CN104256295B

CN104256295B - The vegetarian diet powder and preparation method thereof of plant phenols glycinate phytic acid salt composite stability maintenance

Info

Publication number: CN104256295B
Application number: CN201410466389.9A
Authority: CN
Inventors: 贾福怀; 马云龙; 王彩霞; 王俊
Original assignee: NINGBO YUFANGTANG BIOTECHNOLOGY CO Ltd
Current assignee: NINGBO YUFANGTANG BIOTECHNOLOGY CO Ltd
Priority date: 2014-09-12
Filing date: 2014-09-12
Publication date: 2019-06-21
Anticipated expiration: 2034-09-12
Also published as: CN104256295A

Abstract

The invention discloses a kind of vegetarian diet powder of plant phenols glycinate phytic acid salt composite stability maintenance, in parts by weight, its component includes: 0.5~3 part of phytate of food-grade plant phenols glycinate, 0.05~1 part of food-grade vitamin E unsaturated fatty acid ester, ten 0.2~2 part of polyglycereol monounsaturated fatty acids ester of food-grade, 0.2~2 part of food grade sucrose aliphatic ester, 0.2~2 part of food-grade SUNSOFT 700P-2, 0.5~1 part of food-grade chitosan acylate, cold 88~95 parts of extruding vegetarian diet original powder, 1~5 part of food-grade Glycerin, mixed triester with caprylic acid capric acid, simultaneously, aforementioned vegetarian diet powder uses reasonable preparation method and is prepared.The advantages of vegetarian diet powder, is: can appropriateness supplement the nutrients, promote body health, anti-ageing life-prolonging and other effects, and lasting stability, at low cost, preparation is simple, is suitable for conventional equipment expanding production.The invention also discloses the preparation methods of the vegetarian diet powder.

Description

The vegetarian diet powder and preparation method thereof of plant phenols glycinate phytic acid salt composite stability maintenance

Technical field

The present invention relates to technical field of nutritional food, tie up more particularly, to a kind of plant phenols glycinate phytic acid salt composite Steady vegetarian diet powder.The invention further relates to the preparation methods of the vegetarian diet powder.

Background technique

The reasons such as diet structure is unreasonable, grain nutrition decline, excessive pesticide residues, hormone and abuse of antibiotics are directed at group The decline of the most basic unit cell quality of adult body makes the people in modernization fast pace life environment that inferior health be presented The ratio of state increasingly increases.Meanwhile appearing on the market for health food various in style is expedited the emergence of.

Wherein, there are some vegetarian diet powder class health foods to follow the traditional Chinese medicine tonic for enabling Chinese to multiply prosperity to support Physiology is read, and the U.S. face of the imperial disease of body-building and nutrition general equilibrium are achieved the effect that by food intake rather than in the form of drug injection, is become The domestic crazy favorite robbed of export trade expense person.Related hot-sale products mostly with vegetables and fruits powder, attainment powder and eats powder using names raw, as novel Health food has occupied entire health food market larger share.Certainly, related invention patent and application also emerge one after another.Example Such as: the Chinese invention patent of Publication No. CN 101467690A: containing there are five types of the alimentation compositions of kinds of processed vegetable and fruit articles, using five Kind color vegetable and fruit is raw material, and adds plant element and be composed.The Chinese invention patent of Publication No. CN101971985A: A kind of eating five-element's vegetables and fruits health care product, it is theoretical using Chinese medicine five-element health care, according to raw material color and taste, by various paddy Object powder, Vegetable powder and Fruit powder are mixed according to different proportion, and the health food of five kinds of colors is made.Publication No. The Chinese invention patent of CN101926463A: a kind of production method of cold cut fast food vegetables and fruits healthy food, it will be pollution-free, green Color, the fresh plant source raw-food material cereal of safety, vegetables and fruit carry out non-thermal physical field energy-saving dewatering and are dried, and powder Be broken to 80~120 mesh, by weight for cereal 10%~60%, vegetables 10%~50%, fruit 10%~40% ratio and Micronutrient function factor compounding is uniformly mixed, and the pure natural vegetables and fruits nutraceutical of available cold boiling water preparing fast food is made.It is public The number of opening is the Chinese invention patent of CN102613460A: instant full abdomen cereal fruit-vegetable powder of one kind and preparation method thereof discloses cereal Fruit vegetable powder is made of natural grain, fruits and vegetables and auxiliary material, and the cereal mainly includes brown rice, corn, wheat embryo, oat, buckwheat Wheat and bean dregs；Fruits and vegetables mainly include carrot meal, banaina, red date powder, burdock powder and tea powder；Auxiliary material mainly improves brew Can be with maltodextrin, cycloheptaamylose, monoglyceride and the lecithin of mouthfeel, auxiliary material further includes the high konjaku of expansion rate of water absorption Glue, pearl fruit and chitosan, main preparation step include: the cleaning of raw material, cereal curing, processing powder processed, pulverize and sieve, claim Amount is mixed and is packed in proportion.

But careful consumer can have found: beneficial effect and not up to advertisement of the such product of long term usage to health The boundary declared in publicity.To find out its cause, the mainly above-mentioned serial nutritious food of vegetarian diet powder has a defect to life: no Easy long-term preservation.That is, polyenoid grease contained therein, flavone compound, sterol, vitamin, polypeptide, protein, chlorogenic acid And the delay at any time of polysaccharide isoreactivity effective component and a series of deterioration reactions such as oxidation, denaturation, degradation and mildew occur, sternly The normal performance of product efficacy is affected again.Even, only half a year just starts rotten drop effect to some products, some are then because of metamorphic process It generates the toxin of aflatoxins etc and damages consumer health.

For this purpose, industry uses following proposal and measure to improve the long storage stability of the serial nutritious food of vegetarian diet powder:

(1) made with superpower antioxidant astaxanthin, Lycopene or natural vegetable powder containing substance of this kind and algae powder It is mixed for additive with vegetarian diet powder, it is intended to extend shelf life of products.Such as: the middle promulgated by the State Council of 103110112 A of Publication No. CN Bright patent: a kind of compound antioxidation nutritive food and its processing method are related to astaxanthin and are cooperateing with having for potent anti-oxidant aspect Beneficial effect.But the coupled difference of substance of this kind, is difficult in the biological tissue for penetrating into related fine powder, until make add uniformity it is undesirable and Influence antioxidant effect.In addition astaxanthin or Lycopene self stability are poor, expensive, until this technical solution is made always can not For in mass production.

(2) natural of conventional type moderate cost is modified, with improve its oxidation resistance, stability, Lipophilic, hydrophily and coupled with vegetarian diet powder, it is intended to can be fully infiltrated into after mixing such composition with vegetarian diet powder it is related carefully The fresh-keeping effect of antioxygen is played in the biological tissue of powder.Such as: the Chinese invention patent of 102675100 A of Publication No. CN: The ester derivant and medical application of resveratrol are involved in the problems, such as solving antioxidant resveratrol facile hydrolysis itself.Publication number It is related to improving hydrophily antioxygen for the Chinese invention patent of 1263083 A of CN: the preparation method of tea polyphenols higher fatty acids acid The compatibility problem of agent tea polyphenols and lipid material.The Chinese invention patent of 1800173 A of Publication No. CN: vitamin E is sub- The preparation of numb acid esters and vitamin E oleate is related to by carrying out esterification preparation between vitamin E and unsaturated fatty acid Vitamin E unsaturated fatty acid ester not only can achieve mutual protection, reduce oxidative deformation level, and the chemistry for improving them is steady It is qualitative, but also the dual mesh for enhancing original performance each other and assigning new function can be reached by novel bifunctional molecule 's.The Chinese invention patent of Publication No. CN 101390641A: phytic acid amino-acid ester salt is answered as edible grease antioxidant Be related to phytic acid amino-acid alkyl ester salt has good oil-soluble, excellent antioxidant activity and stabilization in edible oil Property, it is a kind of antioxidant of novel green.Aforementioned modified product is had taken great strides in one's progress on the antioxygen fresh-keeping effect of vegetarian diet powder, but Without important breakthrough in terms of persistence, and enzyme and microorganism can not be restrained to the negative effect of vegetarian diet powder.

(3) cladding processing is made to sensitive component using microcapsules or nano-lipid body technique, it is relatively steady is redispersed in other In fixed component, by advanced packaging, shelf-life longer vegetarian diet powder is prepared.But this technical solution complex process, it is raw High expensive is produced, practical value is little.

In conclusion so far, industry is not developed yet by having the superpower anti-of the multi-efficiencies such as coupling anti-corrosive fresh-keeping concurrently Nutrient food series of products of the storage period of oxidant stability maintenance up to 3 years.

Summary of the invention

The object of the present invention is to provide a kind of vegetarian diet powder of plant phenols glycinate phytic acid salt composite stability maintenance, it has energy Enough appropriateness supplement the nutrients, and promote body health, anti-ageing life-prolonging and other effects, and lasting stability, it is at low cost, prepare it is simple, suitable In the conventional equipment expanding production the characteristics of.The invention also discloses the vegetarian diets of the plant phenols glycinate phytic acid salt composite stability maintenance The preparation method of powder.

First technical solution of the present invention is: the vegetarian diet of plant phenols glycinate phytic acid salt composite stability maintenance Powder, in parts by weight, component includes:

Food-grade plant phenols glycinate phytate --- 0.5~3 part,

Food-grade vitamin E unsaturated fatty acid ester --- 0.05~1 part,

Ten polyglycereol monounsaturated fatty acids ester of food-grade --- 0.2~2 part,

Food grade sucrose aliphatic ester --- 0.2~2 part,

Food-grade SUNSOFT 700P-2 --- 0.2~2 part,

Food-grade chitosan acylate --- 0.5~1 part,

Cold extruding vegetarian diet original powder --- 88~95 parts,

Food-grade Glycerin, mixed triester with caprylic acid capric acid --- 1~5 part.

The glycine of the food-grade plant phenols glycinate phytate system choosing without amido protecting group is directly sub- with dichloro The high-purity glycyl chloride hydrochloride of pharmaceutical grade made from sulfone chloride technique, with plant phenols by 1:1.25 molar ratio in food-grade inertia Carry out esterification in solvent, vacuum dechlorination hydrogen, purification adds sodium carbonate alkali tune to pH to be 8-10, and solvent extraction is done It is dry, it purifies and obtains food-grade plant phenols glycinate, then neutralized with food-grade phytic acid, adjust food-grade made of pH value 6.8~7.2 Amino-acid ester phytate gathers sweet in Glycerin, mixed triester with caprylic acid capric acid with food-grade vitamin E unsaturated fatty acid ester, food-grade ten Oily monounsaturated fatty acids ester, food grade sucrose aliphatic ester and food-grade SUNSOFT 700P-2 be tuned into it is a kind of have self-emulsifying and The long-acting antioxidant of anti-corrosive fresh-keeping performance, meanwhile, the plant phenols in the food-grade plant phenols glycinate phytate are can The edible plant type antioxidant from natural phenolic hydroxy group, and the glycine and phytic acid are that food-grade or pharmaceutical grade produce Product.

Unsaturated fatty acid ester in the food-grade vitamin E unsaturated fatty acid ester is edible is originated from naturally Long-chain unsaturated fatty acid containing monoene, diene and polyenoid；Vitamin E is from natural food-grade or pharma grade product；Food Grade vitamin E unsaturated fatty acid ester system food-grade ester.

Unsaturated fatty acid ester in the ten polyglycereol monounsaturated fatty acids ester of food-grade is edible from day The right long-chain unsaturated fatty acid containing monoene, diene and polyenoid；The ten polyglycereol monounsaturated fatty acids ester of food-grade is source From food-grade made of natural Raw material processing or pharmaceutical grade high sterling, and appearance transparent, 1% aqueous solution are fully transparent.

The food grade sucrose aliphatic ester is food-grade or pharma grade product, and HLB value is greater than 15.

The monoester content of the food-grade SUNSOFT 700P-2 is greater than 98%.

Cationic product after food-grade chitosan acylate system's natural chitosan and organic acid reaction, 1% Aqueous solution is fully transparent, and pH value is 4.2~4.8, and the organic acid is edible organic acid.

The low viscosity that the food-grade Glycerin, mixed triester with caprylic acid capric acid product system is colourless, tasteless, taste is pure and mild, oxidation stability is good is saturating Prescribed liquid, acid value are less than 0.1mg KOH/g.

The cold extruding vegetarian diet original powder system is by the non-animal including cereal, water fruits and vegetables, algae, herbal medicine, probiotics The edible resource of property, the fine powder through water content obtained by washing, impurity elimination and freeze-drying process less than 1% are placed in puffing apparatus, Dry ice is added, and the weight ratio of fine powder and dry ice is 5~7: 1, and after being forced into 21~30 atmospheric pressure, instantaneous controlled pressure drop is to normal The bulk powder that Material tissue generates microfissure because pulling loose is made in pressure.

The advantages of vegetarian diet powder of plant phenols glycinate phytic acid salt composite stability maintenance of the invention, is: being capable of appropriateness benefit Nutrition is filled, promotes body health, anti-ageing life-prolonging and other effects, and lasting stability, at low cost, preparation simply, suitable for conventional equipment expand Mass production.That is:

(1) the raw materials used glycyl chloride hydrochloride of plant phenols glycinate phytate selects the sweet ammonia without amido protecting group Acid directly with pharmaceutical grade high sterling made from thionyl chloride chloride technique, avoids deamination blocking group and necessary complexity Operation and the micro objectionable impurities thus brought into.Glycyl chloride hydrochloride feeds intake with possessed by plant phenols moles can make plant phenols Glycine ester hydrochloride yield highest, and the non-effective composition in target product is made to belong to innocuous substance to omit resin or film The complex process of method purification.In addition, the introducing of phytic acid base increases the Activity and stabill of vegetable phenol natural substantially Add.

(2) introducing of unsaturated fat base makes the anti-oxidant of vitamin E in food-grade vitamin E unsaturated fatty acid ester Activity and stabill is significantly increased.

(3) food grade surfactant containing ten polyglycereol monounsaturated fatty acids esters and sucrose fatty ester is glued with low Spend carrier food-grade Glycerin, mixed triester with caprylic acid capric acid synergistic effect, hence it is evident that increase plant phenols glycinate phytate or raw element E unsaturated lipid The affinity of fat acid esters and powder infiltrates vegetarian diet powder for long-acting anti-oxidant compositions rapid osmotic and lays the foundation.

(4) the cold expanding treatment of the instantaneous draught head of carbon dioxide is carried out to the vegetarian diet original powder of freeze-drying, makes powder knot of tissue Structure pulls loose, and generates microfissure, until histocyte or organelle are broken, resists convenient for self-emulsifying and the long-acting of anti-corrosive fresh-keeping performance Oxidant liquor can sufficiently be infiltrated and be played a role.In addition, the instantaneous cold extruding of draught head can be such that microorganism and enzyme inactivates, be conducive to The long storage of product.

(5) scientific compatibility of the chitosan of different molecular weight enables chitosan acylate obtained to form antibacterial cladding Film constructs perfect closure bacteria mildew-proof system in conjunction with the food grade bacteriostatic agent SUNSOFT 700P-2 penetrated into material.

Second technical solution of the present invention is: the vegetarian diet powder of plant phenols glycinate phytic acid salt composite stability maintenance Preparation method, comprising the following steps:

1) preparation of long-acting antioxidant A

Select the glycine without amido protecting group directly with the high-purity sweet ammonia of pharmaceutical grade made from thionyl chloride chloride technique Acyl chloride hydrochloride presses 1:1.25 molar ratio 50-65 DEG C of progress esterifications 3 of temperature control in food-grade atent solvent with plant phenols ~8h, vacuum dechlorination hydrogen, alkali cleaning, desolventizing is water-soluble, active carbon removal of impurities, add sodium carbonate alkali tune to pH be 8-10, it is molten Agent extraction, it is dry, it purifies and obtains food-grade plant phenols glycinate, then press effective ingredient 1:1 with food-grade phytic acid aqueous solution It mole feeds intake, 40~60 DEG C of temperature control, quickly stirs 1~2h and carry out neutralization reaction, adjust pH value 6.8~7.2, obtain food-grade plant phenols Glycinate phytate；

Food-grade plant phenols glycinate phytate, food-grade vitamin E unsaturated fatty acid ester and the pungent capric acid of food-grade Glyceride is mixed well up to long-acting antioxidant A；

2) preparation of self-emulsifying and the long-acting antioxidant B of anti-corrosive fresh-keeping performance

Food-grade SUNSOFT 700P-2 is added in food-grade Glycerin, mixed triester with caprylic acid capric acid, room temperature mixes well transparent state, then is warming up to 60~70 DEG C, it is added ten polyglycereol monounsaturated fatty acids ester of food-grade and food grade sucrose aliphatic ester, 1~2h of stirring is to complete Complete uniformly to add above-mentioned long-acting antioxidant A, 50~55 DEG C of temperature control are stirred 1~2 hour to substantially uniformity state up to self-emulsifying And the long-acting antioxidant B of anti-corrosive fresh-keeping performance, it the use of preceding plus 0.5~1.5 times of sterile purified water tune is in easily spraying dilute emulsion；

3) preparation of antimicrobial form fruit glaze agent chitosan acylate C

Deacetylation at least 80%, molecular weight at least 1700kDa and 80~100kDa of molecular weight are taken, by equal proportion mixing Chitosan dried powder calculates amino content in sample according to the deacetylation of chitosan, measures 1.5~2.0 times moles Organic acid is added in organic acid soln, stirs 1~3h, powdered substance is obtained by filtration, is dried in vacuo under room temperature, obtains antimicrobial form Fruit glaze agent chitosan acylate C uses preceding plus 10~15 times of transparent weak solutions of sterile purified water tune；

4) preparation of cold extruding vegetarian diet original powder D

By the edible resource of inanimacy including cereal, water fruits and vegetables, algae, herbal medicine, probiotics, through washing, Fine powder of the water content less than 1% obtained by the freeze-drying process of impurity elimination and classics mixes to obtain blending powder with conventional mixer；It will The blending powder is put into bulking machine, addition dry ice, and the weight ratio of fine powder and dry ice is 5~7: 1, and is forced into 21~30 atmosphere After pressure, instantaneous controlled pressure drop to normal pressure completes the cold puffing process of carbon dioxide, and Material tissue is made because pulling loose and generates microfissure Bulk powder claims cold extruding vegetarian diet original powder D；

5) preparation of the vegetarian diet powder of plant phenols glycinate phytic acid salt composite stability maintenance

The addition extruding vegetarian diet original powder D in the good mixing kettle of leakproofness for connecing Minton dryer, rate controlling 30~ 50rpm stirs 1~2h to material in spraying into above-mentioned long-acting antioxidant B dilute emulsion in 0.5~1h with spraying device while stirring Liquid is mixed well and is absorbed, and then starts Minton dryer, 30~50rpm of rate controlling, while stirring normal-temperature vacuum dry 5~ 10h is to powder water content less than 0.1%；30~50rpm of rate controlling again, it is above-mentioned in being sprayed into 2~3h with spraying device while stirring Chitosan acylate C weak solution, 1~2h of stirring are mixed well and are absorbed to feed liquid, then start Minton dryer, rate controlling 30~50rpm, the dry 10~15h of normal-temperature vacuum to powder water content is less than 0.1% to get the plant of Chitosan-coated type while stirring The vegetarian diet powder of object phenol glycinate phytic acid salt composite stability maintenance, is store using the vegetarian diet powder under the conditions of aluminum-plastic composite membrane bag Vacuum Package It puts 3 years and never degenerates.

Advantage possessed by the preparation method of the vegetarian diet powder of plant phenols glycinate phytic acid salt composite stability maintenance of the invention It is: products made thereby stability brilliance and nutrition general equilibrium.This method uses " the extruding particle elder generation of lasting fresh-keeping nutrient baking soda Wrapped after leaching " mode, i.e., reached in reference Design of Organic Synthesis by novel bifunctional molecule enhances original performance and tax each other This principle of the dual purpose of new function is given, the superpower antioxidant plant phenols glycinate phytic acid of long-acting type is originally prepared Salt, and then preferably go out to have distinguished anti-corrosive fresh-keeping performance concurrently and to the long-acting antioxidant combination of the splendid self-emulsifying of powder affinity Object, is sprayed in the cold extruding vegetarian diet siccative original powder of carbon dioxide and completes impregnation process, then with antibiotic property chitosan acylate packet It covers.The mode can farthest protect polyenoid grease, flavone compound contained in nutrient baking soda, sterol, vitamin, Polypeptide, protein, chlorogenic acid and polysaccharide isoreactivity effective component, protect it from air, light, heat, metal ion, enzyme and microorganism The destruction of equal environment unfavorable factor, stably and lastingly plays the effect of vegetarian diet powder moderately supplements the nutrients.Meanwhile from by inanimacy Vegetable source obtained by freeze drying is so-called to be eaten raw, and can avoid the strong sterilization, enzyme inhibitor condition such as microwave, high temperature and radiation can It is fresh-keeping 3 years enough.

Specific embodiment

Embodiment 1

The vegetarian diet powder of plant phenols glycinate phytic acid salt composite stability maintenance, component include:

Food-grade schisanhenol glycinate phytate --- 5kg,

Food-grade linoleic acid ester of vitamin e --- 0.5kg,

Ten polyglycereol list linoleate --- 2kg of food-grade,

Food grade sucrose oleate --- 2kg,

Food-grade SUNSOFT 700P-2 --- 2kg,

Food-grade chitosan acetate --- 5kg,

Cold extruding vegetarian diet original powder --- 880kg,

Food-grade Glycerin, mixed triester with caprylic acid capric acid --- 10kg.

Preparation method is:

L) preparation of long-acting antioxidant A

Select the glycine without amido protecting group directly with the high-purity sweet ammonia of pharmaceutical grade made from thionyl chloride chloride technique Acyl chloride hydrochloride (glycyl chloride hydrochloride content is greater than 99.8%) meter 129.8kg, the schisanhenol meter 513.2kg of content 98% (i.e. sour phenol feed ratio is 1:1.25 molar ratio), food level ethyl acetate meter 350kg is in 80rpm stirring condition in enamel reaction pot Under, 55 DEG C of progress esterification 6h of temperature control, (vacuum degree is to control material for water-jetting type vacuum air-removed system micro-vacuum dehydrochlorination gas Subject to liquid does not boil), then 78 DEG C of back flow reaction 2h of material controlling temperature are divided with 15% aqueous sodium carbonate meter 180kg alkali cleaning in three times Sub-cloud salt water is put after layer.After vacuum deviates from ethyl acetate 280kg, add pure water 500kg, 60 DEG C of temperature control boilings under vacuum condition 3h takes off remaining ethyl acetate (having deviate from ester water mixed liquid 200kg), then plus pure water 1500kg, stir it is completely saturating to system It is bright, add 70 DEG C of stirring 1h of pharmaceutical grade active carbon 50kg temperature control, clean, filters pressing while hot, filtrate adds the sodium carbonate alkali tune to be to pH 9.0, it is added food level ethyl acetate 1500kg solvent extraction 3 times, wherein third time extraction material play is stirred to even rear investment medicine Grade sodium chloride 400kg, then play are stirred 20 minutes, are stood to promote sufficiently to be layered with system.Gained organic phase vacuum purifies after extraction Ethyl acetate obtains schisanhenol glycinate.

98.5% food grade phytic acid 670kg is dissolved in 800kg pure water, and 50 DEG C of temperature control or less on being added in five batches in 1h Schisanhenol glycinate (phytic acid and schisanhenol glycinate feed intake by 1:1 moles) is stated, control 300rpm stirring condition carries out Salt-forming reaction 1h is neutralized, material pH to 7.0 is adjusted, 50 DEG C of vacuum decompression dehydrations of temperature control obtain food-grade five of the water content less than 0.5% Taste phenol glycinate phytate.

Weigh above-mentioned food-grade schisanhenol glycinate phytate 5kg, food-grade linoleic acid ester of vitamin e 0.5kg with Food-grade Glycerin, mixed triester with caprylic acid capric acid 5kg mixes well up to long-acting antioxidant A.

Food-grade Glycerin, mixed triester with caprylic acid capric acid 5kg and food-grade SUNSOFT 700P-2 2kg, room temperature mixes well transparent state, then heats up To 70 DEG C, food-grade ten polyglycereol list linoleate 2kg and food grade sucrose aliphatic ester 2kg is added, stirring 1h is to completely It is even, add above-mentioned long-acting antioxidant A meter 10.5kg, 55 DEG C of temperature control stirrings 1 hour to substantially uniformity state up to self-emulsifying and The long-acting antioxidant B of anti-corrosive fresh-keeping performance counts 21.5kg, the use of preceding plus 30kg sterile purified water tune is in easily spraying dilute emulsion.

3) preparation of antimicrobial form fruit glaze agent chitosan acetate C

Take deacetylation 82%, the chitosan dried powder meter 10kg and deacetylation 82% of molecular weight 1800kDa, molecule The chitosan dried powder meter 10kg of 80kDa is measured, is mixed, mediates stirring 2h with 99% food grade Acetometer 12kg, filters pressing obtains Powdered substance, vacuum desacetoxy and drying under room temperature, obtains antimicrobial form fruit glaze agent chitosan acetate C, takes the chitosan acetic acid Salt C meter 5kg adds the transparent weak solution of 66kg sterile purified water tune.

4) preparation of cold extruding vegetarian diet original powder D

By the edible resource of inanimacy including cereal, water fruits and vegetables, algae, herbal medicine, probiotics etc., through net It washes, fine powder of the water content less than 1% obtained by the freeze-drying process of impurity elimination and classics, it is mixed with conventional mixer by following formulas It is even to concoct powder:

Brown rice 15kg, scented rice 20kg, black rice 5kg, ripe brown rice 20kg, glutinous rice 13kg, oat 3kg, sorghum 8kg, small Semen setariae 18kg, corn 5kg, soybean 10kg, semen sojae atricolor 5kg, red bean 12kg, white peas or beans 4kg, mung bean 16kg, peanut 19kg, sesame 4kg, Semen Coicis 15kg；

Apple 10kg, banana 13kg, mango 9kg, sweet orange 15kg, strawberry 8kg；Tomato 10kg；Balsam pear 4kg；

Carrot 15kg, pumpkin 15kg, celery 3kg, konjaku 10kg, broccoli 16kg, wild cabbage 2kg；

Mushroom 3kg, thallus laminariae 12.5kg, seaweed 12.5kg, green tea 5.5kg, malt 14kg；Lotus leaf 3.5kg, walnut 8kg； Pawpaw 10kg, blueberry 8kg, beet root 5.5kg；

Lily 6kg, Chinese yam 5kg, pueraria lobata 3kg, matrimony vine 8kg, pollen pini 4.kg, cordyceps sinensis 2.5kg:

Lecithin 4.5kg, oligomeric glycitols prebiotics 18kg, rice bran 6kg；Spirulina 6kg, haematococcus pluvialis 3kg；Spiral Algae 16kg, sea-buckthorn 3kg.

Nutritious yeast 5.5kg, algae oil DHA 2kg, valve rose 3kg.

Above-mentioned blending powder is put into bulking machine, addition dry ice, the weight ratio of fine powder and dry ice is 5: 1, and is forced into 28 After a atmospheric pressure, instantaneous controlled pressure drop to normal pressure completes the cold puffing process of carbon dioxide, and obtained Material tissue generates microcosmic because pulling loose The bulk powder of crackle claims cold extruding vegetarian diet original powder D.At least two material are continuously done by this formula, in case needed for the production of following finished products.

5) preparation of the vegetarian diet powder of schisanhenol glycinate phytic acid salt composite stability maintenance

Extruding vegetarian diet original powder D is added in the good mixing kettle of leakproofness for connecing Minton dryer and counts 880kg, rate controlling 50rpm stirs 2h to material in spraying into above-mentioned long-acting antioxidant B dilute emulsion meter 51.5kg in 1h with spraying device while stirring Liquid is mixed well and is absorbed, and then starts Minton dryer, rate controlling 50rpm, normal-temperature vacuum dries 8h extremely when mediating stirring Powder water content is less than 0.1%.Rate controlling 50rpm again, when mediating stirring with spraying device in spraying into above-mentioned food-grade shell in 3h Glycan acetate C weak solution 71kg, stirring 2h are mixed well and are absorbed to feed liquid, then start Minton dryer, rate controlling 30 ~50rpm, when mediating stirring the dry 12h of normal-temperature vacuum to powder water content less than 0.1% to get the Chitosan-coated type five tastes The vegetarian diet powder of sub- phenol glycinate phytic acid salt composite stability maintenance, can store under the conditions of aluminum-plastic composite membrane bag Vacuum Package 3 years it is constant Matter.

Embodiment 2

Food-grade vitamin E glycinate phytate --- 8kg,

Food-grade vitamin E eicosapentaenoic acid esters --- 0.6kg,

Ten polyglycerol monooleate of food-grade --- 1kg,

Food grade sucrose oleate --- 8kg,

Food-grade SUNSOFT 700P-2 --- 8kg,

Food-grade chitosan propionic acid salt --- 6kg,

Cold extruding vegetarian diet original powder --- 900kg,

Food-grade Glycerin, mixed triester with caprylic acid capric acid --- 20kg.

Preparation method is:

L) preparation of long-acting antioxidant A

Select the glycine without amido protecting group directly with the high-purity sweet ammonia of pharmaceutical grade made from thionyl chloride chloride technique Acyl chloride hydrochloride (glycyl chloride hydrochloride content is greater than 99.8%) meter 129.8kg, the food-grade vitamin E meter of content 99% 543.8kg (sour phenol feed ratio is 1:1.25 molar ratio), food level ethyl acetate meter 430kg is stirred in 80rpm in enamel reaction pot Under the conditions of mixing, 60 DEG C of progress esterification 5h of temperature control, water-jetting type vacuum air-removed system micro-vacuum dehydrochlorination gas (vacuum degree with Subject to control feed liquid is not boiled), then 78 DEG C of back flow reaction 3h of material controlling temperature, in three times with 15% aqueous sodium carbonate meter 210kg Sub-cloud salt water is put in alkali cleaning after layering.After vacuum deviates from ethyl acetate 320kg, add pure water 500kg, temperature control under vacuum condition 60 DEG C of boiling 3h take off remaining ethyl acetate (having deviate from ester water mixed liquid 180kg), then plus pure water 1500kg, stirring is to body Be it is fully transparent, add 70 DEG C of stirring 1h of pharmaceutical grade active carbon 50kg temperature control, clean, filters pressing while hot, filtrate adds sodium carbonate alkali tune It is 9.0 to pH, is added food level ethyl acetate 1500kg solvent extraction 3 times, wherein third time extraction material play is stirred to even rear throwing Enter medical grade sodium chloride 430kg, then play is stirred 20 minutes, stands to promote sufficiently to be layered with system.Gained organic phase is true after extraction Sky purifies ethyl acetate, obtains vitamin E glycinate.

98.5% food grade phytic acid 670kg is dissolved in 800kg pure water, and 50 DEG C of temperature control or less on being added in five batches in 1h It states vitamin E glycinate (phytic acid and vitamin E glycinate feed intake by 1:1 moles), in control 300rpm stirring condition progress With salt-forming reaction 2h, material pH to 7.0 is adjusted, 60 DEG C of vacuum decompression dehydrations of temperature control obtain food-grade dimension life of the water content less than 0.5% Plain E glycinate phytate.

Weigh above-mentioned food-grade vitamin E glycinate phytate 8kg, food-grade vitamin E eicosapentaenoic acid esters 0.6kg and food-grade Glycerin, mixed triester with caprylic acid capric acid 10kg mixes well up to long-acting antioxidant A.

Food-grade Glycerin, mixed triester with caprylic acid capric acid 10kg and food-grade SUNSOFT 700P-2 8kg, room temperature mixes well transparent state, then heats up To 70 DEG C, food-grade ten polyglycerol monooleate 1kg and food grade sucrose aliphatic ester 8kg is added, stirring 1.5h is to completely It is even, add above-mentioned long-acting antioxidant A meter 18.6kg, 55 DEG C of temperature control stirrings 1 hour to substantially uniformity state up to self-emulsifying and The long-acting antioxidant B of anti-corrosive fresh-keeping performance counts 45.6kg, the use of preceding plus 62kg sterile purified water tune is in easily spraying dilute emulsion.

3) preparation of antimicrobial form fruit glaze agent chitosan propionic acid salt C

Take deacetylation 85%, the chitosan dried powder meter 10kg and deacetylation 82% of molecular weight 1800kDa, molecule The chitosan dried powder meter 10kg of 80kDa is measured, is mixed, mediates stirring 2h with 99% food grade propionic acid meter 15kg, filters pressing obtains Powdered substance, vacuum takes off propionic acid and drying under room temperature, obtains antimicrobial form fruit glaze agent chitosan propionic acid salt C, takes the chitosan propionic acid Salt C meter 6kg adds the sterile pure transparent weak solution of water purification tune of 75kg.

4) preparation of cold extruding vegetarian diet original powder D

Brown rice 10kg, scented rice 20kg, black rice 10kg, ripe brown rice 20kg, glutinous rice 16kg, oat 3kg, sorghum 8kg, small Semen setariae 15kg, corn 7kg, soybean 10kg, semen sojae atricolor 8kg, red bean 10kg, white peas or beans 4kg, mung bean 16kg, peanut 19kg, sesame 4kg, Semen Coicis 15kg；

Apple 13kg, banana 13kg, mango 9kg, sweet orange 12kg, strawberry 8kg；Tomato 10kg；Balsam pear 4kg；

Carrot 15kg, pumpkin 15kg, celery 5kg, konjaku 10kg, broccoli 13kg, wild cabbage 2kg；

Mushroom 5kg, thallus laminariae 10.5kg, seaweed 12.5kg, green tea 5.5kg, malt 12kg；Lotus leaf 3.5kg, walnut 8kg； Pawpaw 10kg, blueberry 8kg, beet root 5.5kg；

Lily 6kg, Chinese yam 8kg, pueraria lobata 3kg, matrimony vine 5kg, pollen pini 4.kg, cordyceps sinensis 2.5kg:

Nutritious yeast 7.5kg, algae oil DHA 2kg, valve rose 1kg.

Above-mentioned blending powder is put into bulking machine, addition dry ice, the weight ratio of fine powder and dry ice is 6: 1, and is forced into 23 After a atmospheric pressure, instantaneous controlled pressure drop to normal pressure completes the cold puffing process of carbon dioxide, and obtained Material tissue generates microcosmic because pulling loose The bulk powder of crackle claims cold extruding vegetarian diet original powder D.At least two material are continuously done by this formula, in case needed for the production of following finished products.

5) preparation of the vegetarian diet powder of vitamin E glycinate phytic acid salt composite stability maintenance

Extruding vegetarian diet original powder D is added in the good mixing kettle of leakproofness for connecing Minton dryer and counts 900kg, rate controlling 50rpm stirs 1h to material in spraying into above-mentioned long-acting antioxidant B dilute emulsion meter 107.6kg in 1h with spraying device while stirring Liquid is mixed well and is absorbed, and then starts Minton dryer, rate controlling 30pm, normal-temperature vacuum dries 6h to powder when mediating stirring Expect water content less than 0.1%.Rate controlling 50rpm again, it is poly- in spraying into above-mentioned food-grade shell in 2h with spraying device when mediating stirring Sugared propionate C weak solution 81kg, stirring 1.5h are mixed well and are absorbed to feed liquid, then start Minton dryer, rate controlling 30rpm, when mediating stirring the dry 10h of normal-temperature vacuum to powder water content less than 0.1% to get Chitosan-coated type vitamin The vegetarian diet powder of E glycinate phytic acid salt composite stability maintenance can be stored 3 years under the conditions of aluminum-plastic composite membrane bag Vacuum Package and be never degenerated.

Embodiment 3

Food-grade resveratrol glycinate phytate --- 10kg,

Food-grade vitamin E oleate --- 5kg,

Ten polyglycereol list eicosapentaenoic acid esters --- 15kg of food-grade,

Food grade sucrose linoleate --- 10kg,

Food-grade SUNSOFT 700P-2 --- 10kg,

Food-grade chitosan phytate --- 8kg,

Cold extruding vegetarian diet original powder --- 930kg,

Food-grade Glycerin, mixed triester with caprylic acid capric acid --- 30kg.

Preparation method is:

L) preparation of long-acting antioxidant A

Select the glycine without amido protecting group directly with the high-purity sweet ammonia of pharmaceutical grade made from thionyl chloride chloride technique Acyl chloride hydrochloride (glycyl chloride hydrochloride content is greater than 99.8%) meter 129.8kg, the food-grade resveratrol meter of content 99% 288kg (sour phenol feed ratio is 1:1.25 molar ratio), food level ethyl acetate meter 390kg is stirred in 80rpm in enamel reaction pot Under the conditions of, 65 DEG C of progress esterification 8h of temperature control, (vacuum degree is to control for water-jetting type vacuum air-removed system micro-vacuum dehydrochlorination gas Subject to feed liquid processed is not boiled), then 78 DEG C of back flow reaction 1h of material controlling temperature, with 15% aqueous sodium carbonate meter 210kg alkali in three times It washes, sub-cloud salt water is put after layering.After vacuum deviates from ethyl acetate 310kg, add pure water 500kg, temperature control 60 under vacuum condition DEG C boiling 3h takes off remaining ethyl acetate (having deviate from ester water mixed liquid 230kg), then plus pure water 1500kg, stirring is to system It is fully transparent, add 70 DEG C of stirring 1h of pharmaceutical grade active carbon 50kg temperature control, clean, filters pressing while hot, filtrate adds sodium carbonate alkali tune extremely PH is 10, is added food level ethyl acetate 1800kg solvent extraction 3 times, wherein third time extraction material play is stirred to even rear investment doctor Medicine grade sodium chloride 310kg, then play are stirred 20 minutes, are stood to promote sufficiently to be layered with system.Gained organic phase vacuum is de- after extraction Net ethyl acetate obtains resveratrol glycinate.

98.5% food grade phytic acid 670kg is dissolved in 800kg pure water, and 60 DEG C of temperature control above-mentioned white in being added in five batches in 2h Veratryl alcohol glycinate (phytic acid and resveratrol glycinate feed intake by 1:1 moles), control 300rpm stirring condition are neutralized Salt-forming reaction 1h, adjusts material pH to 7.2, and 55 DEG C of vacuum decompression dehydrations of temperature control obtain water content less than the white black false hellebore of 0.5% food-grade Alcohol glycinate phytate.

Weigh above-mentioned food-grade resveratrol glycinate phytate 10kg, food-grade vitamin E oleate 5kg and food Grade Glycerin, mixed triester with caprylic acid capric acid 15kg mixes well up to long-acting antioxidant A.

Food-grade Glycerin, mixed triester with caprylic acid capric acid 15kg and food-grade SUNSOFT 700P-2 10kg, room temperature mixes well transparent state, then rises Food-grade ten polyglycereol list eicosapentaenoic acid esters 15kg and food grade sucrose linoleate 10kg, stirring is added to 60 DEG C in temperature 2h adds above-mentioned long-acting antioxidant A meter 30kg to substantially uniformity, 53 DEG C of temperature control stirring 1 hour to substantially uniformity state to obtain the final product Self-emulsifying and the long-acting antioxidant B of anti-corrosive fresh-keeping performance count 80kg, using preceding plus 105kg sterile purified water tune in easily spraying Dilute emulsion.

3) preparation of antimicrobial form fruit glaze agent chitosan phytate C

Take deacetylation 80%, the chitosan dried powder meter 10kg and deacetylation 82% of molecular weight 1700kDa, molecule The chitosan dried powder meter 10kg of 90kDa is measured, is mixed, mediates stirring 3h with 99% food grade phytic acid meter 22kg, filters pressing obtains Powdered substance, vacuum desacetoxy and drying under room temperature, obtains antimicrobial form fruit glaze agent chitosan phytate C, takes the chitosan phytic acid Salt C meter 8kg adds the sterile pure transparent weak solution of water purification tune of 80kg.

4) preparation of cold extruding vegetarian diet original powder D

Brown rice 10kg, scented rice 10kg, black rice 5kg, ripe brown rice 10kg, glutinous rice 13kg, oat 3kg, sorghum 8kg, small Semen setariae 8kg, corn 5kg, soybean 10kg, semen sojae atricolor 5kg, red bean 12kg, white peas or beans 4kg, mung bean 16kg, peanut 19kg, sesame 9kg, Semen Coicis 15kg；

Apple 10kg, banana 13kg, mango 5kg, sweet orange 15kg, strawberry 18kg；Tomato 10kg；Balsam pear 4kg；

Carrot 15kg, pumpkin 25kg, celery 3kg, konjaku 10kg, broccoli 16kg, wild cabbage 2kg；

Mushroom 13kg, thallus laminariae 12.5kg, seaweed 12.5kg, green tea 5.5kg, malt 18kg；Lotus leaf 3.5kg, walnut 8kg；Pawpaw 10kg, blueberry 8kg, beet root 5.5kg；

Lily 5kg, Chinese yam 5kg, pueraria lobata 4kg, matrimony vine 8kg, pollen pini 4.kg, cordyceps sinensis 2.5kg:

Lecithin 5kg, oligomeric glycitols prebiotics 18kg, rice bran 7kg；Spirulina 6kg, haematococcus pluvialis 3kg；Spirulina 16kg, sea-buckthorn 3kg.

Nutritious yeast 5kg, algae oil DHA 1kg, valve rose 3kg.

Above-mentioned blending powder is put into bulking machine, addition dry ice, the weight ratio of fine powder and dry ice is 7: 1, and is forced into 21 After a atmospheric pressure, instantaneous controlled pressure drop to normal pressure completes the cold puffing process of carbon dioxide, and obtained Material tissue generates microcosmic because pulling loose The bulk powder of crackle claims cold extruding vegetarian diet original powder D.At least two material are continuously done by this formula, in case needed for the production of following finished products.

5) preparation of the vegetarian diet powder of resveratrol glycinate phytic acid salt composite stability maintenance

Extruding vegetarian diet original powder D is added in the good mixing kettle of leakproofness for connecing Minton dryer and counts 930kg, rate controlling 35rpm, while stirring with spraying device in spraying into above-mentioned long-acting antioxidant B dilute emulsion meter 185kg in 0.5h, stirring 1.5h is extremely Feed liquid is mixed well and is absorbed, and then starts Minton dryer, rate controlling 35rpm, the dry 6h of normal-temperature vacuum when mediating stirring To powder water content less than 0.1%.Rate controlling 35rpm again, when mediating stirring with spraying device in spraying into above-mentioned food in 2.5h Grade chitosan phytate C weak solution 88kg, stirring 1h are mixed well and are absorbed to feed liquid, are then started Minton dryer, are controlled Fast 35rpm, when mediating stirring the dry 15h of normal-temperature vacuum to powder water content less than 0.1% to get the white Chenopodiaceae of Chitosan-coated type The vegetarian diet powder of reed alcohol glycinate phytic acid salt composite stability maintenance, can store under the conditions of aluminum-plastic composite membrane bag Vacuum Package 3 years it is constant Matter.

Embodiment 4

Food-grade tea polyphenols glycinate phytate --- 30kg,

Food-grade vitamin E docosahexaenoic acid ester --- 10kg,

Ten polyglycereol list eicosapentaenoic acid esters --- 20kg of food-grade,

Food grade sucrose oleate --- 20kg,

Food-grade SUNSOFT 700P-2 --- 20kg,

Food-grade chitosan second third mixes hydrochlorate --- 10kg,

Cold extruding vegetarian diet original powder --- 950kg,

Food-grade Glycerin, mixed triester with caprylic acid capric acid --- 50kg.

Preparation method is:

L) preparation of long-acting antioxidant A

Select the glycine without amido protecting group directly with the high-purity sweet ammonia of pharmaceutical grade made from thionyl chloride chloride technique Acyl chloride hydrochloride (glycyl chloride hydrochloride content is greater than 99.8%) meter 129.8kg, the food-grade tea polyphenols meter of content 98% 351.3kg (sour phenol feed ratio is 1:1.25 molar ratio), food level ethyl acetate meter 320kg is stirred in 80rpm in enamel reaction pot Under the conditions of mixing, 64 DEG C of progress esterification 3h of temperature control, water-jetting type vacuum air-removed system micro-vacuum dehydrochlorination gas (vacuum degree with Subject to control feed liquid is not boiled), then 78 DEG C of back flow reaction 2h of material controlling temperature, in three times with 15% aqueous sodium carbonate meter 120kg Sub-cloud salt water is put in alkali cleaning after layering.After vacuum deviates from ethyl acetate 270kg, add pure water 500kg, temperature control under vacuum condition 60 DEG C of boiling 3h take off remaining ethyl acetate (having deviate from ester water mixed liquid 230kg), then plus pure water 1500kg, stirring is to body Be it is fully transparent, add 72 DEG C of stirring 1h of pharmaceutical grade active carbon 50kg temperature control, clean, filters pressing while hot, filtrate adds sodium carbonate alkali tune It is 8.0 to pH, is added food level ethyl acetate 1300kg solvent extraction 3 times, wherein third time extraction material play is stirred to even rear throwing Enter medical grade sodium chloride 310kg, then play is stirred 20 minutes, stands to promote sufficiently to be layered with system.Gained organic phase is true after extraction Sky purifies ethyl acetate, obtains tea polyphenols glycinate.

98.5% food grade phytic acid 670kg is dissolved in 800kg pure water, and 60 DEG C of temperature control or less in being added in five batches in 1.5h Above-mentioned tea polyphenols glycinate (phytic acid and tea polyphenols glycinate feed intake by 1:1 moles), controls in the progress of 300rpm stirring condition With salt-forming reaction 1.5h, material pH to 7.2 is adjusted, 50 DEG C of vacuum decompression dehydrations of temperature control obtain food-grade tea of the water content less than 0.5% Polyphenol glycinate phytate.

Weigh above-mentioned food-grade tea polyphenols glycinate phytate 30kg, food-grade vitamin E docosahexaenoic acid ester 10kg and food-grade Glycerin, mixed triester with caprylic acid capric acid 35kg mixes well up to long-acting antioxidant A.

Food-grade Glycerin, mixed triester with caprylic acid capric acid 15kg and food-grade SUNSOFT 700P-2 20kg, room temperature mixes well transparent state, then rises Food-grade ten polyglycereol list eicosapentaenoic acid esters 20kg and food grade sucrose oleate 20kg is added to 67 DEG C in temperature, stirs 2h To substantially uniformity, above-mentioned long-acting antioxidant A meter 75kg is added, 50 DEG C of temperature control derive from for stirring 2 hours to substantially uniformity state The long-acting antioxidant B of emulsification and anti-corrosive fresh-keeping performance counts 36kg, using preceding plus 200kg sterile purified water tune in easily spraying dilute Lotion.

3) antimicrobial form fruit glaze agent chitosan second third mixes the preparation of hydrochlorate C

Take deacetylation 82%, the chitosan dried powder meter 10kg and deacetylation 82% of molecular weight 1800kDa, molecule The chitosan dried powder meter 10kg of 80kDa is measured, is mixed, with 99% food grade Acetometer 6kg and 99% food grade propionic acid meter The mixed acid of 7.4kg composition mediates stirring 2h, and filters pressing obtains powdered substance, and vacuum takes off mixed acid and drying under room temperature, obtains anti- Bacterial type fruit glaze agent chitosan second third mixes hydrochlorate C, and the chitosan second the third mixed acid hydrochlorate C meter 10kg is taken to add 120kg sterile pure The transparent weak solution of water purification tune.

4) preparation of cold extruding vegetarian diet original powder D

Brown rice 9kg, scented rice 12kg, black rice 5kg, ripe brown rice 10kg, glutinous rice 13kg, oat 3kg, sorghum 8kg, small Semen setariae 15kg, corn 5kg, soybean 16kg, semen sojae atricolor 15kg, red bean 12kg, white peas or beans 4kg, mung bean 16kg, peanut 14kg, sesame 4kg, the heart of a lotus seed Rice 15kg；

Apple 18kg, banana 13kg, mango 9kg, sweet orange 15kg, strawberry 8kg；Tomato 15kg；Balsam pear 4kg；

Carrot 15kg, pumpkin 15kg, celery 7kg, konjaku 10kg, broccoli 16kg, wild cabbage 2kg；

Mushroom 6kg, thallus laminariae 12.5kg, seaweed 12.5kg, green tea 5.5kg, malt 14kg；Lotus leaf 3.5kg, walnut 8kg； Pawpaw 6kg, blueberry 8kg, beet root 5.5kg；

Lily 6kg, Chinese yam 4kg, pueraria lobata 3kg, matrimony vine 8kg, pollen pini 4.kg, cordyceps sinensis 4kg:

Lecithin 4kg, oligomeric glycitols prebiotics 18kg, rice bran 6kg；Spirulina 6kg, haematococcus pluvialis 3kg；Spirulina 16kg, sea-buckthorn 3kg.

Nutritious yeast 5.5kg, algae oil DHA 2kg, valve rose 3kg.

Above-mentioned blending powder is put into bulking machine, addition dry ice, the weight ratio of fine powder and dry ice is 7: 1, and is forced into 30 After a atmospheric pressure, instantaneous controlled pressure drop to normal pressure completes the cold puffing process of carbon dioxide, and obtained Material tissue generates microcosmic because pulling loose The bulk powder of crackle claims cold extruding vegetarian diet original powder D.At least two material are continuously done by this formula, in case needed for the production of following finished products.

5) preparation of the vegetarian diet powder of tea polyphenols glycinate phytic acid salt composite stability maintenance

Extruding vegetarian diet original powder D is added in the good mixing kettle of leakproofness for connecing Minton dryer and counts 950kg, rate controlling 45rpm, while stirring with spraying device in spraying into above-mentioned long-acting antioxidant B dilute emulsion meter 236kg in 0.8h, stirring 1.5h is extremely Feed liquid is mixed well and is absorbed, and then starts Minton dryer, rate controlling 45rpm, the dry 10h of normal-temperature vacuum when mediating stirring To powder water content less than 0.1%.Rate controlling 45rpm again, when mediating stirring with spraying device in spraying into above-mentioned food in 2.5h Grade chitosan second third mixes hydrochlorate C weak solution 130kg, and stirring 2h is mixed well and absorbed to feed liquid, then starting vacuum drying Device, rate controlling 45rpm, when mediating stirring the dry 15h of normal-temperature vacuum to powder water content less than 0.1% to get chitosan packet The vegetarian diet powder of type tea polyphenols glycinate phytic acid salt composite stability maintenance is covered, three can be stored under the conditions of aluminum-plastic composite membrane bag Vacuum Package Year never degenerates.

Embodiment 5

Food-grade chlorogenic acid glycinate phytate --- 30kg,

Food-grade vitamin E linolenin --- 0.5kg,

Ten polyglycereol list linoleate --- 2kg of food-grade,

Food grade sucrose linoleate --- 20kg,

Food-grade SUNSOFT 700P-2 --- 2kg,

Food-grade chitosan third plants mixing hydrochlorate --- 10kg,

Cold extruding vegetarian diet original powder --- 880kg,

Food-grade Glycerin, mixed triester with caprylic acid capric acid --- 50kg.

Preparation method is:

L) preparation of long-acting antioxidant A

Select the glycine without amido protecting group directly with the high-purity sweet ammonia of pharmaceutical grade made from thionyl chloride chloride technique Acyl chloride hydrochloride (glycyl chloride hydrochloride content is greater than 99.8%) meter 129.8kg, the food-grade chlorogenic acid meter of content 98% 442.6kg (sour phenol feed ratio is 1:1.25 molar ratio), food level ethyl acetate meter 410kg is stirred in 80rpm in enamel reaction pot Under the conditions of mixing, 50 DEG C of progress esterification 8h of temperature control, water-jetting type vacuum air-removed system micro-vacuum dehydrochlorination gas (vacuum degree with Subject to control feed liquid is not boiled), with 15% aqueous sodium carbonate meter 150kg alkali cleaning in three times, sub-cloud salt water is put after layering.Very After sky abjection ethyl acetate 370kg, add pure water 500kg, 40 DEG C of boiling 8h of temperature control take off remaining acetic acid second under vacuum condition Ester (has deviate from ester water mixed liquid 290kg), then plus pure water 1500kg, stir it is fully transparent to system, add pharmaceutical grade active carbon 50 DEG C of stirring 3h of 50kg temperature control, removal of impurities, filters pressing while hot, filtrate add sodium carbonate alkali tune to pH be 8.0, be added food-grade acetic acid second Ester 1600kg solvent extraction 3 times is stirred wherein third time extraction material play is stirred to the even rear medical grade sodium chloride 480kg of investment, then play It 20 minutes, stands to promote sufficiently to be layered with system.Gained organic phase vacuum purifies ethyl acetate after extraction, obtains the sweet ammonia of chlorogenic acid Acid esters.

98.5% food grade phytic acid 670kg is dissolved in 800kg pure water, and 40 DEG C of temperature control or less on being added in five batches in 1h Chlorogenic acid glycinate (phytic acid and chlorogenic acid glycinate feed intake by 1:1 moles) is stated, control 300rpm stirring condition is neutralized Salt-forming reaction 1.5h, adjusts material pH to 6.8, and 40 DEG C of vacuum decompression dehydrations of temperature control obtain water content less than the green original of 0.5% food-grade Sour glycinate phytate.

Weigh above-mentioned food-grade chlorogenic acid glycinate phytate 30kg, food-grade vitamin E linolenin 0.5kg and food Grade Glycerin, mixed triester with caprylic acid capric acid 25kg mixes well up to long-acting antioxidant A.

Food-grade Glycerin, mixed triester with caprylic acid capric acid 25kg and food-grade SUNSOFT 700P-2 2kg, room temperature mixes well transparent state, then heats up To 60 DEG C, food-grade ten polyglycereol list linoleate 2kg and food grade sucrose linoleate 20kg is added, stirring 1h is to completely It is even, above-mentioned long-acting antioxidant A meter 55.5kg is added, 50 DEG C of temperature control are stirred 1.5 hours to substantially uniformity state up to self-emulsifying And the long-acting antioxidant B of anti-corrosive fresh-keeping performance counts 104.5kg, using preceding plus 150kg sterile purified water tune in easily spraying dilute Lotion.

3) antimicrobial form fruit glaze agent chitosan third plants the preparation of mixing hydrochlorate C

Deacetylation 85% is taken, the chitosan dried powder meter 10kg and deacetylation 82% of molecular weight 1800kDa divide The chitosan dried powder meter 10kg of son amount 100kDa, mixes, and plants with 99% food grade propionic acid meter 10kg with 99% food grade Acid meter 18kg mediates stirring 1h, and filters pressing obtains powdered substance, and vacuum takes off propionic acid and drying under room temperature, obtains antimicrobial form fruit glaze agent shell Propionate C takes the chitosan third to plant mixed acid C meter 10kg and adds the sterile pure transparent weak solution of water purification tune of 130kg.

4) preparation of cold extruding vegetarian diet original powder D

Brown rice 10kg, scented rice 12kg, black rice 5kg, ripe brown rice 10kg, glutinous rice 10kg, oat 3kg, sorghum 8kg, small Semen setariae 15kg, corn 7kg, soybean 15kg, semen sojae atricolor 15kg, red bean 15kg, white peas or beans 4kg, mung bean 16kg, peanut 14kg, sesame 4kg, the heart of a lotus seed Rice 13kg；

Apple 18kg, banana 19kg, mango 9kg, sweet orange 15kg, strawberry 8kg；Tomato 15kg；Balsam pear 4kg；

Carrot 15kg, pumpkin 15kg, celery 7kg, konjaku 13kg, broccoli 16kg, wild cabbage 2kg；

Mushroom 6kg, thallus laminariae 12kg, seaweed 12.kg, green tea 5.5kg, malt 14kg；Lotus leaf 3.5kg, walnut 9kg；Wood Melon 6kg, blueberry 8kg, beet root 5.5kg；

Lily 6kg, Chinese yam 4kg, pueraria lobata 3kg, matrimony vine 8kg, pollen pini 4.kg, cordyceps sinensis 5kg:

Lecithin 4kg, oligomeric glycitols prebiotics 18kg, rice bran 6kg；Spirulina 6kg, haematococcus pluvialis 2kg；Spirulina 16kg, sea-buckthorn 3kg.

Nutritious yeast 5.5kg, algae oil DHA 2kg, valve rose 3kg.

Above-mentioned blending powder is put into bulking machine, addition dry ice, the weight ratio of fine powder and dry ice is 6: 1, and is forced into 21 After a atmospheric pressure, instantaneous controlled pressure drop to normal pressure completes the cold puffing process of carbon dioxide, and obtained Material tissue generates microcosmic because pulling loose The bulk powder of crackle claims cold extruding vegetarian diet original powder D.At least two material are continuously done by this formula, in case needed for the production of following finished products.

5) preparation of the vegetarian diet powder of chlorogenic acid glycinate phytic acid salt composite stability maintenance

Extruding vegetarian diet original powder D is added in the good mixing kettle of leakproofness for connecing Minton dryer and counts 880kg, rate controlling 30rpm, while stirring with spraying device in spraying into above-mentioned long-acting antioxidant B dilute emulsion meter 154.5kg in 0.8h, stirring 2h is extremely Feed liquid is mixed well and is absorbed, and then starts Minton dryer, rate controlling 30rpm, the dry 10h of normal-temperature vacuum when mediating stirring To powder water content less than 0.1%.Rate controlling 30rpm again, when mediating stirring with spraying device in spraying into above-mentioned food-grade in 2h Chitosan third plants mixing hydrochlorate C weak solution 140kg, and stirring 2h is mixed well and absorbed to feed liquid, then starting vacuum drying dress Set, rate controlling 50rpm, when mediating stirring the dry 14h of normal-temperature vacuum to powder water content less than 0.1% to get Chitosan-coated The vegetarian diet powder of type chlorogenic acid glycinate phytic acid salt composite stability maintenance can store 3 years under the conditions of aluminum-plastic composite membrane bag Vacuum Package It never degenerates.

In above embodiments:

Natural VE, tea polyphenols, schisanhenol, chlorogenic acid and resveratrol belong to edible be originated from naturally The plant type antioxidant of phenolic hydroxy group；

Oleic acid, linoleic acid, linolenic acid, eicosapentaenoic acid and docosahexaenoic acid are belonged to from natural containing single In the long-chain unsaturated fatty acid of alkene, diene and polyenoid；

Vitamin E oleate, linoleic acid ester of vitamin e and vitamin E docosahexaenoic acid ester belong to food-grade dimension Raw element E unsaturated fatty acid ester system food-grade ester；

Oleic acid, linoleic acid, linolenic acid, eicosapentaenoic acid and docosahexaenoic acid belong to edible be originated from naturally The long-chain unsaturated fatty acid containing monoene, diene and polyenoid；

Ten polyglycerol monooleates, ten polyglycereol list linoleates and ten polyglycereol list docosahexaenoic acid esters belong to Ten polyglycereol monounsaturated fatty acids ester of food-grade, and be high-purity from food-grade made of natural Raw material processing or pharmaceutical grade Product；

Sucrose-mono-oleate and sucrose list linoleate belong to food grade sucrose aliphatic ester, and are food-grade or medicine Grade product.

Experimental example:

For the antioxygen bacteriostasis, preservation effect for verifying vegetarian diet powder of the present invention, special commission asks authoritative test agency to made from embodiment The related data of vegetarian diet powder is detected, as a result as shown in the table:

Related data variation table during one, vegetarian diet powder of table stores (material is selected from 1 gained of embodiment)

Related data variation table during two, vegetarian diet powder of table stores (material is selected from 3 gained of embodiment)

Above-mentioned data show, represent vegetarian diet powder freshness core data (including nutrition, hygiene, toxicology and The data such as physical and chemical index) it is substantially unchanged after product room temperature stores 3 years, reflect that plant phenols glycinate of the present invention is planted The vegetarian diet powder of hydrochlorate composition stability maintenance not only nutrition general equilibrium more has brilliant fungi-proofing fresh-keeping storage tolerance effect.

The above description is only a preferred embodiment of the present invention, is not intended to limit the scope of the invention, all utilizations Equivalent structure or equivalent flow shift made by present specification is applied directly or indirectly in other relevant technologies Field is included within the scope of the present invention.

Claims

1. the vegetarian diet powder of plant phenols glycinate phytic acid salt composite stability maintenance, in parts by weight, component includes:

Food-grade plant phenols glycinate phytate --- 0.5~3 part,

Food-grade vitamin E unsaturated fatty acid ester --- 0.05~1 part,

Food grade sucrose aliphatic ester --- 0.2~2 part,

Food-grade SUNSOFT 700P-2 --- 0.2~2 part,

Food-grade chitosan acylate --- 0.5~1 part,

Cold extruding vegetarian diet original powder --- 88~95 parts,

Food-grade Glycerin, mixed triester with caprylic acid capric acid --- 1~5 part；And

The vegetarian diet powder of the plant phenols glycinate phytic acid salt composite stability maintenance is prepared using the method having follow steps:

1) preparation of long-acting antioxidant A

Select the glycine without amido protecting group directly with the high-purity glycyl chloride of pharmaceutical grade made from thionyl chloride chloride technique Hydrochloride presses 1:1.25 molar ratio 50~65 DEG C of progress 3~8h of esterification of temperature control in food-grade atent solvent with plant phenols, Vacuum dechlorination hydrogen, alkali cleaning, desolventizing is water-soluble, active carbon removal of impurities, add sodium carbonate alkali tune to pH be 8~10, solvent extraction It takes, it is dry, it purifies and obtains food-grade plant phenols glycinate, then press 1:1 moles of effective component with food-grade phytic acid aqueous solution It feeds intake, 40~60 DEG C of temperature control, quickly stirs 1~2h and carry out neutralization reaction, adjust pH value 6.8~7.2, obtain the sweet ammonia of food-grade plant phenols Acid esters phytate；

Food-grade plant phenols glycinate phytate, food-grade vitamin E unsaturated fatty acid ester and the pungent capric acid glycerol of food-grade Ester is mixed well up to long-acting antioxidant A；

Food-grade SUNSOFT 700P-2 is added in food-grade Glycerin, mixed triester with caprylic acid capric acid, room temperature mixes well transparent state, then it is warming up to 60~ 70 DEG C, ten polyglycereol monounsaturated fatty acids ester of food-grade and food grade sucrose aliphatic ester is added, 1~2h of stirring is to completely It is even, add above-mentioned long-acting antioxidant A, 50~55 DEG C of temperature control stirrings 1~2 hour to substantially uniformity state are up to self-emulsifying and anti- The long-acting antioxidant B of rotten fresh keeping property is in easily spraying dilute emulsion using preceding plus 0.5~1.5 times of sterile purified water tune；

3) preparation of antimicrobial form fruit glaze agent chitosan acylate C

Deacetylation at least 80%, molecular weight at least 1700kDa and 80~100kDa of molecular weight are taken, the shell by equal proportion mixing is poly- Sugared dried powder calculates the amino content in chitosan dried powder according to the deacetylation of chitosan, with the amino content On the basis of measure 1.5~2.0 times moles organic acid and aforementioned chitosan dried powder mediate stirring 1~3h, powder is obtained by filtration Last shape substance is dried in vacuo under room temperature, obtains antimicrobial form fruit glaze agent chitosan acylate C, uses preceding plus 10~15 times of sterile pures The transparent weak solution of water purification tune；

4) preparation of cold extruding vegetarian diet original powder D

By the edible resource of inanimacy including cereal, water fruits and vegetables, algae, herbal medicine, probiotics, through washing, impurity elimination And fine powder of the water content less than 1% obtained by classical freeze-drying process, blending powder is mixed to obtain with conventional mixer；By the tune It closes powder to be put into bulking machine, addition dry ice, the weight ratio of fine powder and dry ice is 5~7: 1, and is forced into 21~30 atmospheric pressure Afterwards, instantaneous controlled pressure drop completes the cold puffing process of carbon dioxide, Material tissue is made and generates the swollen of microfissure because pulling loose to normal pressure Loose powder end, claims cold extruding vegetarian diet original powder D；

Cold extruding vegetarian diet original powder D, 30~50rpm of rate controlling are added in the good mixing kettle of leakproofness for connecing Minton dryer, While stirring with spraying device in spraying into above-mentioned long-acting antioxidant B dilute emulsion in 0.5~1h, 1~2h of stirring is abundant to feed liquid It mixes and absorbs, then start Minton dryer, 30~50rpm of rate controlling, normal-temperature vacuum dries 5~10h to powder while stirring Expect water content less than 0.1%；30~50rpm of rate controlling again has with spraying device in spraying into above-mentioned chitosan in 2~3h while stirring Machine hydrochlorate C weak solution, 1~2h of stirring are mixed well and are absorbed to feed liquid, then start Minton dryer, and rate controlling 30~ 50rpm, 10~15h of normal-temperature vacuum drying while stirring is to powder water content less than 0.1% to get Chitosan-coated type plant phenols The vegetarian diet powder of glycinate phytic acid salt composite stability maintenance, using vegetarian diet powder storage three under the conditions of aluminum-plastic composite membrane bag Vacuum Package Year never degenerates.

2. the vegetarian diet powder of plant phenols glycinate phytic acid salt composite stability maintenance according to claim 1, it is characterised in that: institute It is anti-for the edible plant type from natural phenolic hydroxy group to state the plant phenols in food-grade plant phenols glycinate phytate Oxidant.

3. the vegetarian diet powder of plant phenols glycinate phytic acid salt composite stability maintenance according to claim 1, it is characterised in that: institute State unsaturated fatty acid ester in food-grade vitamin E unsaturated fatty acid ester be it is edible be originated from it is natural containing monoene, it is double The long-chain unsaturated fatty acid of alkene and polyenoid；Vitamin E is from natural food-grade or pharma grade product；Food-grade vitamin E unsaturated fatty acid ester system food-grade ester.

4. the vegetarian diet powder of plant phenols glycinate phytic acid salt composite stability maintenance according to claim 1, it is characterised in that: institute State unsaturated fatty acid ester in ten polyglycereol monounsaturated fatty acids ester of food-grade be it is edible be originated from it is natural containing monoene, The long-chain unsaturated fatty acid of diene and polyenoid；The ten polyglycereol monounsaturated fatty acids ester of food-grade is from natural raw material The food-grade or pharmaceutical grade high sterling being process, and appearance transparent, 1% aqueous solution are fully transparent.

5. the vegetarian diet powder of plant phenols glycinate phytic acid salt composite stability maintenance according to claim 1, it is characterised in that: institute Stating food grade sucrose aliphatic ester is food-grade or pharma grade product, and HLB value is greater than 15.

6. the vegetarian diet powder of plant phenols glycinate phytic acid salt composite stability maintenance according to claim 1, it is characterised in that: institute The monoester content for stating food-grade SUNSOFT 700P-2 is greater than 98%.

7. the vegetarian diet powder of plant phenols glycinate phytic acid salt composite stability maintenance according to claim 1, it is characterised in that: institute Cationic product after stating food-grade chitosan acylate system's natural chitosan and organic acid reaction, 1% aqueous solution are complete Transparent, pH value is 4.2~4.8, and the organic acid is edible organic acid.

8. the vegetarian diet powder of plant phenols glycinate phytic acid salt composite stability maintenance according to claim 1, it is characterised in that: institute The low viscosity transparency liquid that food-grade Glycerin, mixed triester with caprylic acid capric acid product system is colourless, tasteless, taste is pure and mild, oxidation stability is good is stated, acid Value is less than 0.1mg KOH/g.

9. the preparation method of the vegetarian diet powder of plant phenols glycinate phytic acid salt composite stability maintenance according to claim 1, packet Include following steps:

1) preparation of long-acting antioxidant A

3) preparation of antimicrobial form fruit glaze agent chitosan acylate C

4) preparation of cold extruding vegetarian diet original powder D