CN104241663A - 用于空气电池的空气电极及其制造方法、以及空气电池 - Google Patents
用于空气电池的空气电极及其制造方法、以及空气电池 Download PDFInfo
- Publication number
- CN104241663A CN104241663A CN201410487878.2A CN201410487878A CN104241663A CN 104241663 A CN104241663 A CN 104241663A CN 201410487878 A CN201410487878 A CN 201410487878A CN 104241663 A CN104241663 A CN 104241663A
- Authority
- CN
- China
- Prior art keywords
- air electrode
- catalyst
- air
- mass ratio
- electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 239000003054 catalyst Substances 0.000 claims abstract description 57
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 16
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 16
- 229910052751 metal Inorganic materials 0.000 claims abstract description 10
- 239000002184 metal Substances 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims description 49
- 238000000034 method Methods 0.000 claims description 27
- 239000000843 powder Substances 0.000 claims description 18
- 238000001125 extrusion Methods 0.000 claims description 17
- 239000012528 membrane Substances 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 15
- 239000004020 conductor Substances 0.000 claims description 14
- 239000003792 electrolyte Substances 0.000 claims description 14
- -1 polytetrafluoroethylene Polymers 0.000 claims description 10
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 10
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 10
- 239000006258 conductive agent Substances 0.000 claims description 9
- 239000000839 emulsion Substances 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000084 colloidal system Substances 0.000 claims description 6
- 230000018044 dehydration Effects 0.000 claims description 6
- 238000006297 dehydration reaction Methods 0.000 claims description 6
- HBAGRTDVSXKKDO-UHFFFAOYSA-N dioxido(dioxo)manganese lanthanum(3+) Chemical group [La+3].[La+3].[O-][Mn]([O-])(=O)=O.[O-][Mn]([O-])(=O)=O.[O-][Mn]([O-])(=O)=O HBAGRTDVSXKKDO-UHFFFAOYSA-N 0.000 claims description 6
- 229910002804 graphite Inorganic materials 0.000 claims description 6
- 239000010439 graphite Substances 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 239000006229 carbon black Substances 0.000 claims description 5
- 238000005245 sintering Methods 0.000 claims description 5
- 238000004513 sizing Methods 0.000 claims description 5
- 239000006230 acetylene black Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 230000005518 electrochemistry Effects 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical group [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 230000008569 process Effects 0.000 description 5
- 238000006555 catalytic reaction Methods 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 229920002521 macromolecule Polymers 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 230000004888 barrier function Effects 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000010382 chemical cross-linking Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 238000003828 vacuum filtration Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
- H01M4/80—Porous plates, e.g. sintered carriers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8825—Methods for deposition of the catalytic active composition
- H01M4/8864—Extrusion
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Inert Electrodes (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410487878.2A CN104241663B (zh) | 2014-09-22 | 2014-09-22 | 用于空气电池的空气电极及其制造方法、以及空气电池 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410487878.2A CN104241663B (zh) | 2014-09-22 | 2014-09-22 | 用于空气电池的空气电极及其制造方法、以及空气电池 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104241663A true CN104241663A (zh) | 2014-12-24 |
CN104241663B CN104241663B (zh) | 2016-08-17 |
Family
ID=52229340
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410487878.2A Active CN104241663B (zh) | 2014-09-22 | 2014-09-22 | 用于空气电池的空气电极及其制造方法、以及空气电池 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104241663B (zh) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107437645A (zh) * | 2017-07-17 | 2017-12-05 | 潘科艳 | 一种多孔高性能的金属燃料电池氧电极制作方法 |
CN109524697A (zh) * | 2018-11-05 | 2019-03-26 | 东莞市中航华讯卫星技术有限公司 | 金属空气电池膜电极的制备方法及金属空气电池膜电极 |
CN110112511A (zh) * | 2019-04-26 | 2019-08-09 | 中科(广州)能源科技开发有限公司 | 一种电极膜及其制备方法 |
CN114703496A (zh) * | 2022-04-12 | 2022-07-05 | 中国科学院生态环境研究中心 | 空气电极及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101000954A (zh) * | 2006-12-27 | 2007-07-18 | 南开大学 | 锌负极电极材料及制备方法和应用 |
CN200953374Y (zh) * | 2006-09-25 | 2007-09-26 | 比亚迪股份有限公司 | 一种锌空气电池 |
CN101540411A (zh) * | 2009-04-15 | 2009-09-23 | 中国科学院上海硅酸盐研究所 | 固体电解质直接碳燃料电池 |
CN101683613A (zh) * | 2008-09-22 | 2010-03-31 | 北京长力联合能源技术有限公司 | 一种空气电极用催化剂及用其制作的新型空气电极及空气电极的制作方法 |
CN102544521A (zh) * | 2012-01-09 | 2012-07-04 | 中国科学院宁波材料技术与工程研究所 | 一种硫杂炭材料或硫-氮杂炭材料及其制备方法和应用 |
-
2014
- 2014-09-22 CN CN201410487878.2A patent/CN104241663B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN200953374Y (zh) * | 2006-09-25 | 2007-09-26 | 比亚迪股份有限公司 | 一种锌空气电池 |
CN101000954A (zh) * | 2006-12-27 | 2007-07-18 | 南开大学 | 锌负极电极材料及制备方法和应用 |
CN101683613A (zh) * | 2008-09-22 | 2010-03-31 | 北京长力联合能源技术有限公司 | 一种空气电极用催化剂及用其制作的新型空气电极及空气电极的制作方法 |
CN101540411A (zh) * | 2009-04-15 | 2009-09-23 | 中国科学院上海硅酸盐研究所 | 固体电解质直接碳燃料电池 |
CN102544521A (zh) * | 2012-01-09 | 2012-07-04 | 中国科学院宁波材料技术与工程研究所 | 一种硫杂炭材料或硫-氮杂炭材料及其制备方法和应用 |
Non-Patent Citations (1)
Title |
---|
李山梅等: ""锌空电池空气电极催化剂的研究进展"", 《电源技术》, vol. 35, no. 6, 20 June 2011 (2011-06-20), pages 742 - 745 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107437645A (zh) * | 2017-07-17 | 2017-12-05 | 潘科艳 | 一种多孔高性能的金属燃料电池氧电极制作方法 |
CN107437645B (zh) * | 2017-07-17 | 2020-02-14 | 潘科艳 | 一种多孔高性能的金属燃料电池氧电极制作方法 |
CN109524697A (zh) * | 2018-11-05 | 2019-03-26 | 东莞市中航华讯卫星技术有限公司 | 金属空气电池膜电极的制备方法及金属空气电池膜电极 |
CN110112511A (zh) * | 2019-04-26 | 2019-08-09 | 中科(广州)能源科技开发有限公司 | 一种电极膜及其制备方法 |
CN110112511B (zh) * | 2019-04-26 | 2020-11-03 | 中科(广州)能源科技开发有限公司 | 一种电极膜及其制备方法 |
CN114703496A (zh) * | 2022-04-12 | 2022-07-05 | 中国科学院生态环境研究中心 | 空气电极及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN104241663B (zh) | 2016-08-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102074709B (zh) | 空气电极及制造方法和具有该空气电极的金属空气电池 | |
Wei et al. | Reuse of Ni-Co-Mn oxides from spent Li-ion batteries to prepare bifunctional air electrodes | |
CN103947036B (zh) | 锌空气二次电池 | |
CN104701555B (zh) | 一种基于石墨烯的锌空气电池空气电极及其制备方法 | |
CN103326039A (zh) | 一种空气电极用催化剂、催化层喷涂剂、空气电极及制备方法 | |
CN104393310A (zh) | 一种高活性锂空气电池空气电极材料及其制备方法 | |
US20150162571A1 (en) | Concave cell design for an alkaline battery with a comb spacer | |
CN104241663A (zh) | 用于空气电池的空气电极及其制造方法、以及空气电池 | |
Manikandan et al. | Advanced perspective on the synchronized bifunctional activities of P2-type materials to implement an interconnected voltage profile for seawater batteries | |
CN103985923B (zh) | 准固态电解质pva‑锌‑空气电池 | |
JP2012182050A (ja) | 金属フリーのグラフェンを空気極に用いたリチウム−空気電池 | |
KR20160131217A (ko) | 금속 공기 전지용 양극 복합 촉매, 이의 제조 방법, 이를 포함하는 금속 공기 전지용 양극, 및 이를 포함하는 금속 공기 전지용 양극의 제조 방법 | |
CN106469821B (zh) | 一种半流态锂液流电池 | |
CN113611876A (zh) | 回收废旧锂离子电池正极材料用作电催化剂的方法 | |
CN104466122A (zh) | 一种钴铝水滑石制备镍氢二次电池镍正极的方法及其应用 | |
CN104269560A (zh) | 一种高能量锌锰电池 | |
CN100487035C (zh) | 一种制备石墨基集流体的方法 | |
CN109037595A (zh) | 锂负极保护层及其制备方法和应用 | |
CN108376789A (zh) | 一种废旧碱锰电池回收再利用于一次锌空气电池的方法 | |
US20150162601A1 (en) | Cell design for an alkaline battery with channels in electrodes to remove gas | |
CN101986449A (zh) | 干嵌式空气电极制造方法 | |
CN102306724A (zh) | 一种可充锂离子纽扣电池及其正极的制备方法 | |
CN102437313A (zh) | 一种大功率金属锂电池用负电极 | |
Oh et al. | Design and electrochemical characteristics of single-layer cathode for flexible tubular type zinc-air fuel cells | |
Yuan et al. | Hierarchical carbon-free NiCo 2 O 4 cathode for Li–O 2 batteries |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C41 | Transfer of patent application or patent right or utility model | ||
CB03 | Change of inventor or designer information |
Inventor after: Liu Weichun Inventor after: Wu Hanhong Inventor after: Zhang Yimin Inventor after: Xi Jianguo Inventor after: Huo Zhenguang Inventor after: Qi Yang Inventor before: Liu Weichun |
|
COR | Change of bibliographic data | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20160214 Address after: 100164, room 1201, unit 2, building 1, Xin Xing Temple Road, No. 31, Cheng Shou Temple Road, Beijing, Fengtai District Applicant after: Liu Weichun Address before: 100085, No. 28 information road, Beijing, 7, 7, A137, Haidian District Applicant before: BEIJING SHOUQIYI SCIENCE & TECHNOLOGY CO., LTD. |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20170516 Address after: 100085, No. 28 information road, Beijing, 7, 7, A137, Haidian District Patentee after: BEIJING SHOUQIYI SCIENCE & TECHNOLOGY CO., LTD. Address before: 100164, room 1201, unit 2, building 1, Xin Xing Temple Road, No. 31, Cheng Shou Temple Road, Beijing, Fengtai District Patentee before: Liu Weichun |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20191106 Address after: No. 12, xiannongtan East Street, Xuanwu District, Beijing 100000 Co-patentee after: Qi Yang Patentee after: Liu Weichun Address before: 100085, No. 28 information road, Beijing, 7, 7, A137, Haidian District Patentee before: BEIJING SHOUQIYI SCIENCE & TECHNOLOGY CO., LTD. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20191205 Address after: 221300 No.56, Tiefu Industrial Park, Pizhou City, Xuzhou City, Jiangsu Province Patentee after: Hongmai new energy technology Pizhou Co., Ltd Address before: No. 12, xiannongtan East Street, Xuanwu District, Beijing 100000 Co-patentee before: Qi Yang Patentee before: Liu Weichun |
|
TR01 | Transfer of patent right |