoe sole material provided by the invention is better in conductivity.
Description
Technical field:
The present invention relates to a kind of material for sole of shoe, particularly relate to a kind of conduction PVC sole material and manufacture method thereof.
Background technology:
PVC and polyvinyl chloride, be a kind of macromolecular material using a chlorine atom to replace a hydrogen atom in polyethylene, its structure is as follows: [-CH2-CHCl-] n.PVC is more stable, have fire-retardant, chemical proofing is high, the good advantage of physical strength, therefore can be used as material for sole of shoe.PVC sole material has feature that is wear-resisting, water-fast, good springiness, but does not have the function of conduction.Under the occasion that electrostatic can not be had to produce (such as Electronic Components Manufacturing workshop, petrochemical industry workshop, mine etc.), there is potential safety hazard in existing PVC sole material.
Summary of the invention:
The technical problem to be solved in the present invention is to provide a kind of conduction PVC sole material, possesses good conductivity.
For solving the problems of the technologies described above, technical scheme of the present invention is:
A kind of conduction PVC sole material, its weight part consists of:
Preferably, conductive carbon fibre of the present invention is short incisal guide electric carbon fiber.
Preferably, dispersion agent of the present invention is one or both in polyethylene wax, oxidized polyethlene wax.
Preferably, softening agent of the present invention is one or both in dioctyl phthalate (DOP), dibutyl phthalate, dioctyl sebacate, tritolyl phosphate, triphenylphosphate.
Preferably, stablizer of the present invention is one or both in barium stearate, cadmium stearate.
Preferably, lubricant of the present invention is calcium stearate.
Preferably, filler of the present invention is calcium carbonate.
Another technical problem that the present invention will solve is to provide the manufacture method of above-mentioned conduction PVC sole material.
For solving the problems of the technologies described above, technical scheme is:
Conduct electricity the manufacture method of PVC sole material, comprise the following steps:
(1) mixing: by formula by mixing to PVC, softening agent, stablizer, temperature is 50 ~ 120 DEG C, then other component added in formula is mixing, obtains the material mixed;
(2) extrude: the material that step (1) obtains is added forcing machine, extrude and obtain conduction PVC pellet;
(3) injection moulding: the conduction PVC pellet that step (2) obtains is added injection moulding machine, injection moulding obtains conduction PVC sole material.
Therefore compared with prior art, the present invention has following beneficial effect:
Conductive carbon fibre has high conductivity, adds conductive carbon fibre it can be made to obtain good conductivity in material for sole of shoe; In addition, the dispersion agent in the present invention can make conductivity homogeneous and stable, and softening agent can make the fusion between conductive carbon fibre and PVC more abundant, can give full play to the excellent properties of conductive carbon fibre.
Embodiment:
Describe the present invention in detail below in conjunction with specific embodiment, be used for explaining the present invention in this illustrative examples of the present invention and explanation, but not as a limitation of the invention.
Embodiment 1
A kind of conduction PVC sole material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) mixing: by formula by mixing to PVC, softening agent, stablizer, temperature is 50 DEG C, then other component added in formula is mixing, obtains the material mixed;
(2) extrude: the material that step (1) obtains is added forcing machine, extrude and obtain conduction PVC pellet;
(3) injection moulding: the conduction PVC pellet that step (2) obtains is added injection moulding machine, injection moulding obtains conduction PVC sole material.
Embodiment 2
A kind of conduction PVC sole material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) mixing: by formula by mixing to PVC, softening agent, stablizer, temperature is 100 DEG C, then other component added in formula is mixing, obtains the material mixed;
(2) extrude: the material that step (1) obtains is added forcing machine, extrude and obtain conduction PVC pellet;
(3) injection moulding: the conduction PVC pellet that step (2) obtains is added injection moulding machine, injection moulding obtains conduction PVC sole material.
Embodiment 3
A kind of conduction PVC sole material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) mixing: by formula by mixing to PVC, softening agent, stablizer, temperature is 120 DEG C, then other component added in formula is mixing, obtains the material mixed;
(2) extrude: the material that step (1) obtains is added forcing machine, extrude and obtain conduction PVC pellet;
(3) injection moulding: the conduction PVC pellet that step (2) obtains is added injection moulding machine, injection moulding obtains conduction PVC sole material.
Embodiment 4
A kind of conduction PVC sole material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) mixing: by formula by mixing to PVC, softening agent, stablizer, temperature is 60 DEG C, then other component added in formula is mixing, obtains the material mixed;
(2) extrude: the material that step (1) obtains is added forcing machine, extrude and obtain conduction PVC pellet;
(3) injection moulding: the conduction PVC pellet that step (2) obtains is added injection moulding machine, injection moulding obtains conduction PVC sole material.
Embodiment 5
A kind of conduction PVC sole material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) mixing: by formula by mixing to PVC, softening agent, stablizer, temperature is 80 DEG C, then other component added in formula is mixing, obtains the material mixed;
(2) extrude: the material that step (1) obtains is added forcing machine, extrude and obtain conduction PVC pellet;
(3) injection moulding: the conduction PVC pellet that step (2) obtains is added injection moulding machine, injection moulding obtains conduction PVC sole material.
Embodiment 6
A kind of conduction PVC sole material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) mixing: by formula by mixing to PVC, softening agent, stablizer, temperature is 90 DEG C, then other component added in formula is mixing, obtains the material mixed;
(2) extrude: the material that step (1) obtains is added forcing machine, extrude and obtain conduction PVC pellet;
(3) injection moulding: the conduction PVC pellet that step (2) obtains is added injection moulding machine, injection moulding obtains conduction PVC sole material.
By the examination criteria of conduction PVC sole material obtained for embodiment 1 to 6 according to GB GB21148-2007, test its volume resistance respectively, result is respectively 6.8 × 10
5Ω cm, 2.5 × 10
5Ω cm, 3.2 × 10
5Ω cm, 4.8 × 10
5Ω cm, 5.1 × 10
5Ω cm, 6.3 × 10
5Ω cm, all has good conductivity.
Above-described embodiment is illustrative principle of the present invention and effect thereof only, but not for limiting the present invention.Any person skilled in the art scholar all without prejudice under spirit of the present invention and category, can modify above-described embodiment or changes.Therefore, such as have in art usually know the knowledgeable do not depart from complete under disclosed spirit and technological thought all equivalence modify or change, must be contained by claim of the present invention.
Claims (8)
1. a conduction PVC sole material, is characterized in that: its weight part consists of:
2. one conduction PVC sole material according to claim 1, is characterized in that: described conductive carbon fibre is short incisal guide electric carbon fiber.
3. one conduction PVC sole material according to claim 1, is characterized in that: described dispersion agent is one or both in polyethylene wax, oxidized polyethlene wax.
4. one conduction PVC sole material according to claim 1, is characterized in that: described softening agent is one or both in dioctyl phthalate (DOP), dibutyl phthalate, dioctyl sebacate, tritolyl phosphate, triphenylphosphate.
5. one conduction PVC sole material according to claim 1, is characterized in that: described stablizer is one or both in barium stearate, cadmium stearate.
6. one conduction PVC sole material according to claim 1, is characterized in that: described lubricant is calcium stearate.
7. one conduction PVC sole material according to claim 1, is characterized in that: described filler is calcium carbonate.
8. a kind of according to claim 1 ~ 7 any one conducts electricity the manufacture method of PVC sole material, it is characterized in that: comprise the following steps:
(1) mixing: by formula by mixing to PVC, softening agent, stablizer, temperature is 50 ~ 120 DEG C, then other component added in formula is mixing, obtains the material mixed;
(2) extrude: the material that step (1) obtains is added forcing machine, extrude and obtain conduction PVC pellet;
(3) injection moulding: the conduction PVC pellet that step (2) obtains is added injection moulding machine, injection moulding obtains conduction PVC sole material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410568381.3A CN104262864A (en) | 2014-10-22 | 2014-10-22 | Conductive PVC (polyvinyl chloride) shoe sole material and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410568381.3A CN104262864A (en) | 2014-10-22 | 2014-10-22 | Conductive PVC (polyvinyl chloride) shoe sole material and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104262864A true CN104262864A (en) | 2015-01-07 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410568381.3A Pending CN104262864A (en) | 2014-10-22 | 2014-10-22 | Conductive PVC (polyvinyl chloride) shoe sole material and manufacturing method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106633530A (en) * | 2016-12-28 | 2017-05-10 | 李勇军 | Conductive PVC colloidal particles and manufacturing method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4521553A (en) * | 1984-04-13 | 1985-06-04 | Dycem Limited | Anti-static highly-plasticized polyvinylchloride |
| CN101438869A (en) * | 2008-11-14 | 2009-05-27 | 苏州新纶超净技术有限公司 | Shoes with antibiotic antistatic/conductive function and method for producing the same |
-
2014
- 2014-10-22 CN CN201410568381.3A patent/CN104262864A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4521553A (en) * | 1984-04-13 | 1985-06-04 | Dycem Limited | Anti-static highly-plasticized polyvinylchloride |
| CN101438869A (en) * | 2008-11-14 | 2009-05-27 | 苏州新纶超净技术有限公司 | Shoes with antibiotic antistatic/conductive function and method for producing the same |
Non-Patent Citations (1)
| Title |
|---|
| 陈耀庭等: "碳纤维/聚合物复合材料的导电性及电磁屏蔽性能的研究", 《塑料科技》, no. 6, 31 December 1997 (1997-12-31), pages 4 - 7 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106633530A (en) * | 2016-12-28 | 2017-05-10 | 李勇军 | Conductive PVC colloidal particles and manufacturing method thereof |
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Application publication date: 20150107 |