CN104262799A - High-wear resistance plastic veneer - Google Patents
High-wear resistance plastic veneer Download PDFInfo
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- CN104262799A CN104262799A CN201410567397.2A CN201410567397A CN104262799A CN 104262799 A CN104262799 A CN 104262799A CN 201410567397 A CN201410567397 A CN 201410567397A CN 104262799 A CN104262799 A CN 104262799A
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- plastic
- plastic wrapper
- powder
- wood powder
- raw material
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- 229920003023 plastic Polymers 0.000 title claims abstract description 72
- 239000004033 plastic Substances 0.000 title claims abstract description 72
- 239000002994 raw material Substances 0.000 claims abstract description 30
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims abstract description 12
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 9
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 9
- 239000004642 Polyimide Substances 0.000 claims abstract description 8
- 229920001721 polyimide Polymers 0.000 claims abstract description 8
- WEAPVABOECTMGR-UHFFFAOYSA-N triethyl 2-acetyloxypropane-1,2,3-tricarboxylate Chemical compound CCOC(=O)CC(C(=O)OCC)(OC(C)=O)CC(=O)OCC WEAPVABOECTMGR-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000006057 Non-nutritive feed additive Substances 0.000 claims abstract description 5
- 239000003063 flame retardant Substances 0.000 claims abstract description 5
- 239000000843 powder Substances 0.000 claims description 42
- 239000000463 material Substances 0.000 claims description 36
- 239000002023 wood Substances 0.000 claims description 35
- 230000008878 coupling Effects 0.000 claims description 22
- 238000010168 coupling process Methods 0.000 claims description 22
- 238000005859 coupling reaction Methods 0.000 claims description 22
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 19
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical class [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 15
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 15
- 238000004513 sizing Methods 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 7
- CSHCPECZJIEGJF-UHFFFAOYSA-N methyltin Chemical compound [Sn]C CSHCPECZJIEGJF-UHFFFAOYSA-N 0.000 claims description 7
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 7
- 238000007639 printing Methods 0.000 claims description 6
- 238000011084 recovery Methods 0.000 claims description 6
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- 239000003822 epoxy resin Substances 0.000 claims description 5
- 239000008187 granular material Substances 0.000 claims description 5
- 238000009775 high-speed stirring Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- 229920000728 polyester Polymers 0.000 claims description 5
- 238000010298 pulverizing process Methods 0.000 claims description 5
- 229930188012 Bromoether Natural products 0.000 claims description 3
- 235000007164 Oryza sativa Nutrition 0.000 claims description 3
- HJCMMOODWZOXML-UHFFFAOYSA-N bromo hypobromite Chemical compound BrOBr HJCMMOODWZOXML-UHFFFAOYSA-N 0.000 claims description 3
- 239000010903 husk Substances 0.000 claims description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 3
- 239000000347 magnesium hydroxide Substances 0.000 claims description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 3
- 235000012054 meals Nutrition 0.000 claims description 3
- 235000009566 rice Nutrition 0.000 claims description 3
- 239000010902 straw Substances 0.000 claims description 3
- 240000007594 Oryza sativa Species 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000002910 solid waste Substances 0.000 abstract description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 abstract 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 abstract 2
- -1 polypropylene ethylene Polymers 0.000 abstract 2
- 239000004800 polyvinyl chloride Substances 0.000 abstract 2
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 2
- 230000003712 anti-aging effect Effects 0.000 abstract 1
- YAHBZWSDRFSFOO-UHFFFAOYSA-L dimethyltin(2+);2-(2-ethylhexoxy)-2-oxoethanethiolate Chemical compound CCCCC(CC)COC(=O)CS[Sn](C)(C)SCC(=O)OCC(CC)CCCC YAHBZWSDRFSFOO-UHFFFAOYSA-L 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 241000209094 Oryza Species 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/20—Recycled plastic
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a high-wear resistance plastic veneer. The plastic veneer comprises the following raw materials in percentage by weight: 25-35% of recycled polypropylene ethylene, 15-20% of PVC (polyvinyl chloride), 10-20% of ABS (acrylonitrile butadiene styrene) plastic, 8-15% of a filler, 5-8% of vinyl bisstearamide, 0.5-3% of a fire retardant, 0.5-1% of an antioxygen 1076, 0.5-3% of a processing aid, 2-5% of styrene-butadiene-styrene block copolymer, 5-10% of polyimide, 2-3% of acetyl triethyl citrate, 0.5-1% of methyltin mercaptide and 0.5-1.5% of an anti-aging agent 264. The plastic veneer takes the recycled polypropylene ethylene as a main raw material, so that economical recycle of solid waste is achieved; the plastic veneer can be repeatedly recycled for use; through synergistic effect of multiple raw materials, not only are compatibility of the raw materials and wear resistance of the plastic veneer enhanced, but also mechanical properties of the plastic veneer are significantly improved, the service life of the plastic veneer is prolonged, and thus the production cost and the using cost are reduced.
Description
Technical field
The present invention relates to the Plastic wrapper that a kind of wear resistance is high, belong to Material Field.
Background technology
Plastics and plastics are in the evolution of last 100 years, for the production of the mankind and life bring huge contribution and unlimited convenience, but As time goes on some plastics are after its life cycle terminates, plastic refuse serious environment pollution, has become an increasingly serious problem.Chinese Plastics processing industry association deputy secretary-general, the plastic reclaimed special commission secretary general Ma Zhanfeng that utilizes also think; landfill is not tackle waste plastic the best way; he says: " weight of plastics in rubbish is little, volume is large; determine its unsuitable landfill of ultimate disposal; and it is the macromolecular material that calorific value is very high; recycle the fundamental state policy meeting China's Sustainable development, also can make full use of its inherent value, and economize on resources, protection of the environment ".Therefore, carry out modification to plastics recovery material and make it reuse, for industry provides high performance regenerative raw materials, for society provides the heat recovery approach of clean and effective, the resource regeneration realizing plastics is significant.
Plastic wrapper is applied in the sheet materials such as glued board, multi-ply wood, decorative sheet, building template with its flexible advantage, and the wear resistance of these sheet materials requires higher, Plastic wrapper physical strength prepared by prior art is low, wear no resistance, cause sheet material easy to crack, easy to wear, cannot technical requirements be reached, affect work-ing life.Therefore, the focus that the high Plastic wrapper of a kind of wear resistance becomes research and development is developed.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art, provide a kind of prepare simple, intensity is high, wear resistance good, both artistic and practical Plastic wrapper.Plastic wrapper intensity of the present invention and wear resistance, good toughness, smooth, practical, and effectively can utilize poly-third ethene of recovery, reduce and produce and use cost, realize comprehensive utilization of resources.
For achieving the above object, present invention employs following technical scheme:
The Plastic wrapper that wear resistance is high, is made up of the raw material of following weight percent: reclaim poly-third ethene 25-35, PVC15-20, ABS plastic 10-20, weighting agent 8-15, vinyl bis-stearamides 5-8, fire retardant 0.5-3, antioxidant 1076 0.5-1, processing aid 0.5-3, styrene-butadiene-styrene block copolymer 2-5, polyimide 5-10, acetyl triethyl citrate 2-3, methyl tin 0.5-1, antioxidant 264 0.5-1.5.
In the present invention, styrene-butadiene-styrene block copolymer and vinyl bis-stearamides act synergistically, and gained Plastic wrapper toughness increases, and wear resistance strengthens, and surfacing is smooth.
Described, the Plastic wrapper that a kind of wear resistance is high is prepared by following steps:
A) each raw material is taken by formula;
B) raw material is put into the blended 10-20 minute of high speed mixer, obtain material 1;
C) material 1 is put into pulverizing mill, grind 30-50 minute under 100-120 DEG C of condition, cooler is cooled to 20-40 DEG C, crosses 120 mesh sieves, obtains material 2;
D) material 2 is carried out mixing by flat two plastics machine at 180-200 DEG C, through abrasive tool moulding at 190-210 DEG C, at 20-90 DEG C through three roller plastics sheet machine sizings;
E) pattern printing is carried out through color press after sizing;
F) musculus cutaneus printed plated film under the condition of 250-300 DEG C, coating raw material is polyester granulate, obtains Plastic wrapper.
Plastic wrapper of the present invention, by plated film, makes material brighter, smooth, plays a very good protection, and have waterproof and dampproof excellent properties.
Described, weighting agent is made up of activated Calcium carbonate, talcum powder and coupling wood powder.
Described, fire retardant is the one in TDE, brominated epoxy resin or eight bromo ether.
Described, processing aid is the one in zinc borate or magnesium hydroxide.
Preferably, Plastic wrapper is made up of the raw material of following weight percent: reclaim poly-third ethene 30, PVC 17, ABS plastic 15, weighting agent 12, vinyl bis-stearamides 7, brominated epoxy resin 2, antioxidant 1076 0.8, zinc borate 1.0, styrene-butadiene-styrene block copolymer 4, polyimide 7, acetyl triethyl citrate 2.5, methyl tin 0.7, antioxidant 264 1.0.
Described, coupling wood powder is by 50-200 object wood powder at 90-110 DEG C, with 1000-2000 rev/min of stirring, adds the silane coupling agent KH560 accounting for wood powder weight 0.5-5% while stirring, and high-speed stirring 10-30 minute obtained.
Coupling wood powder is obtained by silane coupler modified wood powder.The consistency of coupling wood powder and other material improves greatly, and interface compatibility improves, and the flexural strength of gained matrix material, tensile strength, resistance to impact shock and water tolerance improve.
Described, wood powder is any one in wood working scrap stock, rice husk meal, straw powder or shell powder.
Described, reclaiming poly-third ethene is any one in trolley part, hot material conveyor belt, electric wire or architectural waterproof material.
Described, reclaiming poly-third ethene, PVC and ABS plastic is 80-120 order powder.
Described, in weighting agent, the weight percent per-cent of activated Calcium carbonate, talcum powder, coupling wood powder is 1:0.3-0.8:1.0-1.5, and the particle diameter of activated Calcium carbonate, talcum powder, coupling wood powder is all less than 50 μm.
Beneficial effect of the present invention: the present invention is to reclaim poly-third ethene for main raw material, and the economic recovery achieving solid waste utilizes, and plastic cover micromicro repeats reclaiming use simultaneously, can not to environment; The present invention, by the synergy of plurality of raw materials, not only improves the wear resistance of material and the consistency of raw material, significantly improves the mechanical property of Plastic wrapper simultaneously, increase the service life, thus reduces production and use cost.The preparation of Plastic wrapper of the present invention is simple, easy to use, can carry out pattern printing according to different demands, elegant in appearance, has good application prospect.
Embodiment
Embodiment 1
The Plastic wrapper that a kind of wear resistance is high is made up of the raw material of following weight percent: reclaim poly-third ethene 25, PVC 20, ABS plastic 20, weighting agent 8, vinyl bis-stearamides 8, TDE 3, antioxidant 1076 0.5, zinc borate 0.5, styrene-butadiene-styrene block copolymer 2, polyimide 10, acetyl triethyl citrate 2, methyl tin 0.5, antioxidant 264 0.5.
Reclaim poly-third ethene for reclaiming wire cable material, PVC is suspension PVC, and proportion is 1.35g/cm
3, ABS plastic proportion is 1.05g/cm
3, reclaim poly-third ethene, PVC and ABS plastic and be 80 powder.
Styrene-butadiene-styrene block copolymer is star structure, and the equal relative molecular mass of number is about 3.6*10
5, styrene block massfraction is 28%.
Coupling wood powder is by 50 object wood working scrap stock at 110 DEG C, with 1000 revs/min of stirrings, adds the silane coupling agent KH560 accounting for wood powder weight 0.5% while stirring, and high-speed stirring 30 minutes is obtained.
Weighting agent is made up of activated Calcium carbonate, talcum powder, coupling wood powder, and wherein the weight percent per-cent of activated Calcium carbonate, talcum powder, coupling wood powder is 1:0.3:1.5, and the particle diameter of activated Calcium carbonate, talcum powder, coupling wood powder is 30 μm.
The Plastic wrapper that a kind of wear resistance is high is prepared by following steps:
A) each raw material is taken by formula;
B) raw material is put into high speed mixer blended 10 minutes, obtain material 1;
C) material 1 is put into pulverizing mill, grind 30 minutes under 120 DEG C of conditions, cooler is cooled to 40 DEG C, crosses 120 mesh sieves, obtains material 2;
D) material 2 is carried out mixing by flat two plastics machine at 180 DEG C, through abrasive tool moulding at 210 DEG C, at 20 DEG C through three roller plastics sheet machine sizings;
E) pattern printing is carried out through color press after sizing;
F) musculus cutaneus printed plated film under the condition of 250 DEG C, coating raw material is polyester granulate, obtains Plastic wrapper.
Embodiment 2
The Plastic wrapper that a kind of wear resistance is high is made up of the raw material of following weight percent: reclaim poly-third ethene 30, PVC 17, ABS plastic 15, weighting agent 12, vinyl bis-stearamides 7, brominated epoxy resin 2, antioxidant 1076 0.8, zinc borate 1.0, styrene-butadiene-styrene block copolymer 4, polyimide 7, acetyl triethyl citrate 2.5, methyl tin 0.7, antioxidant 264 1.0.
Reclaim poly-third ethene for reclaiming hot material conveyor belt, PVC is body PVC, and proportion is 1.42g/cm
3, ABS plastic proportion is 1.10g/cm
3, reclaim poly-third ethene, PVC and ABS plastic and be 100 order powder.
Styrene-butadiene-styrene block copolymer is star structure, and the equal relative molecular mass of number is about 3.8*10
5, styrene block massfraction is 32%.
Coupling wood powder is by 150 object straw powder at 100 DEG C, with 1500 revs/min of stirrings, adds the silane coupling agent KH560 accounting for wood powder weight 3% while stirring, and high-speed stirring 20 minutes is obtained.
Weighting agent is made up of activated Calcium carbonate, talcum powder, coupling wood powder, and wherein the weight percent per-cent of activated Calcium carbonate, talcum powder, coupling wood powder is 1:0.5:1.2, and the particle diameter of activated Calcium carbonate, talcum powder, coupling wood powder is 40 μm.
The Plastic wrapper that a kind of wear resistance is high is prepared by following steps:
A) each raw material is taken by formula;
B) raw material is put into high speed mixer blended 15 minutes, obtain material 1;
C) material 1 is put into pulverizing mill, grind 40 minutes under 110 DEG C of conditions, cooler is cooled to 30 DEG C, crosses 120 mesh sieves, obtains material 2;
D) material 2 is carried out mixing by flat two plastics machine at 190 DEG C, through abrasive tool moulding at 200 DEG C, at 50 DEG C through three roller plastics sheet machine sizings;
E) pattern printing is carried out through color press after sizing;
F) musculus cutaneus printed plated film under the condition of 270 DEG C, coating raw material is polyester granulate, obtains Plastic wrapper.
Embodiment 3
The Plastic wrapper that a kind of wear resistance is high is made up of the raw material of following weight percent: reclaim poly-third ethene 35, PVC 15, ABS plastic 10, weighting agent 15, vinyl bis-stearamides 5, eight bromo ether 0.5, antioxidant 1076 1, magnesium hydroxide 3, styrene-butadiene-styrene block copolymer 5, polyimide 5, acetyl triethyl citrate 3, methyl tin 1, antioxidant 264 1.5.
Reclaim poly-third ethene for reclaiming architectural waterproof material, PVC is suspension PVC, and proportion is 1.35g/cm
3, ABS plastic proportion is 1.15g/cm
3, reclaim poly-third ethene, PVC and ABS plastic and be 120 order powder.
Styrene-butadiene-styrene block copolymer is star structure, and the equal relative molecular mass of number is about 3.5*10
5, styrene block massfraction is 30%.
Coupling wood powder is by 200 object rice husk meals at 90 DEG C, with 2000 revs/min of stirrings, adds the silane coupling agent KH560 accounting for wood powder weight 5% while stirring, and high-speed stirring 10 minutes is obtained.
Weighting agent is made up of activated Calcium carbonate, talcum powder, coupling wood powder, and wherein the weight percent per-cent of activated Calcium carbonate, talcum powder, coupling wood powder is 1:0.8:1.0, and the particle diameter of activated Calcium carbonate, talcum powder, coupling wood powder is 50 μm.
The Plastic wrapper that a kind of wear resistance is high is prepared by following steps:
A) each raw material is taken by formula;
B) raw material is put into high speed mixer blended 20 minutes, obtain material 1;
C) material 1 is put into pulverizing mill, grind 50 minutes under 100 DEG C of conditions, cooler is cooled to 20 DEG C, crosses 120 mesh sieves, obtains material 2;
D) material 2 is carried out mixing by flat two plastics machine at 200 DEG C, through abrasive tool moulding at 190 DEG C, at 90 DEG C through three roller plastics sheet machine sizings;
E) pattern printing is carried out through color press after sizing;
F) musculus cutaneus printed plated film under the condition of 300 DEG C, coating raw material is polyester granulate, obtains Plastic wrapper.
Performance test
After Plastic wrapper obtained for embodiment 1-3 is required to make sample according to relevant criterion, make a service test, reference examples adopts Plastic wrapper obtained in a kind of building template Plastic wrapper and preparation method thereof disclosed in patent CN 103351513 A in contrast, and result is as shown in table 1.
Table 1 test result
| ? | Test method | Embodiment 1 | Embodiment 2 | Embodiment 3 | Reference examples |
| Tensile strength MPa | GB/T1040-2006 | 102 | 105 | 100 | 6.0 |
| Flexural strength MPa | GB/T9341-2000 | 98 | 101 | 95 | 59 |
| Tear strength kNm -1 | GB/T12833-2006 | 158 | 162 | 152 | 116 |
| Wear rate % | GB/T3960-1983 | 0.68 | 0.56 | 0.61 | 1.72 |
As can be seen from Table 1, a kind of Plastic wrapper provided by the invention has excellent mechanical property, and the tensile strength of Plastic wrapper of the present invention can reach more than 100MPa, and the tensile strength of reference examples is 6.0MPa
;the flexural strength of Plastic wrapper of the present invention can reach more than 95MPa, and the flexural strength of reference examples is 59MPa
;the tear strength of Plastic wrapper of the present invention is 150kNm
-1above, the tear strength of reference examples is 116kNm
-1; The wear rate of Plastic wrapper of the present invention is little, and about 0.6%, the wear rate of reference examples is 1.72%.
Finally, it should be noted that above what enumerate is only several specific embodiment of the present invention.Obviously, the present invention is not limited to above embodiment, can also have a lot of distortion.All distortion that those of ordinary skill in the art can directly derive or associate from content disclosed by the invention, all should think protection scope of the present invention.
Claims (7)
1. the Plastic wrapper that a wear resistance is high, it is characterized in that, be made up of the raw material of following weight percent: reclaim poly-third ethene 25-35, PVC15-20, ABS plastic 10-20, weighting agent 8-15, vinyl bis-stearamides 5-8, fire retardant 0.5-3, antioxidant 1076 0.5-1, processing aid 0.5-3, styrene-butadiene-styrene block copolymer 2-5, polyimide 5-10, acetyl triethyl citrate 2-3, methyl tin 0.5-1, antioxidant 264 0.5-1.5;
The Plastic wrapper that described a kind of wear resistance is high is prepared by following steps:
A) each raw material is taken by formula;
B) raw material is put into the blended 10-20 minute of high speed mixer, obtain material 1;
C) material 1 is put into pulverizing mill, grind 30-50 minute under 100-120 DEG C of condition, cooler is cooled to 20-40 DEG C, crosses 120 mesh sieves, obtains material 2;
D) material 2 is carried out mixing by flat two plastics machine at 180-200 DEG C, through abrasive tool moulding at 190-210 DEG C, at 20-90 DEG C through three roller plastics sheet machine sizings;
E) pattern printing is carried out through color press after sizing;
F) musculus cutaneus printed plated film under the condition of 250-300 DEG C, coating raw material is polyester granulate, obtains Plastic wrapper;
Described weighting agent is made up of activated Calcium carbonate, talcum powder and coupling wood powder;
Described fire retardant is the one in TDE, brominated epoxy resin or eight bromo ether;
Described processing aid is the one in zinc borate or magnesium hydroxide.
2. Plastic wrapper according to claim 1, it is characterized in that, described Plastic wrapper is made up of the raw material of following weight percent: reclaim poly-third ethene 30, PVC 17, ABS plastic 15, weighting agent 12, vinyl bis-stearamides 7, brominated epoxy resin 2, antioxidant 1076 0.8, zinc borate 1.0, styrene-butadiene-styrene block copolymer 4, polyimide 7, acetyl triethyl citrate 2.5, methyl tin 0.7, antioxidant 264 1.0.
3. Plastic wrapper according to claim 1 and 2, it is characterized in that, described coupling wood powder is by 50-200 object wood powder at 90-110 DEG C, with 1000-2000 rev/min of stirring, add the silane coupling agent KH560 accounting for wood powder weight 0.5-5% while stirring, high-speed stirring 10-30 minute obtained.
4. Plastic wrapper according to claim 3, is characterized in that, described wood powder is any one in wood working scrap stock, rice husk meal, straw powder or shell powder.
5. Plastic wrapper according to claim 1 and 2, is characterized in that, it is any one in trolley part, hot material conveyor belt, electric wire or architectural waterproof material that described recovery gathers the third ethene.
6. Plastic wrapper according to claim 5, is characterized in that, described recovery poly-third ethene, PVC and ABS plastic are 80-120 order powder.
7. Plastic wrapper according to claim 1 and 2, it is characterized in that, in described weighting agent, the weight percent per-cent of activated Calcium carbonate, talcum powder, coupling wood powder is 1:0.3-0.8:1.0-1.5, and the particle diameter of activated Calcium carbonate, talcum powder, coupling wood powder is all less than 50 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410567397.2A CN104262799B (en) | 2014-10-23 | 2014-10-23 | The Plastic wrapper that a kind of wearability is high |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104804558A (en) * | 2015-05-12 | 2015-07-29 | 山东现代诚信实业有限公司 | Antibacterial powder coating for pipeline |
| CN106928529A (en) * | 2017-05-15 | 2017-07-07 | 临沂大学 | A kind of composite regenerative plastic of high tenacity and preparation method thereof |
| CN107286480A (en) * | 2017-07-31 | 2017-10-24 | 杨化飞 | A kind of high-strength Plastic wrapper of high abrasion |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101921491A (en) * | 2010-08-23 | 2010-12-22 | 东莞市启原实业有限公司 | Wood plastic composite material |
| CN101962459A (en) * | 2010-10-22 | 2011-02-02 | 青岛国恩科技发展有限公司 | Flame retardant composite material with high flow and preparation method |
| CN103351513A (en) * | 2013-07-03 | 2013-10-16 | 卜凡华 | Plastic wrapper for building template and preparation method thereof |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101921491A (en) * | 2010-08-23 | 2010-12-22 | 东莞市启原实业有限公司 | Wood plastic composite material |
| CN101962459A (en) * | 2010-10-22 | 2011-02-02 | 青岛国恩科技发展有限公司 | Flame retardant composite material with high flow and preparation method |
| CN103351513A (en) * | 2013-07-03 | 2013-10-16 | 卜凡华 | Plastic wrapper for building template and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104804558A (en) * | 2015-05-12 | 2015-07-29 | 山东现代诚信实业有限公司 | Antibacterial powder coating for pipeline |
| CN106928529A (en) * | 2017-05-15 | 2017-07-07 | 临沂大学 | A kind of composite regenerative plastic of high tenacity and preparation method thereof |
| CN107286480A (en) * | 2017-07-31 | 2017-10-24 | 杨化飞 | A kind of high-strength Plastic wrapper of high abrasion |
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| CN104262799B (en) | 2016-07-06 |
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