CN104140150B - A kind of one-level materialization intensive treatment coagulating agent of chemical engineering sewage - Google Patents
A kind of one-level materialization intensive treatment coagulating agent of chemical engineering sewage Download PDFInfo
- Publication number
- CN104140150B CN104140150B CN201410348354.5A CN201410348354A CN104140150B CN 104140150 B CN104140150 B CN 104140150B CN 201410348354 A CN201410348354 A CN 201410348354A CN 104140150 B CN104140150 B CN 104140150B
- Authority
- CN
- China
- Prior art keywords
- sewage
- chemical engineering
- coagulating agent
- carbon nanotube
- zine oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Water Treatment By Sorption (AREA)
Abstract
The invention discloses a kind of one-level materialization intensive treatment coagulating agent of chemical engineering sewage, relate to chemical engineering sewage processing technology field, be made up of the raw material of following weight: ferric sulfate 10-18kg, polymer aluminium silicate 8-12kg, sodium lignosulfonate 4-9kg, carbon nanotube 3-7kg, nano zine oxide 5-8kg, activated carbon fiber 3-6kg, polyvinyl alcohol 2-5kg, organo montmorillonite 2-5kg, resol 3-8kg, rapeseed oil 1-4kg, gas-produced black 1.5-3kg, propolis 0.5-2kg, calcium stearate 2-5kg, iron powder 8-12kg.The present invention utilizes carbon nanotube, nano zine oxide, activated carbon fiber and other multiple materialization agents process chemical engineering sewages, and processing speed is fast, effectively can remove COD, the BOD in sewage and organism.
Description
Technical field:
The present invention relates to chemical engineering sewage processing technology field, be specifically related to a kind of one-level materialization intensive treatment coagulating agent of chemical engineering sewage.
Background technology:
The topmost feature of chemical engineering sewage is: greatly, B/C is than low, and biodegradability is poor in water quality and quantity change.General chemical engineering sewage also has higher colourity, and pH value mostly is strongly-acid or strong basicity, therefore intractability is comparatively large, and process chemical engineering sewage becomes global problem.
After a lot of chemical engineering sewage treatment facility builds up, working cost is high, has even exceeded blowdown sustainability of enterprises, and the facility involved great expense becomes ornaments.After chemical enterprise spends huge sums and builds up sewage works, effluent quality can not up to standard or blowdown water quality unstable, the requirement of environmental administration cannot be reached, thus bring huge loss to enterprise.Therefore, the research of the process chemical engineering sewage novel process of efficient, low cost is had very important significance.
Summary of the invention:
Technical problem to be solved by this invention is the one-level materialization intensive treatment coagulating agent of the chemical engineering sewage providing a kind of processing speed fast, effective.
Technical problem to be solved by this invention adopts following technical scheme to realize:
An one-level materialization intensive treatment coagulating agent for chemical engineering sewage, is made up of the raw material of following weight:
Ferric sulfate 10-18kg, polymer aluminium silicate 8-12kg, sodium lignosulfonate 4-9kg, carbon nanotube 3-7kg, nano zine oxide 5-8kg, activated carbon fiber 3-6kg, polyvinyl alcohol 2-5kg, organo montmorillonite 2-5kg, resol 3-8kg, rapeseed oil 1-4kg, gas-produced black 1.5-3kg, propolis 0.5-2kg, calcium stearate 2-5kg, iron powder 8-12kg.
The fineness of described carbon nanotube is 10-20nm.
The particle diameter of described nano zine oxide is 50-100nm.
The invention has the beneficial effects as follows: the present invention utilizes carbon nanotube, nano zine oxide, activated carbon fiber and other multiple materialization agents process chemical engineering sewages, processing speed is fast, efficiently can remove the suspended substance in sewage, fall turbid, decolouring, limpid water quality, effectively remove COD, the BOD in sewage and organism.
Embodiment:
The technique means realized to make the present invention, creation characteristic, reaching object and effect is easy to understand, below in conjunction with specific embodiment, setting forth the present invention further.
Embodiment 1
The one-level materialization intensive treatment coagulating agent of described chemical engineering sewage is made up of the raw material of following weight: ferric sulfate 10kg, polymer aluminium silicate 8kg, sodium lignosulfonate 4kg, carbon nanotube 3kg, nano zine oxide 5kg, activated carbon fiber 3kg, polyvinyl alcohol 2kg, organo montmorillonite 2kg, resol 3kg, rapeseed oil 1kg, gas-produced black 1.5kg, propolis 0.5kg, calcium stearate 2kg, iron powder 8kg, wherein the fineness of carbon nanotube is 10-20nm, and the particle diameter of nano zine oxide is 50-100nm.
Embodiment 2
The one-level materialization intensive treatment coagulating agent of described chemical engineering sewage is made up of the raw material of following weight: ferric sulfate 15kg, polymer aluminium silicate 10kg, sodium lignosulfonate 6kg, carbon nanotube 5kg, nano zine oxide 6kg, activated carbon fiber 5kg, polyvinyl alcohol 3kg, organo montmorillonite 4kg, resol 5kg, rapeseed oil 2kg, gas-produced black 2kg, propolis 1kg, calcium stearate 3kg, iron powder 10kg, wherein the fineness of carbon nanotube is 10-20nm, and the particle diameter of nano zine oxide is 50-100nm.
Embodiment 3
The one-level materialization intensive treatment coagulating agent of described chemical engineering sewage is made up of the raw material of following weight: ferric sulfate 18kg, polymer aluminium silicate 12kg, sodium lignosulfonate 9kg, carbon nanotube 7kg, nano zine oxide 8kg, activated carbon fiber 6kg, polyvinyl alcohol 5kg, organo montmorillonite 5kg, resol 8kg, rapeseed oil 4kg, gas-produced black 3kg, propolis 2kg, calcium stearate 5kg, iron powder 12kg, wherein the fineness of carbon nanotube is 10-20nm, and the particle diameter of nano zine oxide is 50-100nm.
Coagulating agent described in embodiment 1-3 processes the sewage of a certain fertilizer plant in accordance with the following steps:
First ferric sulfate, polymer aluminium silicate, sodium lignosulfonate, polyvinyl alcohol, resol, propolis and calcium stearate solid are joined in the medicament barrel of magnetic force usefulness integrated machine for sewage treatment respectively, then add water and be made into the aqueous solution, in order to the process of 1000L sewage.
Be injected in the dispensing kit of magnetic force usefulness integrated machine for sewage treatment by needing sewage to be processed through sewage pump, then the consumption of required each medicament is calculated according to sewage load, above-mentioned medicament is sequentially added in dispensing kit by medicament barrel automatic gauge, add carbon nanotube, nano zine oxide, activated carbon fiber, organo montmorillonite, rapeseed oil, gas-produced black and iron powder in proportion simultaneously, after a series of process of magnetic force usefulness integrated machine for sewage treatment, obtain clear water.
Fertilizer plant's wastewater influent when embodiment 1-3 implements and the water-quality guideline of water outlet as shown in table 1:
Water inlet when table 1 embodiment 1-3 implements and the water-quality guideline of water outlet
| Control polluted articles | Wastewater influent index | Embodiment 1-3 effluent index |
| pH | 1.5-2 | 6-9 |
| SS(mg/L) | 600 | <200 |
| COD(mg/L) | 524 | <285 |
| BOD(mg/L) | 198 | <75 |
| Ammonia nitrogen (mg/L) | 250 | <80 |
| Total cyanide (mg/L) | 1.2 | <1.0 |
| Volatile phenol (mg/L) | 0.3 | <0.2 |
| Sulfide (mg/L) | 1.1 | <1.0 |
| Fluorochemical (mg/L) | 14 | <10 |
As can be seen from Table 1, the present invention utilizes the one-level materialization enhanced coagulation treatment agent in embodiment 1-3, processes, effectively can remove SS, COD, the BOD in sewage and organism in conjunction with magnetic force usefulness integrated machine for sewage treatment to fertilizer plant's sewage.In addition, the suspended substance can observed in sewage is efficiently removed, and turbidity obviously reduces, and water quality becomes clear.
More than show and describe ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.
Claims (3)
1. the one-level materialization intensive treatment coagulating agent of a chemical engineering sewage, it is characterized in that, be made up of the raw material of following weight: ferric sulfate 10-18kg, polymer aluminium silicate 8-12kg, sodium lignosulfonate 4-9kg, carbon nanotube 3-7kg, nano zine oxide 5-8kg, activated carbon fiber 3-6kg, polyvinyl alcohol 2-5kg, organo montmorillonite 2-5kg, resol 3-8kg, rapeseed oil 1-4kg, gas-produced black 1.5-3kg, propolis 0.5-2kg, calcium stearate 2-5kg, iron powder 8-12kg;
Its treatment process comprises the steps:
(1) first ferric sulfate, polymer aluminium silicate, sodium lignosulfonate, polyvinyl alcohol, resol, propolis and calcium stearate solid are joined in the medicament barrel of magnetic force usefulness integrated machine for sewage treatment respectively, then add water and be made into the aqueous solution, in order to the process of 1000L sewage;
(2) will sewage to be processed be needed to be injected in the dispensing kit of magnetic force usefulness integrated machine for sewage treatment through sewage pump, then the consumption of required each medicament is calculated according to sewage load, above-mentioned medicament is sequentially added in dispensing kit by medicament barrel automatic gauge, add carbon nanotube, nano zine oxide, activated carbon fiber, organo montmorillonite, rapeseed oil, gas-produced black and iron powder in proportion simultaneously, after a series of process of magnetic force usefulness integrated machine for sewage treatment, obtain clear water.
2. the one-level materialization intensive treatment coagulating agent of a kind of chemical engineering sewage according to claim 1, is characterized in that: the fineness of described carbon nanotube is 10-20nm.
3. the one-level materialization intensive treatment coagulating agent of a kind of chemical engineering sewage according to claim 1, is characterized in that: the particle diameter of described nano zine oxide is 50-100nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410348354.5A CN104140150B (en) | 2014-07-21 | 2014-07-21 | A kind of one-level materialization intensive treatment coagulating agent of chemical engineering sewage |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410348354.5A CN104140150B (en) | 2014-07-21 | 2014-07-21 | A kind of one-level materialization intensive treatment coagulating agent of chemical engineering sewage |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104140150A CN104140150A (en) | 2014-11-12 |
| CN104140150B true CN104140150B (en) | 2015-08-05 |
Family
ID=51849506
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410348354.5A Active CN104140150B (en) | 2014-07-21 | 2014-07-21 | A kind of one-level materialization intensive treatment coagulating agent of chemical engineering sewage |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104140150B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104445459B (en) * | 2014-11-13 | 2016-05-25 | 苏州市相城区盛胡特种养殖专业合作社 | A kind of efficient nano water purification agent and preparation method thereof |
| CN106477694A (en) * | 2015-08-26 | 2017-03-08 | 盐城市瓯华化学工业有限公司 | A kind of chemical engineering sewage materialization intensive treatment coagulant |
| CN105271495A (en) * | 2015-10-26 | 2016-01-27 | 苏州书瑞环保科技有限公司 | Nano flocculation material for water treatment and preparation method of nano flocculation material |
| CN106145216A (en) * | 2016-07-29 | 2016-11-23 | 周圣聪 | One breeding enterprise sewage-treating agent and its preparation method and application |
| CN106520110A (en) * | 2016-10-26 | 2017-03-22 | 中国石油化工股份有限公司 | Environment-friendly composite gel breaking agent and preparation method and application thereof |
| CN112645662A (en) * | 2021-01-07 | 2021-04-13 | 中铁城建集团第一工程有限公司 | Carbon oxide nanotube modified cement-based material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1350986A (en) * | 2000-10-26 | 2002-05-29 | 中国石油化工股份有限公司 | Process for treating recovered water in oil field |
| CN101172683A (en) * | 2007-11-07 | 2008-05-07 | 天津大学 | Water treatment combination coagulant and combination coagulating method thereof |
| CN101643261A (en) * | 2009-08-24 | 2010-02-10 | 暨南大学 | Algae-controlling laterite compound flocculant as well as preparation method and applications thereof |
| CN103351045A (en) * | 2013-07-18 | 2013-10-16 | 山东中科天泽净水材料有限公司 | Nano composite polyaluminum ferric chloride flocculant and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2324141B1 (en) * | 2008-01-11 | 2010-05-25 | Universidad De Jaen | PROCEDURE FOR WATER TREATMENT FROM WASHING OF AGRICULTURAL PRODUCTS. |
-
2014
- 2014-07-21 CN CN201410348354.5A patent/CN104140150B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1350986A (en) * | 2000-10-26 | 2002-05-29 | 中国石油化工股份有限公司 | Process for treating recovered water in oil field |
| CN101172683A (en) * | 2007-11-07 | 2008-05-07 | 天津大学 | Water treatment combination coagulant and combination coagulating method thereof |
| CN101643261A (en) * | 2009-08-24 | 2010-02-10 | 暨南大学 | Algae-controlling laterite compound flocculant as well as preparation method and applications thereof |
| CN103351045A (en) * | 2013-07-18 | 2013-10-16 | 山东中科天泽净水材料有限公司 | Nano composite polyaluminum ferric chloride flocculant and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104140150A (en) | 2014-11-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104140150B (en) | A kind of one-level materialization intensive treatment coagulating agent of chemical engineering sewage | |
| CN104150574B (en) | A kind of one-level materialization enhanced coagulation agent of coal mine sewage and treatment process thereof | |
| CN103979678B (en) | A kind of anaerobic ammonia oxidation reactor operation method processing high-salt wastewater | |
| CN105084489A (en) | Environment-friendly water treatment settling agent and preparation method thereof | |
| Wang et al. | A modified BAF system configuring synergistic denitrification and chemical phosphorus precipitation: examination on pollutants removal and clogging development | |
| MY195057A (en) | A Method for Rapid Start-Up of Microbial Granulation In Wastewater Biotreatment Process | |
| CN103708568A (en) | Papermaking sewage treatment agent | |
| CN104140148B (en) | A kind of one-level materialization enhanced coagulation agent of town sewage and treatment process thereof | |
| CN104140147B (en) | A kind of one-level materialization enhanced coagulation agent of oilfield sewage and treatment process thereof | |
| JP2018535093A (en) | Improvement of phosphorus precipitation and membrane flux in membrane bioreactors | |
| CN105253933A (en) | Non-phosphorus water treatment material and preparation method thereof | |
| CN104150575B (en) | A kind of one-level materialization enhanced coagulation agent of dyeing and printing sewage and treatment process thereof | |
| CN104150573B (en) | A kind of one-level materialization enhanced coagulation agent of papermaking wastewater and treatment process thereof | |
| CN104082337A (en) | Compound bactericide used in oilfield flooding | |
| CN105271495A (en) | Nano flocculation material for water treatment and preparation method of nano flocculation material | |
| CN104478104B (en) | A kind of without phosphorus solid anti-scaling compound and using method thereof | |
| CN104140151B (en) | A kind of one-level materialization intensive treatment coagulating agent of electroplating sewerage | |
| CN107720858A (en) | Industrial sewage treating agent | |
| CN204079713U (en) | A kind of sewage disposal additional carbon cascade controller | |
| CN105668742A (en) | Environment-friendly water treatment flocculation material and preparation method thereof | |
| CN105347463A (en) | Sludge reducing method in sewage treatment | |
| CN110627302A (en) | Pharmacy sewage environmental protection processing system | |
| CN108059220A (en) | A kind of flocculant | |
| CN212198844U (en) | Industrial waste water treatment device | |
| CN111099705A (en) | Coal chemical wastewater flocculant and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |