CN104397018A - Isothiazolinone water treatment bactericide and preparation method thereof - Google Patents
Isothiazolinone water treatment bactericide and preparation method thereof Download PDFInfo
- Publication number
- CN104397018A CN104397018A CN201410649183.XA CN201410649183A CN104397018A CN 104397018 A CN104397018 A CN 104397018A CN 201410649183 A CN201410649183 A CN 201410649183A CN 104397018 A CN104397018 A CN 104397018A
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- CN
- China
- Prior art keywords
- isothiazolinone
- water treatment
- wetting agent
- trimethylamine
- chlorine dioxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 42
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 230000000844 anti-bacterial effect Effects 0.000 title abstract description 20
- 239000003899 bactericide agent Substances 0.000 title abstract description 16
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims abstract description 32
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000000080 wetting agent Substances 0.000 claims abstract description 18
- 239000004155 Chlorine dioxide Substances 0.000 claims abstract description 16
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229940073608 benzyl chloride Drugs 0.000 claims abstract description 16
- 235000019398 chlorine dioxide Nutrition 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 16
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 16
- 238000003756 stirring Methods 0.000 claims abstract description 7
- 230000003115 biocidal effect Effects 0.000 claims description 13
- 239000003139 biocide Substances 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 238000011161 development Methods 0.000 abstract description 6
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 239000003344 environmental pollutant Substances 0.000 abstract description 2
- 239000006260 foam Substances 0.000 abstract description 2
- 231100000719 pollutant Toxicity 0.000 abstract description 2
- 239000000047 product Substances 0.000 abstract 2
- 230000007794 irritation Effects 0.000 abstract 1
- 239000012263 liquid product Substances 0.000 abstract 1
- 241000894006 Bacteria Species 0.000 description 14
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 230000018109 developmental process Effects 0.000 description 5
- 241000295146 Gallionellaceae Species 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an isothiazolinone water treatment bactericide, which is characterized by being composed of, by weight, 60-75% of deionized water, 5%-12% of benzyl chloride, 2%-4% of a wetting agent, 6%-12% of trimethylamine, 1.5%-4.5% of isothiazolinone, and 4%-8% of chlorine dioxide. The preparation process includes: adding deionized water, benzyl chloride, the wetting agent, trimethylamine, isothiazolinone and chlorine dioxide sequentially into a stirring reactor to conduct stirring for 30min, thus obtaining a liquid product. The isothiazolinone water treatment bactericide provided by the invention has no corrosivity, no irritation and no foam, is an upgrade product of the oilfield SRB bactericide, and the product effect reaches the domestic leading level. In addition, the preparation process has the advantages of simple operation, no emission of pollutants, mild reaction conditions, and low energy consumption, thus meeting the requirements of sustainable development.
Description
Technical field
The invention belongs to water treatment field, be specifically related to oil field reinjection water treatment agent, refer to a kind of isothiazolinone water treatment biocide and preparation method thereof especially.
Background technology
In tertiary oil production in oil field note is poly-, need a large amount of reinjected water, owing to generally all containing the bacteriums such as sulfate reducing bacteria (SRB), saprophytic bacteria (TGB) and iron bacteria, the raised growth of these bacteriums and breeding in reinjected water, not only reservoir is caused damage blocking, affect development effectiveness, cause oil recovery factor to decline, and make water injection well pressure increase, water injecting consumption rises, therefore, bactericide is selected will to start with for these bacteriums.Reinjected water contains higher calcium ions and magnesium ions simultaneously, easily make waterflood-transmission line and stratum serious scale, thus cause waterflood-transmission line and formation blockage, these cause huge economic loss all to oil field production run, therefore, generally all need to add bactericide before produced-water reinjection and carry out pretreatment.
Because the vitality of bacterium is extremely strong, any one bactericide length service time all can make bacterial resistance occurred, causes the problems such as the germicidal efficiency of bactericide declines, dose increase, therefore, needs constantly to develop new oil field bactericide.China has made extensive work in the research and development of oil field bactericide, at present still based on SAA series bactericidal agent.Along with the development of water technology, people have higher requirement to bactericide.
In sum, in order to raise the efficiency, reduce costs, development environment close friend, potion multiple-effect, adapt to bacterial dissociation pesticide resistance, adapt to different quality, inevitable direction that new product that compatibility is good is bactericide development.
Summary of the invention
The object of the present invention is to provide a kind of oil-field flooding bactericide and manufacture method thereof, mainly solve the problem existing for above-mentioned prior art, maximum bacterium is endangered for oil field, as sulfate reducing bacteria, iron bacteria and saprophytic bacteria, and then a kind of isothiazolinone water treatment biocide of development.
The technical solution adopted in the present invention is as follows:
A kind of isothiazolinone water treatment biocide, it is characterized in that being made up of benzyl chloride, wetting agent, Trimethylamine, isothiazolinone, chlorine dioxide, deionized water, the percentage by weight of each component is:
Deionized water: 50%-75%
Benzyl chloride: 5%-12%
Wetting agent: 2%-4%
Trimethylamine: 6%-12%
Isothiazolinone: 1.5%-4.5%
Chlorine dioxide: 4%-8%.
Further, described a kind of isothiazolinone water treatment biocide be by percentage by weight be deionized water 60-75%, benzyl chloride 7%-8%, wetting agent 2%-3%, Trimethylamine 7%-8.5%, isothiazolinone 2.5%-3%, chlorine dioxide 5%-6% form.
Further, described wetting agent is the one in neopelex, water-solubleazone, spaonin powder.
A preparation method for isothiazolinone water treatment biocide, is characterized in that step is as follows:
Deionized water, benzyl chloride, wetting agent, Trimethylamine, isothiazolinone, chlorine dioxide are added stirred reactor by example successively in mass ratio, stir 30min, obtain light green color or blue liquid.
Beneficial effect of the present invention is:
A kind of isothiazolinone water treatment biocide non-corrosiveness of the present invention, nonirritant, non-foam, it is the regeneration product of oil field SRB bactericide, effectively can solve the resistance problems of sulfate reducing bacteria, and there is good compatibility, can effectively kill and suppress oil field sulfate reductive bacterium, be that a kind of to have height bactericidal effect, pH value be neutral environment-friendly type bactericide, product effect reaches domestically leading level.In addition, a kind of isothiazolinone water treatment biocide preparation technology of the present invention is simple to operate, and without any pollutant emission, reaction condition is gentle, and energy consumption is low.
Embodiment
The following examples further illustrate of the present invention, instead of limit the scope of the invention.
Embodiment one:
Choose raw material by weight percentage
Deionized water: 65%
Benzyl chloride: 10.5%
Wetting agent: 3.5%
Trimethylamine: 10.5%
Isothiazolinone: 3.5%
Chlorine dioxide: 7%
Deionized water, benzyl chloride, wetting agent, Trimethylamine, isothiazolinone, chlorine dioxide are added stirred reactor successively, stirs 30min, obtain product.
Embodiment two:
Choose raw material by weight percentage
Deionized water: 71.5%
Benzyl chloride: 8%
Wetting agent: 4%
Trimethylamine: 8.5%
Isothiazolinone: 3%
Chlorine dioxide: 6%
Deionized water, benzyl chloride, wetting agent, Trimethylamine, isothiazolinone, chlorine dioxide are added stirred reactor successively, stirs 30min, obtain product.
Embodiment three:
Choose raw material by weight percentage
Deionized water: 68%
Benzyl chloride: 10%
Wetting agent: 3%
Trimethylamine: 8%
Isothiazolinone: 4%
Chlorine dioxide: 7%
Deionized water, benzyl chloride, wetting agent, Trimethylamine, isothiazolinone, chlorine dioxide are added stirred reactor successively, stirs 30min, obtain product.
The bactericidal effect table of embodiment is as shown in table 1:
The bactericidal effect of table 1 embodiment
As can be seen from the above table, the product of embodiments of the invention 1, embodiment 2, embodiment 3 is excellent to the bactericidal effect of the bacteriums such as the sulfate reducing bacteria in oil field reinjection water, saprophytic bacteria and iron bacteria, fullys meet the requirement of the present invention to isothiazolinone water treatment biocide bactericidal effect.
Above embodiments of the invention have been described in detail, but described content being only preferred embodiment of the present invention, can not being considered to for limiting practical range of the present invention.All equalizations done according to the present patent application scope change and improve, and all should belong within patent covering scope of the present invention.
Claims (4)
1. an isothiazolinone water treatment biocide, it is characterized in that being made up of benzyl chloride, wetting agent, Trimethylamine, isothiazolinone, chlorine dioxide, deionized water, the percentage by weight of each component is:
Deionized water: 60%-75%
Benzyl chloride: 5%-12%
Wetting agent: 2%-4%
Trimethylamine: 6%-12%
Isothiazolinone: 1.5%-4.5%
Chlorine dioxide: 4%-8%.
2. a kind of isothiazolinone water treatment biocide according to claim 1, it is characterized in that its be by percentage by weight be deionized water 60-75%, benzyl chloride 7%-8%, wetting agent 2%-3%, Trimethylamine 7%-8.5%, isothiazolinone 2.5%-3%, chlorine dioxide 5%-6% form.
3. a kind of isothiazolinone water treatment biocide according to claim 1, is characterized in that: described wetting agent is the one in neopelex, water-solubleazone, spaonin powder.
4. a preparation method for isothiazolinone water treatment biocide, is characterized in that step is as follows:
Deionized water, benzyl chloride, wetting agent, Trimethylamine, isothiazolinone, chlorine dioxide are added stirred reactor by example successively in mass ratio, stir 30min, obtain light green color or blue liquid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410649183.XA CN104397018A (en) | 2014-11-14 | 2014-11-14 | Isothiazolinone water treatment bactericide and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410649183.XA CN104397018A (en) | 2014-11-14 | 2014-11-14 | Isothiazolinone water treatment bactericide and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN104397018A true CN104397018A (en) | 2015-03-11 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410649183.XA Pending CN104397018A (en) | 2014-11-14 | 2014-11-14 | Isothiazolinone water treatment bactericide and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN104397018A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108308194A (en) * | 2018-04-20 | 2018-07-24 | 东莞市顶盛环保科技有限公司 | A kind of composite multifunction fungicide |
| CN115968896A (en) * | 2022-12-27 | 2023-04-18 | 西安吉利电子新材料股份有限公司 | Isothiazolinone bactericide applicable to water treatment system and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101530100A (en) * | 2009-04-27 | 2009-09-16 | 陕西上格之路生物科学有限公司 | Isothiazolone agricultural bactericide |
| CN101564035A (en) * | 2009-06-10 | 2009-10-28 | 郇恒飞 | Mould removing bactericide |
| CN102177913A (en) * | 2011-03-14 | 2011-09-14 | 山东瑞爱特环保科技有限公司 | Sterilizing stripper dedicated for oilfield injection water and preparation method thereof |
| CN102342275A (en) * | 2010-12-13 | 2012-02-08 | 新疆德蓝股份有限公司 | Novel bactericide for oil fields |
| CN103087002A (en) * | 2011-11-03 | 2013-05-08 | Dhc有限公司 | Preparation method of isothiazolinone |
| CN103190439A (en) * | 2013-04-03 | 2013-07-10 | 天津大学 | Compound biocide for circulating cooling water and preparation method thereof |
-
2014
- 2014-11-14 CN CN201410649183.XA patent/CN104397018A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101530100A (en) * | 2009-04-27 | 2009-09-16 | 陕西上格之路生物科学有限公司 | Isothiazolone agricultural bactericide |
| CN101564035A (en) * | 2009-06-10 | 2009-10-28 | 郇恒飞 | Mould removing bactericide |
| CN102342275A (en) * | 2010-12-13 | 2012-02-08 | 新疆德蓝股份有限公司 | Novel bactericide for oil fields |
| CN102177913A (en) * | 2011-03-14 | 2011-09-14 | 山东瑞爱特环保科技有限公司 | Sterilizing stripper dedicated for oilfield injection water and preparation method thereof |
| CN103087002A (en) * | 2011-11-03 | 2013-05-08 | Dhc有限公司 | Preparation method of isothiazolinone |
| CN103190439A (en) * | 2013-04-03 | 2013-07-10 | 天津大学 | Compound biocide for circulating cooling water and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 夏剑军: "二氧化氯杀菌技术在油田注水中的应用", 《大庆油田水处理新技术实践与管理文集》 * |
| 李战等: "化学杀菌剂处理油田回注水的应用研究", 《黑龙江环境通报》 * |
| 陈六平、张剑荣、孟长功: "《化学化工创新性实验》", 31 October 2010, 南京大学出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108308194A (en) * | 2018-04-20 | 2018-07-24 | 东莞市顶盛环保科技有限公司 | A kind of composite multifunction fungicide |
| CN115968896A (en) * | 2022-12-27 | 2023-04-18 | 西安吉利电子新材料股份有限公司 | Isothiazolinone bactericide applicable to water treatment system and preparation method thereof |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150311 |
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| RJ01 | Rejection of invention patent application after publication |