CN104218263B - A kind of power type colloid battery internal formation process - Google Patents

A kind of power type colloid battery internal formation process Download PDF

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Publication number
CN104218263B
CN104218263B CN201410401252.5A CN201410401252A CN104218263B CN 104218263 B CN104218263 B CN 104218263B CN 201410401252 A CN201410401252 A CN 201410401252A CN 104218263 B CN104218263 B CN 104218263B
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China
Prior art keywords
stage
charging
fill
battery
charge
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CN201410401252.5A
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CN104218263A (en
Inventor
万南红
马永泉
朱军平
刘孝伟
陈体衔
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Chaowei Power Supply Co Ltd
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Chaowei Power Supply Co Ltd
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/06—Lead-acid accumulators
    • H01M10/12—Construction or manufacture
    • H01M10/121—Valve regulated lead acid batteries [VRLA]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/14—Electrodes for lead-acid accumulators
    • H01M4/16—Processes of manufacture
    • H01M4/20—Processes of manufacture of pasted electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

The invention discloses a kind of power type colloid battery internal formation process, use four to fill three and put chemical synthesis technology, the charging current in each discharge and recharge stage, charging interval have been also carried out optimizing simultaneously, and the stage of filling that sets further is filled with electricity as 6.5 to 7.5 times of rated capacity, it is ensured that the positive plate overwhelming majorityization is saturating；Two stages of filling were filled with 2.6 to 3 times that electricity is rated capacity；Converting again of two shallow discharges put, beneficially active substance, solves the white macula phenomenon on positive plate surface.Therefore the internal formation process of the present invention can effectively solve the problem that the difficult problem that power type being difficult to of colloid battery is saturating, can guarantee that the chemical conversion of colloid battery positive plate uniformly, and active substance conversion fully, improves colloid battery and is internalized into quality.

Description

A kind of power type colloid battery internal formation process
Technical field
The invention belongs to battery technology field, be specifically related to container formation technique.
Background technology
The chemical synthesis technology of lead-acid accumulator is internalized into and tank formation two kinds, and tank formation is due to its problem of environmental pollution, Gradually banned.Existing power type AGM valve-regulated lead-acid battery generally uses three to fill two and puts internal formation process, and this technique can be protected Uniformly, active substance is fully changed in the positive plate chemical conversion of card AGM battery.The effect being internalized into can be risen by the existence of colloidal electrolyte Negative effect, colloid battery be internalized into employing above-mentioned three fill two knock off skill time, being difficult to of positive plate is saturating, and surface occurs the most in vain Speckle.
Summary of the invention
The technical problem to be solved is just to provide a kind of power type colloid battery internal formation process, effectively solves The difficult problem that certainly power type being difficult to of colloid battery is saturating, can guarantee that the chemical conversion of colloid battery positive plate uniformly, and active substance conversion is abundant, Improve colloid battery and be internalized into quality.
For solving above-mentioned technical problem, the present invention adopts the following technical scheme that a kind of power type colloid battery is internalized into work Skill, specifically includes following steps:
A, standing stage: after colloidal electrolyte adds battery, stand 1.5～2h in a water bath；
B, one fill the stage:
0.07～0.12 I2(A) charging 0.8～1.2h；
0.15～0.25 I2(A) charging 1.5～2.5h；
0.35～0.45 I2(A) charging 20～30h；
0.2～0.3 I2(A) charging 8～12h；
C, one put the stage:
-0.35～0.45 I2(A) only 11V/ it is discharged to；
D, two fill the stage:
0.35～0.45 I2(A) charging 8～12h；
0.2～0.3 I2(A) charging 6～10h；
E, two put the stage:
-0.8～1.2 I2(A) electric discharge 0.8～1.2h；
F, three fill the stage:
0.25～0.35 I2(A) charging 8～12h；
0.15～0.25 I2(A) charging 4～6h；
H, three put the stage:
-0.8～1.2I2(A) only 10.5V/ it is discharged to；
I, four fill the stage:
0.25～0.35 I2(A) charging 8～12h；
0.15～0.25 I2(A) charging 4～6h；
0A stands 0.8～1.2h；
0.15～0.25 I2(A), 15V/ constant-voltage charge 1.5～2.5h takes out acid.
Preferably, a stage of filling be filled with that electricity is battery rated capacity 6.5 to 7.5 times.
Preferably, two stages of filling be filled with that electricity is battery rated capacity 2.6 to 3 times.
Preferably, three stages of filling be filled with that electricity is battery rated capacity 1.8 to 2 times.
Preferably, during whole being internalized into, battery temperature is less than 50 DEG C.
Preferably, in described colloidal electrolyte colloidal content between 0.1%～5%.
Preferably, following steps are specifically included:
A, standing stage: after colloidal electrolyte adds battery, stand 1.5～2h in a water bath；
B, one fill the stage:
0.1 I2(A) charging 1h；
0.2 I2(A) charging 2h；
0.4 I2(A) charging 25h；
0.25 I2(A) charging 10h；
C, one put the stage:
-0.4 I2(A) only 11V/ it is discharged to；
D, two fill the stage:
0.4 I2(A) charging 10h；
0.25 I2(A) charging 8h；
E, two put the stage:
-1.0 I2(A) electric discharge 1h；
F, three fill the stage:
0.3 I2(A) charging 10h；
0.2 I2(A) charging 5h；
H, three put the stage:
-1.0 I2(A) only 10.5V/ it is discharged to；
I, four fill the stage:
0.3 I2(A) charging 10h；
0.2 I2(A) charging 5h；
0A stands 1h；
0.2 I2(A), 15V/ constant-voltage charge 2h takes out acid.
The present invention uses four to fill three and puts chemical synthesis technology, and the charging current in each discharge and recharge stage, charging interval also enter simultaneously Go optimization, and the stage of filling that sets further has been filled with electricity as 6.5 to 7.5 times of rated capacity, it is ensured that positive plate is the biggest Partization is saturating；Two stages of filling were filled with 2.6 to 3 times that electricity is rated capacity；Two shallow discharges put, beneficially active substance is again Convert, solve the white macula phenomenon on positive plate surface.
After using technique scheme, the internal formation process of the present invention can effectively solve the problem that power type being difficult to of colloid battery A saturating difficult problem, can guarantee that the chemical conversion of colloid battery positive plate uniformly, and active substance conversion fully, improves colloid battery and is internalized into matter Amount.
Detailed description of the invention
One power type colloid battery internal formation process of the present invention, specifically includes following steps:
A, standing stage: after colloidal electrolyte adds battery, stand 1.5～2h in a water bath；
B, one fill the stage:
0.07～0.12 I2(A) charging 0.8～1.2h；
0.15～0.25 I2(A) charging 1.5～2.5h；
0.35～0.45 I2(A) charging 20～30h；
0.2～0.3 I2(A) charging 8～12h；
C, one put the stage:
-0.35～0.45 I2(A) only 11V/ it is discharged to；
D, two fill the stage:
0.35～0.45 I2(A) charging 8～12h；
0.2～0.3 I2(A) charging 6～10h；
E, two put the stage:
-0.8～1.2 I2(A) electric discharge 0.8～1.2h；
F, three fill the stage:
0.25～0.35 I2(A) charging 8～12h；
0.15～0.25 I2(A) charging 4～6h；
H, three put the stage:
-0.8～1.2I2(A) only 10.5V/ it is discharged to；
I, four fill the stage:
0.25～0.35 I2(A) charging 8～12h；
0.15～0.25 I2(A) charging 4～6h；
0A stands 0.8～1.2h；
0.15～0.25 I2(A), 15V/ constant-voltage charge 1.5～2.5h takes out acid.
It is described further below in conjunction with specific embodiment.
In embodiment 1: this power type colloid battery internal formation process, comprise the following steps:
A, standing stage
After colloidal electrolyte adds battery, stand 1.5～2h in a water bath.
B, one fill the stage
0.1 I2(A) charging 1h；
0.2 I2(A) charging 2h；
0.4 I2(A) charging 25h；
0.25 I2(A) charging 10h.
C, one put the stage
-0.4 I2(A) only 11V/ it is discharged to.
D, two fill the stage
0.4 I2(A) charging 10h；
0.25 I2(A) charging 8h；
E, two put the stage
-1.0 I2(A) electric discharge 1h
F, three fill the stage
0.3 I2(A) charging 10h；
0.2 I2(A) charging 5h；
H, three put the stage
-1.0 I2(A) only 10.5V/ it is discharged to
I, four fill the stage
0.3 I2(A) charging 10h；
0.2 I2(A) charging 5h；
0A stands 1h；
0.2 I2(A), 15V/ constant-voltage charge 2h takes out acid.
One stage of filling was filled with 6.5 to 7.5 times that electricity is rated capacity, it is ensured that the positive plate overwhelming majorityization is saturating；Two fill rank Section is filled with 2.6 to 3 times that electricity is rated capacity；Converting again of two shallow discharges put, beneficially active substance, solves positive pole The white macula phenomenon on plate surface；Three stages of filling were filled with 1.8 to 2 times that electricity is rated capacity；Whole charging process battery temp Less than 50 DEG C；Colloidal electrolyte colloidal content is between 0.1%～5%.
In embodiment 2: this power type colloid battery internal formation process, comprise the following steps:
A, standing stage: after colloidal electrolyte adds battery, stand 1.5～2h in a water bath；
B, one fill the stage:
0.07 I2(A) charging 1.2h；
0.15 I2(A) charging 2.5h；
0.35I2(A) charging 30h；
0.2 I2(A) charging 12h；
C, one put the stage:
-0.35 I2(A) only 11V/ it is discharged to；
D, two fill the stage:
0.35 I2(A) charging 12h；
0.2 I2(A) charging 10h；
E, two put the stage:
-0.8I2(A) electric discharge 1.2h；
F, three fill the stage:
0.25 I2(A) charging 12h；
0.15I2(A) charging 6h；
H, three put the stage:
-0.8I2(A) only 10.5V/ it is discharged to；
I, four fill the stage:
0.25 I2(A) charging 12h；
0.15 I2(A) charging 6h；
0A stands 1.2h；
0.15 I2(A), 15V/ constant-voltage charge 2.5h takes out acid.
In embodiment 3: this power type colloid battery internal formation process, comprise the following steps:
A, standing stage: after colloidal electrolyte adds battery, stand 1.5～2h in a water bath；
B, one fill the stage:
0.12 I2(A) charging 0.8h；
0.25 I2(A) charging 1.5h；
0.45 I2(A) charging 20h；
-0.3 I2(A) charging 8h；
C, one put the stage:
0.45 I2(A) only 11V/ it is discharged to；
D, two fill the stage:
0.45 I2(A) charging 8h；
0.3 I2(A) charging 6h；
E, two put the stage:
-1.2 I2(A) electric discharge 0.8h；
F, three fill the stage:
0.35 I2(A) charging 8h；
0.25 I2(A) charging 4h；
H, three put the stage:
-1.2I2(A) only 10.5V/ it is discharged to；
I, four fill the stage:
0.35 I2(A) charging 8h；
0.25 I2(A) charging 4h；
0 A stands 0.8h；
0.25 I2(A), 15V/ constant-voltage charge 1.5h takes out acid.

Claims (4)

1. a power type colloid battery internal formation process, it is characterised in that specifically include following steps:
A, standing stage: after colloidal electrolyte adds battery, stand 1.5～2h in a water bath；
B, one fill the stage:
0.07~0.12 I2(A) charging 0.8 ~ 1.2h；
0.15~0.25 I2(A) charging 1.5 ~ 2.5 h；
0.35~0.45 I2(A) charging 20 ~ 30 h；
0.2~0.3 I2(A) charging 8 ~ 12 h；
C, one put the stage:
-0.35 ~ 0.45 I2(A) only 11V/ it is discharged to；
D, two fill the stage:
0.35~0.45 I2(A) charging 8 ~ 12 h；
0.2~0.3 I2(A) charging 6 ~ 10 h；
E, two put the stage:
-0.8 ~ 1.2 I2(A) electric discharge 0.8 ~ 1.2h；
F, three fill the stage:
0.25~0.35 I2(A) charging 8 ~ 12 h；
0.15~0.25 I2(A) charging 4 ~ 6 h；
H, three put the stage:
-0.8 ~ 1.2I2(A) only 10.5V/ it is discharged to；
I, four fill the stage:
0.25~0.35 I2(A) charging 8 ~ 12 h；
0.15~0.25 I2(A) charging 4 ~ 6 h；
0 A stands 0.8 ~ 1.2h；
0.15~0.25 I2(A), 15V/ constant-voltage charge 1.5 ~ 2.5 h takes out acid；
Wherein, a stage of filling is filled with 6.5 to 7.5 times that electricity is battery rated capacity, and it is battery volume that two stages of filling were filled with electricity 2.6 to 3 times of constant volume, three stages of filling were filled with 1.8 to 2 times that electricity is battery rated capacity.
Power type colloid battery internal formation process the most according to claim 1, it is characterised in that: it is internalized into process whole Middle battery temperature is less than 50 DEG C.
Power type colloid battery internal formation process the most according to claim 2, it is characterised in that: in described colloidal electrolyte Colloidal content is between 0.1%～5%.
Power type colloid battery internal formation process the most according to claim 1, it is characterised in that specifically include following steps:
A, standing stage: after colloidal electrolyte adds battery, stand 1.5～2h in a water bath；
B, one fill the stage:
0.1 I2(A) charging 1h；
0.2 I2(A) charge 2 h；
0.4 I2(A) charge 25 h；
0.25 I2(A) charge 10 h；
C, one put the stage:
-0.4 I2(A) only 11V/ it is discharged to；
D, two fill the stage:
0.4 I2(A) charge 10 h；
0.25 I2(A) charge 8 h；
E, two put the stage:
-1.0 I2(A) electric discharge 1h；
F, three fill the stage:
0.3 I2(A) charge 10 h；
0.2 I2(A) charge 5 h；
H, three put the stage:
-1.0 I2(A) only 10.5V/ it is discharged to；
I, four fill the stage:
0.3 I2(A) charge 10 h；
0.2 I2(A) charge 5 h；
0 A stands 1 h；
0.2 I2(A), 15V/ constant-voltage charge 2 h takes out acid.
CN201410401252.5A 2014-08-14 2014-08-14 A kind of power type colloid battery internal formation process Active CN104218263B (en)

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CN104218263B true CN104218263B (en) 2016-08-24

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104900923A (en) * 2015-04-03 2015-09-09 超威电源有限公司 Colloid lead acid battery inner formation method
CN108110333B (en) * 2017-11-06 2019-09-20 超威电源有限公司 A kind of lead-acid accumulator low temperature is internalized into test method
CN108598609B (en) * 2018-03-28 2020-09-01 超威电源集团有限公司 Internal formation process of colloid power lead-acid storage battery
CN108963367A (en) * 2018-08-24 2018-12-07 江苏超威电源有限公司 Colloid power lead-acid accumulator chemical synthesis technology

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102368567A (en) * 2011-10-13 2012-03-07 超威电源有限公司 Formation method for dynamic lead-acid cell jar formation
CN102437380A (en) * 2011-12-06 2012-05-02 河南超威电源有限公司 Method for internal chemical reaction in battery via charging five times and discharging four times
CN102593533A (en) * 2012-03-15 2012-07-18 超威电源有限公司 Method for internalizing valve-regulated lead acid storage battery

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102368567A (en) * 2011-10-13 2012-03-07 超威电源有限公司 Formation method for dynamic lead-acid cell jar formation
CN102437380A (en) * 2011-12-06 2012-05-02 河南超威电源有限公司 Method for internal chemical reaction in battery via charging five times and discharging four times
CN102593533A (en) * 2012-03-15 2012-07-18 超威电源有限公司 Method for internalizing valve-regulated lead acid storage battery

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