CN104150872B - The ceramic tile that a kind of Graphene strengthens - Google Patents
The ceramic tile that a kind of Graphene strengthens Download PDFInfo
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- CN104150872B CN104150872B CN201410382807.6A CN201410382807A CN104150872B CN 104150872 B CN104150872 B CN 104150872B CN 201410382807 A CN201410382807 A CN 201410382807A CN 104150872 B CN104150872 B CN 104150872B
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 72
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 69
- 239000000919 ceramic Substances 0.000 title claims abstract description 54
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 39
- -1 Wingdale Inorganic materials 0.000 claims abstract description 37
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
- 229910001868 water Inorganic materials 0.000 claims abstract description 33
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 26
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 26
- 239000002994 raw material Substances 0.000 claims abstract description 25
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 13
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 13
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 13
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims abstract description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 13
- 229960000892 attapulgite Drugs 0.000 claims abstract description 13
- 229910052796 boron Inorganic materials 0.000 claims abstract description 13
- 239000004927 clay Substances 0.000 claims abstract description 13
- 239000010431 corundum Substances 0.000 claims abstract description 13
- 229910052593 corundum Inorganic materials 0.000 claims abstract description 13
- 239000010433 feldspar Substances 0.000 claims abstract description 13
- 239000000835 fiber Substances 0.000 claims abstract description 13
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 13
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 13
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 13
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 13
- 230000003647 oxidation Effects 0.000 claims abstract description 13
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 13
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 13
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims abstract description 13
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 13
- 239000011591 potassium Substances 0.000 claims abstract description 13
- 239000010453 quartz Substances 0.000 claims abstract description 13
- FKTOIHSPIPYAPE-UHFFFAOYSA-N samarium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Sm+3].[Sm+3] FKTOIHSPIPYAPE-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004576 sand Substances 0.000 claims abstract description 13
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 13
- 239000011734 sodium Substances 0.000 claims abstract description 13
- 239000000454 talc Substances 0.000 claims abstract description 13
- 235000012222 talc Nutrition 0.000 claims abstract description 13
- 229910052623 talc Inorganic materials 0.000 claims abstract description 13
- 238000005496 tempering Methods 0.000 claims abstract description 13
- GWYXTVGANSBRNB-UHFFFAOYSA-N terbium(iii) oxide Chemical compound O=[Tb]O[Tb]=O GWYXTVGANSBRNB-UHFFFAOYSA-N 0.000 claims abstract description 13
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 13
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims abstract description 13
- 239000011787 zinc oxide Substances 0.000 claims abstract description 13
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000002082 metal nanoparticle Substances 0.000 claims abstract description 12
- 238000005507 spraying Methods 0.000 claims abstract description 11
- 238000000498 ball milling Methods 0.000 claims description 60
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 40
- 238000010304 firing Methods 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 20
- 239000000758 substrate Substances 0.000 claims description 14
- 238000002360 preparation method Methods 0.000 claims description 12
- 230000032683 aging Effects 0.000 claims description 10
- 238000000748 compression moulding Methods 0.000 claims description 10
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical group [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 10
- 229910052737 gold Inorganic materials 0.000 claims description 10
- 239000010931 gold Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 239000003595 mist Substances 0.000 claims description 10
- 238000007873 sieving Methods 0.000 claims description 10
- 239000002002 slurry Substances 0.000 claims description 10
- 230000002708 enhancing effect Effects 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 239000010949 copper Substances 0.000 claims description 5
- 229910052709 silver Inorganic materials 0.000 claims description 5
- 239000004332 silver Substances 0.000 claims description 5
- 239000002105 nanoparticle Substances 0.000 claims description 4
- 239000003973 paint Substances 0.000 abstract description 2
- 229910052570 clay Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 4
- 239000002086 nanomaterial Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- 239000002041 carbon nanotube Substances 0.000 description 3
- 229910021393 carbon nanotube Inorganic materials 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
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- Compositions Of Oxide Ceramics (AREA)
- Finishing Walls (AREA)
Abstract
The invention discloses the ceramic tile that a kind of Graphene strengthens, by by potassium felspar sand, triphane, Guangxi white clay, attapulgite, corundum, water, Graphene, tripoly phosphate sodium STPP and tempering fiber are as blank raw material, feldspar, kaolin, quartz, burn talcum, Wingdale, ferric oxide, five oxidation two boron, aluminum oxide, diatomite, magnesium oxide, zirconium silicate, titanium oxide, zinc oxide, terbium sesquioxide, Samarium trioxide, lutecium oxide, metal nanoparticle is as glaze raw material, by the mode of glaze spraying or pouring glaze, glaze is imposed on green surface, the ceramic tile that the Graphene obtaining having good mechanics mechanical property strengthens, and its glaze paint is elegant in appearance.
Description
Technical field
The invention belongs to refractory brick field, particularly the ceramic tile that strengthens of a kind of Graphene.
Background technology
Along with the develop rapidly of China's Building Ceramics Industry, China is also more and more vigorous for the demand of building ceramics, the ceramic tile field of especially Graphene enhancing.In this field, people also more and more pay attention to the impact of the ceramic tile that plastics on new materials strengthens for Graphene.And by introducing plastics on new materials, external attractive in appearance, inherent physical and chemical performance and the health environment-friendly of the ceramic tile that Graphene strengthens can be improved.
And at Material Field, Graphene (Graphene) is a kind of novel material of the individual layer sheet structure be made up of carbon atom.Be a kind ofly form with sp2 hybridized orbital the flat film that hexangle type is honeycomb lattice by carbon atom, only have the two-dimensional material of a carbon atom thickness.Graphene is thin, the hardest nano material in known world, and it is almost completely transparent, only absorbs the light of 2.3%; Thermal conductivity is up to 5300W/ (mK)
, higher than carbon nanotube and diamond, under normal temperature, its electronic mobility is more than 15000cm
2/ (Vs)
, again than CNT (carbon nano-tube) or silicon wafer height, and resistivity only about 10
-6Ω cm, than copper or silver lower, be the material that world resistivity is minimum.The mechanics of the excellence that Graphene has due to it, electricity and chemical property, have broad application prospects, Graphene is applied to the emphasis that ceramic field is also present scientists study, by referring in alumina-ceramic by Graphene, mechanical property and the mechanical property of alumina-ceramic greatly can be improved.But still there is a lot of challenge in research Graphene being applied to the ceramic tile field that Graphene strengthens.Meanwhile, metal nano material has the physical and chemical performances such as different optics due to what have a different size, and the glaze paint how the superior chemical performance of metal nano material being incorporated into the ceramic tile that Graphene strengthens also is a difficult point of research now.
Summary of the invention
The object of the invention is for the problems referred to above, develop one and Graphene is incorporated into base substrate, the ceramic tile that Graphene metal nano material being incorporated into glaze strengthens,
Base substrate weight part consists of:
Potassium felspar sand 10 ~ 45 parts; Triphane 10 ~ 20 parts; Guangxi white clay 15 ~ 20 parts; Attapulgite 30 ~ 50 parts; 20 ~ 30 parts, corundum; 30 ~ 50 parts, water; Graphene 1 ~ 3 part; Tripoly phosphate sodium STPP 1 ~ 2 part; Tempering fiber 1 ~ 5 part;
Glaze weight part consists of:
Feldspar 15 ~ 25 parts, kaolin 10 ~ 15 parts, 8 ~ 10 parts, quartz, burn 10 ~ 20 parts, talcum, 13 ~ 22 parts, Wingdale, ferric oxide 0.5 ~ 5 part, five oxidation two boron 3 ~ 9 parts, 8 ~ 15 parts, aluminum oxide, 5 ~ 12 parts, diatomite, 6 ~ 15 parts, magnesium oxide, zirconium silicate 5 ~ 14 parts, titanium oxide 1 ~ 10 part, 1 ~ 10 part, zinc oxide, terbium sesquioxide 1 ~ 5 part, Samarium trioxide 1 ~ 10 part, lutecium oxide 1 ~ 5 part, metal nanoparticle 1 ~ 5 part;
The ceramic tile that described Graphene strengthens is obtained by following preparation method:
(1) after blank raw material being mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, abrading-ball is aluminum oxide abrading-ball, by ball milling 30-100min, obtains mixing homogeneous slurry, by sieving, after mist projection granulating, by isostatic pressed compression moulding and at room temperature ageing 1-2 days, obtains green compact, carries out biscuiting 30-40min subsequently at 800 ~ 830 DEG C to green compact;
(2) after being mixed in proportion by glaze raw material, carry out ball milling, ball-milling medium is ethanol and water mixture, and abrading-ball is aluminum oxide abrading-ball, by ball milling 30-100min, obtains mixing homogeneous glaze;
(2) adopt the mode of glaze spraying or pouring glaze that glaze is imposed on green surface, then burn till at roller kiln, firing temperature is 1195 ~ 1205 DEG C, and firing period is 50 ~ 55min, by following process, obtains the ceramic tile finished product that Graphene strengthens.
As preferably, described metal nanoparticle is gold nano grain, silver nano-grain or copper nano particles.
As preferably, described metal nanoparticle is of a size of 1-30nm.
As preferably, described base substrate weight part consists of: potassium felspar sand 38 parts; Triphane 16 parts; Guangxi white clay 18 parts; Attapulgite 40 parts; 27 parts, corundum; 47 parts, water; Graphene 2 parts; Tripoly phosphate sodium STPP 1 part; Tempering fiber 4 parts.
As preferably, described glaze weight part consists of: feldspar 18 parts, kaolin 14 parts, 9 parts, quartz, burns 15 parts, talcum, 20 parts, Wingdale, ferric oxide 3 parts, five oxidation two boron 6 parts, 9 parts, aluminum oxide, 10 parts, diatomite, 8 parts, magnesium oxide, zirconium silicate 7 parts, titanium oxide 7 parts, 8 parts, zinc oxide, terbium sesquioxide 4 parts, Samarium trioxide 6 parts, lutecium oxide 3 parts, metal nanoparticle 4 parts.
Beneficial effect of the present invention:
(1) various blank raw material and glaze raw material are organically combined by creationary by the present invention, and pass through optimal preparation technology, obtain good mechanical property, refractory heat-insulating, health environment-friendly, the ceramic tile that heat conductivility coefficient is little, lightweight, water-intake rate is low, obvious and adjustable, the corrosion resistant Graphene of glaze color and luster strengthens.
(2) the present invention is by introducing Graphene as ceramic body material, the not only toughness reinforcing mechanical property of ceramic body, and also reduces the weight of ceramic body;
(3) the present invention is by being incorporated into glaze by metal nanoparticle, it is combined with rare earth glaze, greatly improves the color of glaze.
(4) the ceramic tile preparation technology that the Graphene that prepared by the present invention strengthens is simple, environmental protection, and is convenient to suitability for industrialized production.
Embodiment
Below in conjunction with specific embodiment, and comparable data describes in further detail the present invention.Should be understood that these embodiments just in order to demonstrate the invention, but not limit the scope of the invention by any way.
Embodiment 1:
The ceramic tile that Graphene strengthens, base substrate weight part consists of:
Potassium felspar sand 10 parts; Triphane 10 parts; Guangxi white clay 15 parts; Attapulgite 30 parts; 20 parts, corundum; 30 parts, water; Graphene 1 part; Tripoly phosphate sodium STPP 1 part; Tempering fiber 1 part;
Glaze weight part consists of:
Feldspar 15 parts, kaolin 10 parts, 8 parts, quartz, burn 10 parts, talcum, 13 parts, Wingdale, ferric oxide 0.5 part, five oxidation two boron 3 parts, 8 parts, aluminum oxide, 5 parts, diatomite, 6 parts, magnesium oxide, zirconium silicate 5 parts, titanium oxide 1 part, 1 part, zinc oxide, terbium sesquioxide 1 part, Samarium trioxide 1 part, lutecium oxide 1 part, gold nano grain 1 part; Described size of nanometer gold grain is 10nm;
The ceramic tile that described Graphene strengthens is obtained by following preparation method:
(1) after blank raw material being mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing homogeneous slurry, by sieving, after mist projection granulating, by isostatic pressed compression moulding and at room temperature ageing 1 day, obtain green compact, at 800 DEG C, biscuiting 30min is carried out to green compact subsequently;
(2) after being mixed in proportion by glaze raw material, carry out ball milling, ball-milling medium is ethanol and water mixture, and abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing homogeneous glaze;
(2) adopt the mode of glaze spraying or pouring glaze that glaze is imposed on green surface, then burn till at roller kiln, firing temperature is 1195 DEG C, and firing period is 50min, by following process, obtains the ceramic tile finished product that Graphene strengthens.
Embodiment 2:
The ceramic tile that Graphene strengthens, base substrate weight part consists of:
Potassium felspar sand 10 parts; Triphane 10 parts; Guangxi white clay 15 parts; Attapulgite 30 parts; 20 parts, corundum; 30 parts, water; Graphene 1 part; Tripoly phosphate sodium STPP 1 part; Tempering fiber 1 part;
Glaze weight part consists of:
Feldspar 15 parts, kaolin 10 parts, 8 parts, quartz, burn 10 parts, talcum, 13 parts, Wingdale, ferric oxide 0.5 part, five oxidation two boron 3 parts, 8 parts, aluminum oxide, 5 parts, diatomite, 6 parts, magnesium oxide, zirconium silicate 5 parts, titanium oxide 1 part, 1 part, zinc oxide, terbium sesquioxide 1 part, Samarium trioxide 1 part, lutecium oxide 1 part, silver nano-grain 1 part; Described silver nano-grain is of a size of 10nm;
The ceramic tile that described Graphene strengthens is obtained by following preparation method:
(1) after blank raw material being mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing homogeneous slurry, by sieving, after mist projection granulating, by isostatic pressed compression moulding and at room temperature ageing 1 day, obtain green compact, at 800 DEG C, biscuiting 30min is carried out to green compact subsequently;
(2) after being mixed in proportion by glaze raw material, carry out ball milling, ball-milling medium is ethanol and water mixture, and abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing homogeneous glaze;
(2) adopt the mode of glaze spraying or pouring glaze that glaze is imposed on green surface, then burn till at roller kiln, firing temperature is 1195 DEG C, and firing period is 50min, by following process, obtains the ceramic tile finished product that Graphene strengthens.
Embodiment 3:
The ceramic tile that Graphene strengthens, base substrate weight part consists of:
Potassium felspar sand 10 parts; Triphane 10 parts; Guangxi white clay 15 parts; Attapulgite 30 parts; 20 parts, corundum; 30 parts, water; Graphene 1 part; Tripoly phosphate sodium STPP 1 part; Tempering fiber 1 part;
Glaze weight part consists of:
Feldspar 15 parts, kaolin 10 parts, 8 parts, quartz, burn 10 parts, talcum, 13 parts, Wingdale, ferric oxide 0.5 part, five oxidation two boron 3 parts, 8 parts, aluminum oxide, 5 parts, diatomite, 6 parts, magnesium oxide, zirconium silicate 5 parts, titanium oxide 1 part, 1 part, zinc oxide, terbium sesquioxide 1 part, Samarium trioxide 1 part, lutecium oxide 1 part, copper nano particles 1 part; Described copper nano particles is of a size of 10nm;
The ceramic tile that described Graphene strengthens is obtained by following preparation method:
(1) after blank raw material being mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing homogeneous slurry, by sieving, after mist projection granulating, by isostatic pressed compression moulding and at room temperature ageing 1 day, obtain green compact, at 800 DEG C, biscuiting 30min is carried out to green compact subsequently;
(2) after being mixed in proportion by glaze raw material, carry out ball milling, ball-milling medium is ethanol and water mixture, and abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing homogeneous glaze;
(2) adopt the mode of glaze spraying or pouring glaze that glaze is imposed on green surface, then burn till at roller kiln, firing temperature is 1195 DEG C, and firing period is 50min, by following process, obtains the ceramic tile finished product that Graphene strengthens.
Embodiment 4:
The ceramic tile that Graphene strengthens, base substrate weight part consists of:
Potassium felspar sand 38 parts; Triphane 16 parts; Guangxi white clay 18 parts; Attapulgite 40 parts; 27 parts, corundum; 47 parts, water; Graphene 2 parts; Tripoly phosphate sodium STPP 1 part; Tempering fiber 4 parts;
Glaze weight part consists of:
Feldspar 18 parts, kaolin 14 parts, 9 parts, quartz, burn 15 parts, talcum, 20 parts, Wingdale, ferric oxide 3 parts, five oxidation two boron 6 parts, 9 parts, aluminum oxide, 10 parts, diatomite, 8 parts, magnesium oxide, zirconium silicate 7 parts, titanium oxide 7 parts, 8 parts, zinc oxide, terbium sesquioxide 4 parts, Samarium trioxide 6 parts, lutecium oxide 3 parts, gold nano grain 1 part; Described size of nanometer gold grain is 10nm;
The ceramic tile that described Graphene strengthens is obtained by following preparation method:
(1) after blank raw material being mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing homogeneous slurry, by sieving, after mist projection granulating, by isostatic pressed compression moulding and at room temperature ageing 1 day, obtain green compact, at 800 DEG C, biscuiting 30min is carried out to green compact subsequently;
(2) after being mixed in proportion by glaze raw material, carry out ball milling, ball-milling medium is ethanol and water mixture, and abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing homogeneous glaze;
(2) adopt the mode of glaze spraying or pouring glaze that glaze is imposed on green surface, then burn till at roller kiln, firing temperature is 1195 DEG C, and firing period is 50min, by following process, obtains the ceramic tile finished product that Graphene strengthens.
Embodiment 5:
The ceramic tile that Graphene strengthens, base substrate weight part consists of:
Potassium felspar sand 38 parts; Triphane 16 parts; Guangxi white clay 18 parts; Attapulgite 40 parts; 27 parts, corundum; 47 parts, water; Graphene 1 part; Tripoly phosphate sodium STPP 1 part; Tempering fiber 4 parts;
Glaze weight part consists of:
Feldspar 18 parts, kaolin 14 parts, 9 parts, quartz, burn 15 parts, talcum, 20 parts, Wingdale, ferric oxide 3 parts, five oxidation two boron 6 parts, 9 parts, aluminum oxide, 10 parts, diatomite, 8 parts, magnesium oxide, zirconium silicate 7 parts, titanium oxide 7 parts, 8 parts, zinc oxide, terbium sesquioxide 4 parts, Samarium trioxide 6 parts, lutecium oxide 3 parts, gold nano grain 4 parts; Described size of nanometer gold grain is 30nm;
The ceramic tile that described Graphene strengthens is obtained by following preparation method:
(1) after blank raw material being mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing homogeneous slurry, by sieving, after mist projection granulating, by isostatic pressed compression moulding and at room temperature ageing 1 day, obtain green compact, at 830 DEG C, biscuiting 30min is carried out to green compact subsequently;
(2) after being mixed in proportion by glaze raw material, carry out ball milling, ball-milling medium is ethanol and water mixture, and abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing homogeneous glaze;
(2) adopt the mode of glaze spraying or pouring glaze that glaze is imposed on green surface, then burn till at roller kiln, firing temperature is 1205 DEG C, and firing period is 55min, by following process, obtains the ceramic tile finished product that Graphene strengthens.
Comparative example 1:
The ceramic tile that Graphene strengthens, base substrate weight part consists of:
Potassium felspar sand 10 parts; Triphane 10 parts; Guangxi white clay 15 parts; Attapulgite 30 parts; 20 parts, corundum; 30 parts, water; Tripoly phosphate sodium STPP 1 part; Tempering fiber 1 part;
Glaze weight part consists of:
Feldspar 15 parts, kaolin 10 parts, 8 parts, quartz, burn 10 parts, talcum, 13 parts, Wingdale, ferric oxide 0.5 part, five oxidation two boron 3 parts, 8 parts, aluminum oxide, 5 parts, diatomite, 6 parts, magnesium oxide, zirconium silicate 5 parts, titanium oxide 1 part, 1 part, zinc oxide, terbium sesquioxide 1 part, Samarium trioxide 1 part, lutecium oxide 1 part, gold nano grain 1 part; Described size of nanometer gold grain is 10nm;
The ceramic tile that described Graphene strengthens is obtained by following preparation method:
(1) after blank raw material being mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing homogeneous slurry, by sieving, after mist projection granulating, by isostatic pressed compression moulding and at room temperature ageing 1 day, obtain green compact, at 800 DEG C, biscuiting 30min is carried out to green compact subsequently;
(2) after being mixed in proportion by glaze raw material, carry out ball milling, ball-milling medium is ethanol and water mixture, and abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing homogeneous glaze;
(2) adopt the mode of glaze spraying or pouring glaze that glaze is imposed on green surface, then burn till at roller kiln, firing temperature is 1195 DEG C, and firing period is 50min, by following process, obtains the ceramic tile finished product that Graphene strengthens.
Comparative example 2:
The ceramic tile that Graphene strengthens, base substrate weight part consists of:
Potassium felspar sand 10 parts; Triphane 10 parts; Guangxi white clay 15 parts; Attapulgite 30 parts; 20 parts, corundum; 30 parts, water; Graphene 1 part; Tripoly phosphate sodium STPP 1 part; Tempering fiber 1 part;
Glaze weight part consists of:
Feldspar 15 parts, kaolin 10 parts, 8 parts, quartz, burns 10 parts, talcum, 13 parts, Wingdale, ferric oxide 0.5 part, five oxidation two boron 3 parts, 8 parts, aluminum oxide, 5 parts, diatomite, 6 parts, magnesium oxide, zirconium silicate 5 parts, titanium oxide 1 part, 1 part, zinc oxide, terbium sesquioxide 1 part, Samarium trioxide 1 part, lutecium oxide 1 part;
The ceramic tile that described Graphene strengthens is obtained by following preparation method:
(1) after blank raw material being mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing homogeneous slurry, by sieving, after mist projection granulating, by isostatic pressed compression moulding and at room temperature ageing 1 day, obtain green compact, at 800 DEG C, biscuiting 30min is carried out to green compact subsequently;
(2) after being mixed in proportion by glaze raw material, carry out ball milling, ball-milling medium is ethanol and water mixture, and abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing homogeneous glaze;
(2) adopt the mode of glaze spraying or pouring glaze that glaze is imposed on green surface, then burn till at roller kiln, firing temperature is 1195 DEG C, and firing period is 50min, by following process, obtains the ceramic tile finished product that Graphene strengthens.
Comparative example 3: the ceramic tile that a kind of Graphene strengthens, base substrate weight part consists of:
Potassium felspar sand 10 parts; Triphane 10 parts; Guangxi white clay 15 parts; Attapulgite 30 parts; 20 parts, corundum; 30 parts, water; Tripoly phosphate sodium STPP 1 part; Tempering fiber 1 part;
Glaze weight part consists of:
Feldspar 15 parts, kaolin 10 parts, 8 parts, quartz, burns 10 parts, talcum, 13 parts, Wingdale, ferric oxide 0.5 part, five oxidation two boron 3 parts, 8 parts, aluminum oxide, 5 parts, diatomite, 6 parts, magnesium oxide, zirconium silicate 5 parts, titanium oxide 1 part, 1 part, zinc oxide, terbium sesquioxide 1 part, Samarium trioxide 1 part, lutecium oxide 1 part;
The ceramic tile that described Graphene strengthens is obtained by following preparation method:
(1) after blank raw material being mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing homogeneous slurry, by sieving, after mist projection granulating, by isostatic pressed compression moulding and at room temperature ageing 1 day, obtain green compact, at 800 DEG C, biscuiting 30min is carried out to green compact subsequently;
(2) after being mixed in proportion by glaze raw material, carry out ball milling, ball-milling medium is ethanol and water mixture, and abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing homogeneous glaze;
(2) adopt the mode of glaze spraying or pouring glaze that glaze is imposed on green surface, then burn till at roller kiln, firing temperature is 1195 DEG C, and firing period is 50min, by following process, obtains the ceramic tile finished product that Graphene strengthens.
By being compared with embodiment 1 by comparative example 1-3, when being added with Graphene as blank raw material, mechanical property and the mechanical property increase rate of base substrate reach 30%, and this is a very large progress for the ceramic tile that Graphene strengthens; And by metal nanoparticle is incorporated in glaze, because the metal nanoparticle of different size has distinct colors, therefore, the color regulating glaze will be contributed to, and there is the glaze of metalluster, will greatly improve the aesthetic measure of the ceramic tile that Graphene strengthens.
Claims (5)
1. a ceramic tile for Graphene enhancing, is characterized in that:
Base substrate weight part consists of:
Potassium felspar sand 10 ~ 45 parts; Triphane 10 ~ 20 parts; Guangxi white clay 15 ~ 20 parts; Attapulgite 30 ~ 50 parts; 20 ~ 30 parts, corundum; 30 ~ 50 parts, water; Graphene 1 ~ 3 part; Tripoly phosphate sodium STPP 1 ~ 2 part; Tempering fiber 1 ~ 5 part;
Glaze weight part consists of:
Feldspar 15 ~ 25 parts, kaolin 10 ~ 15 parts, 8 ~ 10 parts, quartz, burn 10 ~ 20 parts, talcum, 13 ~ 22 parts, Wingdale, ferric oxide 0.5 ~ 5 part, five oxidation two boron 3 ~ 9 parts, 8 ~ 15 parts, aluminum oxide, 5 ~ 12 parts, diatomite, 6 ~ 15 parts, magnesium oxide, zirconium silicate 5 ~ 14 parts, titanium oxide 1 ~ 10 part, 1 ~ 10 part, zinc oxide, terbium sesquioxide 1 ~ 5 part, Samarium trioxide 1 ~ 10 part, lutecium oxide 1 ~ 5 part, metal nanoparticle 1 ~ 5 part;
The ceramic tile that described Graphene strengthens is obtained by following preparation method:
(1) after blank raw material being mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, abrading-ball is aluminum oxide abrading-ball, by ball milling 30-100min, obtains mixing homogeneous slurry, by sieving, after mist projection granulating, by isostatic pressed compression moulding and at room temperature ageing 1-2 days, obtains green compact, carries out biscuiting 30-40min subsequently at 800 ~ 830 DEG C to green compact;
(2) after being mixed in proportion by glaze raw material, carry out ball milling, ball-milling medium is ethanol and water mixture, and abrading-ball is aluminum oxide abrading-ball, by ball milling 30-100min, obtains mixing homogeneous glaze;
(2) adopt the mode of glaze spraying or pouring glaze that glaze is imposed on green surface, then burn till at roller kiln, firing temperature is 1195 ~ 1205 DEG C, and firing period is 50 ~ 55min, by following process, obtains the ceramic tile finished product that Graphene strengthens.
2. a ceramic tile for Graphene enhancing as claimed in claim 1, is characterized in that described metal nanoparticle is gold nano grain, silver nano-grain or copper nano particles.
3. a ceramic tile for Graphene enhancing as claimed in claim 1 or 2, is characterized in that described metal nanoparticle is of a size of 1-30nm.
4. a ceramic tile for Graphene enhancing as claimed in claim 3, is characterized in that described base substrate weight part consists of: potassium felspar sand 38 parts; Triphane 16 parts; Guangxi white clay 18 parts; Attapulgite 40 parts; 27 parts, corundum; 47 parts, water; Graphene 2 parts; Tripoly phosphate sodium STPP 1 part; Tempering fiber 4 parts.
5. a ceramic tile for Graphene enhancing as claimed in claim 4, is characterized in that described glaze weight part consists of: feldspar 18 parts, kaolin 14 parts, 9 parts, quartz, burns 15 parts, talcum, 20 parts, Wingdale, ferric oxide 3 parts, five oxidation two boron 6 parts, 9 parts, aluminum oxide, 10 parts, diatomite, 8 parts, magnesium oxide, zirconium silicate 7 parts, titanium oxide 7 parts, 8 parts, zinc oxide, terbium sesquioxide 4 parts, Samarium trioxide 6 parts, lutecium oxide 3 parts, metal nanoparticle 4 parts.
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