CN104232371A - Cleaning agent for moisturizing atomizing bottle - Google Patents
Cleaning agent for moisturizing atomizing bottle Download PDFInfo
- Publication number
- CN104232371A CN104232371A CN201410464572.5A CN201410464572A CN104232371A CN 104232371 A CN104232371 A CN 104232371A CN 201410464572 A CN201410464572 A CN 201410464572A CN 104232371 A CN104232371 A CN 104232371A
- Authority
- CN
- China
- Prior art keywords
- moisturizing
- cleaning agent
- acid
- methyl
- bottle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention relates to a cleaning agent for a moisturizing atomizing bottle and belongs to the technical field of cleaning articles. The cleaning agent is prepared from the following raw materials: water, 10-undecylenic acid, 2-hydroxymethyl-2-methyl-1, 3-propylene glycol, triethylene-glycol dimethacrylate, pentaerythritol tetraacetate, ethylene glycol allyl ether, 2-methyl-2-acrylic acid-1, 4-butanediol ester, ethylmalonic acid, D-cyclohexylalaninol and the like. The cleaning agent for the moisturizing atomizing bottle has a strong cleaning effect as well as an excellent infiltration property, and the cleaning agent can be used for fully infiltrating and spreading in a nozzle of the bottle body so that the bottle body is quickly cleaned without omission. Meanwhile, the material of the cleaning agent is safe and non-irritant; the impurities harmful to skin can be effectively removed out of the moisturizing atomizing bottle and moreover the cleaning agent is free from irritation to skins, thereby fully ensuring the using effect of moisturizing liquid.
Description
?
Technical field
The present invention relates to moisturizing spray bottle sanitising agent, belong to cleaning supplies technical field.
background technology
Along with expanding economy, the use range of skin lotion in women compatriot expands gradually, especially the use of moisture retention liquid, and it is while Glycerin, has good humidity-holding effect.Thus in dry environments, its rate of utilization is the highest, and in order to convenient use whenever and wherever possible, moisturizing spray bottle also becomes the part in people's moisturizing life day by day, and the degree of cleaning of its bottle of wall and shower nozzle thereof also will directly affect the result of use of moisture retention liquid.Thus, during moisture retention liquid production and sales while itself quality of guarantee, also very necessary to cleaning of moisture retention liquid container, namely moisture retention liquid spray bottle is necessary to carry out safely cleaning targetedly to it before holding moisture retention liquid.
Summary of the invention
The object of the present invention is to provide that a kind of cleaning capacity is strong, wetting property good and moisturizing spray bottle sanitising agent to no skin irritation.
Technical problem of the present invention, is achieved by following technical proposals:
Moisturizing spray bottle sanitising agent, special character is to be prepared from by the raw material of following weight: 80 parts, water, 10 hendecenoic acid 30-32 part, 2-methylol-2-methyl isophthalic acid, ammediol 20-22 part, double methyl methacrylate triethylene glycol ester 26-28 part, pentaerythrite tetra-acetate 18-20 part, ethylene glycol monoallyl ether 12-15 part, 2-methyl-2-vinylformic acid-1,4-butanediol ester 18-20 part, ethyl malonic acid 8-10 part, D-cyclohexyl Propanolamine 4-6 part.
Preparation method of the present invention: by deionized water, 10 hendecenoic acid, 2-methylol-2-methyl isophthalic acid, ammediol, double methyl methacrylate triethylene glycol ester, pentaerythrite tetra-acetate to add in reactor 1 stirring and dissolving at 40-50 DEG C, by ethylene glycol monoallyl ether, 2-methyl-2-vinylformic acid-1, 4-butanediol ester, ethyl malonic acid, D-cyclohexyl Propanolamine stirring and dissolving at 50-60 DEG C in reactor 2, mixture in reactor 2 is joined gradually in reactor 1, fully 15-25 minute is stirred in 40 DEG C of waters bath with thermostatic control, leave standstill 1.5-1.8 hour, namely required moisturizing spray bottle sanitising agent is obtained.
This moisturizing spray bottle sanitising agent, has potent cleaning effect, coordinates the wetting property that it is excellent, fully can infiltrate extension for bottle shower nozzle, realizes quick to bottle and cleans without omission.Meanwhile, its material itself is safe and non-stimulating, can not only effectively remove to skin detrimental impurity in moisturizing spray bottle, and itself also without any pungency, fully ensures the result of use of moisture retention liquid to skin.
Embodiment
Below provide the specific embodiment of the present invention, be used for being further described the present invention.In the present invention, if no special instructions, each raw material all in working substance content for 100%.
In following examples and comparative example, raw material introduction:
10 hendecenoic acid, CAS accession number is: 112-38-9;
2-methylol-2-methyl isophthalic acid, ammediol, CAS accession number is: 77-85-0;
Double methyl methacrylate triethylene glycol ester, CAS accession number is: 109-16-0;
Pentaerythrite tetra-acetate, CAS accession number is: 597-71-7;
Ethylene glycol monoallyl ether, CAS accession number is: 111-45-5;
2-methyl-2-vinylformic acid-BDO ester, CAS accession number is: 2082-81-7;
Ethyl malonic acid, CAS accession number is: 601-75-2;
D-cyclohexyl Propanolamine, CAS accession number is: 205445-49-4.
Embodiment 1
Weigh: water 80kg, 10 hendecenoic acid 32kg, 2-methylol-2-methyl isophthalic acid, ammediol 21kg, double methyl methacrylate triethylene glycol ester 26kg, pentaerythrite tetra-acetate 20kg, ethylene glycol monoallyl ether 12kg, 2-methyl-2-vinylformic acid-BDO ester 19kg, ethyl malonic acid 10kg, D-cyclohexyl Propanolamine 4kg.
The preparation method of this embodiment moisturizing spray bottle sanitising agent: by deionized water, 10 hendecenoic acid, 2-methylol-2-methyl isophthalic acid, ammediol, double methyl methacrylate triethylene glycol ester, pentaerythrite tetra-acetate to add in reactor 1 stirring and dissolving at 40-50 DEG C, by ethylene glycol monoallyl ether, 2-methyl-2-vinylformic acid-1, 4-butanediol ester, ethyl malonic acid, D-cyclohexyl Propanolamine stirring and dissolving at 50-60 DEG C in reactor 2, mixture in reactor 2 is joined gradually in reactor 1, fully 15-25 minute is stirred in 40 DEG C of waters bath with thermostatic control, leave standstill 1.5-1.8 hour, namely the moisturizing spray bottle sanitising agent of this embodiment is obtained.
Embodiment 2
Weigh: water 80kg, 10 hendecenoic acid 30kg, 2-methylol-2-methyl isophthalic acid, ammediol 20kg, double methyl methacrylate triethylene glycol ester 28kg, pentaerythrite tetra-acetate 18kg, ethylene glycol monoallyl ether 13kg, 2-methyl-2-vinylformic acid-BDO ester 18kg, ethyl malonic acid 8kg, D-cyclohexyl Propanolamine 5kg.
The preparation method of this embodiment moisturizing spray bottle sanitising agent is with embodiment 1.
Embodiment 3
Weigh: water 80kg, 10 hendecenoic acid 31kg, 2-methylol-2-methyl isophthalic acid, ammediol 22kg, double methyl methacrylate triethylene glycol ester 27kg, pentaerythrite tetra-acetate 19kg, ethylene glycol monoallyl ether 15kg, 2-methyl-2-vinylformic acid-BDO ester 20kg, ethyl malonic acid 9kg, D-cyclohexyl Propanolamine 6kg.
The preparation method of this embodiment moisturizing spray bottle sanitising agent is with embodiment 1.
Comparative example 1
Weigh: water 80kg, 10 hendecenoic acid 32kg, 2-methylol-2-methyl isophthalic acid, ammediol 21kg, double methyl methacrylate triethylene glycol ester 26kg, pentaerythrite tetra-acetate 20kg, 2-methyl-2-vinylformic acid-BDO ester 19kg, ethyl malonic acid 10kg.
The preparation method of this comparative example moisturizing spray bottle sanitising agent: by deionized water, 10 hendecenoic acid, 2-methylol-2-methyl isophthalic acid, ammediol, double methyl methacrylate triethylene glycol ester, pentaerythrite tetra-acetate to add in reactor 1 stirring and dissolving at 40-50 DEG C, by 2-methyl-2-vinylformic acid-1, 4-butanediol ester, ethyl malonic acid stirring and dissolving at 50-60 DEG C in reactor 2, mixture in reactor 2 is joined gradually in reactor 1, fully 15-25 minute is stirred in 40 DEG C of waters bath with thermostatic control, leave standstill 1.5-1.8 hour, namely the moisturizing spray bottle sanitising agent of this comparative example is obtained.
Comparative example 2
Weigh: water 80kg, 10 hendecenoic acid 32kg, double methyl methacrylate triethylene glycol ester 26kg, pentaerythrite tetra-acetate 20kg, ethylene glycol monoallyl ether 12kg, ethyl malonic acid 10kg, D-cyclohexyl Propanolamine 4kg.
The preparation method of this comparative example moisturizing spray bottle sanitising agent: deionized water, 10 hendecenoic acid, double methyl methacrylate triethylene glycol ester, pentaerythrite tetra-acetate to be added in reactor 1 stirring and dissolving at 40-50 DEG C, by ethylene glycol monoallyl ether, ethyl malonic acid, D-cyclohexyl Propanolamine stirring and dissolving at 50-60 DEG C in reactor 2, mixture in reactor 2 is joined gradually in reactor 1, fully 15-25 minute is stirred in 40 DEG C of waters bath with thermostatic control, leave standstill 1.5-1.8 hour, namely obtain the moisturizing spray bottle sanitising agent of this comparative example.
(1), wetting property test is carried out with embodiment 1-3 and comparative example 1-2 gained finished product
With Common detergents as a control group
Getting six pieces of diameters is that the circular glass fiber of 5cm is placed on platform respectively, above-mentioned six kinds of samples of isodose are measured respectively with liquid meter, per sample (p.s.) drips in a glass fibre surrounding simultaneously respectively, there is the blank annulus being spaced apart 3cm between sample and glass fibre.The moment that sample drips to platform starts timing, starts sized glass fibres stop timing to sample.
Sample sized glass fibres required time is as shown in the table:
| ? | Time, s |
| Embodiment 1 | 1.5 |
| Embodiment 2 | 1.4 |
| Embodiment 3 | 1.5 |
| Comparative example 1 | 1.9 |
| Comparative example 2 | 2.5 |
| Control group | 2.3 |
(2), detergency test is carried out with embodiment 1-3 and comparative example 1-2 gained finished product
1) preparation of artificial dirt
Mixing oil is filled a prescription: configure for 0.5:1:0.5:1 with butter, lard, vegetables oil, polymeric impurities mass ratio, and add the glyceryl monostearate of its total mass 5%, this is artificial dirt.
Artificial dirt is put on electric furnace and be heated to 300 DEG C, stir and keep this temperature 15min, beaker is moved to magnetic stirrer, naturally cools to temperature required for subsequent use.To defile temperature reference: when room temperature is 20 DEG C, need oil temperature 80 DEG C; When room temperature is 25 DEG C, need oil temperature 45 DEG C; When room temperature is lower than 17 DEG C or higher than 27 DEG C, test should not be carried out, and needs to carry out under the environment of proper temperature.The Terg-O-Tometer of attached freezing plant should be used if desired.
2) defile
The moisturizing spray bottle of cleaning is one group with five put on weighing frame, is accurately weighed as W0 with balance, the moisturizing spray bottle after weighing is placed on rack one by one.
When greasy dirt remains in stable temperature, one by one moisturizing spray bottle is got on to take off from rack, all immerse in greasy dirt and keep 2-3s, slowly take out, after lower of greasy dirt slows, put back to original rack, prepare dirty moisturizing spray bottle successively.After the greasy dirt of moisturizing spray bottle inside and outside wall solidifies, moisturizing spray bottle is taken off and with filter paper or absorbent cotton, corner or the unnecessary greasy dirt of side is wiped.After left at room temperature 4h, weighing frame is W1 with balance accurate weighing.
3) testing sequence
The moisturizing spray bottle of known greasy dirt amount is inserted in corresponding wash stand and prepare washing.
Switched on power by spotter, wash temperature is set to 32 DEG C, and velocity of rotation is set to 150r/min, and washing time is set to 5min.
Take 5.0g sample to be tested in 2500ml hard water, after shaking up, measure 800ml test solution respectively in five washing becks of Terg-O-Tometer, when test solution temperature rises to 32 DEG C, rapidly the moisturizing spray bottle of known weight is put into washing beck accordingly together with wash stand, start to count soak time after last moisturizing spray bottle puts into washing beck, simultaneously rapid agitator to be installed, when soaking 1min, start spotter, start washing, during 5min, machine auto stop, rapidly agitator is taken off, take out wash stand, rear moisturizing spray bottle will be washed be placed in one by one on rack, after leaving standstill 3h, moisturizing spray bottle is placed on corresponding weighing frame and weighs as W2.
Test result is as shown in the table:
Soil removal efficiency=[(W1-W2)/(W1-W0)] * 100%
| ? | Soil removal efficiency, % |
| Embodiment 1 | 97.8 |
| Embodiment 2 | 97.2 |
| Embodiment 3 | 96.9 |
| Comparative example 1 | 73.4 |
| Comparative example 2 | 52.7 |
(3), pungency test is carried out with embodiment 1-3 and comparative example 1-2 gained finished product
Simulation irritant experiment carries out in laboratory, and experimenter (each 5 people of men and women) is clean in the aqueous detergent solution of 1wt%, and water temperature 23-27 DEG C, water used is deionized water, washs 2 every day, each 3 hours, continuous 1 week.Average after marking according to the standard of following table for the pungency of wrist-watch skin, mark higher, pungency is less again.
| Judge project | Completely unchanged | Flat epidermis has wrinkle | Micro-erythema | Obvious erythema | Edema | Crowfoot cracks |
| Scoring | 100 | 80 | 60 | 40 | 20 | 0 |
Pungency test data table
| ? | Scoring |
| Embodiment 1 | 100 |
| Embodiment 2 | 100 |
| Embodiment 3 | 100 |
| Comparative example 1 | 60 |
| Comparative example 2 | 40 |
Claims (1)
1. moisturizing spray bottle sanitising agent, it is characterized in that being prepared from by the raw material of following weight: 80 parts, water, 10 hendecenoic acid 30-32 part, 2-methylol-2-methyl isophthalic acid, ammediol 20-22 part, double methyl methacrylate triethylene glycol ester 26-28 part, pentaerythrite tetra-acetate 18-20 part, ethylene glycol monoallyl ether 12-15 part, 2-methyl-2-vinylformic acid-1,4-butanediol ester 18-20 part, ethyl malonic acid 8-10 part, D-cyclohexyl Propanolamine 4-6 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410464572.5A CN104232371A (en) | 2014-09-13 | 2014-09-13 | Cleaning agent for moisturizing atomizing bottle |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410464572.5A CN104232371A (en) | 2014-09-13 | 2014-09-13 | Cleaning agent for moisturizing atomizing bottle |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104232371A true CN104232371A (en) | 2014-12-24 |
Family
ID=52221282
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410464572.5A Pending CN104232371A (en) | 2014-09-13 | 2014-09-13 | Cleaning agent for moisturizing atomizing bottle |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104232371A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1034388A (en) * | 1988-12-26 | 1989-08-02 | 苏州肥皂厂 | Germicidal soap |
| CN102482616A (en) * | 2009-10-30 | 2012-05-30 | 东友Fine-Chem股份有限公司 | Cleaner composition for glass substrate of flat panel display device |
| WO2012078950A1 (en) * | 2010-12-09 | 2012-06-14 | Isp Investments Inc. | A visually perceivable image-forming dye scavenging article |
-
2014
- 2014-09-13 CN CN201410464572.5A patent/CN104232371A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1034388A (en) * | 1988-12-26 | 1989-08-02 | 苏州肥皂厂 | Germicidal soap |
| CN102482616A (en) * | 2009-10-30 | 2012-05-30 | 东友Fine-Chem股份有限公司 | Cleaner composition for glass substrate of flat panel display device |
| WO2012078950A1 (en) * | 2010-12-09 | 2012-06-14 | Isp Investments Inc. | A visually perceivable image-forming dye scavenging article |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105062712B (en) | A kind of foam type fruits and vegetables dish washing detergent compositions | |
| JP2021119230A (en) | Cleaning product | |
| CN105296177B (en) | A kind of multifunctional meter surface cleaning agent and preparation method thereof | |
| JP6810141B2 (en) | Cleaning products | |
| US10736832B2 (en) | Aqueous surfactant compositions | |
| JP6813578B2 (en) | Cleaning products | |
| TWI695884B (en) | Liquid detergent | |
| RU2632874C2 (en) | Liquid detergent composition for clothes | |
| CN103242976B (en) | Soapberry vegetable-fruit washing-up liquid | |
| CN103834481A (en) | Compound medical equipment multi-enzyme cleaning agent | |
| CN106318689B (en) | A kind of automobile washing liquid and preparation method thereof | |
| JP2020519746A (en) | Cleaning products | |
| AU2006214237B2 (en) | Cleaning compositions that provide grease removal and fragrance delivery | |
| US8008246B2 (en) | Use of isosorbide ethers in detergents and cleaners | |
| CN103255005B (en) | Rosemary sterilization-deodorization detergent | |
| CN104232371A (en) | Cleaning agent for moisturizing atomizing bottle | |
| US20100324153A1 (en) | Anionic isosorbide derivatives and their use | |
| CN103255004B (en) | Disinfecting and deodorizing liquid detergent of bamboo vinegar | |
| JP2017078098A (en) | Liquid detergent for tableware | |
| JP6259217B2 (en) | Liquid detergent composition for clothing | |
| CN103205326B (en) | Dandelion skin-care detergent liquid for tableware | |
| CN109837142A (en) | Solid detergent without ethoxy compound | |
| CN103205320B (en) | Licorice sterilizing detergent liquid for tableware | |
| CN104313629A (en) | Gold ornament cleaning fluid | |
| CN103266027B (en) | Allantoin skin-care washing-up liquid |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20141224 |