CN104126575A - Environment-friendly household water-based insecticidal aerosol - Google Patents
Environment-friendly household water-based insecticidal aerosol Download PDFInfo
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- CN104126575A CN104126575A CN201410341176.3A CN201410341176A CN104126575A CN 104126575 A CN104126575 A CN 104126575A CN 201410341176 A CN201410341176 A CN 201410341176A CN 104126575 A CN104126575 A CN 104126575A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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Abstract
The invention relates to an environment-friendly household water-based insecticidal aerosol filled with a propellant of dimethyl ether (DME). The prepared environment-friendly household water-based insecticidal aerosol is composed of pyrethroid insecticidal original drug and the like, water, and the propellant which are filled in an aerosol can. The insecticidal original drug is a complex of plant-sourced insecticides with a mass ratio of 0.2-0.61%. The aerosol also comprises, by mass, 1-2.8% of a surfactant, 0.01-0.13% of a corrosion inhibitor, 0.1-0.28% of a penetrating agent, 6-13% of a solubilizer, a proper amount of a complexing agent, a proper amount of a wetting agent, a proper amount of an anti-foaming agent, an excipient of purified water or deionized water, and less than 0.026% of an essence. A total amount of the mass percentages of the above raw materials and auxiliary materials is 100%. The content liquid of the environment-friendly household water-based insecticidal aerosol is homogeneous and transparent. A keeping time is more than 4 years. With the aerosol, mosquitoes, flies, cockroaches, ants, termites, mites, lice, bedbugs, ticks, fleas, and the like can be killed with an environment-friendly manner. The aerosol also has multi-functions (MIK) such as repelling and long effective life. The aerosol is a product with high efficient and high cost performance. Currently the product cannot be found in domestic and international markets.
Description
Technical field
The invention belongs to PCO (PCO) field, especially relate to family expenses water-base pesticide aerosols series of products and preparation method thereof.On the basis of the application patent of invention of patent of invention ZL991059255 and (environmentally-friendly water-based insect aerosol and preparation method thereof) and (environmentally-friendly water-based family expenses insect aerosol and preparation method thereof), to carry out the innovations such as the feature of environmental protection, systematic function to improve.Be applied to insects such as killing mosquito, fly, blattaria, ant, lice, flea, tick, acarid.
Background technology
The level of preventing and treating of the vector insects such as mosquito, fly, cockroach has been listed the measurement index of urban civilization degree in or even has been weighed the very important index of a safe and comfortable level of the national people.So China's domestic pesticide particularly production development of insect aerosol is very fast, annual sales amount has surpassed 10,000,000,000 yuan.At present, the insect aerosol on domestic and international market is to need shake " water base " type before oil base, alcohol fundamental mode and use, all has a large amount of organic volatiles such as the kerosene of interpolation or goods technology immature, has the defects such as secondary pollution.Environment-friendly household water-base pesticide aerosols belongs to green pesticide formulation, is main direction and the development trend of world health desinsection dosage form research, this is carried out research and development abroad existing more than 80 year, and China has also had nearly 60 years to this research.“ ‘ Shake is water base ' need before use shake, illustrate that this formula and technique are still immature, compared with the water-base pesticide aerosols patented technology of Quanzhou, Fujian Cai Rongchang County of China invention like having fallen behind ".(" aerosol safety guide " United Nations Environment Programme, the 75th page of State Environmental Protection Administration's version in 2007).For this reason, urgently exploitation meets the applicable application product of the Market Demand of worldwide environmental protection demand and green consumption, expert opinion both at home and abroad: " this product comes into the market early; still do not offset expense person's a Gospel; and should be evaluated from higher angle; the historical Important Change of Zhe Shi China insect aerosol, an important milestone, Ye Shishi China insect aerosol is in crossing over a mark of world standard ".Application and Development family expenses water-base pesticide aerosols, reduces organic volatile consumption, avoids secondary pollution, the potential hazard that health is brought and produce indirect loss difficult to the appraisal and also can significantly reduce etc.; The annual deodorized kerosine of saving few hundred thousand tonnes of, also meets the energy-conservation industrial policy of national environmental protection.Create the Chinese products of independent intellectual property right, thereby promotion is created global brand and is improved competitiveness in the international market and improve social and economic effects.
Summary of the invention
The object of this invention is to provide family expenses water-base pesticide (spray) aerosol series of products, be under the principle of the healthy and living environment of to protect mankind, reach repellent or kill the optimum efficiency of vector insect.
From patent retrieval, on the patent of invention specification of application water-base pesticide aerosols, learn (not enumerating analysis), 1. fail to reach " homogeneous phase liquid (liquid and gas in tank) "; 2. corrosion inhibition preservative technology is not in place etc.3. on domestic and international market, also there is no the product of this technology maturation etc.In order to solve the upper defect existing of oil base, alcohol radical, " shaking water base " insect aerosol technology and application.The present invention is through the experiment of twenties years several ten thousand times, realized the excellent specific property of tens technology and product application, and multiple actual environment application obtains the index of positive effect.Environment-friendly household water-base pesticide aerosols be water consumption substitution kerosene etc. as excipient, adopting propellant is that dimethyl ether DME replaces aerosol hydro carbons HAPs, LPG, larger reduction volatile organic matter VOCs content; 2. toxicity index LD50 > 15000mg/kg, by the relevant environmental toxicity standard of the Ministry of Agriculture and WHO standard is: micro-(nothing) poison level.3. biological effect: kill mosquito, fly, cockroach, ant, coptotermes formosanus, acarid, louse, bedbug, tick, flea etc., and there is repellent and long multi-functional (MIK) feature of lasting period, meeting or exceeding GB A level (excellent) evaluation criterion, drug effect degradation rate is less than 5% in two years.4. Corrosion Protection original creation is excellent, and the term of validity reaches 4 years above (standard criterion is 2 years), is worldwide the biggest problem of capturing; 5. the propellant adopting is environment-friendly type propellant---the dimethyl ether DME that the UN-World Health Organisation is recommended, and in tank, liquid and dimethyl ether DME form the transparent liquid of homogeneous phase, without flocculation, not stratified, before using, just needn't shake.Physicochemical property and stay-in-grade key technology, this research and development both at home and abroad so far not yet can make the technical barrier of product; 6. atomizing effect is good, and below droplet 50 μ m, this is also water base technical barrier; 7. ejection liquid does not burn! Domestic and international all insect aerosols do not have; 8. viscosity is lower, is interrupted that use can plug nozzle, and ejection liquid is really to furniture, and object leaves no trace, and also can not make wall, the first-class stick-slip that occurs in floor, avoids people is fallen down and the personal injury that causes; 9. main raw and auxiliary material, all adopts nuisanceless, the environmental friendliness of the pertinent regulations such as WHO and the Ministry of Agriculture and national environmental protection portion and standard recommendation, the material of easily biological-degradable, avoids secondary pollution.10. without pessimal stimulation peculiar smell; 11. easily clean, and non-foam, without oil, yellow spot spot; Also have cost performance good; 12. can manufacture according to conventional aerosol production equipment; 13. imitated, forgery difficulties, improve consumption safety reliability etc.
Chemical insecticide, in production and use procedure, can be served negative effect to Human and nature environment band.1. pest resistance to insecticide sustainable growth, effect of chemical control declines; Medicament residual life in environment long, be difficult for degraded and pollute; 3. the abuse of chemical insecticide is dangerous to people and animals, and killed natural enemies and non-target organism, cause Pest rampancy etc.
The chemical insecticide that requires as far as possible to avoid using high malicious high residue from protection of the environment and human health, just must carry out structural reform to insecticide formulation, produces the efficient safety-type insecticide of a new generation.
Adopt the composite of plant insecticide, avoid the toxic and side effect of chemical insecticide.Plant insecticide Botanical insecticides is called as the former medicine of green pesticide.Active component complexity can act on multiple organs and the system of insect, is conducive to overcome the pesticide resistance of insect.Chemical pesticide relatively, advantage: 1. easily decompose; 2. pair pest controling effect is good, nontoxic to person poultry safety, free from environmental pollution, noresidue; 3. pair insect is killed and wounded high specificity, does not injure natural enemy and beneficial organism; 4. many factors and composition play a role, and insect and pathogen are difficult to develop immunity to drugs.
In order to realize above-mentioned high-quality characteristic, technical solution of the present invention is mainly made up of following raw and auxiliary material:
Composition: the 1. former medicine of desinsection: composite between plant insecticide; 2. surfactant: fluorine-containing surfactant, fatty alcohol ethers, MOA series, fatty acid ester T series; 3. inhibition anti-corrosion additive: WY09 series, sorbic acid and its esters; 4. auxiliary agent: (bleeding agent: JFC series; (wetting agent: Tao Shi TRITON X-405, TRITON CF-10, GSK-588/GSK-565); (complexing agent: organic phosphonate, hydroxycarboxylate, citrate); Defoamer: organic silicon compound thing); 5. excipient: pure water or deionized water; 6. solubilizer: alcohol, ketone, ether, acetate type; 7. essence; 8. propellant: dimethyl ether DME.
The present invention carries out repellent or killing effect mechanism and the environmental friendly principle thereof of efficiency test to the characteristic of pest according to the development of the former medicine of desinsection, composite with between plant insecticide of screening; .Plant insecticide is wherein: pyrethrum crude oil, and pyrethrin, nimbin (China tree, melia toosendan print chinaberry), Celastrus angulatus, rotenone etc., product is many, does not enumerate.
Selecting according to WHO and Ministry of Agriculture's related standards of insecticide carried out, scientific and reasonable configuration mass ratio.Composite mass ratio 0.2～0.68% between plant insecticide.Pyrethrum crude oil 0.01～026%, or pyrethrin 0.02～0.3%, or nimbin 0.05～0.27%, Celastrus angulatus 0.1～0.25%, rotenone 0.02～0.18% grade composite.
Other surfactant, auxiliary agent, inhibition anti-corrosion additive, selecting of the compositions such as solubilizer and mass ratio: fluorine-containing surfactant 0.01～0.12%, or fatty alcohol ethers 0.5～1.6%, or MOA series 0.5～1.8%, or fatty acid ester T series 0.6～2%; Or WY09 series 0.01～0.12%, or sorbic acid and its esters 0.01～0.04%, or JFC class 0.1～1.6%; Tao Shi TRITON X-405,0.001～0.006%, GSK-588/GSK-565,0.001～0.006%,, or alcohols 2～13%, or ketone 3～9%, or acetate type 1～3.3%, or ethers 1～6.3%, essence 0.01～0.026%, or organic phosphonate, or hydroxycarboxylate, or citrate is appropriate, organic silicon compound thing is appropriate, pure water or deionized water+and to 100%.
Be preferably: 1. pyrethrin 0.02～0.3%, fluorine-containing surfactant 0.01～0.12%, fatty acid ester T series 0.6～2%; WY09 series 0,01～0.03%; Sorbic acid and its esters 0.01～0.04%; JFC class 0.1～1.6%; Or Silwet 408,0.001～0.006%, alcohols (comprising edible alcohol) 2～13%; Ethers 1～6.3%; Essence 0.01～0.026%, organic phosphonate is appropriate, and organic silicon compound thing is appropriate, pure water or deionized water+to 100%.
2. each composition and consumption can also be: select pyrethrin 0.02～0.2%, nimbin 0.05～0.23%, fluorine-containing surfactant 0.01～0.12%, MOA series 0.5～1.8%, sorbic acid and its esters 0.01～0.04%, WY09 series 0.01～0.12%, JFC class 0.1～1.6%, Tao Shi TRITON X-4050.001～0.004%, ketone 3～9%, alcohols 2～13%, essence 0.01～0.026%, hydroxycarboxylate is appropriate, and organic silicon compound thing is appropriate, pure water or deionized water+and to 100%.
3. also can select: pyrethrin 0.02～0.26%, Celastrus angulatus 0.1～0.25%, fluorine-containing surfactant 0.01～0.12%, fatty alcohol ethers 0.5～1.6%, WY09 series 0,01～0.1%, sorbic acid and its esters 0.01～0.04%, JFC class 0.1～2%, GSK-588/GSK-5650.001～0.0048%, acetate type 1～3.3%, alcohols 2～13%, essence 0.01～0.026%, citrate is appropriate, organic silicon compound thing is appropriate, pure water or deionized water+and to 100%.
Principle of compound between plant insecticide, in strict accordance with the requirement of Ministry of Agriculture's Information for pesticide Product Registration, filter out the significant combination of synergy and best proportioning thereof, and to its surfactant, the multiple auxiliary agent such as solubilizer carries out screening test, develop a series of synergy remarkable, stable, there is good quick-acting and longer duration and broad spectrum type compounded pesticides and corresponding processing technology environmentally friendly, ecological safety.
Composition of the present invention can be suitable for conventional facility, method is made water-base pesticide spray, water-base pesticide aerosols.Described raw and auxiliary material is plant resource insecticides, surfactant, inhibition anti-corrosion additive, bleeding agent, wetting agent, complexing agent, defoamer, excipient, solubilizer, essence, propellant: dimethyl ether DME.
Embodiment
Come by the following examples further to illustrate beneficial effect of the present invention, it should be understood that these embodiment, only for the object of illustration, never limit the scope of the invention.
Embodiment mono-:
1. raw and auxiliary material: pyrethrum crude oil 0.23%, %, fluorine-containing or surfactant 0.1%, fatty acid ester T series 0.8%, WY09 series, 0.02%, JFC class 0.15%, TRITON CF-10 0.001%, alcohols (comprising edible alcohol) 9.2%, ethers 3%, essence 0.026%, citrate is appropriate, and organic silicon compound thing is appropriate, pure water or deionized water, the percentage summation of above-mentioned raw and auxiliary material is 100%.
2. preparation method: according to Principles of Chemical Engineering and the conventional production method of insect aerosol, take each composition according to proportioning, first dissolve the former medicine of desinsection etc., separately get various auxiliary materials successively with excipient, stir, leave standstill, observing it fully dissolves, form after homogeneous phase liquid, be pesticide spray of the present invention, if by the homogeneous phase liquid of this preparation carry out aerosol production line the in-built liquid of tank, insert valve seal, charge dimethyl ether DME and enter tank etc., can make environment-friendly household water-base pesticide aerosols series of products of the present invention.
Embodiment bis-:
A. select pyrethrin 0.2%, nimbin 0.2%, fluorine-containing surfactant 0.012%, MOA series 1.8%, sorbic acid and its esters 0.016%, WY09 series 0.017%, JFC class 0.8%, Tao Shi TRITON X-4050.001%, ketone 6%, alcohols 8.2%, essence 0.026%, hydroxycarboxylate is appropriate, organic silicon compound thing is appropriate, pure water or deionized water+and to 100%.
B. preparation method: as embodiment mono-, conventional method and conventional facility, make environment-friendly household water-base pesticide aerosols series of products of the present invention.
Embodiment tri-:
A. pyrethrin 0.22%, Celastrus angulatus 0.2%, fatty acid ester T series 1.7%, MOA series 0.7%, WY09 series 0,01%, GSK-588/GSK-565,0.002%, JFC class 1.6%, acetate type 3.3%, alcohols 10%, essence 0.02%, appropriate, organic phosphonate, organic silicon compound thing are appropriate, pure water or deionized water+and to 100%.
B. preparation method: make product of the present invention described in embodiment mono-, two.
environment-friendly household water-base pesticide aerosols development product experiment effect?
table 1
Evaluate: belong to A level by agriculture chemical registration hygienic insecticide drug effect.
environment-friendly household water-base pesticide aerosols development product experiment effect table 2
Conclusion: according to the acute toxicity grading criteria of China's agriculture chemical registration toxicology test method, all belong to micro-(nothing) poison.
The foregoing is only the explanation that embodiments of the invention and preparation method do, be not limited to the present invention, this is to those skilled in the art on basis of the present invention, and it is made some modifications or improvements is apparent.Therefore, all on the basis of the present invention spirit and principle and framework, any amendment of making, be equal to replacement, improvement etc., within all should being included in protection scope of the present invention.
Claims (10)
1. environment-friendly household water-base pesticide aerosols, is characterized in that: composite by plant insecticide, and mass ratio is 0.2～0.61%; Also has surfactant 1～2.8%; Inhibition anti-corrosion additive 0.01～0.13%; Bleeding agent 0.1～0.28%; Solubilizer 6～13%; Complexing agent, wetting agent, defoamer are appropriate; Excipient is pure water or deionized water; Essence is below 0.026%, and the mass percent summation of above-mentioned raw and auxiliary material is 100%.Charge and make as propellant with dimethyl ether DME.
2. environment-friendly household water-base pesticide aerosols according to claim 1, is characterized in that: what described insecticide was plant insecticide is composite.
3. environment-friendly household water-base pesticide aerosols according to claim 1, is characterized in that: described surfactant by fluorine-containing, nonionic surface active agent is composite.
4. environment-friendly household water-base pesticide aerosols according to claim 1, is characterized in that: described inhibition anti-corrosion additive by WY09 series, hydroxycarboxylate, sorbic acid salt composite.
5. environment-friendly household water-base pesticide aerosols according to claim 1, is characterized in that: described bleeding agent is JFC series of products, and wetting agent is Silwet 408, Tao Shi TRITONX-405, TRITON CF-10.
6. environment-friendly household water-base pesticide aerosols according to claim 1, is characterized in that: described auxiliary material are that complexing agent is citrate; Defoamer is organic silicon compound thing.
7. environment-friendly household water-base pesticide aerosols according to claim 1, is characterized in that: described propellant is dimethyl ether DME.
8. environment-friendly household water-base pesticide aerosols according to claim 1, is characterized in that: described excipient is pure water or deionized water; Solubilizer is alcohols (comprising edible alcohol), ether, acetate type.
9. a preparation method for environment-friendly household water-base pesticide aerosols claimed in claim 1, is characterized in that it comprises the following steps:
1.. get the composite 0.2～0.61% of plant insecticide, solubilizer 6～13%; Essence 0.01～0.026%.
2.. water intaking adds surfactant 1～2.8%, inhibition anti-corrosion additive 0.01～0.13%; Bleeding agent 0.1～0.28%; Wetting agent, defoamer are appropriate, fully stir, and dissolve.
3.. 1. 2. step added to step while stirring, record pH value, take the circumstances into consideration to add complexing agent, fully stir until obtain the aqueous solution of clear, leave standstill, by filtering, conveyance conduit enters aerosol production line, manufactures the finished product of environment-friendly household water-base pesticide aerosols.
10. be named and be called: environment-friendly household water-base pesticide aerosols or environment-friendly household water-base pesticide spray.
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| CN201410341176.3A CN104126575A (en) | 2014-07-18 | 2014-07-18 | Environment-friendly household water-based insecticidal aerosol |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110477002A (en) * | 2019-08-30 | 2019-11-22 | 泉州中翰龙生物科技有限公司 | A kind of environmentally-friendly water-based domestic insecticide aerosol |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0343486A (en) * | 1989-07-11 | 1991-02-25 | Earth Chem Corp Ltd | Vermin-controlling aerosol composition |
| JPH09175905A (en) * | 1995-12-27 | 1997-07-08 | Earth Chem Corp Ltd | Harmuful insect control aersol |
| CN101554175A (en) * | 2009-05-14 | 2009-10-14 | 许春晖 | Environmental-friendly water-base pesticide aerosols |
| CN101683070A (en) * | 2008-09-25 | 2010-03-31 | 上海联合气雾制品灌装有限公司 | Water-based type insect aerosol research and development |
| CN102669092A (en) * | 2012-05-10 | 2012-09-19 | 山东美多集团有限公司 | Homogeneous and high-efficient water-based pesticide aerosol with low VOC (Volatile Organic Compounds) content |
| CN103463656A (en) * | 2013-09-17 | 2013-12-25 | 成都彩虹电器（集团）中南有限公司 | Emulsifier-free water-based air freshening aerosol |
-
2014
- 2014-07-18 CN CN201410341176.3A patent/CN104126575A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0343486A (en) * | 1989-07-11 | 1991-02-25 | Earth Chem Corp Ltd | Vermin-controlling aerosol composition |
| JPH09175905A (en) * | 1995-12-27 | 1997-07-08 | Earth Chem Corp Ltd | Harmuful insect control aersol |
| CN101683070A (en) * | 2008-09-25 | 2010-03-31 | 上海联合气雾制品灌装有限公司 | Water-based type insect aerosol research and development |
| CN101554175A (en) * | 2009-05-14 | 2009-10-14 | 许春晖 | Environmental-friendly water-base pesticide aerosols |
| CN102669092A (en) * | 2012-05-10 | 2012-09-19 | 山东美多集团有限公司 | Homogeneous and high-efficient water-based pesticide aerosol with low VOC (Volatile Organic Compounds) content |
| CN103463656A (en) * | 2013-09-17 | 2013-12-25 | 成都彩虹电器（集团）中南有限公司 | Emulsifier-free water-based air freshening aerosol |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110477002A (en) * | 2019-08-30 | 2019-11-22 | 泉州中翰龙生物科技有限公司 | A kind of environmentally-friendly water-based domestic insecticide aerosol |
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