CN108598609A - A kind of colloid power container formation process for lead acid storage battery - Google Patents

A kind of colloid power container formation process for lead acid storage battery Download PDF

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CN108598609A
CN108598609A CN201810264825.2A CN201810264825A CN108598609A CN 108598609 A CN108598609 A CN 108598609A CN 201810264825 A CN201810264825 A CN 201810264825A CN 108598609 A CN108598609 A CN 108598609A
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stage
fill
electric currents
battery
charging
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CN108598609B (en
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代少振
项晨
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Chaowei Power Supply Co Ltd
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Chaowei Power Supply Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44Methods for charging or discharging
    • H01M10/446Initial charging measures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/06Lead-acid accumulators
    • H01M10/12Construction or manufacture
    • H01M10/121Valve regulated lead acid batteries [VRLA]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

The present invention relates to battery technology fields, more particularly to a kind of colloid power container formation process for lead acid storage battery, colloidal electrolyte is added in accumulator, stands 0.5~1h, chemical conversion program fills stage, alternate nine discharge regimes including ten successively and stands the stage and take out acid phase.Present invention efficiently solves the saturating problem of power type being difficult to of colloid battery, it can guarantee that the chemical conversion of colloid battery positive plate is uniform, active material conversion is abundant, improves colloid battery and is internalized into quality.The technique is always melted into the time as 27~51h before the detection of the 9th discharge capacity and combo electric discharge simultaneously, total net charge volume is 3.4~8.75 times of rated capacity, reduce battery charge and chemical conversion time, enhancing battery is effectively filled with electricity, it improves power colloid battery and produces production capacity, it reduces battery production cost and improves production efficiency, improve battery competitiveness in the market.

Description

A kind of colloid power container formation process for lead acid storage battery
Technical field
The present invention relates to battery technology field more particularly to a kind of colloid power container formation process for lead acid storage battery.
Background technology
The chemical conversion of lead-acid accumulator is a very crucial procedure in lead-acid accumulator manufacture, the quality of formation process Directly influence the performance and service life of lead-acid accumulator.Even with formula, same to technique, the lead-acid accumulator with batch, Also result in the granular size and arrangement shape of active material from the different chemical conversion time using different electric currents in formation process The variation of formula.
Lead-acid accumulator chemical synthesis technology be generally divided to be internalized into two kinds of tank formation, be internalized into and tank formation (channelization at) phase Than haing the following advantages:Technological process simplifies pole plate washing, the load of dry and battery supplement electricity and slot type chemical conversion, weldering It connects, take the processes such as piece, save a large amount of energy (energy such as pure water, acid and electricity), working hour, floor space is small, without purchasing Grooving equipment and acid-mist equipment, battery obtain certain reduction at instinct.Pole plate is not easy to be polluted by impurity, can reduce battery Self discharge improves battery with two side terminals, extends battery life.
Existing power type AGM valve-regulated lead-acid batteries generally use three is filled two and is put, and four fill three internal formation process put, the work Artistic skill enough ensures that the positive plate chemical conversion of AGM battery is uniform, and active material is fully converted.But the presence of colloidal electrolyte can prolong The diffusion velocity of slow electrolyte, the internal resistance for increasing battery play negative effect, therefore colloid power plumbic acid to the effect being internalized into Container formation using above-mentioned three fill two put technique, four fill three and put internal formation process when, being difficult to of positive plate is saturating, and surface occurs very More hickies, internal resistance is big in formation process, and anode polarization increases, and big volume and electricity is used for the electrolysis of water in formation process, causes a large amount of Energy loss increases battery production cost, increases the moisture loss in formation process, to influence battery performance.
Invention content
The present invention in order to overcome in existing colloid power type container formation process for lead acid storage battery there is being difficult to thoroughly, energy consumption It is high, internal resistance is big, influences the problem of battery performance, provide that a kind of battery positive plate chemical conversion is uniform, and active material conversion is sufficient Colloid power container formation process for lead acid storage battery.
To achieve the goals above, the present invention uses following technical scheme:
Colloidal electrolyte is added in a kind of colloid power container formation process for lead acid storage battery in accumulator, stands 0.5~1h, changes Include the following steps successively at program:
(1) one fills the stage:First with 0.1~0.15C electric currents, 3~5h of charging, then with 0.15~0.2C electric currents charging, 3~5h;
(2) one put the stage:With 0.1~0.2C current discharges, 0.5~1h;
(3) two fill the stage:With 0.15~0.2C electric currents charging, 3~5h;
(4) two put the stage:With 0.1~0.2C current discharges, 0.5~1h;
(5) three fill the stage:With 0.2~0.25C electric currents charging, 2~4h;
(6) three put the stage:With 0.1~0.2C current discharges, 0.5~1h;
(7) four fill the stage:With 0.25~0.3C electric currents charging, 2~4h;
(8) four put the stage:With 0.1~0.2C current discharges, 0.5~1h;
(9) five fill the stage:With 0.3~0.35C electric currents charging, 2~4h;
(10) five put the stage:With 0.1~0.2C current discharges, 0.5~1h;
(11) six fill the stage:With 0.15~0.25C electric currents charging, 2~4h;
(12) six put the stage:With 0.5~1h of 0.2C current discharges;
(13) seven fill the stage:With 0.15~0.25C electric currents charging, 2~4h;
(14) seven put the stage:With 0.1~0.2C current discharges, 0.5~1h;
(15) eight fill the stage:With 0.15~0.25C electric currents charging, 2~4h;
(16) eight put the stage:With 0.1~0.2C current discharges, 0.5~1h;
(17) nine fill the stage:With 0.15~0.25C electric currents charging, 2~4h;
(18) nine put the stage:With 0.5C current discharges to 1.75V/ single lattices;
(19) ten fill the stage:First with 0.25~0.35C electric currents, 3~5h of charging, then with 0.1~0.15C electric currents charging, 1~2h;
(20) stage is stood:Stand 0.5~1h;
(21) acid phase is taken out:To carry out taking out acid after 0.02~0.04C constant-current charges, 2~3h.
Preferably, in formation process, the temperature of accumulator is controlled at 25~50 DEG C.
Colloid power container formation process for lead acid storage battery of the present invention fills 9 using 10 puts charge technology, stringent in formation process Between controlling 25 to 50 DEG C of battery temperature, while the charging current in each charge and discharge stage, charging time are optimized, In, C indicates the rated capacity of battery.
Preferably, in step (1), a stage of filling is filled with 0.75~1.75 times that electricity is rated capacity, it is ensured that early period Grid corrosion layer generate, enhance grid and active material binding force, then carry out 0.5~1h low discharging current go electrification Learn polarization.
Preferably, step (2) is to (10), two fill that stage to five stages of putting are filled with that electricity is specified electric quantity 1.25~ 3.8 again.
Two, which fill the stage, puts stage gradually slow raising charging current to five, while low current being used alternatingly in charging process Discharge depolarization, the utilization ratio of intensified charging electric current allow most active materials to convert completely, and two, which fill the stage, puts rank to five Section is filled with 1.25~3.8 times of net charge volume specified electric quantity.Six to nine charge and discharge stages passed through continuous charge and discharge pulse formation solution The hickie phenomenon for positive plate surface of having determined improves battery performance and cycle life.Nine put the stage as battery capacity detection and electricity Pond combo discharge regime, ten fill the stage to supplement capacitance Restoration stage after battery discharge.
Therefore, the present invention has the advantages that:Solve the problems, such as that power type being difficult to of colloid battery is saturating, It can guarantee that the chemical conversion of colloid battery positive plate is uniform, active material conversion is abundant, improves colloid battery and is internalized into quality.The work simultaneously Skill is always melted into the time as 27~55h before the detection of the 9th discharge capacity and combo electric discharge, and total net charge volume is rated capacity 3.4~8.75 times, battery charge and chemical conversion time are reduced, enhancing battery is effectively filled with electricity, improves power colloid battery Production capacity is produced, battery production cost is reduced and improves production efficiency, improve battery competitiveness in the market.
Specific implementation mode
Below by specific embodiment, the technical solutions of the present invention will be further described.
In the present invention, if not refering in particular to, all devices and raw material is commercially available or the industry is common are following Method in embodiment is unless otherwise instructed this field conventional method.
The embodiment of the present invention uses 6-DZM-20, and (rated capacity is the electric boosted automobile-used power colloid lead acid storage battery of 20Ah For pond.
Embodiment 1
Colloidal electrolyte is added in accumulator:First use the concentrated sulfuric acid, pure water (conductivity is less than 2 μ S/cm), sodium sulphate, sulfuric acid sub- Tin is configured to sulfuric acid mass fraction 37.5%, sodium sulphate 1.5%, the electrolyte of stannous sulfate 0.5%, then side sheared edge addition Aerosil is configured to colloid concentration 2.5%, and the colloidal electrolyte of 1.250~1.260g/ml of sulfuric acid electrolyte density is matched The colloidal electrolyte set is added to by priming by vacuum mode in battery, and 0.5h is stood, and the temperature of accumulator is controlled at 25 DEG C, Chemical conversion program includes the following steps successively:
(1) one fills the stage:First with 0.1C electric currents charging 5h, then with 0.15C electric currents charging 5h;It is specified that one stage of filling, which was filled with electricity, 1.25 times of capacity;
(2) one put the stage:With 0.1C current discharges 1h;
(3) two fill the stage:With 0.15C electric currents charging 5h;
(4) two put the stage:With 0.1C current discharges 1h;
(5) three fill the stage:With 0.2C electric currents charging 4h;
(6) three put the stage:With 0.1C current discharges 1h;
(7) four fill the stage:With 0.25C electric currents charging 4h;
(8) four put the stage:With 0.1C current discharges 1h;
(9) five fill the stage:With 0.3C electric currents charging 4h;
(10) five put the stage:With 0.1C current discharges 1h;Two fill stage to five stages of putting be filled with electricity be specified electric quantity 3.35 Times;
(11) six fill the stage:With 0.15C electric currents charging 4h;
(12) six put the stage:With 0.2C current discharges 0.5h;
(13) seven fill the stage:With 0.15C electric currents charging 4h;
(14) seven put the stage:With 0.1C current discharges 1h;
(15) eight fill the stage:With 0.15C electric currents charging 4h;
(16) eight put the stage:With 0.1C current discharges 1h;
(17) nine fill the stage:With 0.15C electric currents charging 4h;
(18) nine put the stage:With 0.5C current discharges to 1.75V/ single lattices;
(19) ten fill the stage:First with 0.25C electric currents charging 5h, then with 0.1C electric currents charging 2h;
(20) stage is stood:Stand 0.5h;
(21) acid phase is taken out:To carry out taking out acid after 0.02C constant-current charges 3h.
Embodiment 2
Be added colloidal electrolyte in accumulator, stand 1h, the temperature of accumulator is controlled at 30 DEG C, chemical conversion program include successively with Lower step:
(1) one fills the stage:First with 0.15C electric currents charging 3h, then with 0.2C electric currents charging 3h;It is specified that one stage of filling, which was filled with electricity, 1.05 times of capacity;
(2) one put the stage:With 0.2C current discharges 0.5h;
(3) two fill the stage:With 0.2C electric currents charging 3h;
(4) two put the stage:With 0.2C current discharges 0.5h;
(5) three fill the stage:With 0.25C electric currents charging 2h;
(6) three put the stage:With 0.2C current discharges 0.5h;
(7) four fill the stage:With 0.3C electric currents charging 2h;
(8) four put the stage:With 0.2C current discharges 0.5h;
(9) five fill the stage:With 0.35C electric currents charging 2h;
(10) five put the stage:With 0.2C current discharges 0.5h;Two fill stage to five stages of putting be filled with electricity be specified electric quantity 2 Times;
(11) six fill the stage:With 0.25C electric currents charging 2h;
(12) six put the stage:With 0.2C current discharges 0.5h;
(13) seven fill the stage:With 0.25C electric currents charging 2h;
(14) seven put the stage:With 0.2C current discharges 0.5h;
(15) eight fill the stage:With 0.25C electric currents charging 2h;
(16) eight put the stage:With 0.2C current discharges 0.5h;
(17) nine fill the stage:With 0.25C electric currents charging 2h;
(18) nine put the stage:With 0.5C current discharges to 1.75V/ single lattices;
(19) ten fill the stage:First with 0.35C electric currents charging 3h, then with 0.15C electric currents charging 1h;
(20) stage is stood:Stand 1h;
(21) acid phase is taken out:To carry out taking out acid after 2~3h of 0.04C constant-current charges.
Embodiment 3
Colloidal electrolyte is added in accumulator, stands 0.75h, the temperature of accumulator is controlled at 45 DEG C, and chemical conversion program is wrapped successively Include following steps:
(1) one fills the stage:First with 0.125C electric currents charging 4h, then with 0.15C electric currents charging 3h;It is volume that one stage of filling, which was filled with electricity, 0.95 times of constant volume;
(2) one put the stage:With 0.1C current discharges 0.75h;
(3) two fill the stage:With 0.175 electric current charging 3h;
(4) two put the stage:With 0.15C current discharges 0.5h;
(5) three fill the stage:With 0.2C electric currents charging 4h;
(6) three put the stage:With 0.15C current discharges 0.5h;
(7) four fill the stage:With 0.25C electric currents charging 4h;
(8) four put the stage:With 0.15C current discharges 0.5h;
(9) five fill the stage:With 0.35C electric currents charging 4h;
(10) five put the stage:With 0.15C current discharges 0.5h;Two fill stage to five stages of putting, and to be filled with electricity be specified electric quantity 3.425 again;
(11) six fill the stage:With 0.175C electric currents charging 3h;
(12) six put the stage:With 0.2C current discharges 0.5h;
(13) seven fill the stage:With 0.175C electric currents charging 3h;
(14) seven put the stage:With 0.2C current discharges 0.5h;
(15) eight fill the stage:With 0.175C electric currents charging 3h;
(16) eight put the stage:With 0.2C current discharges 0.5h;
(17) nine fill the stage:With 0.175C electric currents charging 3h;
(18) nine put the stage:With 0.5C current discharges to 1.75V/ single lattices;
(19) ten fill the stage:First with 0.35C electric currents charging 4h, then with 0.15C electric currents charging 2h;
(20) stage is stood:Stand 0.5h;
(21) acid phase is taken out:To carry out taking out acid after 0.03C constant-current charges 2h.
Comparative example
Comparative example is melted into using workshop common process:
Colloidal electrolyte is added in accumulator, stands 1.5h, the temperature of accumulator is controlled at 50 DEG C, and chemical conversion program includes successively Following steps:
(1) one fills the stage:First with 0.075C electric currents charging 2h;
(2) two fill the stage:With 0.185C electric currents charging 35h;
(3) three fill the stage:With 0.14C electric currents charging 15h;
(4) one put the stage:With 0.25C current discharges 3h;
(5) four fill the stage:With 0.175C electric currents charging 20h;
(6) five fill the stage:With 0.125C current discharges 20h;
(7) two put the stage:With 0.25C current discharges 5h;
(8) two put the stage:Then with 0.5C current discharges to 1.75v/ single lattices;
(9) six fill the stage:With 0.175C electric currents charging 8h;
(10) seven fill the stage:With 0.125C electric currents charging 10h;
(11) it stands:2h;
(12) acid is taken out:With 0.1C electric currents, pressure limiting 2.5v/ single lattices charging 2h;.
The colloid storage battery and comparative example obtained to embodiment 1-3 colloid power container formation process for lead acid storage battery is internalized into Technique obtains colloid storage battery, by GB/T 22199-2008《Sealing lead acid storage battery for electric vehicle》And other countries' mark Standard carries out performance detection, and the results are shown in Table 1:
1. testing result of table
As can be seen from Table 1, the colloid storage battery that colloid power container formation process for lead acid storage battery through the invention obtains Performance indicator meets national standard, and the performance of the colloid being melted into the method in other respects is melted into also superior to conventional method Battery reduces battery charge and chemical conversion time, and enhancing battery is effectively filled with electricity, improves the production production of power colloid battery Can, it reduces battery production cost and improves production efficiency, improve battery competitiveness in the market.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the present invention in any form, and is not surpassing There are other variations and modifications under the premise of going out the technical solution recorded in claim.

Claims (4)

1. a kind of colloid power container formation process for lead acid storage battery, which is characterized in that colloidal electrolyte is added in accumulator, it is quiet .5~1h is set to 0, chemical conversion program includes the following steps successively:
(1) one fills the stage:First with 0.1~0.15C electric currents, 3~5h of charging, then with 0.15~0.2C electric currents charging, 3~5h;
(2) one put the stage:With 0.1~0.2C current discharges, 0.5~1h;
(3) two fill the stage:With 0.15~0.2C electric currents charging, 3~5h;
(4) two put the stage:With 0.1~0.2C current discharges, 0.5~1h;
(5) three fill the stage:With 0.2~0.25C electric currents charging, 2~4h;
(6) three put the stage:With 0.1~0.2C current discharges, 0.5~1h;
(7) four fill the stage:With 0.25~0.3C electric currents charging, 2~4h;
(8) four put the stage:With 0.1~0.2C current discharges, 0.5~1h;
(9) five fill the stage:With 0.3~0.35C electric currents charging, 2~4h;
(10) five put the stage:With 0.1~0.2C current discharges, 0.5~1h;
(11) six fill the stage:With 0.15~0.25C electric currents charging, 2~4h;
(12) six put the stage:With 0.5~1h of 0.2C current discharges;
(13) seven fill the stage:With 0.15~0.25C electric currents charging, 2~4h;
(14) seven put the stage:With 0.1~0.2C current discharges, 0.5~1h;
(15) eight fill the stage:With 0.15~0.25C electric currents charging, 2~4h;
(16) eight put the stage:With 0.1~0.2C current discharges, 0.5~1h;
(17) nine fill the stage:With 0.15~0.25C electric currents charging, 2~4h;
(18) nine put the stage:With 0.5C current discharges to 1.75V/ single lattices;
(19) ten fill the stage:First with 0.25~0.35C electric currents, 3~5h of charging, then with 0.1~0.15C electric currents charging, 1~2h;
(20) stage is stood:Stand 0.5~1h;
(21) acid phase is taken out:To carry out taking out acid after 0.02~0.04C constant-current charges, 2~3h.
2. a kind of colloid power container formation process for lead acid storage battery according to claim 1, which is characterized in that formation process In, the temperature of accumulator is controlled at 25~50 DEG C.
3. a kind of colloid power container formation process for lead acid storage battery according to claim 1 or 2, which is characterized in that step (1) in, a stage of filling is filled with 0.75~1.75 times that electricity is rated capacity.
4. a kind of colloid power container formation process for lead acid storage battery according to claim 1 or 2, which is characterized in that step (2) to (10), two fill stage to five stages of putting, and to be filled with electricity be 1.25~3.8 times of specified electric quantity.
CN201810264825.2A 2018-03-28 2018-03-28 Internal formation process of colloid power lead-acid storage battery Active CN108598609B (en)

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CN109148992A (en) * 2018-11-29 2019-01-04 湖南丰日电源电气股份有限公司 Tubular colloidal battery rapid internalization is at technique
CN109659638A (en) * 2018-12-18 2019-04-19 超威电源有限公司 A kind of power type lead storage battery high current chemical synthesis technology
CN110085933A (en) * 2019-03-26 2019-08-02 天能电池集团股份有限公司 A kind of lead storage battery method for group matching
CN111477982A (en) * 2020-04-15 2020-07-31 天能电池(芜湖)有限公司 Formation process of low-charging-rate CNF battery for energy storage
CN113471560A (en) * 2021-06-29 2021-10-01 浙江巨江电源制造有限公司 Formation method of horizontal lead-acid storage battery

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CN109148992A (en) * 2018-11-29 2019-01-04 湖南丰日电源电气股份有限公司 Tubular colloidal battery rapid internalization is at technique
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CN110085933A (en) * 2019-03-26 2019-08-02 天能电池集团股份有限公司 A kind of lead storage battery method for group matching
CN111477982A (en) * 2020-04-15 2020-07-31 天能电池(芜湖)有限公司 Formation process of low-charging-rate CNF battery for energy storage
CN113471560A (en) * 2021-06-29 2021-10-01 浙江巨江电源制造有限公司 Formation method of horizontal lead-acid storage battery

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