CN104149513A - Coating class printing media and manufacturing method thereof - Google Patents

Coating class printing media and manufacturing method thereof Download PDF

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Publication number
CN104149513A
CN104149513A CN201410442141.9A CN201410442141A CN104149513A CN 104149513 A CN104149513 A CN 104149513A CN 201410442141 A CN201410442141 A CN 201410442141A CN 104149513 A CN104149513 A CN 104149513A
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CN
China
Prior art keywords
parts
printed medium
coating class
coating
class printed
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Granted
Application number
CN201410442141.9A
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Chinese (zh)
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CN104149513B (en
Inventor
赵镇
王玉丰
陆建辉
徐雄飞
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JIANGSU GEMEI HIGH-TECH DEVELOPMENT Co Ltd
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JIANGSU GEMEI HIGH-TECH DEVELOPMENT Co Ltd
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Priority to CN201410442141.9A priority Critical patent/CN104149513B/en
Publication of CN104149513A publication Critical patent/CN104149513A/en
Application granted granted Critical
Publication of CN104149513B publication Critical patent/CN104149513B/en
Expired - Fee Related legal-status Critical Current
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Abstract

The invention discloses coating class printing media. The coating class printing media evenly coat a base material, and the coating class printing media are characterized by being composed of 100 parts of water, eight parts to 12 parts of silicon dioxide, six parts to ten parts of titanium dioxide, 50 parts to 100 parts of PM-2 acrylic acid rubber polymer, 50 parts of 676-class rubber polymer, 1.4 parts to 2.2 parts of dispersing auxiliaries, 0.5 parts of defoaming auxiliaries, 0.3 part to 0.5 part of leveling auxiliaries and five parts of cross-linking agents. Compared with traditional printing media, the coating class printing media can greatly improve the printing ink adherence in the printing ink printing process, the printing color density is improved, and scratch resistance of the printed matter is greatly improved.

Description

A kind of coating class printed medium and preparation method thereof
Technical field
The present invention relates to a kind of coating class printed medium and preparation method thereof, be applicable to the occasion of letterpress, intaglio printing, lithographic printing, serigraphy and ink jet printing, and be applicable to producing various colored printing label papers and various colored printing packaging material.
Background technology
Synthetic material is a kind of widely used new material, taking PP paper as example, PP synthetic paper is taking the resins such as polyolefin and inorganic filler as primary raw material, processes by expressing technique, there is the multi-functional material of plastics and paper feature simultaneously, being a kind of Novel plastic material product, is also a kind of environment-friendly products, has that light specific gravity, intensity are large, tear-proof, printing is good, shading, uvioresistant, durable in use, the features such as economic environmental protection.
Based on above advantage, the synthetic materials such as PP synthetic paper and PET film are widely used in printed label and printed apcksging material industry.But because the self character of the synthetic stationery of PP and PET film material determines that its material surface energy is low, printing-ink is difficult for adhering to, and after printing, the adherence of ink is poor, color density is low, affects greatly practical application effect.
Traditional processing method is to add sided corona treatment at printing leading portion, corona rear surface produce-OH and-COOH can and ink build bridge, initial effect is good, but sided corona treatment rear surface tension force is decay rapidly, taking PET film as example, after its initial sided corona treatment, effect can continue about 7 days at most; Due to the feature of the unstable and easy weakening of sided corona treatment effect, make the long-term fastness of ink layer after printing not strong, be easy to scraping, thus at present traditional, color density low, scraping and wiping resistance performance poor problem poor without coating class printing material ubiquity ink adherence solved, necessary.
Summary of the invention
Problem to be solved by this invention is to provide a kind of coating class printed medium and preparation method thereof, the feature that while having printing, ink adherence is strong, color density is high, scraping and wiping resistance performance is good.
For solving the problems of the technologies described above, technical scheme of the present invention is: a kind of coating class printed medium, described coating class printed medium is evenly coated on base material, and its innovative point is: described coating class printed medium is made up of the water of 100 parts, the silica of 8-12 part, the titanium dioxide of 6-10 part, the PM-2 acrylic compounds rubber polymer of 50-100 part, the 676 class rubber polymers of 50 parts, the dispersing aid of 1.4-2.2 part, the froth breaking auxiliary agent of 0.5 part, the leveling auxiliary agent of 0.3-0.5 part and the crosslinking agent of 5 parts.
Preferably, described defoamer is modified organic silicon alkanes or castor-oil plant oils modification derivant.
Preferably, described levelling agent is fluorinated levelling agent.
Preferably, described crosslinking agent is the special crosslinking agent of acrylic emulsion.
Preferably, described dispersant is Nano filling dispersant special.
Preferably, described base material is the one in PP synthetic paper after corona or chemical treatment, PET film, PE leaching membrane paper, wood-free paper.
A preparation method for coating class printed medium, prepares above-mentioned a kind of coating class printed medium, comprises the following steps:
A, first the dispersing aid of above-mentioned umber, froth breaking auxiliary agent, leveling auxiliary agent and crosslinking agent are added to the water, continue to stir 30min with the speed of 1000r/min;
B, the silica of above-mentioned umber and titanium dioxide are joined in above-mentioned solution, continue to stir 60min with the speed of 4000r/min;
C, the PM-2 acrylic compounds rubber polymer that is then blended into above-mentioned umber, 676 class rubber polymers, continue to stir 30min with the speed of 1000r/min;
D, finally by obtain solution left standstill until froth breaking can obtain for being coated on the coating class printed medium on base material.
The invention has the advantages that: coating class printed medium of the present invention has the following advantages compared to traditional printed medium tool: 1, on the printing elements such as PP synthetic paper, PET film, introduce suitable coating, increase substantially the ink adherence in ink printing process, improve process color density, increased substantially the scraping and wiping resistance performance of printed matter; 2, in traditional Nano filling dispersion process, production process airborne dust is large, and the dispersed with stirring time is long, high energy consumption; The present invention, owing to having introduced suitable Nano filling dispersing aid, more easily disperses filler, thereby makes coating production process airborne dust little, and energy consumption is low; 3, select suitable rubber polymer system and crosslinking agent system, made, in coating production process, to have saved the bottoming process of traditional coating process, reduced production routine, improved production efficiency, reduced production cost.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further detailed explanation.
embodiment 1
Coating class printed medium of the present invention is evenly coated on base material, is made up of the water of 100 parts, the silica of 8 parts, the titanium dioxide of 6 parts, the PM-2 acrylic compounds rubber polymer of 100 parts, the 676 class rubber polymers of 50 parts, the dispersing aid of 1.4 parts, the froth breaking auxiliary agent of 0.5 part, the leveling auxiliary agent of 0.3 part and the crosslinking agent of 5 parts.
Above-mentioned defoamer is modified organic silicon alkanes or castor-oil plant oils modification derivant, levelling agent is fluorinated levelling agent, crosslinking agent is the special crosslinking agent of acrylic emulsion, dispersant is Nano filling dispersant special, and base material is the one in PP synthetic paper after corona or chemical treatment, PET film, PE leaching membrane paper, wood-free paper.
The preparation method who prepares above-mentioned coating class printed medium, comprises the following steps:
A, first the dispersing aid of above-mentioned umber, froth breaking auxiliary agent, leveling auxiliary agent and crosslinking agent are added to the water, continue to stir 30min with the speed of 1000r/min;
B, the silica of above-mentioned umber and titanium dioxide are joined in above-mentioned solution, continue to stir 60min with the speed of 4000r/min;
C, the PM-2 acrylic compounds rubber polymer that is then blended into above-mentioned umber, 676 class rubber polymers, continue to stir 30min with the speed of 1000r/min;
D, finally by obtain solution left standstill until froth breaking can obtain for being coated on the coating class printed medium on base material.
embodiment 2
Coating class printed medium of the present invention is evenly coated on base material, is made up of the water of 100 parts, the silica of 10 parts, the titanium dioxide of 8 parts, the PM-2 acrylic compounds rubber polymer of 50 parts, the 676 class rubber polymers of 50 parts, the dispersing aid of 1.7 parts, the froth breaking auxiliary agent of 0.5 part, the leveling auxiliary agent of 0.4 part and the crosslinking agent of 5 parts.
Above-mentioned defoamer is modified organic silicon alkanes or castor-oil plant oils modification derivant, levelling agent is fluorinated levelling agent, crosslinking agent is the special crosslinking agent of acrylic emulsion, dispersant is Nano filling dispersant special, and base material is the one in PP synthetic paper after corona or chemical treatment, PET film, PE leaching membrane paper, wood-free paper.
The preparation method who prepares above-mentioned coating class printed medium, comprises the following steps:
A, first the dispersing aid of above-mentioned umber, froth breaking auxiliary agent, leveling auxiliary agent and crosslinking agent are added to the water, continue to stir 30min with the speed of 1000r/min;
B, the silica of above-mentioned umber and titanium dioxide are joined in above-mentioned solution, continue to stir 60min with the speed of 4000r/min;
C, the PM-2 acrylic compounds rubber polymer that is then blended into above-mentioned umber, 676 class rubber polymers, continue to stir 30min with the speed of 1000r/min;
D, finally by obtain solution left standstill until froth breaking can obtain for being coated on the coating class printed medium on base material.
embodiment 3
Coating class printed medium of the present invention is evenly coated on base material, is made up of the water of 100 parts, the silica of 12 parts, the titanium dioxide of 8 parts, the PM-2 acrylic compounds rubber polymer of 70 parts, the 676 class rubber polymers of 50 parts, the dispersing aid of 1.7 parts, the froth breaking auxiliary agent of 0.5 part, the leveling auxiliary agent of 0.4 part and the crosslinking agent of 5 parts.
Above-mentioned defoamer is modified organic silicon alkanes or castor-oil plant oils modification derivant, levelling agent is fluorinated levelling agent, crosslinking agent is the special crosslinking agent of acrylic emulsion, dispersant is Nano filling dispersant special, and base material is the one in PP synthetic paper after corona or chemical treatment, PET film, PE leaching membrane paper, wood-free paper.
The preparation method who prepares above-mentioned coating class printed medium, comprises the following steps:
A, first the dispersing aid of above-mentioned umber, froth breaking auxiliary agent, leveling auxiliary agent and crosslinking agent are added to the water, continue to stir 30min with the speed of 1000r/min;
B, the silica of above-mentioned umber and titanium dioxide are joined in above-mentioned solution, continue to stir 60min with the speed of 4000r/min;
C, the PM-2 acrylic compounds rubber polymer that is then blended into above-mentioned umber, 676 class rubber polymers, continue to stir 30min with the speed of 1000r/min;
D, finally by obtain solution left standstill until froth breaking can obtain for being coated on the coating class printed medium on base material.
embodiment 4
Coating class printed medium of the present invention is evenly coated on base material, is made up of the water of 100 parts, the silica of 12 parts, the titanium dioxide of 10 parts, the PM-2 acrylic compounds rubber polymer of 90 parts, the 676 class rubber polymers of 50 parts, the dispersing aid of 2.2 parts, the froth breaking auxiliary agent of 0.5 part, the leveling auxiliary agent of 0.5 part and the crosslinking agent of 5 parts.
Above-mentioned defoamer is modified organic silicon alkanes or castor-oil plant oils modification derivant, levelling agent is fluorinated levelling agent, crosslinking agent is the special crosslinking agent of acrylic emulsion, dispersant is Nano filling dispersant special, and base material is the one in PP synthetic paper after corona or chemical treatment, PET film, PE leaching membrane paper, wood-free paper.
The preparation method who prepares above-mentioned coating class printed medium, comprises the following steps:
A, first the dispersing aid of above-mentioned umber, froth breaking auxiliary agent, leveling auxiliary agent and crosslinking agent are added to the water, continue to stir 30min with the speed of 1000r/min;
B, the silica of above-mentioned umber and titanium dioxide are joined in above-mentioned solution, continue to stir 60min with the speed of 4000r/min;
C, the PM-2 acrylic compounds rubber polymer that is then blended into above-mentioned umber, 676 class rubber polymers, continue to stir 30min with the speed of 1000r/min;
D, finally by obtain solution left standstill until froth breaking can obtain for being coated on the coating class printed medium on base material.
Above the invention embodiment is had been described in detail, but content is only for the preferred embodiment of the invention, can not be considered to the practical range for limiting the invention.All equalization variation and improvement etc. of doing according to the invention application range, within all belonging to the patent covering scope of the invention.

Claims (7)

1. a coating class printed medium, described coating class printed medium is evenly coated on base material, its feature
Be: described coating class printed medium is made up of the water of 100 parts, the silica of 8-12 part, the titanium dioxide of 6-10 part, the PM-2 acrylic compounds rubber polymer of 50-100 part, the 676 class rubber polymers of 50 parts, the dispersing aid of 1.4-2.2 part, the froth breaking auxiliary agent of 0.5 part, the leveling auxiliary agent of 0.3-0.5 part and the crosslinking agent of 5 parts.
2. a kind of coating class printed medium as claimed in claim 1, is characterized in that: described defoamer is modified organic silicon alkanes or castor-oil plant oils modification derivant.
3. a kind of coating class printed medium as claimed in claim 1, is characterized in that: described levelling agent is fluorinated levelling agent.
4. a kind of coating class printed medium as claimed in claim 1, is characterized in that: described crosslinking agent is the special crosslinking agent of acrylic emulsion.
5. a kind of coating class printed medium as claimed in claim 1, is characterized in that: described dispersant is Nano filling dispersant special.
6. a kind of coating class printed medium as claimed in claim 1, is characterized in that: described base material is the one in PP synthetic paper after corona or chemical treatment, PET film, PE leaching membrane paper, wood-free paper.
7. a preparation method for coating class printed medium, a kind of coating class printed medium described in any one wherein in preparation claim 1 to 6, is characterized in that comprising the following steps:
A, first the dispersing aid of above-mentioned umber, froth breaking auxiliary agent, leveling auxiliary agent and crosslinking agent are added to the water, continue to stir 30min with the speed of 1000r/min;
B, the silica of above-mentioned umber and titanium dioxide are joined in above-mentioned solution, continue to stir 60min with the speed of 4000r/min;
C, the PM-2 acrylic compounds rubber polymer that is then blended into above-mentioned umber, 676 class rubber polymers, continue to stir 30min with the speed of 1000r/min;
D, finally by obtain solution left standstill until froth breaking can obtain for being coated on the coating class printed medium on base material.
CN201410442141.9A 2014-09-02 2014-09-02 A kind of coating class printed medium and preparation method thereof Expired - Fee Related CN104149513B (en)

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Application Number Priority Date Filing Date Title
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CN104149513A true CN104149513A (en) 2014-11-19
CN104149513B CN104149513B (en) 2016-07-13

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108752615A (en) * 2018-06-11 2018-11-06 江苏万宝瑞达高新技术有限公司 A kind of BOPP thermosensitive film production methods suitable for the printing of UV ink
CN114574117A (en) * 2022-02-25 2022-06-03 深圳昌茂粘胶新材料有限公司 Weather-proof medium-resistant high-temperature-resistant label tape and manufacturing method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003022576A1 (en) * 2001-08-30 2003-03-20 Tianjin Boyuan New Materials Co., Ltd Base sheet specially for digital card-marking and its preparing method
JP2004507389A (en) * 2000-08-30 2004-03-11 アルコア インコーポレーテツド Pre-treated sheet products for lithographic plates
CN102092209A (en) * 2010-10-29 2011-06-15 哈尔滨工业大学 Ink-jet recording material and preparation method thereof as well as method for preparing ink absorption layer coating liquid
CN102501676A (en) * 2011-10-14 2012-06-20 江苏格美高科技发展有限公司 Matte waterproof polypropylene photo paper applicable for aqueous ink
US20120282447A1 (en) * 2010-02-12 2012-11-08 Gringoire Bruno R Coated Polymeric Film
CN102922893A (en) * 2012-10-30 2013-02-13 江苏格美高科技发展有限公司 Medical laser color printing and imaging PET (Polyester) film and preparation method thereof
CN103897529A (en) * 2012-12-27 2014-07-02 青岛佳艺影像新材料技术有限公司 Manufacturing method of coating liquid for dual-layer front-spray light box sheets

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004507389A (en) * 2000-08-30 2004-03-11 アルコア インコーポレーテツド Pre-treated sheet products for lithographic plates
WO2003022576A1 (en) * 2001-08-30 2003-03-20 Tianjin Boyuan New Materials Co., Ltd Base sheet specially for digital card-marking and its preparing method
US20120282447A1 (en) * 2010-02-12 2012-11-08 Gringoire Bruno R Coated Polymeric Film
CN102092209A (en) * 2010-10-29 2011-06-15 哈尔滨工业大学 Ink-jet recording material and preparation method thereof as well as method for preparing ink absorption layer coating liquid
CN102501676A (en) * 2011-10-14 2012-06-20 江苏格美高科技发展有限公司 Matte waterproof polypropylene photo paper applicable for aqueous ink
CN102922893A (en) * 2012-10-30 2013-02-13 江苏格美高科技发展有限公司 Medical laser color printing and imaging PET (Polyester) film and preparation method thereof
CN103897529A (en) * 2012-12-27 2014-07-02 青岛佳艺影像新材料技术有限公司 Manufacturing method of coating liquid for dual-layer front-spray light box sheets

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108752615A (en) * 2018-06-11 2018-11-06 江苏万宝瑞达高新技术有限公司 A kind of BOPP thermosensitive film production methods suitable for the printing of UV ink
CN114574117A (en) * 2022-02-25 2022-06-03 深圳昌茂粘胶新材料有限公司 Weather-proof medium-resistant high-temperature-resistant label tape and manufacturing method thereof

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