CN104231820B - A kind of imitative brick true mineral varnish dedicated elas-tic black alkali-resistant primer and preparation method thereof - Google Patents
A kind of imitative brick true mineral varnish dedicated elas-tic black alkali-resistant primer and preparation method thereof Download PDFInfo
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Abstract
The invention provides a kind of imitative brick true mineral varnish dedicated elas-tic black alkali-resistant primer and preparation method thereof, this imitative brick true mineral varnish dedicated elas-tic black alkali-resistant primer is composed of the following components in parts by weight: self-produced nano-composite emulsion 100～600 parts, defoamer 1～5 parts, preservative 1～5 parts, dispersant 1～10 parts, pigment 0～100 parts, nano silicasol latex solution 0～150 parts, thickening agent 1～10 parts, levelling agent 1～10 parts, black slurry 0～50 parts, fluorine surfactant 1～10 parts, water 0～350 parts.Alkali-resistant primer of the present invention is to aim at the true mineral varnish of imitative brick to arrange, and has good springiness, and ability at the bottom of lid is good, water-fast impervious, alkali resistant resistance to salting-out.And there is splendid adhesive force and tissue adhesion effect, will not be torn up by U.S. stricture of vagina paper.
Description
Technical field
The present invention relates to functional environment-friendly paint field, particularly relate to a kind of imitative brick true mineral varnish dedicated elas-tic black alkali resistant
Priming paint and preparation method thereof.
Background technology
Along with development and the affluence of people's life of society, increasing skyscraper is rised sheer from level ground, how to these
The exterior wall in the building of skyscraping carries out protecting box decoration and the most increasingly causes the attention of people.Outside the most common external wall decorative material has
Wall flat paint, ceramic tile, granite and marble, glass curtain wall etc..Ceramic tile is asked owing to its energy consumption is big, consume land resource etc.
Topic, already by generation, This is what people generally disapprove of, and a lot of areas promulgate that specification proposes to limit, and even eliminate this finishing material.
The stone material such as granite, marble, exploitation had both destroyed ecology, and even more serious is exactly that TERRAZZO exists in various degree
Aberration and reflexive pollute two large problems.
The intense light of its reflection of glass curtain wall have impact on the orthobiosis of people to a certain extent;It maps around
Environment causes change image, causes visual fatigue, obstacle to pedestrian, driver, easily causes health problem and contingency
Occurring, these phenomenons are referred to as ' light pollution '.In recent years, the most to curtain buildings (particularly glass curtain wall) ' light
Pollute ' paid attention to, some country has put into effect and has limited regulation or the proposal that glass curtain wall uses.And the rigidity exterior wall dresses such as ceramic tile
Another potential safety hazard that exterior material there is also: structural weight per square meter.Building is from great, and in earthquake, potential safety hazard is bigger, should
To significantly alleviate structural weight per square meter with exterior coating, destructive power of the earthquake is the least, so the antidetonation energy of building can be greatly improved
Power, and in the north along with the rigidity external wall decorative material such as universal ceramic tile of insulation material is because from great, with insulation material
Adhesion strength is low, and its event of hurting sb.'s feelings that comes off happens occasionally.Although exterior wall flat paint has the advantages such as Environmental Safety, but decorates
Effect is dull, it is impossible to embody building individual demand.The safety and environmental protection that the imitative true mineral varnish of brick had both maintained exterior wall flat paint is excellent
Gesture has and solves the defect that exterior wall flat paint decorative effect is single.The most imitative true mineral varnish of brick the most slowly starts to make
With, being in use frequently encountered by a problem is exactly the bad process of separation lines, and conventional way is carried out after imitative brick effect again
With pitch-dark separator bar of retouching, such workload is big, and to be easily caused separator bar be not the most smooth.Additionally there is employing at seal coat
In add black color paste, then tear up with U.S. stricture of vagina paper patch separator bar, but this way cannot solve U.S.'s stricture of vagina paper when tearing up always
Priming paint part adhesive tape is got up, affects the attractive in appearance of separation lines, and affect the saline and alkaline harm to finish paint of basic unit.
Summary of the invention
It is an object of the invention to provide a kind of imitative brick true mineral varnish dedicated elas-tic black alkali-resistant primer and preparation method thereof, with gram
Take the defect that prior art exists.The present invention designs a kind of imitative brick true mineral varnish dedicated elas-tic black alkali-resistant primer, by following weight
The one-tenth of part is grouped into: nano-composite emulsion 100～600 parts, defoamer 1～5 parts, preservative 1～5 parts, dispersant 1～10 parts,
Pigment 0～100 parts, nano silicasol latex solution 0～150 parts, thickening agent 1～10 parts, levelling agent 1～10 parts, black slurry 0～50
Part, fluorine surfactant 1～10 parts, water 0～350 parts.It is composed of the following components in parts by weight: nano-composite emulsion 300～600
Part, defoamer 2～4 parts, preservative 1～3 parts, dispersant 2～6 parts, pigment 20～80 parts, nano silicasol latex solution 30～100
Part, thickening agent 1～10 parts, levelling agent 1～10 parts, black slurry 0～50 parts, fluorine surfactant 1～10 parts, water 0～350 parts.
Described nano-composite emulsion is pure acrylate emulsion, and its particle diameter is 50-150nm.Described defoamer selected from nano polysilicon oxygen alkane-
In copolyether type of latex type, polypropylene glycols, Polyethylene Glycol-hydrophobic solid-polysiloxane mixture class or mineral oil base class
Two kinds.Described dispersant is selected from ammonium polyacrylate salt, modified polypropene acid solution class or modified polycarboxylic acid salt.Described face
Material is Rutile type titanium dioxide；Described black slurry is white carbon black or iron black mill base.Described levelling agent is selected from cross-linking organosilicon polyethers
Acrylic acid esters co-polymer, dimethyl polysiloxane emulsion or polysiloxane-polyether copolymer class.Described fluorine surfactant is
The water base fluorocarbon surfactant of nonionic containing 50% effective ingredient.Described nano silicasol latex solution is that nano silicon is molten
Liquid, its particle diameter is 5-100nm., a kind of method preparing imitative brick true mineral varnish dedicated elas-tic black alkali-resistant primer, it is characterised in that
Comprise the steps:
1) water, preservative, dispersant, fluorine surfactant and defoamer are mixed, stir；
2) add pigment, improve dispersion viscosity with thickening agent, high speed dispersion to less than 30 microns under vacuum state；
3) add nano-composite emulsion, nano silicasol latex solution, levelling agent, black slurry, stir, to obtain final product.The present invention
Advantage be: use priming paint special-purpose nanometer elasticity pure acrylate emulsion, its particle diameter is 30-150nm, can penetrate into base material
In, improving adhesive force, addition nano silicasol latex solution due to nano silicasol latex solution, has good permeability, after film forming easily
Form water-fast transparent lamina, there is infiltration, the comprehensive effect of hardening bonding, be easily generated mechanical snap with stromal surface
With chemical bonding, substantially increase the permeability resistance of priming paint, prevent the ground saline and alkaline precipitation injury to finish paint.Nonionic is water base
The addition of fluorocarbon surfactant greatly reduces coating surface tension force, reduces U.S. stricture of vagina paper adhesive force on pitch-dark, is spraying
The paint film of priming paint will not be torn up when tearing up U.S. stricture of vagina paper after true mineral varnish.And the present invention uses priming paint special-purpose nanometer elasticity pure acrylic acid
Ester emulsion good percentage elongation, the priming paint crack resistance made is good, it is possible to cover the blind crack that base material occurs, reduces the anti-of finish paint appearance
Split risk.
Detailed description of the invention
Following example are used for the present invention is described, should not be taken to limit the scope of the present invention.
Buying situation to various raw materials illustrates that the raw material of the present invention has availability below, and can not be to this
Bright composition limits: wherein said nano-composite emulsion as the self-produced commercially available fine grain nano-composite emulsion of our company, its
Consist of binary polymerization nano fluorine-silicon polymer E perfluoro caprylic acid (DMF)+methyl methacrylate (MMA)+mano-porous material
(nano-TiO2), hydrogen containing siloxane (PHMS)+polyacrylic acid P (BA/A)+mano-porous material (SiO2), vinyl acetate
(Vac)+mano-porous material (nano-ZnO), solids content is 48.5 ± 1%, and vitrification point is-1 DEG C, and minimum film formation temperature is
0 DEG C, pH is 7 ~ 9, and proportion is 1.05g/ml, and particle diameter is 50-150nm, it would however also be possible to employ the nanoscale primer emulsion of DOW Chemical
R-64.Described defoamer is selected from polysiloxane-polyether copolymer type of latex type, polypropylene glycols, Polyethylene Glycol-hydrophobic solid-poly-
In mixture of siloxanes class or mineral oil base class two kinds, can use the A10(nano polysilicon oxygen alkane-polyethers of Kening Co., Ltd of the U.S.
Copolymer emulsion class), the SN-154(polypropylene glycols of Kening Co., Ltd), use Germany Bi Ke chemistry (Asia-Pacific) private limited partnership
BYK024(Polyethylene Glycol-hydrophobic solid-polysiloxane mixture the class produced), use Shenzhen Hai Chuan Chemical Co., Ltd. raw
The Foamster309A(mineral oil base class produced).Described preservative is selected from 2-(4-thiazolyl) benzimidazole, isopropyl methyl be different
Thiazolinone or organic bromine synthetic, such as the Nipacide GSF(organic bromine synthetic of Clariant Corporation), this product is the widest
Spectrum, without formaldehyde, meets the requirement of EN71.Described dispersant selected from sodium polyacrylate salt, modified polypropene acid solution class or
Modified polycarboxylic acid salt.Commercially available prod can be used, the Hydropalat 640A produced such as Hai Chuan Chemical Co., Ltd. of Shenzhen
(sodium polyacrylate salt), can use Germany Di Gao Chemical Co., Ltd. produce TEGO Dispers750W(modified polypropene
Acid solution class), can use Germany BASF Chemical Co., Ltd. produce Sokalan PA30CL(modified polycarboxylic acid salt).Institute
Stating pigment is Rutile type titanium dioxide；Described filler is selected from calcined kaolin, ground calcium carbonate, kieselguhr, Pulvis Talci, silicon ash
The mica powder of the two or more in stone, mica powder or blanc fixe, preferably acicular wollastonite and lamellar.Described thickening agent is
Nano fumed silica class or hydroxyethyl cellulose.The nano-gas-phase two that such as Shenzhen nano development in science and technology company limited produces
Silica powder, the nano fumed silica powder body of Zhejiang Province Yuda Chemical Co., Ltd, it would however also be possible to employ the sub-hydroxyl second across dragon
Base cellulose 250MBR.Described levelling agent is selected from cross-linking organosilicon polyoxyalkylene acrylate lipin polymer, dimethyl polysiloxane
Emulsion or polysiloxane-polyether copolymer class.The levelling agent RM-2020(polysiloxane-polyether copolymer of such as ROHM AND HAAS
Type) versatility is good, without APEO, without organic solvent.Described nano silicasol latex solution is nano silica microsphere, its particle diameter
For 5-100nm, there is good penetrability, the comprehensive effect of hardening bonding, and be easily generated mechanical snap and chemical bond with stromal surface
Closing, have fabulous impermeabilisation, alkali resistant separates out effect, without APEO, without formaldehyde.Such as Qingdao City's base hundred million reaches silica gel chemical reagent work
JYD-01.Described fluorine surfactant is the water base fluorocarbon surfactant of the nonionic containing 50% effective ingredient, such as Du Pont
The FS610 of chemical industry.Described black slurry is white carbon black or iron black mill base, such as Germany's Clariant black B 3G or section's enlightening color
Iron black BK9011, in order to more preferable alkaline resistance properties preferentially selects iron black mill base BK9011.It is special that one of the present invention imitates the true mineral varnish of brick
The method of elastic black alkali-resistant primer, comprises the steps: 1) by water, preservative, dispersant, fluorine surfactant and defoamer
Mixing, stirs；2) add pigment, improve dispersion viscosity with thickening agent, high speed dispersion to less than 30 microns under vacuum state；
3) add nano-composite emulsion, nano silicasol latex solution, levelling agent, black slurry, stir, to obtain final product.The present invention imitates the true stone of brick
Paint dedicated elas-tic black alkali-resistant primer is applicable to brush, roller coating and spraying, during coating decoration, can add appropriate as the case may be
Water regulation viscosity.
Embodiment 1
1, component: self-produced nano-composite emulsion 550g, section peaceful defoamer A-10 1.5g, Clariant Liquid BPF ipacide
GSF 1.5g, enlightening high score powder TEGO Dispers750W 5g, pigment Du Pont Rutile type titanium dioxide R-706 50g, mica powder
50g, thickening agent nano nano fumed silica powder body 8g, ROHM AND HAAS levelling agent RM-2020 8g, nano silicasol latex solution
JYD-01150g, fluorine surfactant 8g, iron black mill base BK9011 50g, water 118g.
2, preparation method 1) by water, Clariant Liquid BPF ipacide GSF, enlightening high score powder TEGO Dispers750W,
Section peaceful defoamer A-10, stirs；2) add titanium dioxide R-706, mica powder, improve dispersion viscosity, vacuum shape with thickening agent
High speed dispersion to less than 30 microns under state；3) nano-composite emulsion, nano silicasol latex solution JYD-01, levelling agent RM-are added
2020, iron black mill base BK9011, stirs, to obtain final product.
Embodiment 2
1, component: self-produced nano-composite emulsion 530g, section peaceful defoamer A-10 1.5g, Clariant Liquid BPF ipacide
GSF 1.5g, enlightening high score powder TEGO Dispers750W 5g, pigment Du Pont Rutile type titanium dioxide R-706 40g, mica powder
60g, nano nano fumed silica powder body 7g, ROHM AND HAAS levelling agent RM-2020 8g, nano silicasol latex solution JYD-
01120g, fluorine surfactant 6g, iron black mill base BK9011 45g, water 148g.
2, preparation method 1) by water, Clariant Liquid BPF ipacide GSF, enlightening high score powder TEGO Dispers750W,
Section peaceful defoamer A-10, stirs；2) add titanium dioxide R-706, mica powder, improve dispersion viscosity, vacuum shape with thickening agent
High speed dispersion to less than 30 microns under state；3) nano-composite emulsion, nano silicasol latex solution JYD-01, levelling agent RM-are added
2020, iron black mill base BK9011, stirs, to obtain final product.
Embodiment 3
1, component: self-produced nano-composite emulsion 500g, section peaceful defoamer SN-154 1g, Clariant Liquid BPF ipacide
GSF 1.5g, enlightening high score powder TEGO Dispers750W 3.5g, pigment Du Pont Rutile type titanium dioxide R-706 70g, Muscovitum
Powder 30g, nano nano fumed silica powder body 8g, ROHM AND HAAS levelling agent RM-2020 5g, nano silicasol latex solution JYD-
01 100g, fluorine surfactant 5g, iron black mill base BK9011 40g, water 168g.
2, preparation method 1) by water, Clariant Liquid BPF ipacide GSF, enlightening high score powder TEGO Dispers750W,
Section peaceful defoamer SN-154 mixes, and stirs；2) add titanium dioxide R-706, mica powder, improve dispersion viscosity with thickening agent,
High speed dispersion to less than 30 microns under vacuum state；3) nano-composite emulsion, nano silicasol latex solution JYD-01, levelling agent are added
RM-2020, iron black mill base BK9011, stir, to obtain final product.
Embodiment 4
1, component: self-produced nano-composite emulsion 450g, section peaceful defoamer A-10 1.5g, Clariant Liquid BPF ipacide
GSF 1.5g, enlightening high score powder TEGO Dispers750W 4g, pigment Du Pont Rutile type titanium dioxide R-706 100g, silicon ash
Stone powder 20g, nano nano fumed silica powder body 8g, ROHM AND HAAS levelling agent RM-2020 8g, nano silicasol latex solution
JYD-01 80g, fluorine surfactant 4g, carbon black color paste B3G 30g, water 293g.
2, preparation method 1) by water, Clariant Liquid BPF ipacide GSF, enlightening high score powder TEGO Dispers750W,
Section peaceful defoamer A-10 mixes, and stirs；2) add titanium dioxide R-706, wollastonite in powder, improve dispersion viscosity with thickening agent,
High speed dispersion to less than 30 microns under vacuum state；3) nano-composite emulsion, nano silicasol latex solution JYD-01, levelling agent are added
RM-2020, carbon black color paste B3G, stir, to obtain final product.
The prevailing quality technical specification of the imitative brick true mineral varnish dedicated elas-tic black alkali-resistant sealing primer of embodiment 1 gained is as follows
Table (table 1):
Table 1
Embodiment 2 prepares the prevailing quality technical specification such as following table of imitative brick true mineral varnish dedicated elas-tic black alkali-resistant sealing primer
(table 2):
The prevailing quality technical specification of the imitative brick true mineral varnish dedicated elas-tic black alkali-resistant sealing primer of embodiment 3 gained is as follows
Table (table 3):
Table 3:
The prevailing quality technical specification of the imitative brick true mineral varnish dedicated elas-tic black alkali-resistant sealing primer of embodiment 4 gained is as follows
Table (table 4):
Although, used general explanation, detailed description of the invention and test, the present invention made detailed retouching
Stating, but on the basis of the present invention, can make some modifications or improvements it, this is apparent to those skilled in the art
's.Therefore, these modifications or improvements without departing from theon the basis of the spirit of the present invention, belong to claimed
Scope.
There is presently no and imitate, with the present invention, the related fields patent that brick true mineral varnish dedicated elas-tic black alkali-resistant primer is close, with
Patent of invention 201010530481 " a kind of alkali-resistant sealing primer for outer wall and using method thereof " and patent of invention 201010534536-
" alkali-resistant sealing primer for outer wall " is compared, and this patent uses elastic nanoemulsion to coordinate nano silicasol latex solution, has and preferably oozes
Property, more preferably prevents the ground saline and alkaline precipitation injury to finish paint, and adhesive force is more preferable thoroughly.Add the water base fluorocarbon surface of nonionic
The addition of activating agent greatly reduces coating surface tension force, reduces U.S. stricture of vagina paper adhesive force on pitch-dark, solves common very well
Exterior wall base paint sticks up the defect of paint film when tearing up the U.S. stricture of vagina paper of protection after being made in the good true mineral varnish cut-off rule of spray.
Claims (1)
1. an imitative brick true mineral varnish dedicated elas-tic black alkali-resistant primer, is composed of the following components in parts by weight: nano-composite emulsion
300～600 parts, defoamer 2～4 parts, preservative 1～3 parts, dispersant 2～6 parts, pigment 20～80 parts, nano silicasol latex solution
30～100 parts, thickening agent 1～10 parts, levelling agent 1～10 parts, black slurry 0～50 parts, fluorine surfactant 1～10 parts, water 0～
350 parts；
Described nano-composite emulsion is pure acrylate emulsion, and its particle diameter is 50-150nm；
Described defoamer selected from nano polysilicon oxygen alkane-copolyether type of latex type, polypropylene glycols, Polyethylene Glycol-hydrophobic solid-
In polysiloxane mixture class or mineral oil base class two kinds；
Described dispersant is selected from ammonium polyacrylate salt, modified polypropene acid solution class or modified polycarboxylic acid salt；Described pigment
For Rutile type titanium dioxide；Described black slurry is white carbon black or iron black mill base；
Described levelling agent is selected from cross-linking organosilicon polyoxyalkylene acrylate lipin polymer, dimethyl polysiloxane emulsion or poly-silica
Alkane-copolyether class；
Described fluorine surfactant is the water base fluorocarbon surfactant of the nonionic containing 50% effective ingredient；
Described nano silicasol latex solution is nanosilica solution, and its particle diameter is 5-100nm.
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| CN105086714A (en) * | 2015-09-09 | 2015-11-25 | 山东秦恒科技有限公司 | Coloring modified alkali-resistant seal primer and preparation method thereof |
| CN105672600A (en) * | 2016-01-22 | 2016-06-15 | 凌旭姣 | Rock crystal heat-insulating integrated board |
| CN105713471A (en) * | 2016-03-16 | 2016-06-29 | 陈威 | Waterborne inorganic building closed alkali-resistant primer formula and preparation technology |
| CN106675296A (en) * | 2016-07-14 | 2017-05-17 | 深圳市长辉新材料科技有限公司 | Water-based coating composition |
| CN106675266A (en) * | 2016-12-28 | 2017-05-17 | 芜湖普乐士新型建筑材料配套有限公司 | Waterborne colored steel paint |
| CN107312400A (en) * | 2017-06-21 | 2017-11-03 | 河北晨阳工贸集团有限公司 | It is pitch-dark and preparation method thereof that exterior wall imitates brickwork skill special jointing |
| CN108102501A (en) * | 2017-11-09 | 2018-06-01 | 河北晨阳工贸集团有限公司 | A kind of soft and graceful soft rock finished product patch Special plaster color bottom paint and preparation method thereof |
| CN108314968A (en) * | 2018-02-26 | 2018-07-24 | 东丰县广宁建材科技有限公司 | A kind of water paint and preparation method thereof containing nano inorganic silica |
| CN110606701B (en) * | 2019-09-23 | 2021-07-30 | 浙江志强涂料有限公司 | Limestone-like coating and preparation method thereof |
| CN111944343A (en) * | 2020-08-21 | 2020-11-17 | 河北品致涂料有限公司 | Black primer and preparation method thereof |
| CN114456656B (en) * | 2022-01-17 | 2022-08-19 | 嘉宝莉化工集团股份有限公司 | Bio-based black primer for tearing and tracing line of anti-wrinkle paper and preparation method thereof |
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Free format text: CORRECT: APPLICANT; FROM: ZHANCHEN COATINGS GROUP CO., LTD. BEIJING ZHANCHEN CHEMICAL INDUSTRY CO., LTD. QINGDAO VISION CHEMICAL CO., LTD. CHENGDU ZHANCHEN CHEMICAL CO., LTD. TO: ZHANCHEN COATINGS GROUP CO., LTD. BEIJING ZHANCHEN CHEMICAL INDUSTRY CO., LTD. QINGDAO ZHANCHEN NEW MATERIAL CO., LTD. CHENGDU ZHANCHEN CHEMICAL CO., LTD. Free format text: CORRECT: APPLICANT; FROM: SHANGHAI FUCHEN CHEMICAL CO. LTD. TO: SHANGHAI ZHANCHEN PAINT CO., LTD. |
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Address after: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue Applicant after: Shanghai Zhanchen Paint Co., Ltd. Applicant after: CHINA ZHANCHEN PAINTS GROUP LTD. Applicant after: Beijing Zhan Chen novel material company limited Applicant after: Qingdao Zhan Chen novel material company limited Applicant after: Chengdu Zhan Chen coating company limited Address before: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue Applicant before: Shanghai Zhanchen Paint Co., Ltd. Applicant before: Zhanchen Coatings Group Co., Ltd. Applicant before: Beijing Zhanchen Chemical Industry Co., Ltd. Applicant before: Qingdao Zhan Chen novel material company limited Applicant before: Chengdu Zhanchen Chemical Co., Ltd. |
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| COR | Change of bibliographic data | ||
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Effective date of registration: 20200513 Address after: 201799 8555 Songze Avenue, Qingpu District, Shanghai Co-patentee after: Zhuhai zhanchen New Material Co., Ltd Patentee after: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Co-patentee after: QINGDAO ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee after: CHENGDU ZHANCHEN PAINTS Co.,Ltd. Address before: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue Co-patentee before: ZHANCHEN NEW MATERIAL GROUP Co.,Ltd. Patentee before: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Co-patentee before: BEIJING ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee before: QINGDAO ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee before: CHENGDU ZHANCHEN PAINTS Co.,Ltd. |