CN104131467B - 一种腈纶导电长丝的制备方法 - Google Patents
一种腈纶导电长丝的制备方法 Download PDFInfo
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- CN104131467B CN104131467B CN201410324156.5A CN201410324156A CN104131467B CN 104131467 B CN104131467 B CN 104131467B CN 201410324156 A CN201410324156 A CN 201410324156A CN 104131467 B CN104131467 B CN 104131467B
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- yarn cylinder
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- loose yarn
- acrylic
- aniline
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- 229920002972 Acrylic fiber Polymers 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims abstract description 54
- 239000000835 fiber Substances 0.000 claims abstract description 41
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 25
- 238000004513 sizing Methods 0.000 claims abstract description 14
- 238000001179 sorption measurement Methods 0.000 claims abstract description 12
- 230000018044 dehydration Effects 0.000 claims abstract description 11
- 238000006297 dehydration reaction Methods 0.000 claims abstract description 11
- 239000000178 monomer Substances 0.000 claims abstract description 8
- 230000008021 deposition Effects 0.000 claims abstract description 6
- 238000007598 dipping method Methods 0.000 claims abstract description 6
- 230000003647 oxidation Effects 0.000 claims abstract description 6
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 6
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 6
- 238000007654 immersion Methods 0.000 claims abstract description 4
- 238000005406 washing Methods 0.000 claims abstract description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 52
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 17
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000008367 deionised water Substances 0.000 claims description 16
- 229910021641 deionized water Inorganic materials 0.000 claims description 16
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 claims description 8
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 8
- 238000002803 maceration Methods 0.000 claims description 7
- 238000009835 boiling Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims 2
- 238000005516 engineering process Methods 0.000 abstract description 5
- 229920000642 polymer Polymers 0.000 description 7
- 239000010949 copper Substances 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 230000000536 complexating effect Effects 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920000767 polyaniline Polymers 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005485 electric heating Methods 0.000 description 2
- 229910000765 intermetallic Inorganic materials 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910021595 Copper(I) iodide Inorganic materials 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 1
- LSXDOTMGLUJQCM-UHFFFAOYSA-M copper(i) iodide Chemical compound I[Cu] LSXDOTMGLUJQCM-UHFFFAOYSA-M 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
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CN201410324156.5A CN104131467B (zh) | 2014-07-09 | 2014-07-09 | 一种腈纶导电长丝的制备方法 |
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CN104131467A CN104131467A (zh) | 2014-11-05 |
CN104131467B true CN104131467B (zh) | 2016-03-30 |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107956108A (zh) * | 2017-11-09 | 2018-04-24 | 常熟市翔鹰特纤有限公司 | 一种腈纶导电长丝及其络合掺杂法的制备方法 |
CN108589275A (zh) * | 2018-04-10 | 2018-09-28 | 常熟市翔鹰特纤有限公司 | 一种腈纶导电长丝及其化学镀银制备的方法 |
CN108588942B (zh) * | 2018-04-10 | 2021-03-23 | 常熟市翔鹰特纤有限公司 | 一种腈纶镀铜-硼合金导电长丝及其制备方法 |
CN110093777A (zh) * | 2019-05-23 | 2019-08-06 | 余晨 | 一种导电纤维的工业化制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0667143A1 (fr) * | 1994-01-24 | 1995-08-16 | L'oreal | Composition de teinture d'oxydation des fibres kératiniques comprenant une paraphénylènediamine, une métaphénylènediamine et un paraaminophénol ou un métaaminophénol |
CN102337679A (zh) * | 2010-07-27 | 2012-02-01 | 五邑大学 | 一种制备聚苯胺复合导电织物的新方法 |
JP2012102304A (ja) * | 2010-11-15 | 2012-05-31 | Nagase Chemtex Corp | 導電性コーティング組成物及び積層体 |
CN103184546A (zh) * | 2011-12-30 | 2013-07-03 | 南通美铭锦纶有限公司 | 锦纶6高强力丝的生产方法 |
CN103357387A (zh) * | 2013-08-02 | 2013-10-23 | 河南省科学院化学研究所有限公司 | 聚苯胺/改性腈纶纤维吸附剂及其制备方法 |
Family Cites Families (1)
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KR20010029238A (ko) * | 1999-09-30 | 2001-04-06 | 허증수 | 전기전도성 고분자 물질을 이용한 환자의 체온유지용 발열포 제조방법 |
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- 2014-07-09 CN CN201410324156.5A patent/CN104131467B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0667143A1 (fr) * | 1994-01-24 | 1995-08-16 | L'oreal | Composition de teinture d'oxydation des fibres kératiniques comprenant une paraphénylènediamine, une métaphénylènediamine et un paraaminophénol ou un métaaminophénol |
CN102337679A (zh) * | 2010-07-27 | 2012-02-01 | 五邑大学 | 一种制备聚苯胺复合导电织物的新方法 |
JP2012102304A (ja) * | 2010-11-15 | 2012-05-31 | Nagase Chemtex Corp | 導電性コーティング組成物及び積層体 |
CN103184546A (zh) * | 2011-12-30 | 2013-07-03 | 南通美铭锦纶有限公司 | 锦纶6高强力丝的生产方法 |
CN103357387A (zh) * | 2013-08-02 | 2013-10-23 | 河南省科学院化学研究所有限公司 | 聚苯胺/改性腈纶纤维吸附剂及其制备方法 |
Non-Patent Citations (1)
Title |
---|
聚苯胺/聚丙烯腈导电复合材料的研究;张旺玺 等;《塑料工业》;20041231;第32卷(第12期);第43-45页 * |
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Effective date of registration: 20240125 Address after: Room 406, No.1 Shengang Avenue, Lingang New Area, China (Shanghai) Pilot Free Trade Zone, Pudong New Area, Shanghai, March 2013 Patentee after: China Petroleum (Shanghai) New Materials Research Institute Co.,Ltd. Country or region after: China Address before: 215500 Tongjiang Road (Haiyu town), Changshu City, Suzhou City, Jiangsu Province Patentee before: CHANGSHU XIANGYING SPECIAL FIBER Co.,Ltd. Country or region before: China |
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