CN105271495A - Nano flocculation material for water treatment and preparation method of nano flocculation material - Google Patents
Nano flocculation material for water treatment and preparation method of nano flocculation material Download PDFInfo
- Publication number
- CN105271495A CN105271495A CN201510700420.5A CN201510700420A CN105271495A CN 105271495 A CN105271495 A CN 105271495A CN 201510700420 A CN201510700420 A CN 201510700420A CN 105271495 A CN105271495 A CN 105271495A
- Authority
- CN
- China
- Prior art keywords
- weight part
- flocculation material
- water process
- parts
- nano
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses a nano flocculation material for water treatment and a preparation method of the nano flocculation material. The nano flocculation material for water treatment comprises components in parts by weight as follows: 45-55 parts of dimethylamino ethyl methacrylate, 8-12 parts of diallyl dimethyl ammonium chloride, 8-11 parts of mannitol, 7-9 parts of N-(5-ethoxy) nicotinamide nitrate, 3-5 parts of hydroxypropyl methyl cellulose, 2-3 parts of polyoxyethylene sorbitan monooleate, 3-5 parts of cetyl alcohol, 1-1.5 parts of activated carbon fiber and 0.5-1 part of borax. The invention further provides a preparation method of the nano flocculation material for water treatment.
Description
Technical field
The invention belongs to technical field of water treatment, particularly a kind of nanometer water process flocculation material and preparation method thereof.
Background technology
Water treatment effectively can remove the dirt in pending water, reduces the pollution load of sewage subsequent disposal.Conventional water treatment reagent has flocculation agent, and flocculation agent can be divided into inorganic flocculating agent and organic floculant two class according to its chemical composition.Wherein organic floculant comprises again organic coagulant and organic polymer coargulator; Organic floculant comprises again Syn-Organic flocculants, natural organic high-molecular flocculant and microbial flocculant.Inorganic flocculating agent can be divided into low molecule flocculation agent and polymeric flocculant again, and low molecule flocculation agent has aluminium salt system and molysite system, and low molecule flocculation agent cost is lower, but its flocculation sediment speed is slow, flocculation agent consumption is high; Conventional polymeric flocculant has aluminum chloride hydrocarbon complex, polyaluminium sulfate, bodied ferric sulfate etc., although the problem that the processing efficiency overcoming the existence of low molecule flocculation agent is low, its use cost is higher, and treatment effect is poor when low temperature.
Summary of the invention
For above-mentioned demand, invention especially provides a kind of nanometer water process flocculation material and preparation method thereof.
Object of the present invention can be achieved through the following technical solutions:
A kind of nanometer water process flocculation material, be made up of the component comprising following weight part:
Dimethylamino ethylene methacrylate 45-55 part,
Dimethyl diallyl ammonium chloride 8-12 part,
N.F,USP MANNITOL 8-11 part,
N-(5-hydroxyethyl) Nicorandil 7-9 part,
Vltra tears 3-5 part,
Poly ethylene oxide sorbitol monooleate 2-3 part,
Cetyl alcohol 3-5 part,
Activated carbon fiber 1-1.5 part,
Borax 0.5-1 part.
Described component also comprises polylysine 0-2 weight part.
The diameter of described activated carbon fiber is 40-55 nanometer.
A preparation method for nanometer water process flocculation material, the method comprises the following steps:
(1) take dimethylamino ethylene methacrylate 45-55 weight part, dimethyl diallyl ammonium chloride 8-12 weight part, N.F,USP MANNITOL 8-11 weight part, N-(5-hydroxyethyl) Nicorandil 7-9 weight part, Vltra tears 3-5 weight part, poly ethylene oxide sorbitol monooleate 2-3 weight part, cetyl alcohol 3-5 weight part, activated carbon fiber 1-1.5 weight part, borax 0.5-1 weight part and polylysine 0-2 weight part, stir;
(2) add in high pressure homogenizer and mix 5-10 minute, be cooled to room temperature, obtain nanometer water process flocculation material.
Mixing temperature in described high pressure homogenizer is 65-75 DEG C, and blend pressure is 15-18MPa.
compared with prior art, its beneficial effect is in the present invention:(1) the nanometer water process flocculation material that obtains of the present invention with dimethylamino ethylene methacrylate for main raw material, by adding dimethyl diallyl ammonium chloride, N.F,USP MANNITOL, N-(5-hydroxyethyl) Nicorandil, Vltra tears, poly ethylene oxide sorbitol monooleate, cetyl alcohol, activated carbon fiber and borax, obtained nanometer water process flocculation material has good Adsorption and flocculation performance, and this nanometer water process flocculation material has good stability.
(2) the nanometer water process flocculation material that the present invention obtains still can effectively flocculate in lower or higher envrionment temperature, can remove impurities in water in a large number.
(3) nanometer water process flocculation material of the present invention, its preparation method is simple, is easy to suitability for industrialized production.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
(1) take dimethylamino ethylene methacrylate 45kg, dimethyl diallyl ammonium chloride 8kg, activated carbon fiber 1kg, borax 0.5kg that N.F,USP MANNITOL 8kg, N-(5-hydroxyethyl) Nicorandil 7kg, Vltra tears 3kg, poly ethylene oxide sorbitol monooleate 2kg, cetyl alcohol 3kg, diameter are 40 nanometers, stir;
(2) to add in high pressure homogenizer 65 DEG C, mixing 5 minutes under 15MPa, be cooled to room temperature, obtain nanometer water process flocculation material.
The performance test results of obtained nanometer water process flocculation material is as shown in table 1.
Embodiment 2
(1) take dimethylamino ethylene methacrylate 55kg, dimethyl diallyl ammonium chloride 12kg, activated carbon fiber 1.5kg, borax 1kg and polylysine 2kg that N.F,USP MANNITOL 11kg, N-(5-hydroxyethyl) Nicorandil 9kg, Vltra tears 5kg, poly ethylene oxide sorbitol monooleate 3kg, cetyl alcohol 5kg, diameter are 55 nanometers, stir;
(2) to add in high pressure homogenizer 75 DEG C, mixing 10 minutes under 18MPa, be cooled to room temperature, obtain nanometer water process flocculation material.
The performance test results of obtained nanometer water process flocculation material is as shown in table 1.
Embodiment 3
(1) take dimethylamino ethylene methacrylate 50kg, dimethyl diallyl ammonium chloride 10kg, activated carbon fiber 1kg, borax 0.8kg and polylysine 1kg that N.F,USP MANNITOL 9kg, N-(5-hydroxyethyl) Nicorandil 8kg, Vltra tears 4kg, poly ethylene oxide sorbitol monooleate 2.5kg, cetyl alcohol 4kg, diameter are 45 nanometers, stir;
(2) to add in high pressure homogenizer 70 DEG C, mixing 8 minutes under 17MPa, be cooled to room temperature, obtain nanometer water process flocculation material.
The performance test results of obtained nanometer water process flocculation material is as shown in table 1.
The flocculation material of embodiment 1-3 is used for sewage disposal: when to use it for COD be in the sewage of 600mg/L, the consumption of flocculation material is the treatment effect that 0.2g/L can reach good, and concrete outcome asks for an interview table 1.
Table 1
| Test event | Turbidity (NTU) clearance | COD（mg/L） |
| Embodiment 1 | 96% | 34 |
| Embodiment 2 | 95% | 28 |
| Embodiment 3 | 93% | 36 |
The invention is not restricted to embodiment here, those skilled in the art, according to announcement of the present invention, do not depart from improvement that scope makes and amendment all should within protection scope of the present invention.
Claims (5)
1. a nanometer water process flocculation material, is characterized in that, is made up of the component comprising following weight part:
Dimethylamino ethylene methacrylate 45-55 part,
Dimethyl diallyl ammonium chloride 8-12 part,
N.F,USP MANNITOL 8-11 part,
N-(5-hydroxyethyl) Nicorandil 7-9 part,
Vltra tears 3-5 part,
Poly ethylene oxide sorbitol monooleate 2-3 part,
Cetyl alcohol 3-5 part,
Activated carbon fiber 1-1.5 part,
Borax 0.5-1 part.
2. nanometer water process flocculation material according to claim 1, it is characterized in that, described component also comprises polylysine 0-2 weight part.
3. nanometer water process flocculation material according to claim 1, it is characterized in that, the diameter of described activated carbon fiber is 40-55 nanometer.
4. a preparation method for nanometer water process flocculation material, is characterized in that, the method comprises the following steps:
(1) take dimethylamino ethylene methacrylate 45-55 weight part, dimethyl diallyl ammonium chloride 8-12 weight part, N.F,USP MANNITOL 8-11 weight part, N-(5-hydroxyethyl) Nicorandil 7-9 weight part, Vltra tears 3-5 weight part, poly ethylene oxide sorbitol monooleate 2-3 weight part, cetyl alcohol 3-5 weight part, activated carbon fiber 1-1.5 weight part, borax 0.5-1 weight part and polylysine 0-2 weight part, stir;
(2) add in high pressure homogenizer and mix 5-10 minute, be cooled to room temperature, obtain nanometer water process flocculation material.
5. the preparation method of nanometer water process flocculation material according to claim 4, it is characterized in that, the mixing temperature in described high pressure homogenizer is 65-75 DEG C, and blend pressure is 15-18MPa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510700420.5A CN105271495A (en) | 2015-10-26 | 2015-10-26 | Nano flocculation material for water treatment and preparation method of nano flocculation material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510700420.5A CN105271495A (en) | 2015-10-26 | 2015-10-26 | Nano flocculation material for water treatment and preparation method of nano flocculation material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105271495A true CN105271495A (en) | 2016-01-27 |
Family
ID=55141433
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510700420.5A Pending CN105271495A (en) | 2015-10-26 | 2015-10-26 | Nano flocculation material for water treatment and preparation method of nano flocculation material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105271495A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105668742A (en) * | 2016-03-30 | 2016-06-15 | 苏州能华节能环保科技有限公司 | Environment-friendly water treatment flocculation material and preparation method thereof |
| CN106365283A (en) * | 2016-11-24 | 2017-02-01 | 刘可 | Flocculant for treating slaughter wastewater, and preparation method and application thereof |
| CN106904707A (en) * | 2017-03-13 | 2017-06-30 | 苏州顶裕生物科技有限公司 | A kind of flocculant |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101143743A (en) * | 2006-09-15 | 2008-03-19 | 中国石油化工股份有限公司 | Method for preparing cation type polymeric flocculant |
| CN102452709A (en) * | 2010-10-15 | 2012-05-16 | 中国石油化工股份有限公司 | Fly ash composite flocculating agent and preparation method thereof |
| CN104140150A (en) * | 2014-07-21 | 2014-11-12 | 安徽三环水泵有限责任公司 | Primary physicochemical enhanced treatment coagulant for chemical waste water |
| CN104843844A (en) * | 2015-05-07 | 2015-08-19 | 苏州能华节能环保科技有限公司 | Environmental protection treating agent for metal processing waste water and preparation method thereof |
-
2015
- 2015-10-26 CN CN201510700420.5A patent/CN105271495A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101143743A (en) * | 2006-09-15 | 2008-03-19 | 中国石油化工股份有限公司 | Method for preparing cation type polymeric flocculant |
| CN102452709A (en) * | 2010-10-15 | 2012-05-16 | 中国石油化工股份有限公司 | Fly ash composite flocculating agent and preparation method thereof |
| CN104140150A (en) * | 2014-07-21 | 2014-11-12 | 安徽三环水泵有限责任公司 | Primary physicochemical enhanced treatment coagulant for chemical waste water |
| CN104843844A (en) * | 2015-05-07 | 2015-08-19 | 苏州能华节能环保科技有限公司 | Environmental protection treating agent for metal processing waste water and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105668742A (en) * | 2016-03-30 | 2016-06-15 | 苏州能华节能环保科技有限公司 | Environment-friendly water treatment flocculation material and preparation method thereof |
| CN106365283A (en) * | 2016-11-24 | 2017-02-01 | 刘可 | Flocculant for treating slaughter wastewater, and preparation method and application thereof |
| CN106365283B (en) * | 2016-11-24 | 2019-08-16 | 神美科技有限公司 | A kind of flocculant and its preparation method and application handling slaughtering wastewater |
| CN106904707A (en) * | 2017-03-13 | 2017-06-30 | 苏州顶裕生物科技有限公司 | A kind of flocculant |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105271496A (en) | Environment-friendly nano sedimentation agent for water treatment and preparation method of sedimentation agent | |
| CN105084489A (en) | Environment-friendly water treatment settling agent and preparation method thereof | |
| CN105271495A (en) | Nano flocculation material for water treatment and preparation method of nano flocculation material | |
| CN101041495A (en) | High polymer composite coagulant for treatment of oily waste water and making method thereof | |
| CN102674657A (en) | Sludge dewatering method for urban sewage plant | |
| CN105130009A (en) | Microbial coagulant for municipal wastewater and preparation method thereof | |
| CN104140150B (en) | A kind of one-level materialization intensive treatment coagulating agent of chemical engineering sewage | |
| CN104973680A (en) | Efficient multi-purpose sewage treatment agent and sewage treatment method utilizing same | |
| CN105198061A (en) | Flocculant composition and application thereof | |
| CN112390321B (en) | Phosphorus removal agent for sewage treatment and preparation method thereof | |
| CN104355373A (en) | Sewage purification disinfectant and preparation method thereof | |
| CN105327683A (en) | Carbon nanotube printing and dyeing wastewater treatment complexing agent based on SiO<2>/TiO<2> mesoporous composite microsphere carrier and preparation method | |
| CN102557218A (en) | Composite flocculating agent containing various polyacrylamides and preparation method for composite flocculating agent | |
| CN105084488A (en) | Nano water treatment flocculation material and preparation method thereof | |
| CN104478056A (en) | Sewage disposal agent | |
| CN102126780B (en) | Application of efficient COD (chemical oxygen demand) remover to wastewater treatment | |
| CN104140148B (en) | A kind of one-level materialization enhanced coagulation agent of town sewage and treatment process thereof | |
| CN104724810B (en) | Environment-friendly flocculant with natural high polymer as major component | |
| CN103723808A (en) | Method adopting polymeric ferric sulfate and polyacrylamide for treating sewage | |
| CN103663730B (en) | A kind of zymin processing papermaking wastewater | |
| CN105293667A (en) | Environment-friendly water treatment agent for removing chromium ions and preparation method thereof | |
| CN107792927B (en) | Inorganic-cationic polymer composite coagulant and preparation method thereof | |
| CN110642349A (en) | Flocculation treatment method for landfill leachate | |
| CN105268409A (en) | Arsenic adsorption treatment agent and preparation method thereof | |
| CN104291442A (en) | Method for inhibiting activated sludge bulking of SBR pool |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160127 |