High-phosphorus, high-calcium liquid composite fertilizer and preparation method thereof and application method
Technical field
The invention belongs to technical field of fertilizer production, and in particular to a kind of a large amount of and middle trace element fertilizers of crops application
Material, more particularly to be a kind of high-phosphorus, high-calcium liquid composite fertilizer and preparation method thereof and application method.
Background technology
Phosphorus is one of macronutrient necessary to crop growth.It is to form Nuclear extract, lecithin etc. no
The element that can lack.P elements can accelerate cell division, promote root system and overground part to accelerate growth, promote bud differentiation, ahead of time
Maturation, improves fruit quality.The decomposition of respiration, photosynthesis, sugar and transport for example to crop etc. play important work
With.Phosphorus can promote germination, contribute to bud differentiation, promote to bloom well, and promote ripe solid ahead of time;May additionally facilitate root
System's development, makes root system early growth and quick tiller;Phosphorus can influence the normal growth of crop, bloom when lacking, and flower is diminished, and petal is reduced,
Pattern is bad;And making that branch is short, leaf is small, germinating power weakens, and the obfuscation of lower blade leaf color is in aubergine.
Calcium is one of middle amount nutrient necessary to crop growth.Calcium has in the formation and holding of fruit quality
Play an important role, particularly in the fruit development later stage, the formation of how many pairs of fruit qualities of calcium content of fruit and the storage after adopting
There is material impact with transport.Perhaps fructuous disorder symptom such as apple bitter pit, cherry dehiscent fruit, the softening of peach, pear
Black heart etc. all has substantial connection with calcium deficiency.Calcium is not only a kind of a great number of elements necessary to growth and development of fruit tree, prior
It is the regulation and control that fruit tree growth and development are participated in as the second messenger of extracellular signal and intracellular biochemical reactions.Ca2+- CaM joins
With regulation differentiation of floral bud of fruit tree, pollen germination, fruit maturation and degeneration-resistant expression etc..
Calcium is one of most abundant element of content in soil, and fruit tree calcium deficiency is also not meant to soil hypocalcia, even if
Growing plants still has the situation that physiological disease occurs on calacareous soil rich in calcium.Plant calcium deficiency is caused to be primarily due to calcium
It is again not easily shifted after being difficult to be absorbed by plants and absorb, cause substantial amounts of calcium to be present in leaf, it is very few in fruit.Calcium can only be unidirectional
Up shift, and influenceed by transpiration, the phenomenon that the calcium in low-transpiration fruit flows backwards to branches and leaves, thus fruit can usually occur
It is real easily to show calcium deficiency symptom.Fruit losses in cultivation of fruit tree only as caused by calcium deficiency account for yield 20%~
30%.Therefore, the more crops of calcium (such as banana, oranges and tangerines) easily calcium deficiency is needed, it is necessary to apply External Calcium, and it is maximally effective
Method is by foliage-spray through blade and fruit surface, so as to shorten calcium constituent displacement.
Calcium and phosphorus are all the essential nutrient elements of growth and development of plants.Therefore, phosphate fertilizer and calcareous fertilisers are matched somebody with somebody in agricultural production
The synthos of indissoluble are easily formed during it is inevitable that conjunction is applied, but phosphate fertilizer is manured into soil with calcareous fertilisers, so as to have impact on calcium
Leaching Character and validity.More researchs show that there is the calcium carbonate in soil stronger solid phosphorus to act on, and its main mechanism is
Absorption and precipitation, the calcium carbonate of high content can substantially reduce soil P availability.
With the continuous promotion and application of the Integration of Water into Fertilizer, liquid fertilizer starts gradually to popularize in China.At present, China
Liquid fertilizer also in Primary Study stage, particularly high concentration, the research of compound liquid fertilizer high, be substantially at home
Blank.Liquid fertilizer because its it is instant, uniform the advantages of, be irrigation equipment fertilising first-selected fertilizer.Because it is the property used, without stirring
Dissolving is mixed, automation fertilising is especially suitable for.In irrigation technique and the country of automation fertilising popularization, liquid fertilizer is obtained widely
Using.
In order to allow crop to be absorbed to the nutrient of balance, can add various big needed for plant growth in general liquid compound fertilizer
Amount and Meso- and micro-nutrients, such as nitrogen, phosphorus, potassium, calcium, magnesium, manganese, zinc, boron.But, in the liquid phase of liquid fertilizer, phosphate radical
Ion easily reacts with the metal ion such as zinc, calcium, magnesium, forms substantial amounts of precipitation, substantially reduces phosphorus and metal ion nutrient
Validity, so as to reduce the plant recovery of nutrient of fertilizer.At the same time, the easy clogging drip irrigation system of precipitation of these indissolubles
Filter and water dropper, can cause very big loss to agricultural dropleting enemaing system.
In the liquid fertilizer of high phosphorus, calcium is easy to be produced with phosphate anion the precipitation of indissoluble.So, liquid at home
In body fertilizer production, while phosphorous and calcium liquid composite fertilizer higher is substantially blank.Therefore, exploitation phosphorus, calcium content compared with
It is high and the complete liquid fertilizer of nutrient has important social and economic benefit.
The content of the invention
The invention aims to overcome calcium in the prior art easily to produce indissoluble to sink with phosphorus in high phosphorus liquid fertilizer
The technological deficiency in shallow lake, there is provided a kind of high-phosphorus, high-calcium liquid composite fertilizer and preparation method thereof and application method, the high-phosphorus, high-calcium liquid
Phosphorus and calcium content are high in compound fertilizer, while coordinating the trace elements such as nitrogen, potassium, magnesium, boron, manganese, zinc, are meeting crop growth
The symptom that can effectively prevent it from calcium deficiency occurring while needs.
The first aspect of the invention is to provide a kind of high-phosphorus, high-calcium liquid composite fertilizer, by including following parts by weight
Raw material is prepared from:0.2~1.2 part of four Boratex of water eight, 0.05~2 part of EDTA-Mn (EDTA Chelated Manganeses), 0.05~1.8 part
EDTA-Zn (EDTA chelated zincs), 10~50 parts of calcareous fertilisers, 0.5~6 part of fertiliser containing magnesium, 20~75 parts of phosphoric acid, 1~9 part of urea phosphate, 2~13
Part APP, 3~15 parts of potash fertilizer, 0.5~4 part of cosolvent, 0.5~4.5 part of stabilizer and 8~40 parts of water.
Preferably, the high-phosphorus, high-calcium liquid composite fertilizer is prepared from by the raw material including following parts by weight:0.5~
1 part of four Boratex of water eight, 0.4~0.8 part of EDTA-Mn, 0.4~0.8 part of EDTA-Zn, 18~35 parts of calcareous fertilisers, 2~3 parts of fertiliser containing magnesiums,
40~50 parts of phosphoric acid, 1.8~4 parts of urea phosphates, 6~8 parts of APPs, 6~9 parts of potash fertilizer, 1.5~2 parts of cosolvents, 1.5~2.5
Part stabilizer and 17~25 parts of water.
It is further preferred that the high-phosphorus, high-calcium liquid composite fertilizer is by the raw material preparation including following parts by weight
Into:0.5~1 part of four Boratex of water eight, 0.4~0.8 part of EDTA-Mn, 0.4~0.8 part of EDTA-Zn, 18~35 parts of calcareous fertilisers, 2~3
Part fertiliser containing magnesium, 40~50 parts of phosphoric acid, 1.8~4 parts of urea phosphates, 6~8 parts of APPs, 6~9 parts of potash fertilizer, 1.5~2 parts of cosolvents,
1.5~2.5 parts of stabilizers and 17~25 parts of water.
Most preferably, the high-phosphorus, high-calcium liquid composite fertilizer is prepared from by the raw material including following parts by weight:0.8
Part four water eight Boratex, 0.6 part of EDTA-Mn, 0.6 part of EDTA-Zn, 9.6 parts of calcium nitrate, 8.7 parts of calcium oxide, 2.9 parts of magnesia,
41.3 parts of phosphoric acid, 1.9 parts of urea phosphates, 6.7 parts of APPs, 6.7 parts of potassium chloride, 2 parts of cosolvents, 2 parts of stabilizers and 17.4 parts
Water.
In the above of the present invention, the calcareous fertilisers are preferably in calcium oxide, calcium nitrate or EDTA-Ca (EDTA chelates calcium)
One or more
In the above of the present invention, the phosphate fertilizer is preferably MAP, Diammonium phosphate (DAP), urea phosphate, phosphoric acid or polyphosphoric acid
One or more in ammonium.
In the above of the present invention, the fertiliser containing magnesium is preferably magnesia, magnesium chloride, magnesium nitrate or EDTA-Mg, and (EDTA is chelated
Magnesium) in one or more.
In the above of the present invention, the potash fertilizer is preferably in potassium chloride, potassium nitrate, potassium dihydrogen phosphate or dipotassium hydrogen phosphate
One or more.
In the above of the present invention, the cosolvent is preferably aminobenzoic acid, sodium salicylate, DBSA
One or more in sodium, glycerine, dodecyldimethylamine base tertiary amine, diethylene glycol (DEG) or diethylene glycol monoethyl ether.
In the above of the present invention, the stabilizer be preferably be nitric acid, citric acid, malic acid or poly- asparagus fern door propylhomoserin in
One or more.
Phosphate source of the present invention can use phosphoric acid by wet process and/or thermal phosphoric acid.
The second aspect of the invention is a kind of high-phosphorus, high-calcium liquid composite fertilizer provided described in present invention one side
The preparation method of material, comprises the following steps:
S1. mother liquor is obtained after the Boratex of four water eight, EDTA-Mn, EDTA-Zn and stabilizer being dissolved in into water;
It is stirring while adding to formation to water-soluble calcareous fertilizer is added in mother liquor if S2. including water-soluble calcareous fertilizer in calcareous fertilisers
Transparent supernatant liquid, omits this step if water-soluble calcareous fertilizer is not contained;
S3. in the liquid for being formed to S2 phosphoric acid is added, it is stirring while adding under the conditions of 75~85 DEG C to form sticky clarification
Fluid;
S4. urea phosphate and APP are rapidly joined in order in the fluid for being formed to S3 under the conditions of 50~60 DEG C, are stirred
Mix to the fluid for forming clear;
If water-soluble fertiliser containing magnesium and potash fertilizer S5. to be added the fluid of S4 formation respectively comprising water-soluble fertiliser containing magnesium in fertiliser containing magnesium
In, it is stirring while adding;
If S6. including slightly water-soluble calcareous fertilisers comprising slightly water-soluble fertiliser containing magnesium and/or calcareous fertilisers in fertiliser containing magnesium, fluid in S5 is treated
After temperature is reduced to room temperature, slightly water-soluble fertiliser containing magnesium and/or slightly water-soluble calcareous fertilisers are slowly added to, it is 70~80 to keep reaction temperature
DEG C, if not containing slightly water-soluble fertiliser containing magnesium and slightly water-soluble calcareous fertilisers, omit this step;
S7. keep fluid temperature (F.T.) at 50~60 DEG C, be slowly added to cosolvent, room temperature is cooled to after mixing, and to obtain final product high phosphorus high
Calcium liquid composite fertilizer.
Wherein, water-soluble calcareous fertilizer refers to meltage >=1g in 100g water, such as calcium nitrate, EDTA-Ca at 20 DEG C
Deng.
Wherein, water-soluble fertiliser containing magnesium refer at 20 DEG C, meltage >=1g in 100g water, such as magnesium chloride, magnesium nitrate,
EDTA-Mg etc..
Wherein, slightly water-soluble calcareous fertilisers refer to the meltage < 1g in 100g water at 20 DEG C, such as calcium oxide etc..
Wherein, slightly water-soluble fertiliser containing magnesium refers to that meltage < 1g, for example, aoxidize calcium and magnesium in 100g water at 20 DEG C.
Preferably, mixing time is preferably 10~15min described in step S2.
Preferably, mixing time described in step S3 is 20~25min.
Preferably, mixing time described in step S4 is 10~15 minutes.
Preferably, the mixing time of step S5 is 20~25min.
Preferably, the mixing time of step S6 is 15~20min.
Preferably, the mixing time of step S7 is 20~25 minutes.
In above-mentioned steps S3, the speed for adding phosphoric acid must be controlled to maintain the temperature at 75~85 DEG C, it is stirring while adding, because
It is that, when phosphoric acid is added, the material in the fluid that phosphoric acid can be formed with S2 occurs violent exothermic reaction, too high or too low for temperature
The activity of metal ion in liquid phase will be influenceed.
In above-mentioned steps S6, the temperature in step S5 must be waited to add slightly water-soluble calcium again after dropping to room temperature completely
Fertilizer, and to control to add the speed of slightly water-soluble calcareous fertilisers and keep reaction temperature for 70~80 DEG C, it is stirring while adding, because
Addition slightly water-soluble calcareous fertilisers when, slightly water-soluble calcareous fertilisers can with the phosphoric acid in liquid phase, urea phosphate occur exothermic reaction, temperature it is too high or
It is too low all to influence phosphorus and calcium stability in the liquid phase.
The third aspect of the invention is to provide the high-phosphorus, high-calcium liquid composite fertilizer described in a kind of one side of the invention
The application method of material:The high-phosphorus, high-calcium liquid composite fertilizer is applied for pouring, drip irrigation or spray.
When pouring is applied, crops seedling stage dilutes 200~300 times, and other time dilutes 100~200 times, directly drenches in root of the crop
Portion, the breeding time according to crop determines that number of times is applied in pouring, and time interval is 10~15 days, and vegetables can suitably increase application times, fruit
Tree can suitably increase amount of application.
When spraying, vegetables and field crop dilute 800~1000 times, and fruit tree dilutes 500~800 times, is sprayed on blade surface
, positive and negative uniformly sprays, and is sprayed onto untill blade just drips.
When drip irrigation is applied, seedling stage extension rate is 200~300 times, and the middle and later periods is 100~200 times, general every 7~10 days
Can drip and apply once.During drip irrigation, fertilization time must be got hold of, the shallower crop of root system, fertilization time must be controlled 30
Within minute, the deep crop of root system, fertilization time was controlled at 1~1.5 hour.
The control that the present invention passes through particular order and the technique of special reaction condition, reaction generation phosphoric acid-calcium complex, energy
Coexist in liquid phase with enough making phosphate radical and calcium ion Simultaneous Stabilization in, it is to avoid produce the indissolubles such as calcium phosphate precipitation, effectively improve phosphorus
The utilization rate of calcium liquid fertilizer.Overcome calcium ion in the prior art and easily produce indissoluble with phosphate radical in high phosphorus liquid fertilizer
The low technological deficiency of precipitation, high cost, metal ion content.
High-phosphorus, high-calcium liquid composite fertilizer of the present invention can be different according to addition the need for crop different growing
The growth regulator of type and concentration, the high-phosphorus, high-calcium liquid composite fertilizer can also be with fulvic acid, humic acid or ulmic acid
It is used in mixed way Deng Organic Ingredients, improves the utilization rate of fertilizer nutrient.
Compared with prior art, the present invention has the advantages that:
(1) high-phosphorus, high-calcium liquid composite fertilizer total nutrient content of the present invention is high, physics and chemical properties stabilization, high temperature,
The phenomenon such as nodeless mesh, precipitation, layering under low temperature and normal temperature condition.
(2) high-phosphorus, high-calcium liquid composite fertilizer of the present invention belongs to clear liquid type liquid fertilizer, can be applied with foliage-spray, pouring, also may be used
It is easy to use for sprinkling irrigation and drip irrigation system, have the advantages that time saving, saving of labor, province's fertilizer, fertilizer efficiency are fast.
(3) phosphorus and calcium content in high-phosphorus, high-calcium liquid composite fertilizer of the present invention are higher, provide acid by adding phosphoric acid
Condition, coexist in liquid phase with making phosphate radical and calcium ion Simultaneous Stabilization in, it is to avoid produce the indissolubles such as calcium phosphate precipitation.
(4) good fluidity of the invention, and nutrient is highly enriched, it is adaptable to the larger automation fertilising operation of area, can be bright
It is aobvious to improve fertilising efficiency.
(5) the invention provides the ternary liquid fertilizer containing middle trace element, nutrient is that crop provides simultaneously comprehensively
Grow required a great number of elements and middle trace element, wherein crop root can be promoted to give birth to the characteristics of high-phosphorus, high-calcium of the present invention
It is long, flower and fruit protecting, while the calcium deficiency symptom of crop can be prevented effectively.
(6) N+P in the liquid fertilizer that the present invention is provided2O5+K2O >=500g/L, Mn+Ca >=100g/L, Zn+B+Mn >=5g/
L, nutrient content therein both can reach People's Republic of China's agricultural industry criteria (NY1107-2010) " a great number of elements water
Molten fertilizer (microelement type) " fluid product technical indicator, can reach People's Republic of China (PRC) agricultural industry criteria (NY again
2266-2012) " moderate-element water-soluble fertilizer " fluid product technical indicator, is flexible life of the fertilizer output enterprise in liquid fertilizer
Produce and sale provides splendid convenience.
Specific embodiment
The present invention is made with reference to specific embodiment further being elaborated, to more fully understand the present invention.
Embodiment 1
High-phosphorus, high-calcium liquid composite fertilizer described in the present embodiment contains each component of following parts by weight:
Water |
18.8 parts |
The Boratex of four water eight |
0.8 part |
EDTA-Mn |
0.6 part |
EDTA-Zn |
0.6 part |
Calcium nitrate |
9.5 parts |
Calcium oxide |
7.6 parts |
Magnesia |
2.8 parts |
Magnesium chloride |
1.1 parts |
Phosphoric acid |
40.7 parts |
Urea phosphate |
2.8 parts |
APP |
5.7 parts |
Potassium chloride |
5.7 parts |
Neopelex |
1.9 parts |
Nitric acid |
1.4 parts |
The specific preparation method of the high-phosphorus, high-calcium liquid composite fertilizer comprises the following steps:
S1. the Boratex of four water eight, EDTA-Mn, EDTA-Zn and stabilizer nitric acid are dissolved in water stirring 10min, are clarified
Transparent mother liquor;
S2., calcium nitrate is slowly added to the mother liquor in S1, stirring while adding, the back of 20min is to forming transparent clarified solution
Body;
S3., phosphoric acid is slowly added to the mixed liquor in S2, it is stirring while adding, stable reaction is kept at 80 DEG C, after 10min
Form the fluid of sticky clarification;
S4. keep reacting the temperature of generation at 55 DEG C in S3, rapidly join urea phosphate and APP respectively in order, stir
10min is mixed, the fluid of clear is formed;
S5., magnesium chloride and potassium chloride are slowly added to the fluid of the clear in S4, stirring while adding, 25min respectively
Relief fluid natural cooling;
S6. after the fluid in S5 is cooled to room temperature, calcium oxide, magnesia are slowly added to, it is stirring while adding, keep reaction
Temperature stabilization stirs 20min at 80 DEG C;
S7. keep reacting the temperature of generation at 60 DEG C in S6, be slowly added to cosolvent neopelex, side edged
Stirring, is cooled to room temperature after 20min, finished product sealing is filled in the liquid storing barrel of 30L.
The comprehensive content's index of fertilizer is determined using People's Republic of China's agricultural industry criteria (NY 1107-2010), is seen
Shown in table 1.
Embodiment 2
High-phosphorus, high-calcium liquid composite fertilizer described in the present embodiment contains each component of following parts by weight:
Water |
17.4 parts |
The Boratex of four water eight |
0.8 part |
EDTA-Mn |
0.6 part |
EDTA-Zn |
0.6 part |
Calcium nitrate |
9.6 parts |
Calcium oxide |
8.7 parts |
Magnesia |
2.9 parts |
Phosphoric acid |
41.3 parts |
Urea phosphate |
1.9 parts |
APP |
6.7 parts |
Potassium chloride |
6.7 parts |
Dodecyldimethylamine base tertiary amine |
1.4 parts |
Malic acid |
1.4 parts |
The specific preparation method of the high-phosphorus, high-calcium liquid composite fertilizer comprises the following steps:
S1. the Boratex of four water eight, EDTA-Mn, EDTA-Zn and stabilizer malic acid are dissolved in water stirring 10min, obtain clear
Clear bright mother liquor;
S2., calcium nitrate is slowly added to the mother liquor in S1, stirring while adding, the back of 20min is to forming transparent clarified solution
Body;
S3., phosphoric acid is slowly added to the mixed liquor in S2, it is stirring while adding, stable reaction is kept at 85 DEG C, after 15min
Form the fluid of sticky clarification;
S4. keep reacting the temperature of generation at 60 DEG C in S3, rapidly join urea phosphate and APP respectively in order, stir
10min is mixed, the fluid of clear is formed;
The fluid of the clear S5. potassium chloride being slowly added in S4, stirring while adding, the relief fluid of 20min is certainly
So cooling;
S6. after the fluid in S5 is cooled to room temperature, calcium oxide and magnesia are slowly added to, it is stirring while adding, keep steady
75 DEG C are scheduled on, 20min is stirred;
S7. keep reacting the temperature of generation at 55 DEG C in S6, be slowly added to cosolvent dodecyldimethylamine base tertiary amine, Bian Jia
Side is stirred, and room temperature is cooled to after 20min, and finished product sealing is filled in the liquid storing barrel of 30L.
The comprehensive content's index of fertilizer is determined using People's Republic of China's agricultural industry criteria (NY 1107-2010), is seen
Shown in table 1.
Embodiment 3
High-phosphorus, high-calcium liquid composite fertilizer described in the present embodiment contains each component of following parts by weight:
Water |
19.0 parts |
The Boratex of four water eight |
0.8 part |
EDTA-Mn |
0.6 part |
EDTA-Zn |
0.6 part |
Calcium nitrate |
7.8 parts |
Calcium oxide |
8.8 parts |
Magnesia |
2.9 parts |
Phosphoric acid |
37 parts |
Urea phosphate |
5.8 parts |
APP |
5.9 parts |
Potassium chloride |
6.8 parts |
Poly-aspartic-acid |
2.0 parts |
Diethylene glycol (DEG) |
2.0 parts |
The specific preparation method of the high-phosphorus, high-calcium liquid composite fertilizer comprises the following steps:
S1. the Boratex of four water eight, EDTA-Mn, EDTA-Zn and stabilizer poly-aspartic-acid are dissolved in water stirring 15min,
Obtain the mother liquor of clear;
S2., calcium nitrate is slowly added to the mother liquor in S1, stirring while adding, the back of 20min is light to transparent clarification is formed
Yellow liquid;
S3., phosphoric acid is slowly added to the mixed liquor in S2, it is stirring while adding, stable reaction is kept at 75 DEG C, after 10min
Form the fluid of sticky clarification;
S4. keep reacting the temperature of generation at 50 DEG C in S3, rapidly join APP, urea phosphate respectively in order, stir
15min is mixed, the fluid of clear is formed;
S5. after the fluid in S4 naturally cools to room temperature, calcium oxide and magnesia are slowly added to, it is stirring while adding, protect
Keep steady and be scheduled on 70 DEG C, stir 25min;
S6. keep reacting the temperature of generation at 50 DEG C in S6, be slowly added to cosolvent diethylene glycol (DEG), stirring while adding, 25min
Room temperature is cooled to afterwards, and finished product sealing is filled in the liquid storing barrel of 30L.
The comprehensive content's index of fertilizer is determined using People's Republic of China's agricultural industry criteria (NY 1107-2010), is seen
Shown in table 1.
Embodiment 4
High-phosphorus, high-calcium liquid composite fertilizer described in the present embodiment contains each component of following parts by weight:
Water |
19.3 parts |
The Boratex of four water eight |
0.8 part |
EDTA-Mn |
0.6 part |
EDTA-Zn |
0.6 part |
Calcium nitrate |
10.7 parts |
Calcium oxide |
7.8 parts |
Magnesia |
2.9 parts |
Phosphoric acid |
38.8 parts |
APP |
8.7 parts |
Potassium chloride |
5.8 parts |
Glycerine |
2.0 parts |
Malic acid |
2.0 parts |
The specific preparation method of the high-phosphorus, high-calcium liquid composite fertilizer comprises the following steps:
S1. the Boratex of four water eight, EDTA-Mn, EDTA-Zn and stabilizer malic acid are dissolved in water stirring 10min, obtain clear
Clear bright mother liquor;
S2., calcium nitrate is slowly added to the mother liquor in S1, stirring while adding, the back of 20min is to forming transparent clarified solution
Body;
S3., phosphoric acid is slowly added to the mixed liquor in S2, it is stirring while adding, stable reaction is kept at 85 DEG C, after 15min
Form the fluid of sticky clarification;
S4. keep reacting the temperature of generation at 60 DEG C in S3, rapidly join APP respectively in order, stir 10min,
Form the fluid of clear;
The fluid of the clear S5. potassium chloride being slowly added in S4, stirring while adding, the relief fluid of 20min is certainly
So cooling;
S6. after the fluid in S5 is cooled to room temperature, calcium oxide and magnesia are slowly added to, it is stirring while adding, keep steady
75 DEG C are scheduled on, 20min is stirred;
S7. keep S6 in react the temperature of generation at 55 DEG C, be slowly added to cosolvent glycerine, it is stirring while adding, 20min it
After be cooled to room temperature, by finished product sealing be filled in the liquid storing barrel of 30L.
The comprehensive content's index of fertilizer is determined using People's Republic of China's agricultural industry criteria (NY 1107-2010), is seen
Shown in table 1.
Embodiment 5
High-phosphorus, high-calcium liquid composite fertilizer described in the present embodiment contains each component of following parts by weight:
Water |
19.3 parts |
The Boratex of four water eight |
0.9 part |
EDTA-Mn |
0.5 part |
EDTA-Zn |
0.6 part |
Calcium nitrate |
8.2 parts |
Calcium oxide |
8.6 parts |
Magnesia |
3.0 parts |
Phosphoric acid |
41.5 parts |
APP |
8.1 parts |
Potassium chloride |
6.1 parts |
Aminobenzoic acid |
1.6 parts |
Malic acid |
1.6 parts |
The specific preparation method of the high-phosphorus, high-calcium liquid composite fertilizer is with embodiment 4
The comprehensive content's index of fertilizer is determined using People's Republic of China's agricultural industry criteria (NY 1107-2010), is seen
Shown in table 1.
Embodiment 6
High-phosphorus, high-calcium liquid composite fertilizer contains each component of following parts by weight described in the present embodiment:
Water |
20.7 parts |
The Boratex of four water eight |
0.9 part |
EDTA-Mn |
0.5 part |
EDTA-Zn |
0.6 part |
Calcium nitrate |
6.6 parts |
Calcium oxide |
9.5 parts |
Magnesia |
2.4 parts |
Phosphoric acid |
39.6 parts |
APP |
9.5 parts |
Potassium chloride |
5.7 parts |
Aminobenzoic acid |
2.0 parts |
Poly- asparagus fern door propylhomoserin |
2.0 parts |
The specific preparation method of the high-phosphorus, high-calcium liquid composite fertilizer is with embodiment 3
The comprehensive content's index of fertilizer is determined using People's Republic of China's agricultural industry criteria (NY 1107-2010), is seen
Shown in table 1.
Embodiment 7
High-phosphorus, high-calcium liquid composite fertilizer described in the present embodiment contains each component of following parts by weight:
Water |
20.1 parts |
The Boratex of four water eight |
0.9 part |
EDTA-Mn |
0.5 part |
EDTA-Zn |
0.6 part |
Calcium nitrate |
6.5 parts |
Calcium oxide |
8.6 parts |
Magnesia |
2.5 parts |
Phosphoric acid |
43.2 parts |
APP |
5.0 parts |
Potassium nitrate |
8.1 parts |
Sodium salicylate |
2.0 parts |
Citric acid |
2.0 parts |
S1. the Boratex of four water eight, EDTA-Mn, EDTA-Zn and stabilizer citric acid are dissolved in water stirring 15min, obtain clear
Clear bright mother liquor;
S2., calcium nitrate is slowly added to the mother liquor in S1, stirring while adding, the back of 20min is to forming transparent clarified solution
Body;
S3., phosphoric acid is slowly added to the mixed liquor in S2, it is stirring while adding, stable reaction is kept at 85 DEG C, after 15min
Form the fluid of sticky clarification;
S4. keep reacting the temperature of generation at 60 DEG C in S3, rapidly join APP respectively in order, stir 10min,
Form the fluid of clear;
The fluid of the clear S5. potassium nitrate being slowly added in S4, stirring while adding, the relief fluid of 20min is certainly
So cooling;
S6. after the fluid in S5 is cooled to room temperature, calcium oxide and magnesia are slowly added to, it is stirring while adding, keep steady
75 DEG C are scheduled on, 20min is stirred;
S7. keep reacting the temperature of generation at 55 DEG C in S6, be slowly added to cosolvent sodium salicylate, it is stirring while adding,
Room temperature is cooled to after 20min, finished product sealing is filled in the liquid storing barrel of 30L.
The comprehensive content's index of fertilizer is determined using People's Republic of China's agricultural industry criteria (NY 1107-2010), is seen
Shown in table 1.
Embodiment 8
High-phosphorus, high-calcium liquid composite fertilizer described in the present embodiment contains each component of following parts by weight:
Water |
17.9 parts |
The Boratex of four water eight |
0.9 part |
EDTA-Mn |
0.6 part |
EDTA-Zn |
0.5 part |
Calcium nitrate |
7.3 parts |
Calcium oxide |
9.2 parts |
Magnesia |
2.4 parts |
Phosphoric acid |
43.6 parts |
APP |
5.8 parts |
Potassium nitrate |
7.8 parts |
Citric acid |
2 parts |
Diethylene glycol (DEG) |
1 part |
Dodecyldimethylamine base tertiary amine |
1 part |
The specific preparation method of the high-phosphorus, high-calcium liquid composite fertilizer comprises the following steps:
S1. the Boratex of four water eight, EDTA-Mn, EDTA-Zn and stabilizer citric acid are dissolved in water stirring 15min, obtain clear
Clear bright mother liquor;
S2., calcium nitrate is slowly added to the mother liquor in S1, stirring while adding, the back of 20min is to forming transparent clarified solution
Body;
S3., phosphoric acid is slowly added to the mixed liquor in S2, it is stirring while adding, stable reaction is kept at 85 DEG C, after 15min
Form the fluid of sticky clarification;
S4. keep reacting the temperature of generation at 60 DEG C in S3, rapidly join APP respectively in order, stir 10min,
Form the fluid of clear;
The fluid of the clear S5. potassium nitrate being slowly added in S4, stirring while adding, the relief fluid of 20min is certainly
So cooling;
S6. after the fluid in S5 is cooled to room temperature, calcium oxide and magnesia are slowly added to, it is stirring while adding, keep steady
75 DEG C are scheduled on, 20min is stirred;
S7. keep reacting the temperature of generation at 60 DEG C in S6, be slowly added to cosolvent dodecyldimethylamine base tertiary amine and two
Glycol, it is stirring while adding, room temperature is cooled to after 20min, finished product sealing is filled in the liquid storing barrel of 30L.
The comprehensive content's index of fertilizer is determined using People's Republic of China's agricultural industry criteria (NY 1107-2010), is seen
Shown in table 1.
Embodiment 9
High-phosphorus, high-calcium liquid composite fertilizer described in the present embodiment contains each component of following parts by weight:
Water |
17.5 parts |
The Boratex of four water eight |
0.9 part |
EDTA-Mn |
0.6 part |
EDTA-Zn |
0.5 part |
Calcium nitrate |
6.2 parts |
Calcium oxide |
9.0 parts |
Magnesia |
2.4 parts |
Magnesium nitrate |
1.0 parts |
Phosphoric acid |
41.7 parts |
APP |
7.6 parts |
Potassium nitrate |
8.6 parts |
Poly- asparagus fern door propylhomoserin |
2 parts |
Aminobenzoic acid |
0.5 part |
Sodium salicylate |
0.5 part |
Neopelex |
1 part |
The specific preparation method of the high-phosphorus, high-calcium liquid composite fertilizer comprises the following steps:
S1. the Boratex of four water eight, EDTA-Mn, EDTA-Zn and the poly- asparagus fern door propylhomoserin of stabilizer are dissolved in water stirring 15min,
Obtain the mother liquor of clear;
S2., calcium nitrate is slowly added to the mother liquor in S1, stirring while adding, the back of 20min is to forming transparent clarified solution
Body;
S3., phosphoric acid is slowly added to the mixed liquor in S2, it is stirring while adding, stable reaction is kept at 85 DEG C, after 15min
Form the fluid of sticky clarification;
S4. keep reacting the temperature of generation at 60 DEG C in S3, rapidly join APP respectively in order, stir 10min,
Form the fluid of clear;
S5., magnesium nitrate and potassium nitrate are slowly added to the fluid of the clear in S4, stirring while adding, 20min respectively
Relief fluid natural cooling;
S6. after the fluid in S5 is cooled to room temperature, calcium oxide and magnesia are slowly added to, it is stirring while adding, keep steady
75 DEG C are scheduled on, 20min is stirred;
S7. keep reacting the temperature of generation at 60 DEG C in S6, be slowly added to cosolvent aminobenzoic acid, sodium salicylate, ten
Dialkyl benzene sulfonic acids sodium, it is stirring while adding, room temperature is cooled to after 20min, finished product sealing is filled in the liquid storing barrel of 30L.
The comprehensive content's index of fertilizer is determined using People's Republic of China's agricultural industry criteria (NY 1107-2010), is seen
Shown in table 1.
The performance test of the high-phosphorus, high-calcium liquid composite fertilizer of the present invention of embodiment 10
The high-phosphorus, high-calcium liquid composite fertilizer that the methods described of the embodiment of the present invention 1~9 is prepared make high content phosphorus and
Calcium is present in the liquid phase of liquid fertilizer simultaneously, and formation total nutrient content is high, middle trace element is complete, good fluidity Liquid Fertilizer
Material.The content's index for measuring fertilizer using People's Republic of China's agricultural industry criteria (NY 1107-2010) is shown in Table 1-1 and table
1-2。
Table 1-1 high-phosphorus, high-calcium liquid fertilizer quality index
Table 1-2 high-phosphorus, high-calcium liquid fertilizer quality index
From table 1-1 and table 1-2 results:By the present invention in that with stabilizer nitric acid, citric acid, malic acid or poly- asparagus fern
Door propylhomoserin, in the addition speed and the temperature of reaction of strict control phosphoric acid, can effectively prevent the calcium of the high content in fertilizer
Element and phosphatase reaction form precipitation, reduce effective content of the calcium in liquid fertilizer.The high-phosphorus, high-calcium liquid of the present invention of embodiment 11
The application test of compound fertilizer
(1) drench and apply experiment
Test site:Guangzhou, Guangdong Zengcheng City rock patch town barrow village
Test period:In September, 2012 in December, -2012
Trial crops:Pakchoi
Experiment soil:Sandy loam
Testing program:Two treatment of high-phosphorus, high-calcium liquid composite fertilizer sample of the present invention and comparative example are chosen in this experiment.Contrast
Example is fertile (a great number of elements Water soluble fertilizer) using the pakchoi dedicated liquid of Guangdong Lv Xing bio tech ltd production, N+P2O5+
K2O >=500g/L, B+Zn >=5g/L.High-phosphorus, high-calcium liquid composite fertilizer of the present invention designs 5 treatment, and numbering is treatment 1 respectively
(the high-phosphorus, high-calcium liquid composite fertilizer prepared using the embodiment of the present invention 1), treatment 2 (is prepared using the embodiment of the present invention 2
The high-phosphorus, high-calcium liquid composite fertilizer for obtaining), (the high-phosphorus, high-calcium liquid prepared using the embodiment of the present invention 3 is combined for treatment 3
Fertilizer), 4 (the high-phosphorus, high-calcium liquid composite fertilizers prepared using the embodiment of the present invention 4) are processed, treatment 5 is (using the present invention
The high-phosphorus, high-calcium liquid composite fertilizer that embodiment 5 is prepared).Sowed within 10th in September in 2012, September final singling on the 30th, mu plants 3
Wan Zhu.November 10 harvested.Each treatment liquid fertilizer respectively drenches respectively at October 7, October 17, October 27 to be applied once, and 10
It is 250 times that concentration is applied in the pouring on the moon 7, and the pouring in October 17 and October 27 applies concentration for 150 times.Comparative example is with same administration
Concentration and time carry out pouring and apply.Result of the test is as shown in table 2-1.
Table 2-1 high-phosphorus, high-calcium liquid composite fertilizers of the present invention and Vegetable Sold special fertilizer comparative result
Treatment |
Plant height (cm) |
Growth rate |
Per mu yield (kg) |
Rate of growth |
Control |
18.3 |
- |
1341.8 |
- |
Treatment 1 |
23.3 |
20.7% |
1518.5 |
13.2% |
Treatment 2 |
24.6 |
27.5% |
1561.6 |
16.4% |
Treatment 3 |
22.9 |
18.7% |
1489.3 |
11.0% |
Treatment 4 |
21.8 |
13.0% |
1467.9 |
9.4% |
Treatment 5 |
23.8 |
23.3% |
1511.8 |
12.7% |
Result shows, compared with comparative example, pouring is applied high-phosphorus, high-calcium liquid composite fertilizer of the present invention and increased to a certain extent
The yield of pakchoi is added.The effect of increasing production of wherein embodiment 2 is the most notable, and 219.8kg is increased per per mu yield, and rate of growth is
16.4%.Meanwhile, the plant height that high-phosphorus, high-calcium liquid composite fertilizer of the invention significantly improves pakchoi is applied in pouring, embodiment 1,2,
3rd, 4,5 plant height it is higher than comparative example by 20.7% respectively, 27.5%, 18.7%, 13.0%, 23.3%.Therefore, the present invention is provided
High-phosphorus, high-calcium liquid composite fertilizer promotes the nutrient growth of pakchoi and the absorption of mineral nutrient, improve pakchoi yield and
Quality.Meanwhile, the liquid composite fertilizer that the present invention is provided can be obviously promoted the root system development of pakchoi such that it is able to obtain more
Nutrition, so as to improve the yield of pakchoi.
(2) spraying test
Test site:Shaoguan City of Guangdong Province Xinfeng County new meaning fruit field
Test period:2 months in December, -2012 in 2012
Trial crops:Tribute mandarin orange
Experiment soil:Laterite
Testing program:Two treatment of high-phosphorus, high-calcium liquid composite fertilizer of the present invention and comparative example are chosen in this experiment.Comparative example
The oranges and tangerines dedicated liquid fertilizer (containing humic acid water-soluble fertilizer) produced using Guangdong Lv Xing bio tech ltd, N+P2O5+K2O≥
200g/L, humic acid >=40g/L.High-phosphorus, high-calcium liquid composite fertilizer of the present invention designs 5 treatment, and numbering is that treatment 1 (is adopted respectively
The high-phosphorus, high-calcium liquid composite fertilizer prepared with the embodiment of the present invention 1), treatment 2 (is prepared into using the embodiment of the present invention 2
The high-phosphorus, high-calcium liquid composite fertilizer for arriving), process 3 (the high-phosphorus, high-calcium liquid composite fertilizers prepared using the embodiment of the present invention 3
Material), 4 (the high-phosphorus, high-calcium liquid composite fertilizers prepared using the embodiment of the present invention 4) are processed, treatment 5 is (real using the present invention
Apply the high-phosphorus, high-calcium liquid composite fertilizer that example 5 is prepared).Each treatment liquid fertilizer was respectively at 10 days, 2012 2 months 2012
20 days 2 months, on March 12nd, 2012, on April 1st, 2012, on May 1st, 2012 respectively spray once, spraying concentration is 500 times.It is right
Ratio is sprayed with same spraying concentration and time.Result of the test is as shown in table 2-2.
Table 2-2 high-phosphorus, high-calcium liquid composite fertilizers of the present invention and commercially available oranges and tangerines special fertilizer comparative result
Treatment |
Single fruit weight (g) |
Growth rate (%) |
Single plant yield (kg) |
Rate of growth (%) |
Comparative example |
123.4 |
- |
58.9 |
- |
Treatment 1 |
136.5 |
10.6 |
69.8 |
18.5 |
Treatment 2 |
142.1 |
15.2 |
73.2 |
24.3 |
Treatment 3 |
134.4 |
8.9 |
67.7 |
14.9 |
Treatment 4 |
132.1 |
7.1 |
65.5 |
11.2 |
Treatment 5 |
139.8 |
13.3 |
70.4 |
19.5 |
Result shows, is compared with comparative example, sprays high-phosphorus, high-calcium liquid composite fertilizer of the present invention and increase to a certain extent
The yield of tribute mandarin orange is added.The effect of increasing production of wherein embodiment 2 is the most notable, and compared with comparative example, single plant yield increases 14.3kg,
Rate of growth is 24.3%.Meanwhile, the single fruit weight that high-phosphorus, high-calcium liquid composite fertilizer of the invention significantly improves tribute mandarin orange is sprayed, it is real
Apply the single fruit weight of example 1,2,3,4,5 it is higher than comparative example by 10.6% respectively, 15.2%, 8.9%, 7.1%, 13.3%.It can be seen that, the present invention
The high-phosphorus, high-calcium liquid composite fertilizer of offer promotes the absorption of tribute mandarin orange fruit growth and mineral nutrient, improves the solid of fruit
Degree, while improve the fruit-setting rate and single fruit weight of tribute mandarin orange, effectively prevents calcium deficiency to lack phosphorus phenomenon, so as to improve tribute mandarin orange yield and
Quality.
Additionally, the high-phosphorus, high-calcium liquid composite fertilizer that the present invention is provided can effectively prevent the symptom of tribute mandarin orange calcium deficiency, effectively subtract
The generation of few tribute mandarin orange dehiscent fruit and malformed fruit.
Specific embodiment of the invention has been described in detail above, but it is intended only as example, and the present invention is not limited
It is formed on particular embodiments described above.To those skilled in the art, any equivalent modifications carried out to the present invention and
Replacement is also all among scope of the invention.Therefore, the impartial conversion made without departing from the spirit and scope of the invention and
Modification, all should be contained within the scope of the invention.