CN104163735A - soluble particle sulphur fertilizer and manufacture method for the same - Google Patents
soluble particle sulphur fertilizer and manufacture method for the same Download PDFInfo
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- CN104163735A CN104163735A CN201410098125.2A CN201410098125A CN104163735A CN 104163735 A CN104163735 A CN 104163735A CN 201410098125 A CN201410098125 A CN 201410098125A CN 104163735 A CN104163735 A CN 104163735A
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- sulphur
- weight
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- wilkinite
- sulphur fertilizer
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
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- Pest Control & Pesticides (AREA)
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Abstract
The invention provides a soluble particle sulphur fertilizer and a manufacture method for the same. The soluble particle sulphur fertilizer consists of 88 weight parts-93 weight parts of sulphur and 7 weight parts%-12 weight parts of bentonite. According to the manufacture method of the invention, the soluble particle sulphur fertilizer can be uniform through accurately mixing and produce quality product without foam removing agents, can perform continuous production in short time, can perform batch production. The particle sulphuer produced by the invention has fast-acting property and slow action property which are applicable to the breeding of the crops.
Description
Technical field
The present invention relates to sol particle type sulphur fertilizer and manufacture method thereof, more particularly, relate to the sol particle type sulphur fertilizer and the manufacture method thereof that are formed by the sulphur of 88 % by weight～93 % by weight and the wilkinite of 7 % by weight～12 % by weight.
Background technology
Sulphur (sulphur) is as the one in main and necessary nutrient for plants, very large to the output contribution of crop.It was reported title, sulphur is not only three seed amino acids in breeding plant, the i.e. constituent of Gelucystine, halfcystine, methionine(Met), and be necessary composition in the nodule formation of leguminous crop, in the time lacking this composition, can suppress breeding plant, and this composition also there are much relations for harvest and the quality of farm crop.In addition, the great advantage of sulphur fertilizer is to be to be applicable to the acidity that crop breeds by the acidity adjustment of soil, thereby increases soil fertility.
But the fusing point of sulphur is 118 DEG C, insoluble in the water of normal temperature, therefore when for agricultural, there is inconvenience.
In order to improve the problem of this sulphur, attempting mixing in sulphur appends composition and produces corpuscular sulphur fertilizer, but mixing is in the past to stir constantly for a long time in the larger cylinder (Pit) that stirrer and impeller are installed, thereby many batches ofly manufacture (one batch).But during two kinds of materials that as mentioned above proterties differed from one another mix with batch mode, cause deposited phenomenon at cylinder interior, and expended a lot of time.And, although mix for a long time, can not realize uniform mixing, and because agglomerating phenomenon is given the moulding of subsequent handling and brought detrimentally affect.
Therefore, require to develop a kind of evenly mixed sulphur fertilizer and manufacture method thereof of decomposing in water of being incorporated in of appending composition that proterties is different that realize always.
Summary of the invention
To this, in the result of inventor's lucubrate, the granule type sulphur fertilizer of having found sulphur and wilkinite (Bentonite) to mix under given conditions with the weight ratio of about 9:1 and manufacture has solubility (quick-acting and slow) in water, possesses excellent characteristic as the fertilizer of crop, and also excellent as soil improvement agent, complete thus the present invention.
The sol particle type sulphur fertilizer (Soluble flake typed sulphur fertilizer) that provides the wilkinite of a kind of sulphur by 88 % by weight～93 % by weight and 7 % by weight～12 % by weight to form is provided.
Another object of the present invention is to, the manufacture method of the sol particle type sulphur fertilizer being made up of the sulphur of 88 % by weight～93 % by weight and the wilkinite of 7 % by weight～12 % by weight is provided.
In order to realize the object of the invention described above, the invention provides the manufacture method of sol particle type sulphur fertilizer, the method comprises the steps:
I) after liquid sulphur is filtered with 5 order～20 orders, be supplied to stirrer (Inline mixer) with the mass flow rate of 4000Kg/hr～10000Kg/hr, supply with pulverous wilkinite with 300Kg/hr～1360Kg/hr simultaneously;
Ii) in stirrer, sulphur and wilkinite are mixed 0.6 second～6.0 seconds with 3000rpm～3600rpm;
Iii) be shaped to the particle form of suitable size; And
Iv) the particle of moulding is cooled to 1 DEG C～35 DEG C.
step I) supply with
After liquid sulphur is filtered with 5 order～20 orders, with mass flow rate (the Mass flow rate of 4000Kg/hr～10000Kg/hr, consider that the proportion of sulphur is 1.8) (flow rate approximately 2.2 tons/hr～approximately 5.6 ton/hr) be supplied to stirrer (Inline mixer), supplies with pulverous wilkinite with the feed speed of 300Kg/hr～1360Kg/hr simultaneously.
In the present invention, the proterties of sulphur is liquid state, and bentonitic proterties is solid (powder).
Before supplying with, the fusing point of liquid sulphur is 118 DEG C, therefore in order to maintain molten state, the cylinder (Pit) of storage is seethed with excitement always.
Liquid sulphur is filtered with approximately 5 order～20 orders and remove impurity.
About stirrer, specifically do not limit, possess but preferably use the stirrer that water level signal shows (LI), temperature signal demonstration (TI) and flow signal demonstration (FI), agitator and vapor pipe in series-operation.
Liquid-state sulfur is with mass flow rate (the Mass flow rate of 4000Kg/hr～10000Kg/hr, consider the proportion 1.8 of sulphur) (flow rate approximately 2.2 tons/hr～approximately 5.6 ton/hr) be supplied to stirrer, in the time that mass flow rate exceedes 10000Kg/hr, feed rate too much produces obstruction (Plugging) phenomenon of overflowing (Over flow) phenomenon and pipeline in stirrer, and in the time that mass flow rate is less than 4000Kg/hr, feed rate reduces, and in stirrer, can not realize uniform mixing.
About pulverous wilkinite, although be not limited to this, in series-operation, be preferably and in unloading (Unloading) system of jumbo bag (Ton Bag), measure and automatically put into stirrer.
Pulverous wilkinite is supplied with the feed speed of 300Kg/hr～1360Kg/hr, and in the time that feed speed exceedes 1360Kg/hr, feed rate too much causes the color of product dark, makes the moulding variation of next operation.In the time that feed speed is less than 300Kg/hr, feed rate reduces and causes the of light color of product, makes the moulding variation of next operation.
According to the flow rate of liquid-state sulfur as above and pulverous bentonitic feed speed, sulphur-bentonitic ratio of mixture maintains sulphur 88 % by weight～93 % by weight and wilkinite 7 % by weight～12 % by weight.
step I i) is mixed
In stirrer, sulphur and wilkinite are mixed 0.6 second～6.0 seconds with 3000rpm～3600rpm.
Bentoniticly more than 85% formed by montmorillonite (Montmorillonite forms a group of mineral of polynite/clay), therefore, compared with other materials, there is the extra high characteristic of viscosity.Only have the mixing of the material at short notice with this specific character, can improve the effect of mixing.Therefore,, in stirrer of the present invention, transfer within the short period of time (0.6 second～6.0 seconds), liquid sulphur and solid-state wilkinite to be mixed equably with 3000rpm～3600rpm high-speed rotary.
step I is moulding ii)
Use general forming machine and be the suitable particle form of size by the sulphur-wilkinite mixture forming mixing in i) in step I.
About suitable size, limit, but be preferably diameter 2.5mm～5mm, height 1.2mm～1.8mm, and particle form can be beans (pea) form of splitting.
step I is v) cooling
By step I ii) in the sulphur fertilizer of particle form of moulding under 1 DEG C～35 DEG C (room temperature), carry out cooling.
Although be not limited to this, for series-operation, also can by cooling bring carry out cooling.
After cooling step, as required, further implement the step that the sulphur fertilizer of the particle form of manufacture is transferred and measured and packs.
Decompose absorbing when moisture according to the granule type sulphur fertilizer of manufacture method manufacture as above, and in latter 6 months of fertilising sulphur 80% be converted to the SO that crop can absorb
4 -2.When the wilkinite that contains at sulphur fertilizer of the present invention absorbs moisture and when swelling, sulfur granules is decomposed into imperceptibly to the sulphur particle of 20 μ m～200 μ m scopes, and Quick Oxidation and be converted to the available vitriol of plant (sulphate).Granule type sulphur fertilizer of the present invention does not have dust in addition, health and health in the time of fertilising.
As another example of the present invention, provide the sol particle type sulphur being formed by the sulphur of 88 % by weight～93 % by weight and the wilkinite of 7 % by weight～12 % by weight fertilizer.
Wilkinite reduces the resistive of sulphur in bulk (Bulk sulfur), reduces the tendency that sulphur in bulk keeps static charge, thereby reduces the possibility of fire.In sulphur fertilizer of the present invention, if wilkinite is less than 7 % by weight, the speed that absorbs moisture is slow, quick-acting as sulphur-bentonitic characteristic declines, if and wilkinite exceedes 12 % by weight,, because the content of sulphur is relatively low, therefore the necessary nutrient substance of plant reduces, and causes crop to breed slowly.
Manufacturing method according to the invention, realizes homogeneity with accurate mixed effect, and product that can production high-quality, without defoamer, is produced at short notice continuously, therefore can produce in a large number.
Granule type sulphur fertilizer constructed in accordance has and is suitable for quick-acting that crop breeds and the feature of slow.In latter 6 months of fertilising, 80% is converted to the SO that crop can absorb
4 -2form, the pol of raising apple, pears, peach, grape, persimmon, chestnut, oranges and tangerines, plum etc., makes color good, in the crops such as garlic, onion, ginger, increase sulfur-containing amino acid, possess thus unique fragrance, and improve the storage in house, can cultivating high quality agricultural-food.
The sugar and the Vitamin C content that improve the leaf vegetabless such as radish, Chinese cabbage, improve intrinsic taste, productivity gain, and output, starch value, the reducing sugar content of raising potato, with the potato of production high-quality.In addition, improve the crop absorption ratio of phosphorus, potassium, calcium, boron, iron, magnesia, lead etc., and sulphur amount is about 90%, concentration is high, and therefore rate of fertilizer application is few, thereby can save labor force and expense.
Brief description of the drawings
Fig. 1 is the manufacturing procedure picture of an example of manufacture method of the present invention.
Fig. 2 is the photo of the granule type sulphur fertilizer of manufacture in Production Example 1～4.
Fig. 3 a and Fig. 3 b are the photos that is illustrated in Production Example 4 test that the granule type sulphur fertilizer manufactured and general sulphur fertilizer in the past dissolves in water and the test of dissolving that the wilkinite of different content is carried out in water.
Fig. 4 a, Fig. 4 b and Fig. 4 c are the photos that is illustrated in the fertilising result of the granule type sulphur fertilizer of manufacturing in Production Example 4.
Embodiment
For the ease of understanding the present invention, further describe formation of the present invention and effect by specific embodiment below.But following embodiment is only used to more be expressly understood the present invention and the illustration of carrying out, interest field of the present invention is not limited to following embodiment.
Embodiment
production Example 1
After the liquid-state sulfur of storage cylinder that is stored at 130 DEG C is filtered with 10 orders, mass flow rate (3.5 tons/hr of flow rate) with 6300Kg/hr is supplied to stirrer (Inline mixer, the IKA of manufacturing company), pulverous wilkinite is equivalent to 8.0 % by weight with 548Kg/hr(simultaneously) feed speed be supplied to stirrer, afterwards sulphur and wilkinite are mixed in stirrer with 3600rpm approximately 0.6 second, then after being shaped to the spheroidal particle form of diameter 3mm, highly about 1.5mm, carrying out at room temperature cooling and manufactured granule type sulphur fertilizer.Fig. 2 illustrates the photo of the granule type sulphur fertilizer of manufacturing.
production Example 2
After the liquid-state sulfur of storage cylinder that is stored at 130 DEG C is filtered with 10 orders, mass flow rate (3.5 tons/hr of flow rate) with 6300Kg/hr is supplied to stirrer (Inline mixer, the IKA of manufacturing company), pulverous wilkinite being equivalent to 8.5 % by weight with 585Kg/hr(simultaneously) feed speed is supplied to stirrer, afterwards sulphur and wilkinite are mixed in stirrer with 3600rpm approximately 3 seconds, then after being shaped to the spheroidal particle form of diameter 3mm, highly about 1.5mm, carrying out at room temperature cooling and manufactured granule type sulphur fertilizer.The granule type sulphur fertilizer of manufacturing as shown in Figure 2.
production Example 3
After the liquid-state sulfur of storage cylinder that is stored at 130 DEG C is filtered with 10 orders, mass flow rate (3.5 tons/hr of flow rate) with 6300Kg/hr is supplied to stirrer (Inline mixer, the IKA of manufacturing company), pulverous wilkinite is equivalent to 9.0 % by weight with 623Kg/hr(simultaneously) feed speed be supplied to stirrer, afterwards sulphur and wilkinite are mixed in stirrer with 3600rpm approximately 4 seconds, then after being shaped to the spheroidal particle form of diameter 3mm, highly about 1.5mm, carrying out at room temperature cooling and produce granule type sulphur fertilizer.The granule type sulphur fertilizer of manufacturing as shown in Figure 2.
production Example 4
After the liquid-state sulfur of storage cylinder that is stored at 130 DEG C is filtered with 10 orders, mass flow rate (3.5 tons/hr of flow rate) with 6300Kg/hr is supplied to stirrer (Inline mixer, the IKA of manufacturing company), pulverous wilkinite being equivalent to 10 % by weight with 700Kg/hr(simultaneously) feed speed is supplied to stirrer, afterwards sulphur and wilkinite are mixed in stirrer with 3600rpm approximately 5 seconds, then after being shaped to the spheroidal particle form of diameter 3mm, highly about 1.5mm, carrying out at room temperature cooling and produce granule type sulphur fertilizer.The granule type sulphur fertilizer of manufacturing as shown in Figure 2.
production Example 5
After the liquid-state sulfur of storage cylinder that is stored at 130 DEG C is filtered with 10 orders, mass flow rate (3.5 tons/hr of flow rate) with 6300Kg/hr is supplied to stirrer (Inline mixer, the IKA of manufacturing company), pulverous wilkinite being equivalent to 11.5 % by weight with 810Kg/hr(simultaneously) feed speed is supplied to stirrer, afterwards sulphur and wilkinite are mixed in stirrer with 3600rpm approximately 6 seconds, then after being shaped to the spheroidal particle form of diameter 3mm, highly about 1.5mm, carrying out at room temperature cooling and produce granule type sulphur fertilizer.The granule type sulphur fertilizer of manufacturing as shown in Figure 2.
test example 1
By scorification analysis (Soxhlet extraction method) and these two kinds of methods of grey point-score analysis (Furnace), the granule type sulphur fertilizer in 1～3 kind of manufacture of Production Example is carried out to content analysis, and the results are shown in table 1.
[table 1]
(% is % by weight)
Soxhlet extraction method is following method: utilize experimental apparatus Soxhlet (Soxhlet) equipment to add as the toluene of solvent and till being heated to toluene and being vaporized, in three hours, make sulfur melting 12 times, and mensuration separate with wilkinite and the weight of the sulphur that extracts (because toluene fusing sulphur is limited, therefore the end value that obtained is lower than actual value), and Furnace analytical method is following method: apply the heat of 600 DEG C, make sulfur burning one hour, the method that deducts residual bentonitic content and obtain end value from 100% is (under 600 DEG C of high temperature, be not only that sulphur is burnt, and wilkinite composition also has the part of being burnt, therefore during by end value and input bentonite content addition at the beginning, exceed 100%).In these two methods, select a kind of method, and carry out 5 identical tests by selected test method, remove maximum value, minimum value and average after getting three intermediate values.
As confirmed from above-mentioned table 1, granule type sulphur fertilizer of the present invention is realized uniformly and being mixed, and all maintains certain sulphur and bentonitic content in each particle.
test example 2
By the granule type sulphur fertilizer of manufacturing in Production Example 4 and general sulphur fertilizer (ProductName: S/G in the past, manufacturing company: generation photochemistry industry (strain)) weigh 5g and put into beaker, and add the water 50ml of 20 DEG C～25 DEG C and carried out solubility test, by through the results are shown in Fig. 3 a after two hours.
Granule type sulphur fertilizer of the present invention absorbs moisture and decomposes in the process through two hours, but general sulphur fertilizer in the past is not almost dissolved in the water.
In addition, the granule type sulphur fertilizer (containing respectively wilkinite 6 % by weight, 7 % by weight, 8 % by weight, 8.5 % by weight, 9 % by weight) that manufacturing method according to the invention is manufactured weighs 5g and puts into culture dish, and add the water of 20 DEG C～25 DEG C of 50ml and carried out solubility test, by through the results are shown in Fig. 3 b after two hours.The granule type sulphur fertilizer that comprises bentonite content that belongs to scope of the present invention absorbs moisture and suitably decomposes in the process through two hours, but in the situation that comprising 6 % by weight, fails to dissolve well in water.
test example 3
Fig. 4 a is illustrated in the pickles seedtime (late August) of radish of passing the winter, using the granule type sulphur fertilizer of manufacturing in Production Example 4 as base fertilizer with 10Kg/1000m
2apply fertilizer, and carry out ploughing and weeding and dig, so that mix well with soil, the result of then sowing and gathering in the crops in mid-November, and Fig. 4 b shows at the beginning of 4 months of the lawn of golf course alley rudiment as topdressing with 4Kg/1000m
2～5Kg/1000m
2apply fertilizer, and the developmental condition result on lawn at the beginning of the period completing to the greening of lawn surface, 8 months.
As shown in Fig. 4 a and Fig. 4 b, confirm, compared with non-processor district (do not apply fertilizer and cultivate), in the treatment zone that has applied granule type sulphur fertilizer of the present invention, to cultivate radish and the lawn of high-quality.
In addition, Fig. 4 c and table 2 show the granule type sulphur fertilizer of manufacturing in Production Example 4 with the 15kg/10a result of cultivating after strawberry of applying fertilizer.
[table 2]
As confirmed from Fig. 4 c and table 2, (do not apply fertilizer and cultivate) compared with non-processor district, improve 150% in the strawberry weight of strawberry of the treatment zone that has applied granule type sulphur fertilizer of the present invention, the also phenomenal growth of root and stem, has cultivated the strawberry of high-quality.
Claims (7)
1. a manufacture method for sol particle type sulphur fertilizer, is characterized in that, the method comprises the following steps:
I) after liquid sulphur is filtered with 5 order～20 orders, be supplied to stirrer with the mass flow rate of 4000Kg/hr～10000Kg/hr, supply with pulverous wilkinite with 300Kg/hr～1360Kg/hr simultaneously;
Ii) in stirrer, sulphur and wilkinite are mixed 0.6 second～6.0 seconds with 3000rpm～3600rpm;
Iii) be shaped to particle form; And
Iv) the particle of moulding is cooled to 1 DEG C～35 DEG C.
2. method according to claim 1, is characterized in that,
Described method also comprises: step I v) after, transfer the granule type sulphur fertilizer of manufacturing the step of measuring and packing.
3. method according to claim 1, is characterized in that,
Described granule type sulphur fertilizer is made up of the sulphur of 88 % by weight～93 % by weight and the wilkinite of 7 % by weight～12 % by weight.
4. method according to claim 3, is characterized in that,
Described granule type sulphur fertilizer is made up of the sulphur of 90 % by weight and the wilkinite of 10 % by weight.
5. method according to claim 1, is characterized in that,
Described granule type sulphur fertilizer has the size of diameter 2.5mm～5mm, height 1.2mm～1.8mm.
6. a sol particle type sulphur fertilizer, it is manufactured by any one method in claim 1 to 5, is made up of the sulphur of 88 % by weight～93 % by weight and the wilkinite of 7 % by weight～12 % by weight.
7. sol particle type sulphur fertilizer according to claim 6, is characterized in that, described sol particle type sulphur fertilizer is made up of the sulphur of 90 % by weight and the wilkinite of 10 % by weight.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2013-0055899 | 2013-05-16 | ||
| KR1020130055899A KR101439262B1 (en) | 2013-05-16 | 2013-05-16 | Soluble flake typed sulphur fertilizer and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104163735A true CN104163735A (en) | 2014-11-26 |
| CN104163735B CN104163735B (en) | 2017-04-12 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410098125.2A Active CN104163735B (en) | 2013-05-16 | 2014-03-17 | Decomposable particle sulphur fertilizer and manufacture method for the same |
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| Country | Link |
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| KR (1) | KR101439262B1 (en) |
| CN (1) | CN104163735B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020087621A1 (en) * | 2018-10-31 | 2020-05-07 | 湖北富邦科技股份有限公司 | Round particle quick-acting high-concentration sulfur fertilizer and production method |
| WO2020133698A1 (en) * | 2018-12-27 | 2020-07-02 | 湖北富邦科技股份有限公司 | Multifunctional plant nutrient masterbatch and production method |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102474511B1 (en) | 2022-03-21 | 2022-12-06 | 농업회사법인 주식회사 닛시 | Beneficial sulfur that removed the toxicity of sulfur, Fertilizer, sterilization, pesticide using beneficial sulfur and manufacturing method thereof |
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| US2292140A (en) * | 1939-11-28 | 1942-08-04 | Electrolux Corp | Electric cord holder |
| US4133669A (en) * | 1977-04-20 | 1979-01-09 | Agri-Prassco Joint Venture | Process for pelletizing a sulphur-bentonite clay mixture and the product formed thereby |
| CA1054821A (en) * | 1975-09-17 | 1979-05-22 | Bob L. Caldwell | Granular sulfur-bentonite mixture for fertilizer |
| US4569859A (en) * | 1984-07-10 | 1986-02-11 | Sulpetro Limited | Process for forming prill for sulphur and bentonite |
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| KR100980707B1 (en) | 2008-02-18 | 2010-09-07 | 박운순 | The liquefied sulfuric fertilizer with radish juice and the manufacturing method thereof |
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| KR101259061B1 (en) | 2012-05-02 | 2013-04-29 | 안상표 | Granule typed sulfur fertilizer and manufacturing process thereof |
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2013
- 2013-05-16 KR KR1020130055899A patent/KR101439262B1/en active IP Right Grant
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| US2292140A (en) * | 1939-11-28 | 1942-08-04 | Electrolux Corp | Electric cord holder |
| CA1054821A (en) * | 1975-09-17 | 1979-05-22 | Bob L. Caldwell | Granular sulfur-bentonite mixture for fertilizer |
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| US4569859A (en) * | 1984-07-10 | 1986-02-11 | Sulpetro Limited | Process for forming prill for sulphur and bentonite |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020087621A1 (en) * | 2018-10-31 | 2020-05-07 | 湖北富邦科技股份有限公司 | Round particle quick-acting high-concentration sulfur fertilizer and production method |
| WO2020133698A1 (en) * | 2018-12-27 | 2020-07-02 | 湖北富邦科技股份有限公司 | Multifunctional plant nutrient masterbatch and production method |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101439262B1 (en) | 2014-09-11 |
| CN104163735B (en) | 2017-04-12 |
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