CN104230264B - A kind of cement group water-proofing material and preparation method thereof - Google Patents

A kind of cement group water-proofing material and preparation method thereof Download PDF

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CN104230264B
CN104230264B CN201410442850.7A CN201410442850A CN104230264B CN 104230264 B CN104230264 B CN 104230264B CN 201410442850 A CN201410442850 A CN 201410442850A CN 104230264 B CN104230264 B CN 104230264B
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CN104230264A (en
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林德
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DEQING YANGTAI BUILDING MATERIAL Co Ltd
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DEQING YANGTAI BUILDING MATERIAL Co Ltd
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Abstract

A kind of cement group water-proofing material, is mainly used in lightweight sand and adds building block, it is also possible to plaster use in basal planes such as concrete hollow block, fly ash building block, plasterboard and cast-in-place concretes.This material and basal plane adhere well to power, and construction thickness is very thin, and material is economical and practical, material can be saved, even if the basic unit after this material processes is in for a long time in the environment that humidity is very big and flakes without hollowing simultaneously, it is ensured that job site is cleaned, and more meets environmental requirement.

Description

A kind of cement group water-proofing material and preparation method thereof
Technical field
The invention belongs to building material field, be specifically related to a kind of cement group water-proofing material and preparation method thereof.
Background technology
Along with the fast development of building industry, plastering engineering, as a part important in construction, is increasingly paid attention to by this industry.Plaster and can protect body of wall and improve indoor sanitation condition, strengthen light line reflection, beautify the environment, also can protect the erosion of the position not wind-engagings such as wall body, ceiling, roofing, rain, snow, improve metope protection against the tide, efflorescence prevention, heat insulation ability, strengthen the durability of wall body.But the plastering material of traditional handicraft such as cement mortar, mixed mortar etc., it is impossible to the surface adapting to the novel wall material such as building block, sheet material is whitewashed, it may appear that hollowing, ftracture, the phenomenon such as come off, and affects construction quality.Domestic this type of plastering material is done big quantity research, as Chinese invention patent CN1483092A discloses a kind of gypsum substrate render material, this plastering material is with Gypsum Fibrosum for primary raw material, add the additives such as anhydrous citric acid adjustable solidification agent, solve cement mortar preferably, the hollowing that mixed mortar is plastered, cracking, the common fault such as come off, Chinese invention patent CN10303250A discloses a kind of aerated blocks wall plastering agent, this plastering material is with portland cement for primary raw material, add modifying agent, antimitotic agent, the additives such as water-retaining agent also can effectively solve cement mortar, the hollowing that mixed mortar is plastered, cracking, the common fault such as come off.But the painting of this plastering material is scraped thickness and remained a need for 5-8mm, operating expenses is still higher.In the environment that humidity is bigger, still can there is hollowing, ftracture, the phenomenon such as come off in product in the market, therefore market demand has a kind of cement group water-proofing material, replaces existing technique, to reduce cost, improves work efficiency.
Summary of the invention
It is an object of the invention to provide a kind of cement group water-proofing material.This material is a kind of cement group water-proofing material after modified, is mainly used in lightweight sand and adds building block, it is also possible to plaster use in basal planes such as concrete hollow block, fly ash building block, plasterboard and cast-in-place concretes.
The invention provides a kind of cement group water-proofing material, be made up of the component of following percentage by weight:
Preferably, described portland cement is 32.5R or 42.5R cement;
Preferably, described quartz sand is 30 order-80 order sand;
Preferably, described bentonite is organobentonite;
Preferably, described redispersable latex powder is the rubber powder that polyvinyl acetate generates through copolyreaction with polyvinyl alcohol;
Preferably, described cellulose ether is methyl hydroxyethylcellulose ether or methylhydroxypropylcellulose ether.
Preferably, described organosilicon powder be mainly composed of organic silane compound, chemical formula is (ORa)3Si(CH2)m-X-Y-(CH2)nSi(ORb)3, in formula: Ra、RbFor C1-C4Alkyl, m, n=1-4, in formula, X, Y are the group generated after amido reacts with isocyanate group.
One, Binder Materials:
In raw material of the present invention, portland cement plays cementation, it is preferred that for 32.5R or 42.5R portland cement;
Two, aggregate
Quartz sand is that quartz is through the broken quartz particles processed, quartz is a kind of nonmetallic mineral, it it is the silicate mineral of a kind of hard, wear-resisting, stable chemical performance, its main mineral constituent is silicon dioxide, in quartz sand selected by the present invention, dioxide-containing silica is not less than 98%, and intensity is high, anti-wear performance is good;The present invention adds a small amount of wollastonite powder simultaneously in order to increase the intensity of product after solidification.
Three, filler
The crystalline solid of calcium carbonate mainly has the calcite of inclined three crystal class of multiple tripartite and the aragonite of iris class, and ground calcium carbonate is exactly calcite in powder.The present invention adds ground calcium carbonate and can be effectively increased toughness and the intensity of product;
Four, water-retaining agent
Cellulose ether is a kind of conventional water-retaining agent in paint coating field, and it can make the moisture in mortar not easily lose, and progressively discharges within long period of time, gives the good water-retaining property of mortar and workability,
Bentonite is the moisture argillic horizon based on montmorillonite, and it has excellent ion exchangeable, dilatancy, adhesiveness, plasticity, fire resistance, and bentonite has stronger water absorption, it is possible to improve the intensity of material;It also has unique selective absorption, it is possible to the permanent absorption solidification of the radioactive substance in block material, have the function purified with repairing environment.
Five, thickening agent
Often being expanded with heat and contract with cold after powder body building materials molding and weather, temperature, humidity etc. affect, dry, ftracture, the phenomenon such as come off happens occasionally, especially after material chance water and stress, this phenomenon is more serious.The method of appropriate thickening agent is added to reach product anticracking and to increase elastic effect for this present invention.Redispersable latex powder has prominent adhesion strength, can improve the elasticity of binding agent, and give the alkali resistance that binding agent is excellent;
Six, retarder
Citric acid can postpone hydrated reaction of cement as cement retarder, thus extending the setting time of plastering material so that it is the long period can keep plasticity, conveniently build, improve efficiency of construction.Citric acid can also effectively suppress the phenomenons such as the material accumulation of salt in the surface soil to produce simultaneously;
Seven, specially good effect binding agent
Organosilicon powder with a large amount of organic groups all can well link with portland cement, quartz sand, block surfaces, owing to organic group has certain length, the plastering material made possesses good pliability, thus having good impact strength, not easily hollowing, ftracture, come off, also have good water resistance simultaneously.
Eight, Li-montmorillonite
Li-montmorillonite is between montmorillonite layer or lattice exists lithium (ion), and Li-montmorillonite can make mortar criticize and scrape smooth and non-stick knife, improves construction comfort level;Meanwhile, Li-montmorillonite and organosilicon powder react in polar solvent and form the organosilicon colloid that intensity is significantly high in the present invention, it is possible to be greatly improved the water resistance of material.
Nine, modifying agent
Calcium formate is as modifying agent, it is possible to improve the setting rate of cement, shortens setting time, improves strength of cement, has good anti-freeze thawing simultaneously.
The preparation method that the invention provides a kind of cement group water-proofing material, comprises the following steps:
Step one: after being opened by blender, adds in blender by the order of ground calcium carbonate-bentonite-calcium formate-redispersable latex powder-wollastonite powder-cellulose ether-citric acid-organosilicon powder-Li-montmorillonite and stirs, make additive package;
Step 2: after being opened by blender, first adds the 50% of portland cement weight, then adds the 50% of quartz sand weight, then adds the 50% of additive package weight, adds residue 50% material after slightly mixing again in this order.
A kind of cement group water-proofing material provided by the invention, should be noted that during its construction:
One, base treatment
Need to the substrate surface at the place of plastering should dry, without greasy dirt, floating ash or other foreign material.
Two, construction method
1, waterproof material is added water stir into pasty state (ratio of mud is about 1:3.5) with motor stirrer, be directly put on substrate surface with mud plate;
2, construction thickness is about 2-3mm, 2~3 times are smeared at required waterproof position of doing with mud plate, and ensure, can need to carry out when one after smearing constructing after front one surface drying (different depending on temperature, about 4~6 hours, interval), gross thickness is not preferably greater than 5mm or less than 2mm, every square metre of consumption about 3 kilograms;
3, mixed waterproof material needs to be finished at 3-4 hour;
4, construction environment temperature should not be constructed lower than 5 DEG C or higher than 35 DEG C.
If 5 metopes are relatively dry, should first sprinkle water before construction moistening.
The useful of the present invention is effectively in that: adhere well to power with basal plane, construction thickness is very thin, material is economical and practical, material can be saved, even if the basic unit after this material processes is in for a long time in the environment that humidity is very big and flakes without hollowing simultaneously, can ensure that job site is cleaned, more meet environmental requirement.
Detailed description of the invention
Embodiment 1
A kind of cement group water-proofing material, is made up of the component of following percentage by weight:
Described redispersable latex powder is the rubber powder that polyvinyl acetate generates through copolyreaction with polyvinyl alcohol;
Described organosilicon powder be mainly composed of organic silane compound, chemical formula is (ORa)3Si(CH2)m-X-Y-(CH2)nSi(ORb)3, in formula: Ra、RbFor C1-C4Alkyl, m, n=1-4, in formula, X, Y are the group generated after amido reacts with isocyanate group.
The preparation method of a kind of cement group water-proofing material, comprises the following steps:
Step one: after being opened by blender, adds in blender by the order of ground calcium carbonate-bentonite-calcium formate-redispersable latex powder-wollastonite powder-cellulose ether-citric acid-organosilicon powder-Li-montmorillonite and stirs, make additive package;
Step 2: after being opened by blender, first adds the 50% of portland cement weight, then adds the 50% of quartz sand weight, then adds the 50% of additive package weight, adds residue 50% material after slightly mixing again in this order.
Embodiment 2
A kind of cement group water-proofing material, is made up of the component of following percentage by weight:
Described redispersable latex powder is the rubber powder that polyvinyl acetate generates through copolyreaction with polyvinyl alcohol;
Described organosilicon powder be mainly composed of organic silane compound, chemical formula is (ORa)3Si(CH2)m-X-Y-(CH2)nSi(ORb)3, in formula: Ra、RbFor C1-C4Alkyl, m, n=1-4, in formula, X, Y are the group generated after amido reacts with isocyanate group.
The preparation method of a kind of cement group water-proofing material, comprises the following steps:
Step one: after being opened by blender, adds in blender by the order of ground calcium carbonate-bentonite-calcium formate-redispersable latex powder-wollastonite powder-cellulose ether-citric acid-organosilicon powder-Li-montmorillonite and stirs, make additive package;
Step 2: after being opened by blender, first adds the 50% of portland cement weight, then adds the 50% of quartz sand weight, then adds the 50% of additive package weight, adds residue 50% material after slightly mixing again in this order.
Embodiment 3
A kind of cement group water-proofing material, is made up of the component of following percentage by weight:
Described redispersable latex powder is the rubber powder that polyvinyl acetate generates through copolyreaction with polyvinyl alcohol;
Described organosilicon powder be mainly composed of organic silane compound, chemical formula is (ORa)3Si(CH2)m-X-Y-(CH2)nSi(ORb)3, in formula: Ra、RbFor C1-C4Alkyl, m, n=1-4, in formula, X, Y are the group generated after amido reacts with isocyanate group.
The preparation method of a kind of cement group water-proofing material, comprises the following steps:
Step one: after being opened by blender, adds in blender by the order of ground calcium carbonate-bentonite-calcium formate-redispersable latex powder-cellulose ether-citric acid-organosilicon powder-Li-montmorillonite and stirs, make additive package;
Step 2: after being opened by blender, first adds the 50% of portland cement weight, then adds the 50% of quartz sand weight, then adds the 50% of additive package weight, adds residue 50% material after slightly mixing again in this order.
Embodiment 4
A kind of cement group water-proofing material, is made up of the component of following percentage by weight:
Described quartz sand is 30 order sand and 50 order sand, and both percentage by weights are 1:3;
Described redispersable latex powder is the rubber powder that polyvinyl acetate generates through copolyreaction with polyvinyl alcohol;
Described organosilicon powder be mainly composed of organic silane compound, chemical formula is (ORa)3Si(CH2)m-X-Y-(CH2)nSi(ORb)3, in formula: Ra、RbFor C1-C4Alkyl, m, n=1-4, in formula, X, Y are the group generated after amido reacts with isocyanate group.
The preparation method of a kind of cement group water-proofing material, comprises the following steps:
Step one: after being opened by blender, adds in blender by the order of ground calcium carbonate-bentonite-calcium formate-redispersable latex powder-wollastonite powder-cellulose ether-citric acid-organosilicon powder-Li-montmorillonite and stirs, make additive package;
Step 2: after being opened by blender, first adds the 50% of portland cement weight, then adds the 50% of quartz sand weight, then adds the 50% of additive package weight, adds residue 50% material after slightly mixing again in this order.
Embodiment 5
A kind of cement group water-proofing material, is made up of the component of following percentage by weight:
Described quartz sand is 30 order sand and 60 order sand, and both percentage by weights are 1:1;
Described redispersable latex powder is the rubber powder that polyvinyl acetate generates through copolyreaction with polyvinyl alcohol;
Described organosilicon powder be mainly composed of organic silane compound, chemical formula is (ORa)3Si(CH2)m-X-Y-(CH2)nSi(ORb)3, in formula: Ra、RbFor C1-C4Alkyl, m, n=1-4, in formula, X, Y are the group generated after amido reacts with isocyanate group.
The preparation method of a kind of cement group water-proofing material, comprises the following steps:
Step one: after being opened by blender, adds in blender by the order of ground calcium carbonate-bentonite-calcium formate-redispersable latex powder-wollastonite powder-cellulose ether-citric acid-organosilicon powder-Li-montmorillonite and stirs, make additive package;
Step 2: after being opened by blender, first adds the 50% of portland cement weight, then adds the 50% of quartz sand weight, then adds the 50% of additive package weight, adds residue 50% material after slightly mixing again in this order.
Embodiment 1-5 is detected:
Embodiment sample detects according to industry standard JC890-3001 " steam aerated coagulation masonry mortar and decorative mortar ".
These detection data are just for above-mentioned detection sample.
The above; it is only the present invention preferably detailed description of the invention; but protection scope of the present invention is not limited thereto; any those familiar with the art is in the technical scope that the invention discloses; it is equal to replacement according to technical scheme and inventive concept thereof or is changed, all should be encompassed within protection scope of the present invention.

Claims (2)

1. the preparation method of a cement group water-proofing material, it is characterised in that comprise the steps of
Step one: after being opened by blender, adds in blender by the order of ground calcium carbonate-bentonite-calcium formate-redispersable latex powder-wollastonite powder-cellulose ether-citric acid-organosilicon powder-Li-montmorillonite and stirs, make additive package;
Step 2: after being opened by blender, first adds the 50% of portland cement weight, then adds the 50% of quartz sand weight, then adds the 50% of additive package weight, adds residue 50% material after slightly mixing again in this order;
Described cement group water-proofing material, is made up of the component of following percentage by weight:
Portland cement 30%-50%
Quartz sand 35%-50%
Ground calcium carbonate 5%-15%
Bentonite 3%-5%
Redispersable latex powder 0.1%-0.3%
Cellulose ether 0.3%-0.5%
Citric acid 0%-0.2%
Calcium formate 0.5-1.0%
Wollastonite powder 0-5%
Organosilicon powder 0.1%-0.5%
The 10-15% of Li-montmorillonite organosilicon powder weight;
Described portland cement is 32.5R or 42.5R cement;
Described quartz sand is 30 order-80 order sand;
Described bentonite is organobentonite;
Described redispersable latex powder is the rubber powder that polyvinyl acetate generates through copolyreaction with polyvinyl alcohol;
Described organosilicon powder be mainly composed of organic silane compound, chemical formula is (ORa)3Si(CH2)m-X-Y-(CH2)nSi(ORb)3, in formula: Ra、RbFor C1-C4Alkyl, m, n=1-4, in formula, X, Y are the group generated after amido reacts with isocyanate group.
2. the preparation method of cement group water-proofing material as claimed in claim 1, it is characterised in that be made up of the component of following percentage by weight:
42.5R portland cement 40%
Quartz sand 60 order 42%
Ground calcium carbonate 10%
Organobentonite 4%
Redispersable latex powder 0.2%
Methyl hydroxyethylcellulose ether 0.4%
Citric acid 0.1%
Calcium formate 1.0%
Wollastonite powder 2%
Organosilicon powder 0.27%
Li-montmorillonite 0.03%;
Described redispersable latex powder is the rubber powder that polyvinyl acetate generates through copolyreaction with polyvinyl alcohol;
Described organosilicon powder be mainly composed of organic silane compound, chemical formula is (ORa)3Si(CH2)m-X-Y-(CH2)nSi(ORb)3, in formula: Ra、RbFor C1-C4Alkyl, m, n=1-4, in formula, X, Y are the group generated after amido reacts with isocyanate group.
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CN105967576A (en) * 2016-05-18 2016-09-28 常德市万福达环保节能建材有限公司 Ternary copolymer latex powder waterproof mortar
CN106145819A (en) * 2016-07-01 2016-11-23 德清扬泰建筑材料有限公司 A kind of kitchen special-purpose anti-flaming sound-proof interior wall dry powder and mortar
CN106186972B (en) * 2016-07-06 2018-08-31 德清扬泰建筑材料有限公司 A kind of method that reclaimed materials prepares dry powder and mortar
CN106904930A (en) * 2017-03-23 2017-06-30 苏州顶裕节能设备有限公司 A kind of NEW TYPE OF COMPOSITE energy-saving and heat-insulating material and preparation method thereof
CN107188474A (en) * 2017-07-18 2017-09-22 合肥万之景门窗有限公司 A kind of cracking resistance cement-base waterproof coating and preparation method thereof
CN107628788B (en) * 2017-09-22 2021-06-01 北京东方雨虹防水技术股份有限公司 Cement-based waterproof material for repairing concrete cracks and preparation method thereof
CN107902990B (en) * 2017-11-15 2020-07-28 新沂市晶润石英材料有限公司 Method for preparing polymer cement waterproof mortar by using quartz sand dust

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WO2012073258A2 (en) * 2010-11-30 2012-06-07 Pradeep Vasant Joshi A composition suitable for use in building construction
CN102249595A (en) * 2011-04-29 2011-11-23 山东秦恒科技有限公司 Special flexible texture coating for external heat insulating wall, and preparation method thereof
CN102850026A (en) * 2012-09-24 2013-01-02 上海宝冶工程技术有限公司 Heat-resistant high-strength shrinkage-free grouting material
CN103553495B (en) * 2013-10-21 2016-08-17 苏州市姑苏新型建材有限公司 A kind of rapid-hardening ornamental stone early strong rubber stick

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Denomination of invention: A cement-based waterproof material and its preparation method

Granted publication date: 20160629

Pledgee: Qianyuan sub branch of Zhejiang Deqing Rural Commercial Bank Co.,Ltd.

Pledgor: DEQING YANGTAI BUILDING MATERIAL Co.,Ltd.

Registration number: Y2024980017709