CN104082337A - Compound bactericide used in oilfield flooding - Google Patents
Compound bactericide used in oilfield flooding Download PDFInfo
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- CN104082337A CN104082337A CN201410358519.7A CN201410358519A CN104082337A CN 104082337 A CN104082337 A CN 104082337A CN 201410358519 A CN201410358519 A CN 201410358519A CN 104082337 A CN104082337 A CN 104082337A
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- bactericide
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- flooding
- bacteria
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Abstract
The invention provides a compound bactericide used in oilfield flooding, relating to oilfield water treatment. The bactericide comprises the following components by weight percent: 50-60% of deionized water, 5-10% of surfactant, 25-30% of quaternary phosphonium salt and 5-10% of methylene dithiocyanate. The bactericide used in oilfield flooding can act under the conditions of high hardness, high alkalinity and high temperature, has good bactericidal effects on fungi and slime saprophytic bacteria, especially has terrific treatment effects on sulfate reducing bacteria, has long bactericidal efficiency duration, can effectively maintain reproduction of microorganisms in oil wells and can be widely used in the fields of oilfield flooding and sewage treatment in the oilfield industry.
Description
Technical field
The present invention relates to water treatment field, relate to specifically oil-field flooding bactericide.
Background technology
In the secondary oil recovery of oil field, need a large amount of water fillings, in flood pattern, contain various microorganisms as sulfate reducing bacteria (SRB), saprophytic bacteria (TGB) and iron bacteria etc., they are in growth, metabolism, reproductive process, can cause heavy corrosion the blocking pipe of the metal materials such as drilling-production equipment, waterflood-transmission line, infringement oil reservoir, causes water injection rate, oil production rate, oil gas Quality Down, also for crude oil processing brings exceptional hardship, cause great economic loss.Therefore, generally all need to before water filling, add bactericide and carry out pretreatment.The bactericide that oil field is used is at present all generally the medicament of continuing to use domestic use of water and industrial circulating water, by its sterilization mechanism, can be divided into aerobic type bactericide and non-oxygen type bactericide.Due to oil field environment and different to the requirement of water quality, the kind of bacterium and harm thereof are different, therefore also different to the performance requirement of bactericide.
Maximum bacterium is endangered in oil field sulfate reducing bacteria, iron bacteria and saprophytic bacteria, therefore, selects bactericide to start with for these bacteriums.Sulfate reducing bacteria is anaerobic bacteria, and oxidable carbon containing organic compound or hydrogen, sulphate reducing produce H
2s.Corrosion product FeS again can blocking pipe and water injection well.Because the harm of sulfate reducing bacteria is maximum, almost hinder and recover the oil in all its bearings, so people take much count of the research to it in recent years, as found the new bacterial strain of sulfate reducing bacteria, the scope of its oxidation carbonaceous organic material etc.Saprophytic bacteria claims again mucus to form bacterium, it is aerobic heterotroph, it is secreted a large amount of mucus and is attached on pipeline and equipment, cause biofouling to stop up water injection well and filter, meanwhile, also can produce oxygen concentration cell and cause the corrosion of e-quipment and pipe and the environment etc. of existence, breeding is provided to sulfate reducing bacteria.Wherein most important saprophytic bacteria-iron bacteria is the Duo Muduo section bacterium that distributes very wide, it is mainly that ferrous oxidation is become to high price iron, the energy that utilizes iron oxidation to discharge meets the needs of its existence, its general saprophytic bacteria of hazard ratio harm large, the bacterial classification of selecting while detecting fungicide effect often.The vitality of bacterium is extremely strong, and any bactericide service time is long all can make bacterium develop immunity to drugs, and causes the problems such as germicidal efficiency decline, dose increase of bactericide, therefore, need to constantly develop new oil field bactericide.China is making extensive work aspect the research and development of oil field bactericide, still take at present SAA series bactericidal agent as main.
Summary of the invention
The present invention is directed to the shortcoming of above-mentioned existence, a kind of Compositional type oil-field flooding bactericide is provided.
Compositional type oil-field flooding bactericide comprises deionized water, surfactant, season phosphonium salt, dithiocyano-methane.The percentage by weight of each component is:
Deionized water 50-60%
Surfactant 5-10%
Season phosphonium salt 25-30%
Dithiocyano-methane 5-10%
This oil-field flooding bactericide can act under high rigidity, high alkalinity, high-temperature condition, and good to fungi, foundry loam saprophytic bacteria bactericidal effect, particularly processing sulfate reducing bacteria has fabulous effect.The germicidal efficiency duration is long, can effectively maintain the breeding of the microorganism in oil well.This product can be widely used in sewage treatment area in oil-field flooding and oilfield applications.
embodiment
Embodiment 1:
Choose by weight percentage raw material
Deionized water 60%
Sodium hexadecyl sulfate 8%
Tetrakis hydroxymetyl phosphonium sulfuric 27%
Dithiocyano-methane 5%
Embodiment 2:
Choose by weight percentage raw material
Deionized water 55%
Lauryl sodium sulfate 10%
Tetra methylol phosphonium chloride 30%
Dithiocyano-methane 5%
Embodiment 3:
Choose by weight percentage raw material
Deionized water 55%
Sodium hexadecyl sulfate 8%
Tetra methylol phosphonium chloride 30%
Dithiocyano-methane 7%
application test and result
Medicament and single season phosphonium salt bactericidal effect contrast table 1
The bactericidal effect contrast of table 1 medicament and single quaternary alkylphosphonium salt
2. the bactericidal effect contrast table 1 of embodiment and single quaternary ammonium salt
The bactericidal effect contrast of table 2 embodiment and single quaternary ammonium salt
as can be seen from the above table, the product of embodiments of the invention 1, embodiment 2, embodiment 3 is excellent to the bactericidal effect of sulfate reducing bacteria, much larger than current conventional non oxidizing bactericide, has reached the requirement of the present invention to sulphate bactericidal effect completely.
Claims (3)
1. Compositional type oil-field flooding bactericide comprises deionized water, surfactant, season phosphonium salt, a dithiocyano-methane, and the percentage by weight of each component is:
Deionized water 50-60%
Surfactant 5-10%
Season phosphonium salt 25-30%
Dithiocyano-methane 5-10%.
2. oil-field flooding bactericide as claimed in claim 1, is characterized in that: said season phosphonium salt be a kind of in tetra methylol phosphonium chloride, tetra methylol sulfuric acid phosphine.
3. oil-field flooding bactericide as claimed in claim 1, is characterized in that: said a kind of surfactant is a kind of in lauryl sodium sulfate, sodium hexadecyl sulfate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410358519.7A CN104082337A (en) | 2014-07-26 | 2014-07-26 | Compound bactericide used in oilfield flooding |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410358519.7A CN104082337A (en) | 2014-07-26 | 2014-07-26 | Compound bactericide used in oilfield flooding |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104082337A true CN104082337A (en) | 2014-10-08 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410358519.7A Pending CN104082337A (en) | 2014-07-26 | 2014-07-26 | Compound bactericide used in oilfield flooding |
Country Status (1)
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| CN (1) | CN104082337A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104397055A (en) * | 2014-10-19 | 2015-03-11 | 无棣华信石油技术服务有限公司 | Oilfield compound type bactericide and preparation method thereof |
| CN104488957A (en) * | 2014-12-10 | 2015-04-08 | 山东天庆科技发展有限公司 | Efficient composite germicide for circulating water system and preparation method thereof |
| CN105152501A (en) * | 2015-08-14 | 2015-12-16 | 成都科衡环保技术有限公司 | Cleaning agent for treating three-sulfonated system water-base mud waste and preparation method |
| CN116195604A (en) * | 2023-02-23 | 2023-06-02 | 内蒙古南大环保科技有限公司 | Non-oxidizing bactericide for double-membrane method and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1491907A (en) * | 2002-10-23 | 2004-04-28 | 中国石油化工股份有限公司北京燕山分 | Composite scale resistant corrosion inhibitor and its use in reusing ammonia-nitrogen containing waste water in circulating cooling water |
| CN101779654A (en) * | 2009-12-21 | 2010-07-21 | 许庆华 | Attapulgite oil-extracting and water-injecting sterilizing algicide for oil field |
| CN102942908A (en) * | 2012-11-22 | 2013-02-27 | 中国海洋石油总公司 | Water injected pitting-corrosion composite inhibitor and application thereof |
| CN103444760A (en) * | 2013-08-21 | 2013-12-18 | 苏州康华净化系统工程有限公司 | Sterilizing algicide for circulating cooling water and preparation method of sterilizing algicide |
-
2014
- 2014-07-26 CN CN201410358519.7A patent/CN104082337A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1491907A (en) * | 2002-10-23 | 2004-04-28 | 中国石油化工股份有限公司北京燕山分 | Composite scale resistant corrosion inhibitor and its use in reusing ammonia-nitrogen containing waste water in circulating cooling water |
| CN101779654A (en) * | 2009-12-21 | 2010-07-21 | 许庆华 | Attapulgite oil-extracting and water-injecting sterilizing algicide for oil field |
| CN102942908A (en) * | 2012-11-22 | 2013-02-27 | 中国海洋石油总公司 | Water injected pitting-corrosion composite inhibitor and application thereof |
| CN103444760A (en) * | 2013-08-21 | 2013-12-18 | 苏州康华净化系统工程有限公司 | Sterilizing algicide for circulating cooling water and preparation method of sterilizing algicide |
Non-Patent Citations (1)
| Title |
|---|
| 宋绍富 等: ""油田杀菌工艺及杀菌剂研究进展"", 《石油化工应用》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104397055A (en) * | 2014-10-19 | 2015-03-11 | 无棣华信石油技术服务有限公司 | Oilfield compound type bactericide and preparation method thereof |
| CN104488957A (en) * | 2014-12-10 | 2015-04-08 | 山东天庆科技发展有限公司 | Efficient composite germicide for circulating water system and preparation method thereof |
| CN104488957B (en) * | 2014-12-10 | 2016-08-24 | 山东天庆科技发展有限公司 | Circulation high efficiency composition antibacterial and preparation method thereof |
| CN105152501A (en) * | 2015-08-14 | 2015-12-16 | 成都科衡环保技术有限公司 | Cleaning agent for treating three-sulfonated system water-base mud waste and preparation method |
| CN105152501B (en) * | 2015-08-14 | 2018-09-25 | 成都科衡环保技术有限公司 | A kind of cleaning agent and preparation method of the processing series water-based mud waste of three sulphurs |
| CN116195604A (en) * | 2023-02-23 | 2023-06-02 | 内蒙古南大环保科技有限公司 | Non-oxidizing bactericide for double-membrane method and preparation method thereof |
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Application publication date: 20141008 |
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