CN104145965B - A kind of insecticidal and bactericidal composition containing mould spirit - Google Patents
A kind of insecticidal and bactericidal composition containing mould spirit Download PDFInfo
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- CN104145965B CN104145965B CN201410361773.2A CN201410361773A CN104145965B CN 104145965 B CN104145965 B CN 104145965B CN 201410361773 A CN201410361773 A CN 201410361773A CN 104145965 B CN104145965 B CN 104145965B
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Abstract
The invention discloses a kind of insecticidal and bactericidal composition containing two kinds of active component, the first active component is mould spirit, and second active ingredient is the chloro-N of 3-1-(2-methyl-4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide.The insecticidal and bactericidal composition that the present invention provides is suitable for preventing and treating rice seedling pest and disease damage.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of insecticidal and bactericidal composition that can be used for rice terrace.
Background technology
In rice cropping, raising rice seedlings, seedling stage are particularly significant.In China early spring, temperature is the most unstable, at water
The rice seedling phase meets with when microthermal climate, water logging, and rice seedlings often occurs seedling rot phenomenon.Through investigation, there is the main of seedling rot
Reason is damping-off, bacterial wilt etc..Meanwhile, the most often there is the situations such as bakanae disease at rice seedling, have a strong impact on Oryza sativa L. normal
Growth.Additionally, raising rice seedlings, seedling stage are on the occasion of overwinter generation rice stem borer spawning and hatching stage, larva harm to be infected
Oryza sativa L..At present, the industrialized agribusiness areas such as China is in cooperative association's Rapid development stage such as big farming household, raising rice seedlings are fast
Speed increases.In southern area, it is increasingly severe, to agriculture that rice seedling stage striped rice borer, damping-off, bakanae disease etc. merge generation
Industry produces and brings considerable influence.
In prior art, China is mainly single pest control or single controlling disease for the pesticide of rice seedling, can prevent simultaneously
The product development controlling insect pest and disease is little.Therefore, the insecticidal and bactericidal composition of exploitation preventing and treating rice seedling pest and disease damage, for pushing away
Enter agricultural large-scale development and there is positive effect.
Summary of the invention
The technical problem to be solved in the present invention can provide a kind of efficiently, low toxicity and can effectively prevent and treat the parasite killing of rice seedling pest and disease damage and kill
Bacteria composition.
For solving the problems referred to above, the technical solution adopted in the present invention is:
A kind of insecticidal and bactericidal composition, containing two kinds of active component, the first active component is mould spirit, second active ingredient
For the chloro-N of 3-1-(2-methyl-4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) O-phthalic
Amide, the first active component described is 1～10:20～100 with the quality proportioning of second active ingredient.
In the insecticidal and bactericidal composition that the present invention provides, above-mentioned mould spirit (hymexazol) belongs to systemic fungicide, in having
Inhale and conduction, be again simultaneously a kind of soil sterilants, to various plant soil-borne diseases: pythium spp, Seedling corruption bacterium, Fusarium spp.,
Rhizoctonia, root shell bacterium etc. have good prevention effect, in being manured into soil after, can be combined with the ferrum in soil, aluminium ion, can press down
The sprouting of pathogenic bacteria spore processed, by the Root Absorption of plant and can move in root system.Meanwhile, 2 kinds of sugar are produced at plant intracellular metabolite
Glycosides, is improved plant physiology activity, promotes the tiller of root, increase root approximate number amount and effect of plant strain growth.
In the insecticidal and bactericidal composition that the present invention provides, the chloro-N of above-mentioned 3-1-(2-methyl-4-sevoflurane isopropyl base)-
N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide (hereinafter referred to as " ZJ4042 "), is Zhejiang Provincial Chemical Engineering Research Inst
The novel pesticide developed voluntarily, shown in structural formula following (I):
The insecticidal activity of this compound is the most suitable with the fipronil bisamide of recent development.Fipronil bisamide, English common name
(flubendiamide) being researched and developed by Nihon Nihyaku Co., Ltd, chemical name is the iodo-N-of 3-(2-first sulfonephthalein base-1,1-diformazan
Base ethyl group-N-{4-" 1,2,2,2-tetra-fluoro-1-(trifluoromethyl) ethyl-o-tolyl } phthalamide, molecule
Formula is: C23H22F7N2O4, belong to Novel ortho benzenedicarboxamide insecticides, activate calcium release channel in blue Buddhist nun's alkali recipient cell, cause
The runaway release of storage calcium ion, is the most few in number chemical combination acting on insect cell orchid Buddhist nun's alkali (Ryanodine) receptor
Thing.Lepidoptera pest is had wide spectrum preventive effect, produces with existing insecticide no interactions resistance, be extremely suitable for existing insecticide and produce
The preventing and treating of the insect of resistance.
As preferred mode, the quality proportioning of the first active component above-mentioned and second active ingredient be preferably 2～4:20～
40。
Present invention also offers a kind of insecticidal bactericide, contain 5～90% above-mentioned insecticidal and bactericidal composition by weight, remaining is agriculture
Acceptable carrier and auxiliary agent in industry.As preferred embodiment, in described insecticidal bactericide, containing by weight 5～40%
Insecticidal and bactericidal composition.
Carrier of the present invention can be solid or liquid, is generally used for preparing the equal energy of any carrier of insecticidal bactericide compositions
Use.
Suitably solid carrier includes: mineral substance, plant, synthetic filling class and inorganic salts.Wherein mineral substance includes silicic acid
Salt, carbonate, Sulfates and oxide-based.Silicates such as Kaolin, meerschaum, nacrite, montmorillonite,
Muscovitum, Vermiculitum, pyrophyllite, Talcum.Carbonate is such as: calcium carbonate, dolomite.Sulfates such as ammonium sulfate, sodium sulfate,
Calcium sulfate.Oxide-based such as quick lime, magnesium lime, kieselguhr.Plant is such as: citrus pulp, corncob cellulose, rice husk powder,
Rice husk, big soybean stem meal, tobacco powder, Endocarpium Juglandis, sawdust.Synthetic filling class such as winnofil hydrate, winnofil,
White carbon.Inorganic salts such as potassium chloride, sodium chloride.
Liquid-carrier includes water and organic solvent.When effective ingredient is suspension emulsion, organic solvent plays solubilized and antifreeze effect.
Suitably organic solvent includes aromatic hydrocarbons, such as benzene, dimethylbenzene, toluene, alkylbenzene, alkylnaphthalene and chlorinated aromatic hydrocarbons；Chloro fat
Hydrocarbon, such as vinyl chloride, chloroform, dichloromethane, chloroform, carbon tetrachloride and many ethyl chloride；Aliphatic hydrocarbon, such as oil evaporate
Point, hexamethylene, light mineral oil and paraffin.Alcohols such as methanol, ethanol, isopropanol, butanol, isobutanol, ethylene glycol,
Propylene glycol, glycerol, fatty alcohol etc.；Ethers such as Propylene Glycol ether, ethohexadiol ether, petroleum ether.Ketone such as third
Ketone, butanone, methyl iso-butyl ketone (MIBK), Ketohexamethylene and isophorone, N-methyl-pyrrolidon；Special solvent also has dimethyl
Methanamide, dimethyl sulfoxide, Polyethylene Glycol, nitrile；Vegetable oil and methylated vegetable oils.Above-mentioned organic solvent both can be independent
Use, it is also possible to be used in mixed way, it is also possible to mix together with water.
Auxiliary agent of the present invention can include in surfactant, defoamer, thickening agent, suspending agent and antifreezing agent as required
One or more, it is also possible to include other auxiliary agents that the industry is conventional as required.
Surfactant can be emulsifying agent, dispersant, stabilizer or wetting agent；Can be ion-type or nonionic.
Suitably surfactant includes: polyacrylic acid and the sodium salt of lignin sulfonic acid and calcium salt；Containing at least 12 carbon atoms in molecule
Fatty acid or fatty amine and oxirane and the polycondensation product of/expoxy propane；Glycerol, dodecanol-1, tetradecanol-1, mountain
The fatty acid ester of pears alcohol, sucrose or tetramethylolmethane；And they are with oxirane and/or the polycondensation product of expoxy propane；Their contracting
The sulfate of poly-product or sulfonate；The most at least contain the sulphuric acid of 10 carbon atoms or the alkali metal of sulfonic acid or alkaline-earth metal
Salt, is preferably sodium salt, such as sodium lauryl sulphate, Teepol, the sodium salt of sulfonated castor oil, alkylaryl sodium sulfonate
And dodecylbenzene sodium sulfonate；The copolymer of the polymer of oxirane, oxirane and expoxy propane.
Emulsifying agent includes nonionic emulsifier and anionic emulsifier.The preferred NPE of nonionic emulsifier,
Fatty alcohol-polyoxyethylene ether, styryl phenyl polyoxyethylene ether, alkyl phenol formaldehyde resin polyoxyethylene ether, terminal hydroxy group polyoxy second
Alkene polyethenoxy ether, styrylphenol formaldehyde resin polyoxyethylene poly-oxygen propylene aether, castor oil polyoxyethylene ether.Anionic
Emulsifying agent mainly includes calcium dodecyl benzene sulfonate, triphen ethyl phenol polyoxy ether phosphate amine salt, NPE phosphorus
Acid esters amine salt, castor oil polyoxyethylene ether phosphate amine salt.
Dispersant of the present invention includes: acrylate homopolymer sodium salt, maleic acid disodium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt,
Rosin segmented polyoxyethylene ether polyoxypropylene ether sulfonate, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether block copolymer, three phenethyls
Phenol polyethenoxy ether phosphate, fatty alcohol-polyoxyethylene ether phosphoric acid, one or more in p-hydroxyphenyl lignin sulfonic acid sodium salt.
Wetting agent of the present invention includes: fatty alcohol-polyoxyethylene ether, naphthalene sulfonate, sodium lauryl sulphate, alkyl phenol tree
One or more combinations in fat polyoxyethylene ether sulfate.
Thickening agent of the present invention includes xanthan gum, aluminium-magnesium silicate, sodium alginate, sodium carboxymethyl cellulose, arabic gum,
Gelatin, one or more in polyvinyl alcohol.Defoamer of the present invention is preferably: bubble enemy, silicone, C8~10Fatty alcohol,
C10～20Saturated fat acids and amide etc..
Insecticidal bactericide of the present invention can according to method generally in the art be configured to cream, oil suspending agent, suspending agent,
Wettable powder or water dispersible granules.
Insecticidal and bactericidal composition and insecticidal bactericide that the present invention provides are particularly suitable for preventing and treating rice seedling pest and disease damage, the suitableeest
Close preventing and treating rice seedling blight, bakanae disease and striped rice borer.
Insecticidal and bactericidal composition of the present invention has the advantage that compared to existing technology
(1) in compositions, two kinds of composite reagents show in certain ratio range and can substantially expand pesticide-germicide spectrum effect, reach disease
The double effect controlled of worm, and have that quick-acting is good and the feature of lasting effect length；
(2) reduce times for spraying, reduce peasant's drug cost.
Detailed description of the invention
The following examples are the several detailed description of the invention for the present invention is described, but it is concrete not limit the invention to these
Embodiment.One skilled in the art would recognize that potentially included in present invention encompasses Claims scope owns
Alternative, improvement project and equivalents.
In following embodiment material prescription select can treatment in accordance with local conditions, on result without substantial impact.In these embodiments, remove
Outside being otherwise noted, all percentage ratios are all weight percentage.
Embodiment 1 (20% mould spirit ZJ4042 suspending agent)
By mould clever 5%, ZJ404215%, phosphate dispersant (FS3000) 4%, sulfonate wetting agent (SXC) 1%, silicon
Acid magnalium 1%, xanthan gum 0.1%, organic silicon defoamer 0.3%, ethylene glycol 5%, surplus are deionized water.Above-mentioned formula is pressed
Ratio is pulverized in advance, adds in sand mill and grinds, and after high shear mixing, the prepared 20% mould spirit ZJ4042 of allotment hangs
Floating agent.
It is applied to prevent and treat rice seedling striped rice borer, damping-off by the 20% of preparation mould spirit ZJ4042 suspending agent.20% is mould
Spirit ZJ4042 suspending agent press effective ingredient 5 grams/acre in striped rice borer egg hatching larva occurance peak, and at the beginning of damping-off generation
Phase is watered even spraying, and after medicine, 7 days preventive effects to striped rice borer, damping-off are respectively 97.9%, 87.4%.Comparison single dose 30%
Mould Lingshui Spring agent (formulation rate is 15 grams/acre), 20%ZJ4042 suspending agent (effective ingredient formulation rate is 3 grams/acre) are pressed
Same method dispenser, after medicine 7 days, 50% mould Lingshui Spring agent was respectively 0.8%, 88.3% to the preventive effect of striped rice borer, damping-off,
20%, ZJ4042 suspending agent is respectively 98.4%, 2.7% to the preventive effect of striped rice borer, damping-off.Mould spirit and ZJ4042 mixture
After can substantially increase pesticide-germicide spectrum, reach that disease pest is double controls effect, double preventive effect of controlling is better than single dose.
Embodiment 2 (15% mould spirit ZJ4042 suspension seed-coating agent)
By mould clever 1.0%, ZJ404214.0%, film former PVA1.0%, NP-101.0%, polyoxyethylene ether phosphate 3.0%,
Ethylene glycol 5.0%, BIT 0.01%, organic silicon defoamer 0.3%, xanthan gum 0.1%, warning coloration basic rhodamine 1.5%, remaining
Amount is water.Above-mentioned formula is pulverized the most in advance, adds in sand mill and grind, after high shear mixing, add film forming
Agent and warning coloration allotment prepare 15% mould spirit ZJ4042 suspension seed-coating agent.
It is applied to prevent and treat rice seedling striped rice borer, bakanae disease by the 15% of preparation mould spirit ZJ4042 suspension seed-coating agent.15%
Mould spirit ZJ4042 suspension seed-coating agent carries out rice paddy seed Dressing, normally by effective ingredient 10 grams/double centner seed
Seedling, after medicine, 30 days preventive effects to striped rice borer, bakanae disease are respectively 99.1%, 88.9%.The comparison mould spirit of single dose 30% is hanged
Floating seed coat agent (formulation rate is 10 grams/double centner seed), 20%ZJ4042 suspending agent (effective ingredient formulation rate is 5 grams/
Double centner seed), by same method Dressing, after medicine 30 days, 30% mould spirit suspension seed-coating agent was to striped rice borer, bakanae disease
Preventive effect be 0.7%, 85.9%, 20%, ZJ4042 suspending agent is respectively 97.1%, 5.4% to the preventive effect of striped rice borer, bakanae disease.
Can substantially increase pesticide-germicide spectrum after mould spirit and ZJ4042 mixture, reach that disease pest is double controls effect, double preventive effect of controlling is better than single dose.
Embodiment 3 (50% mould spirit ZJ4042 water-dispersible granules)
By mould clever 10%, ZJ404240%, dispersant (NNO+ wood sodium) 5%, Nekal BX 3%, K-12 (dodecyl sulfur
Acid sodium) 4%, binding agent carboxymethyl (ethyl) cellulose 5%, disintegrating agent (glucose) 5%, kieselguhr 3%, Kaolin mend
It is charged to 100%.By recipe requirements, aforementioned each composition mix homogeneously is become wettable powder through comminution by gas stream, is subsequently adding suitable quantity of water
Carry out pelletize, drying, granulate obtain 50% mould spirit ZJ4042 water dispersion granule.
It is applied to prevent and treat rice seedling striped rice borer, damping-off by the 50% of preparation mould spirit ZJ4042 water dispersion granule.50%
Mould spirit ZJ4042 water dispersion granule carries out rice paddy seed Dressing, normally by effective ingredient 5 grams/double centner seed
Seedling, after medicine, 25 days preventive effects to striped rice borer, damping-off are respectively 97.5%, 87.6%.The mould spirit of comparison single dose 30% suspends
Seed coat agent (formulation rate is 10 grams/double centner seed), (effective ingredient formulation rate is 5 grams/100 to 20%ZJ4042 suspending agent
Kilogram seed), by same method Dressing, after medicine 30 days, 30% mould spirit suspension seed-coating agent was to striped rice borer, bakanae disease
Preventive effect is 1.5%, 89.0%, and 20%ZJ4042 suspending agent is respectively 98.9%, 3.3% to the preventive effect of striped rice borer, bakanae disease.
Can substantially increase pesticide-germicide spectrum after mould spirit and ZJ4042 mixture, reach that disease pest is double controls effect, double preventive effect of controlling is better than single dose.
Claims (8)
1. an insecticidal and bactericidal composition, it is characterised in that described insecticidal and bactericidal composition contains two kinds of active component, the first activity becomes
Being divided into mould spirit, second active ingredient is the chloro-N of 3-1-(2-methyl-4-sevoflurane isopropyl base)-N2-(1-
Methyl isophthalic acid-cyano ethyl) phthalic amide, the quality proportioning of the first active component described and second active ingredient be 1～
10:20～100.
2. according to the insecticidal and bactericidal composition described in claim 1, it is characterised in that the first active component described becomes with the second activity
The quality proportioning divided is 2～4:20～40.
3. an insecticidal bactericide, it is characterised in that containing by weight 5～the insecticidal and bactericidal composition of 90% in described insecticidal bactericide,
Remaining is agriculturally acceptable carrier and auxiliary agent；Described insecticidal and bactericidal composition contains two kinds of active component, and the first activity becomes
Being divided into mould spirit, second active ingredient is the chloro-N of 3-1-(2-methyl-4-sevoflurane isopropyl base)-N2-(1-
Methyl isophthalic acid-cyano ethyl) phthalic amide, the quality proportioning of the first active component described and second active ingredient be 1～
10:20～100.
4. according to the insecticidal bactericide described in claim 3, it is characterised in that containing by weight 5～40% in described insecticidal bactericide
Insecticidal and bactericidal composition.
5. according to the insecticidal bactericide described in claim 3, it is characterised in that described insecticidal bactericide be formulated into cream, suspending agent,
Wettable powder or water dispersible granules.
6. according to the insecticidal bactericide described in claim 5, it is characterised in that described suspending agent is oil suspending agent.
7. the application of an insecticidal and bactericidal composition, it is characterised in that:
Described insecticidal and bactericidal composition is used for preventing and treating rice seedling pest and disease damage；
Described insecticidal and bactericidal composition contains two kinds of active component, and the first active component is mould spirit, and second active ingredient is
The chloro-N of 3-1-(2-methyl-4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalyl
Amine, the first active component described is 1～10:20～100 with the quality proportioning of second active ingredient.
8. according to the application of the insecticidal and bactericidal composition described in claim 7, it is characterised in that described insecticidal and bactericidal composition is used for preventing
Control rice seedling blight, bakanae disease and striped rice borer.
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| CN201410361773.2A CN104145965B (en) | 2014-07-28 | 2014-07-28 | A kind of insecticidal and bactericidal composition containing mould spirit |
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| CN104145965B true CN104145965B (en) | 2016-08-24 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104823766A (en) * | 2015-04-17 | 2015-08-12 | 常州百富电子有限公司 | Coriander trialeurodes vaporariorum prevention and cure method |
| CN106614662A (en) * | 2016-12-29 | 2017-05-10 | 成都格瑞赛斯科技有限公司 | Insecticide and fungicide composition containing cycloxaprid |
| CN106614613A (en) * | 2016-12-29 | 2017-05-10 | 成都格瑞赛斯科技有限公司 | Insecticide and fungicide composition for preventing and treating rice insect pests and diseases |
| CN108157371B (en) * | 2018-03-06 | 2021-06-01 | 冯夏 | Pesticide composition for seed coating agent |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008072783A1 (en) * | 2006-12-14 | 2008-06-19 | Ishihara Sangyo Kaisha, Ltd. | Pesticidal compositions |
| CN102613183A (en) * | 2012-03-07 | 2012-08-01 | 中化蓝天集团有限公司 | Insecticide |
| CN103250731A (en) * | 2013-05-30 | 2013-08-21 | 王鲁 | Insecticide sterilization compound agent containing hymexazol |
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2014
- 2014-07-28 CN CN201410361773.2A patent/CN104145965B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008072783A1 (en) * | 2006-12-14 | 2008-06-19 | Ishihara Sangyo Kaisha, Ltd. | Pesticidal compositions |
| CN102613183A (en) * | 2012-03-07 | 2012-08-01 | 中化蓝天集团有限公司 | Insecticide |
| CN103250731A (en) * | 2013-05-30 | 2013-08-21 | 王鲁 | Insecticide sterilization compound agent containing hymexazol |
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Denomination of invention: Insecticidal and bactericidal composition containing oxamyl Effective date of registration: 20211011 Granted publication date: 20160824 Pledgee: Industrial and Commercial Bank of China Limited Hangzhou Zhaohui sub branch Pledgor: SINOCHEM LANTIAN Co.,Ltd. Registration number: Y2021330001830 |
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Date of cancellation: 20220507 Granted publication date: 20160824 Pledgee: Industrial and Commercial Bank of China Limited Hangzhou Zhaohui sub branch Pledgor: SINOCHEM LANTIAN Co.,Ltd. Registration number: Y2021330001830 |