CN104218263A - Power gel battery container formation technology - Google Patents
Power gel battery container formation technology Download PDFInfo
- Publication number
- CN104218263A CN104218263A CN201410401252.5A CN201410401252A CN104218263A CN 104218263 A CN104218263 A CN 104218263A CN 201410401252 A CN201410401252 A CN 201410401252A CN 104218263 A CN104218263 A CN 104218263A
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- China
- Prior art keywords
- charge
- stage
- fills
- puts
- battery
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/06—Lead-acid accumulators
- H01M10/12—Construction or manufacture
- H01M10/121—Valve regulated lead acid batteries [VRLA]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/14—Electrodes for lead-acid accumulators
- H01M4/16—Processes of manufacture
- H01M4/20—Processes of manufacture of pasted electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
The invention discloses a power gel battery container formation technology. The technology uses a four charge and three discharge formation process, the charge current and the charge time in each of charge and discharge stages are optimized, and the charge level in the first charge stage is 6.5-7.5 times a rated capacity to ensure most formation of a positive plate; the charge level in the second charge stage is 2.6-3 times the rated capacity; and incomplete discharge in the second discharge stage is in favor of re-converting an active substance, so the blaze phenomenon of the surface of the positive plate is solved. The container formation technology can effectively solve the problem that power gel batteries are difficult to completely form, can guarantee the uniform formation of the positive plate of the gel battery and the full conversion of the active substance, and improves the container formation quality of the gel battery.
Description
Technical field
The invention belongs to battery technology field, be specifically related to container formation technique.
Background technology
The chemical synthesis technology of lead acid accumulator is internalized into and tank formation two kinds, and tank formation, due to its problem of environmental pollution, is banned gradually.Existing power type AGM valve-regulated lead-acid battery usually adopts three to fill two and puts internal formation process, and this technique can ensure that the positive plate of AGM battery changes into evenly, and active material is fully changed.The existence of colloidal electrolyte can play negative effect to the effect be internalized into, colloid battery be internalized into adopt above-mentioned three fill two knock off skill time, being difficult to of positive plate is saturating, a lot of hickie of surface appearance.
Summary of the invention
Technical problem to be solved by this invention is just to provide a kind of power type colloid battery internal formation process, the difficult problem that effective being difficult to of solution power type colloid battery is saturating, can ensure that colloid battery positive plate changes into evenly, active material conversion fully, improves colloid battery and is internalized into quality.
For solving the problems of the technologies described above, the present invention adopts following technical scheme: a kind of power type colloid battery internal formation process, specifically comprises the steps:
A, standing stage: after colloidal electrolyte adds battery, leave standstill 1.5 ~ 2h in a water bath;
B, one fills the stage:
0.07 ~ 0.12 I
2(A) charge 0.8 ~ 1.2h;
0.15 ~ 0.25 I
2(A) charge 1.5 ~ 2.5h;
0.35 ~ 0.45 I
2(A) charge 20 ~ 30h;
0.2 ~ 0.3 I
2(A) charge 8 ~ 12h;
C, one puts the stage:
-0.35 ~ 0.45 I
2(A) only 11V/ is discharged to;
D, two fills the stage:
0.35 ~ 0.45 I
2(A) charge 8 ~ 12h;
0.2 ~ 0.3 I
2(A) charge 6 ~ 10h;
E, two puts the stage:
-0.8 ~ 1.2 I
2(A) discharge 0.8 ~ 1.2h;
F, three fills the stage:
0.25 ~ 0.35 I
2(A) charge 8 ~ 12h;
0.15 ~ 0.25 I
2(A) charge 4 ~ 6h;
H, three puts the stage:
-0.8 ~ 1.2I
2(A) only 10.5V/ is discharged to;
I, four fills the stage:
0.25 ~ 0.35 I
2(A) charge 8 ~ 12h;
0.15 ~ 0.25 I
2(A) charge 4 ~ 6h;
0A leaves standstill 0.8 ~ 1.2h;
0.15 ~ 0.25 I
2(A), 15V/ constant voltage charge 1.5 ~ 2.5h takes out acid.
Preferably, a stage of filling is filled with 6.5 to 7.5 times that electricity is battery rated capacity.
Preferably, two stages of filling were filled with 2.6 to 3 times that electricity is battery rated capacity.
Preferably, three stages of filling were filled with 1.8 to 2 times that electricity is battery rated capacity.
Preferably, at the whole battery temperature that to be internalized in process lower than 50 DEG C.
Preferably, in described colloidal electrolyte colloidal content between 0.1% ~ 5%.
Preferably, specifically comprise the steps:
A, standing stage: after colloidal electrolyte adds battery, leave standstill 1.5 ~ 2h in a water bath;
B, one fills the stage:
0.1 I
2(A) charge 1h;
0.2 I
2(A) charge 2h;
0.4 I
2(A) charge 25h;
0.25 I
2(A) charge 10h;
C, one puts the stage:
-0.4 I
2(A) only 11V/ is discharged to;
D, two fills the stage:
0.4 I
2(A) charge 10h;
0.25 I
2(A) charge 8h;
E, two puts the stage:
-1.0 I
2(A) discharge 1h;
F, three fills the stage:
0.3 I
2(A) charge 10h;
0.2 I
2(A) charge 5h;
H, three puts the stage:
-1.0 I
2(A) only 10.5V/ is discharged to;
I, four fills the stage:
0.3 I
2(A) charge 10h;
0.2 I
2(A) charge 5h;
0A leaves standstill 1h;
0.2 I
2(A), 15V/ constant voltage charge 2h takes out acid.
The present invention uses four to fill three and puts chemical synthesis technology, and simultaneously the charging current in each discharge and recharge stage, charging interval are also optimized, and one stage of filling of setting is filled with 6.5 to 7.5 times that electricity is rated capacity further, guarantees that the positive plate overwhelming majorityization thoroughly; Two stages of filling were filled with 2.6 to 3 times that electricity is rated capacity; Two shallow discharges put, are conducive to transforming again of active material, solve the hickie phenomenon on positive plate surface.
After adopting technique scheme, internal formation process of the present invention effectively can solve the saturating difficult problem of being difficult to of power type colloid battery, can ensure that colloid battery positive plate changes into evenly, and active material conversion fully, improves colloid battery and is internalized into quality.
Embodiment
A kind of power type colloid battery of the present invention internal formation process, specifically comprises the steps:
A, standing stage: after colloidal electrolyte adds battery, leave standstill 1.5 ~ 2h in a water bath;
B, one fills the stage:
0.07 ~ 0.12 I
2(A) charge 0.8 ~ 1.2h;
0.15 ~ 0.25 I
2(A) charge 1.5 ~ 2.5h;
0.35 ~ 0.45 I
2(A) charge 20 ~ 30h;
0.2 ~ 0.3 I
2(A) charge 8 ~ 12h;
C, one puts the stage:
-0.35 ~ 0.45 I
2(A) only 11V/ is discharged to;
D, two fills the stage:
0.35 ~ 0.45 I
2(A) charge 8 ~ 12h;
0.2 ~ 0.3 I
2(A) charge 6 ~ 10h;
E, two puts the stage:
-0.8 ~ 1.2 I
2(A) discharge 0.8 ~ 1.2h;
F, three fills the stage:
0.25 ~ 0.35 I
2(A) charge 8 ~ 12h;
0.15 ~ 0.25 I
2(A) charge 4 ~ 6h;
H, three puts the stage:
-0.8 ~ 1.2I
2(A) only 10.5V/ is discharged to;
I, four fills the stage:
0.25 ~ 0.35 I
2(A) charge 8 ~ 12h;
0.15 ~ 0.25 I
2(A) charge 4 ~ 6h;
0A leaves standstill 0.8 ~ 1.2h;
0.15 ~ 0.25 I
2(A), 15V/ constant voltage charge 1.5 ~ 2.5h takes out acid.
Be described further below in conjunction with specific embodiment.
In embodiment 1: this power type colloid battery internal formation process, comprises the following steps:
A, standing stage
After colloidal electrolyte adds battery, leave standstill 1.5 ~ 2h in a water bath.
B, one fills the stage
0.1 I
2(A) charge 1h;
0.2 I
2(A) charge 2h;
0.4 I
2(A) charge 25h;
0.25 I
2(A) charge 10h.
C, one puts the stage
-0.4 I
2(A) only 11V/ is discharged to.
D, two fills the stage
0.4 I
2(A) charge 10h;
0.25 I
2(A) charge 8h;
E, two puts the stage
-1.0 I
2(A) discharge 1h
F, three fills the stage
0.3 I
2(A) charge 10h;
0.2 I
2(A) charge 5h;
H, three puts the stage
-1.0 I
2(A) only 10.5V/ is discharged to
I, four fills the stage
0.3 I
2(A) charge 10h;
0.2 I
2(A) charge 5h;
0A leaves standstill 1h;
0.2 I
2(A), 15V/ constant voltage charge 2h takes out acid.
One stage of filling was filled with 6.5 to 7.5 times that electricity is rated capacity, guaranteed that the positive plate overwhelming majorityization is saturating; Two stages of filling were filled with 2.6 to 3 times that electricity is rated capacity; Two shallow discharges put, are conducive to transforming again of active material, solve the hickie phenomenon on positive plate surface; Three stages of filling were filled with 1.8 to 2 times that electricity is rated capacity; Whole charging process battery temp is lower than 50 DEG C; Colloidal electrolyte colloidal content is between 0.1% ~ 5%.
In embodiment 2: this power type colloid battery internal formation process, comprises the following steps:
A, standing stage: after colloidal electrolyte adds battery, leave standstill 1.5 ~ 2h in a water bath;
B, one fills the stage:
0.07 I
2(A) charge 1.2h;
0.15 I
2(A) charge 2.5h;
0.35I
2(A) charge 30h;
0.2 I
2(A) charge 12h;
C, one puts the stage:
-0.35 I
2(A) only 11V/ is discharged to;
D, two fills the stage:
0.35 I
2(A) charge 12h;
0.2 I
2(A) charge 10h;
E, two puts the stage:
-0.8I
2(A) discharge 1.2h;
F, three fills the stage:
0.25 I
2(A) charge 12h;
0.15I
2(A) charge 6h;
H, three puts the stage:
-0.8I
2(A) only 10.5V/ is discharged to;
I, four fills the stage:
0.25 I
2(A) charge 12h;
0.15 I
2(A) charge 6h;
0A leaves standstill 1.2h;
0.15 I
2(A), 15V/ constant voltage charge 2.5h takes out acid.
In embodiment 3: this power type colloid battery internal formation process, comprises the following steps:
A, standing stage: after colloidal electrolyte adds battery, leave standstill 1.5 ~ 2h in a water bath;
B, one fills the stage:
0.12 I
2(A) charge 0.8h;
0.25 I
2(A) charge 1.5h;
0.45 I
2(A) charge 20h;
-0.3 I
2(A) charge 8h;
C, one puts the stage:
0.45 I
2(A) only 11V/ is discharged to;
D, two fills the stage:
0.45 I
2(A) charge 8h;
0.3 I
2(A) charge 6h;
E, two puts the stage:
-1.2 I
2(A) discharge 0.8h;
F, three fills the stage:
0.35 I
2(A) charge 8h;
0.25 I
2(A) charge 4h;
H, three puts the stage:
-1.2I
2(A) only 10.5V/ is discharged to;
I, four fills the stage:
0.35 I
2(A) charge 8h;
0.25 I
2(A) charge 4h;
0 A leaves standstill 0.8h;
0.25 I
2(A), 15V/ constant voltage charge 1.5h takes out acid.
Claims (7)
1. a power type colloid battery internal formation process, is characterized in that specifically comprising the steps:
A, standing stage: after colloidal electrolyte adds battery, leave standstill 1.5 ~ 2h in a water bath;
B, one fills the stage:
0.07 ~ 0.12 I
2(A) charge 0.8 ~ 1.2h;
0.15 ~ 0.25 I
2(A) charge 1.5 ~ 2.5h;
0.35 ~ 0.45 I
2(A) charge 20 ~ 30h;
0.2 ~ 0.3 I
2(A) charge 8 ~ 12h;
C, one puts the stage:
-0.35 ~ 0.45 I
2(A) only 11V/ is discharged to;
D, two fills the stage:
0.35 ~ 0.45 I
2(A) charge 8 ~ 12h;
0.2 ~ 0.3 I
2(A) charge 6 ~ 10h;
E, two puts the stage:
-0.8 ~ 1.2 I
2(A) discharge 0.8 ~ 1.2h;
F, three fills the stage:
0.25 ~ 0.35 I
2(A) charge 8 ~ 12h;
0.15 ~ 0.25 I
2(A) charge 4 ~ 6h;
H, three puts the stage:
-0.8 ~ 1.2I
2(A) only 10.5V/ is discharged to;
I, four fills the stage:
0.25 ~ 0.35 I
2(A) charge 8 ~ 12h;
0.15 ~ 0.25 I
2(A) charge 4 ~ 6h;
0A leaves standstill 0.8 ~ 1.2h;
0.15 ~ 0.25 I
2(A), 15V/ constant voltage charge 1.5 ~ 2.5h takes out acid.
2. power type colloid battery internal formation process according to claim 1, is characterized in that: a stage of filling is filled with 6.5 to 7.5 times that electricity is battery rated capacity.
3. power type colloid battery internal formation process according to claim 2, is characterized in that: two stages of filling were filled with 2.6 to 3 times that electricity is battery rated capacity.
4. power type colloid battery internal formation process according to claim 3, is characterized in that: three stages of filling were filled with 1.8 to 2 times that electricity is battery rated capacity.
5. the power type colloid battery internal formation process according to Claims 1-4 any one, is characterized in that: at the whole battery temperature that to be internalized in process lower than 50 DEG C.
6. power type colloid battery internal formation process according to claim 5, is characterized in that: in described colloidal electrolyte, colloidal content is between 0.1% ~ 5%.
7. power type colloid battery internal formation process according to claim 1, is characterized in that specifically comprising the steps:
A, standing stage: after colloidal electrolyte adds battery, leave standstill 1.5 ~ 2h in a water bath;
B, one fills the stage:
0.1 I
2(A) charge 1h;
0.2 I
2(A) charge 2h;
0.4I
2(A) charge 25h;
0.25 I
2(A) charge 10h;
C, one puts the stage:
-0.4 I
2(A) only 11V/ is discharged to;
D, two fills the stage:
0.4 I
2(A) charge 10h;
0.25 I
2(A) charge 8h;
E, two puts the stage:
-1.0 I
2(A) discharge 1h;
F, three fills the stage:
0.3 I
2(A) charge 10h;
0.2 I
2(A) charge 5h;
H, three puts the stage:
-1.0I
2(A) only 10.5V/ is discharged to;
I, four fills the stage:
0.3 I
2(A) charge 10h;
0.2 I
2(A) charge 5h;
0A leaves standstill 1h;
0.2 I
2(A), 15V/ constant voltage charge 2h takes out acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410401252.5A CN104218263B (en) | 2014-08-14 | 2014-08-14 | A kind of power type colloid battery internal formation process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410401252.5A CN104218263B (en) | 2014-08-14 | 2014-08-14 | A kind of power type colloid battery internal formation process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104218263A true CN104218263A (en) | 2014-12-17 |
| CN104218263B CN104218263B (en) | 2016-08-24 |
Family
ID=52099544
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410401252.5A Active CN104218263B (en) | 2014-08-14 | 2014-08-14 | A kind of power type colloid battery internal formation process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104218263B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104900923A (en) * | 2015-04-03 | 2015-09-09 | 超威电源有限公司 | Colloid lead acid battery inner formation method |
| CN108110333A (en) * | 2017-11-06 | 2018-06-01 | 超威电源有限公司 | A kind of lead-acid accumulator low temperature is internalized into test method |
| CN108598609A (en) * | 2018-03-28 | 2018-09-28 | 超威电源有限公司 | A kind of colloid power container formation process for lead acid storage battery |
| CN108963367A (en) * | 2018-08-24 | 2018-12-07 | 江苏超威电源有限公司 | Colloid power lead-acid accumulator chemical synthesis technology |
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| CN102368567A (en) * | 2011-10-13 | 2012-03-07 | 超威电源有限公司 | Formation method for dynamic lead-acid cell jar formation |
| CN102437380A (en) * | 2011-12-06 | 2012-05-02 | 河南超威电源有限公司 | Method for internal chemical reaction in battery via charging five times and discharging four times |
| CN102593533A (en) * | 2012-03-15 | 2012-07-18 | 超威电源有限公司 | Method for internalizing valve-regulated lead acid storage battery |
-
2014
- 2014-08-14 CN CN201410401252.5A patent/CN104218263B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102368567A (en) * | 2011-10-13 | 2012-03-07 | 超威电源有限公司 | Formation method for dynamic lead-acid cell jar formation |
| CN102437380A (en) * | 2011-12-06 | 2012-05-02 | 河南超威电源有限公司 | Method for internal chemical reaction in battery via charging five times and discharging four times |
| CN102593533A (en) * | 2012-03-15 | 2012-07-18 | 超威电源有限公司 | Method for internalizing valve-regulated lead acid storage battery |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104900923A (en) * | 2015-04-03 | 2015-09-09 | 超威电源有限公司 | Colloid lead acid battery inner formation method |
| CN108110333A (en) * | 2017-11-06 | 2018-06-01 | 超威电源有限公司 | A kind of lead-acid accumulator low temperature is internalized into test method |
| CN108110333B (en) * | 2017-11-06 | 2019-09-20 | 超威电源有限公司 | A kind of lead-acid accumulator low temperature is internalized into test method |
| CN108598609A (en) * | 2018-03-28 | 2018-09-28 | 超威电源有限公司 | A kind of colloid power container formation process for lead acid storage battery |
| CN108963367A (en) * | 2018-08-24 | 2018-12-07 | 江苏超威电源有限公司 | Colloid power lead-acid accumulator chemical synthesis technology |
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| CN104218263B (en) | 2016-08-24 |
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