CN102669092A - Homogeneous and high-efficient water-based pesticide aerosol with low VOC (Volatile Organic Compounds) content - Google Patents
Homogeneous and high-efficient water-based pesticide aerosol with low VOC (Volatile Organic Compounds) content Download PDFInfo
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- CN102669092A CN102669092A CN2012101428563A CN201210142856A CN102669092A CN 102669092 A CN102669092 A CN 102669092A CN 2012101428563 A CN2012101428563 A CN 2012101428563A CN 201210142856 A CN201210142856 A CN 201210142856A CN 102669092 A CN102669092 A CN 102669092A
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- 239000000443 aerosol Substances 0.000 title claims abstract description 25
- 239000000575 pesticide Substances 0.000 title claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract description 14
- 239000012855 volatile organic compound Substances 0.000 title abstract 5
- 239000003599 detergent Substances 0.000 claims description 8
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical group CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 claims description 4
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 5
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 abstract description 5
- 235000010234 sodium benzoate Nutrition 0.000 abstract description 5
- 239000004299 sodium benzoate Substances 0.000 abstract description 5
- 229940008203 d-transallethrin Drugs 0.000 abstract description 4
- 239000008367 deionised water Substances 0.000 abstract description 4
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 abstract description 4
- 229960000490 permethrin Drugs 0.000 abstract description 4
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 abstract 2
- PJOOIDMBBQPBAC-UHFFFAOYSA-M S(=O)(=O)(OCCCCCCCCCCCC)[O-].[Na+].C(CCC(=O)O)(=O)O Chemical compound S(=O)(=O)(OCCCCCCCCCCCC)[O-].[Na+].C(CCC(=O)O)(=O)O PJOOIDMBBQPBAC-UHFFFAOYSA-M 0.000 abstract 1
- OOWCJRMYMAMSOH-UHFFFAOYSA-N [2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound FC1=C(F)C(COC)=C(F)C(F)=C1COC(=O)C1C(C)(C)C1C=C(C)C OOWCJRMYMAMSOH-UHFFFAOYSA-N 0.000 abstract 1
- 235000010288 sodium nitrite Nutrition 0.000 abstract 1
- 239000012071 phase Substances 0.000 description 15
- 241000238631 Hexapoda Species 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 5
- XHCYBIGJUPTJRR-UHFFFAOYSA-N OC(=O)CC(C(O)=O)S(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O.CCCCCCCCCCCC[Na] XHCYBIGJUPTJRR-UHFFFAOYSA-N 0.000 description 4
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 4
- 239000008346 aqueous phase Substances 0.000 description 4
- 239000001273 butane Substances 0.000 description 4
- 230000000749 insecticidal effect Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- ZCVAOQKBXKSDMS-PVAVHDDUSA-N (+)-trans-(S)-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)O[C@@H]1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-PVAVHDDUSA-N 0.000 description 3
- FJDPATXIBIBRIM-QFMSAKRMSA-N (1R)-trans-cyphenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 FJDPATXIBIBRIM-QFMSAKRMSA-N 0.000 description 3
- GQNBIMLHUAWKHJ-UHFFFAOYSA-N [4-(methoxymethyl)phenyl]methyl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound C1=CC(COC)=CC=C1COC(=O)C1C(C)(C)C1C=C(C)C GQNBIMLHUAWKHJ-UHFFFAOYSA-N 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000002917 insecticide Substances 0.000 description 3
- 239000003380 propellant Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 241000723353 Chrysanthemum Species 0.000 description 2
- 235000007516 Chrysanthemum Nutrition 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000003260 anti-sepsis Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000003340 mental effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides homogeneous and high-efficient water-based pesticide aerosol with low VOC (Volatile Organic Compounds) content. The homogeneous and high-efficient water-based pesticide aerosol comprises the following components in parts by weight: 25-40 parts of dimethyl ether, 40-60 parts of de-ionized water, 10-20 parts of edible alcohol with mass-percentage concentration of 95 percent, 0.05-2 parts of dimefluthrin, 0.1-0.4 part of rich-d-transallethrin, 0.1-0.3 part of permethrin, 0.05-0.2 part of d-trans-cyphenothrin, 0.05-0.2 part of sodium benzoate, 0.05-0.2 part of sodium nitrite, 0.05-0.2 part of sodium dodecyl sulfate succinate, 0.05-0.2 part of triethanolamine, 0.1-1.0 part of synergist and 0.1-0.5 part of essence. According to the homogeneous and high-efficient water-based pesticide aerosol with low VOC content, disclosed by the invention, the advantages of good atomizing effect and insert-killing effect can be achieved without vibration and shaking before use.
Description
Technical field
The present invention relates to a kind of insect aerosol, specifically, relate in particular to a kind of homogeneous phase heavy duty detergent water-base pesticide aerosols of low VOC content.
Background technology
Water-base pesticide aerosols is a type in the hygienic biocide series of products, and along with the price of international petroleum goods improves always, the bottleneck that oil base insect aerosol product cost increases is day by day restricting the development of industry always.Fundamentally do not solve the drawback of oil base insect aerosol so far, be in particular in: product cost height, material therefor are non-renewable resources, the inflammable and explosive poor stability of product, the greasy excitant of product is strong, product VOC content is high, not environmental protection etc.At present, the quality of domestic main flow water-base pesticide agent product is unstable, and insecticidal effect is undesirable; Poor stability, having gets rusty leaks a jar risk, and the domestic market occupation rate is not high; Though China's water-base pesticide agent product has a certain proportion of share on market; But do not form the characteristic of this system product and general market approval, the consumer does not produce the psychology of trusting the water-base pesticide aerosols product fully, is ready to use the oil base insecticide more.
China's insect aerosol industry exists following subject matter: A, renewable resources to expend seriously, and product cost is high, though the deficiency in economic performance that takes on a certain scale; B, scientific research and development strength weakness, fund input is not enough, and the technological progress of water-base pesticide product is slow; The technology of C, water-base pesticide aerosols product does not pass a test, and has caused the shade of consumer's applied mental.
It is main that external insect aerosol product adopts aqua type more; But how external insect aerosol product is re-dubbed water in oil emulsification system with third butane, organic solvent, deionized water is main; Need firmly jolting before using; Foreign consumers has then adapted to the use of this series products already; But what the domestic consumer got used to oil base insect aerosol product does not need jolting, can take up the just usage of spray, and the water in oil water-base pesticide aerosols system of third butane type outside the native land is not suitable for large-scale popularization at home.
The prior art scheme mainly contains two kinds, and first kind of conventional oil fundamental mode, the type product adopt kerosene to make main solvent; Making active ingredient to intend worm chrysanthemum ester, make auxiliary agent with essence and synergist, is the formula system that master's (portioned product is main with dimethyl ether) makes propellant with third butane; Such good product effect, product is stable, but cost is high; Big to the wasting of resources, not environmental protection, dangerous unhygienic; Second kind is the light water fundamental mode; The type product adopts a small amount of kerosene to make the active ingredient carrier, intends worm chrysanthemum ester and makes active ingredient, through adding emulsifier as auxiliary agent; Introduce a large amount of water as primary solvent with the form of Water-In-Oil or microemulsified, with third butane as propellant.This technical scheme cost is low, and the feature of environmental protection is good, and safety is good, but content is stratification state, needs jolting before the use, and insecticidal effect is unstable, and product content thing and accessory compatibility are poor, and having greatly gets rusty leaks the quality risk of jar.
Summary of the invention
The purpose of this invention is to provide a kind of content system is homogeneous phase, does not need jolting can obtain the homogeneous phase heavy duty detergent water-base pesticide aerosols of the low VOC content of good atomizing effect and insecticidal effect before the use.
The present invention adopts following technical scheme to realize:
The homogeneous phase heavy duty detergent water-base pesticide aerosols of low VOC content is characterized in that, is made up of following components by part by weight:
Said synergist is an azone.
Wherein, dimethyl ether is a propellant; Tetrafluoro methothrin, rich_d_transallethrin, permethrin and dextrorotation cyphenothrin are insecticide; Sodium benzoate, natrium nitrosum, dodecyl sodium sulfosuccinate and triethanolamine play antisepsis, and wherein sodium benzoate and natrium nitrosum are the liquid phase preservative; Dodecyl sodium sulfosuccinate and triethanolamine are vapor-phase inhibitors.
Preferably, the homogeneous phase heavy duty detergent water-base pesticide aerosols of low VOC content, form by following components by part by weight:
The preparation method:
A, each component are got the raw materials ready by above-mentioned weight portion; In a clean agitated reactor, adding mass percent concentration with any order is 95% edible alcohol, tetrafluoro methothrin, rich_d_transallethrin, permethrin, dextrorotation cyphenothrin, synergist; Normal temperature and pressure stirred 15～20 minutes down then; Make it to dissolve fully, add essence at last, the back that stirs is for use as pure phase system;
B, in another clean agitated reactor, add deionized water; Add sodium benzoate, natrium nitrosum, dodecyl sodium sulfosuccinate and triethanolamine with any order; Normal temperature and pressure stirred 10～15 minutes down then, made it to dissolve fully with even, and is for use as aqueous phase system;
C, will more than the pure phase system for preparing and aqueous phase system be filled to (first filling alcohol phase system, back filling water phase system) in the aerosol jar respectively, valve seals back filling dimethyl ether, installs promptly to make finished product after spray is covered.
Compared with prior art, the invention has the beneficial effects as follows: the present invention is through the foundation of alcohol～water～dimethyl ether system, and selected pyrethroid insecticides carries out composite, is synergist with the azone; Add the efficient antiseptic system, make the product material cost obtain significantly reducing, the product material wide material sources are easy to get; Do not belong to non-renewable resources, the product environmentally-friendly sanitary, VOC content meets respective standard; The product atomizing effect is good, and the content homogeneous phase does not need jolting before the use; Improved the insecticidal effect and the fogging degree of product greatly, product safety is stable simultaneously, and not having gets rusty leaks the risk of jar.
Embodiment
Can further understand the present invention through the embodiment of the invention given below, but protection scope of the present invention is not limited thereto.
Embodiment 1
Proportioning:
Preparation method: a, each component are got the raw materials ready by above-mentioned weight portion; In a clean agitated reactor, adding mass percentage concentration with any order is 95% edible alcohol; Tetrafluoro methothrin, rich_d_transallethrin, permethrin, dextrorotation cyphenothrin and azone, normal temperature and pressure stirred 15～20 minutes down then, made it to dissolve fully; Add essence at last, the back that stirs is for use as pure phase system;
B, in another clean agitated reactor, add deionized water; Add sodium benzoate, natrium nitrosum, dodecyl sodium sulfosuccinate, triethanolamine with any order; Normal temperature and pressure stirred 10～15 minutes down then, made it to dissolve fully with even, and is for use as aqueous phase system;
C, will more than the pure phase system for preparing and aqueous phase system be filled to (first filling alcohol phase system, back filling water phase system) in the aerosol jar respectively, valve seals back filling dimethyl ether, installs promptly to make finished product after spray is covered.
Table 1 is the test performance domestic comparison that is up to the standard at present together of the embodiment of the invention 1 products made thereby.
Table 1 product of the present invention compares with the performance test of domestic like product
Can find out that by table 1 performance of products test data of the present invention all is superior to domestic existing level.
Embodiment 2
Proportioning:
The preparation method is with embodiment 1.
Embodiment 3
Proportioning:
The preparation method is with embodiment 1.
Embodiment 4
Proportioning:
The preparation method is with embodiment 1.
Claims (3)
1. the homogeneous phase heavy duty detergent water-base pesticide aerosols of low VOC content is characterized in that, is made up of following components by part by weight:
2. the homogeneous phase heavy duty detergent water-base pesticide aerosols of low VOC content according to claim 1 is characterized in that, said synergist is an azone.
3. the homogeneous phase heavy duty detergent water-base pesticide aerosols of low VOC content according to claim 2 is characterized in that, is made up of following components by part by weight:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210142856.3A CN102669092B (en) | 2012-05-10 | 2012-05-10 | Homogeneous and high-efficient water-based pesticide aerosol with low VOC (Volatile Organic Compounds) content |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210142856.3A CN102669092B (en) | 2012-05-10 | 2012-05-10 | Homogeneous and high-efficient water-based pesticide aerosol with low VOC (Volatile Organic Compounds) content |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102669092A true CN102669092A (en) | 2012-09-19 |
| CN102669092B CN102669092B (en) | 2014-04-09 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210142856.3A Expired - Fee Related CN102669092B (en) | 2012-05-10 | 2012-05-10 | Homogeneous and high-efficient water-based pesticide aerosol with low VOC (Volatile Organic Compounds) content |
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| CN (1) | CN102669092B (en) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102907420A (en) * | 2012-10-30 | 2013-02-06 | 姜燕 | Insect aerosol synergist |
| CN103463656A (en) * | 2013-09-17 | 2013-12-25 | 成都彩虹电器（集团）中南有限公司 | Emulsifier-free water-based air freshening aerosol |
| CN104126575A (en) * | 2014-07-18 | 2014-11-05 | 蔡荣昌 | Environment-friendly household water-based insecticidal aerosol |
| CN104137852A (en) * | 2014-07-17 | 2014-11-12 | 蔡荣昌 | Household water-base insect aerosol and preparation method thereof |
| CN104137851A (en) * | 2014-07-17 | 2014-11-12 | 蔡荣昌 | Environment-friendly water-based insect aerosol and preparation method thereof |
| CN104145998A (en) * | 2014-07-17 | 2014-11-19 | 蔡荣昌 | Environment-friendly water-based household insect aerosol and preparation method thereof |
| CN104186464A (en) * | 2014-07-17 | 2014-12-10 | 蔡荣昌 | Household water-based insect aerosol and preparation method thereof |
| CN104186463A (en) * | 2014-07-17 | 2014-12-10 | 蔡荣昌 | Water-based hygienic insect aerosol and preparation method thereof |
| CN106165699A (en) * | 2016-07-21 | 2016-11-30 | 启东明光企业管理有限公司 | Insect aerosol |
| CN107047549A (en) * | 2017-06-15 | 2017-08-18 | 浙江绿岛科技有限公司 | Environment-friendly type aerial fog pesticide and preparation method thereof |
| CN107333756A (en) * | 2017-06-14 | 2017-11-10 | 江苏敖广日化集团股份有限公司 | The water-base pesticide aerosols of emulsifying agent are used as using the rilanit specials of PEG 40 |
| CN109105383A (en) * | 2018-11-06 | 2019-01-01 | 成都彩虹电器（集团）中南有限公司 | A kind of water base microemulsion aerosol of surfactant-free and preparation method thereof |
| CN109258679A (en) * | 2018-10-09 | 2019-01-25 | 中山凯中有限公司 | A kind of insect aerosol and the preparation method and application thereof |
| CN109258680A (en) * | 2018-11-06 | 2019-01-25 | 成都彩虹电器（集团）中南有限公司 | A kind of water base aerosol of homogeneous phase transparent and preparation method thereof |
| CN113207876A (en) * | 2021-05-19 | 2021-08-06 | 中山榄菊日化实业有限公司 | Water-based insecticidal aerosol and preparation method thereof |
| WO2022191156A1 (en) * | 2021-03-11 | 2022-09-15 | 花王株式会社 | Composition for controlling flying pest insects |
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| CN1101650C (en) * | 1999-06-10 | 2003-02-19 | 黄迪辉 | Germicide composition containing organic copper |
| CN1669428A (en) * | 2004-01-09 | 2005-09-21 | 王红星 | Nontoxic mosquito/fly insecticide with air sterilization and refreshing effect |
| CN100548122C (en) * | 2004-08-12 | 2009-10-14 | 辛根塔参与股份公司 | Fungicidal composition |
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Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102907420A (en) * | 2012-10-30 | 2013-02-06 | 姜燕 | Insect aerosol synergist |
| CN103463656A (en) * | 2013-09-17 | 2013-12-25 | 成都彩虹电器（集团）中南有限公司 | Emulsifier-free water-based air freshening aerosol |
| CN104137852A (en) * | 2014-07-17 | 2014-11-12 | 蔡荣昌 | Household water-base insect aerosol and preparation method thereof |
| CN104137851A (en) * | 2014-07-17 | 2014-11-12 | 蔡荣昌 | Environment-friendly water-based insect aerosol and preparation method thereof |
| CN104145998A (en) * | 2014-07-17 | 2014-11-19 | 蔡荣昌 | Environment-friendly water-based household insect aerosol and preparation method thereof |
| CN104186464A (en) * | 2014-07-17 | 2014-12-10 | 蔡荣昌 | Household water-based insect aerosol and preparation method thereof |
| CN104186463A (en) * | 2014-07-17 | 2014-12-10 | 蔡荣昌 | Water-based hygienic insect aerosol and preparation method thereof |
| CN104126575A (en) * | 2014-07-18 | 2014-11-05 | 蔡荣昌 | Environment-friendly household water-based insecticidal aerosol |
| CN106165699A (en) * | 2016-07-21 | 2016-11-30 | 启东明光企业管理有限公司 | Insect aerosol |
| CN107333756A (en) * | 2017-06-14 | 2017-11-10 | 江苏敖广日化集团股份有限公司 | The water-base pesticide aerosols of emulsifying agent are used as using the rilanit specials of PEG 40 |
| CN107047549A (en) * | 2017-06-15 | 2017-08-18 | 浙江绿岛科技有限公司 | Environment-friendly type aerial fog pesticide and preparation method thereof |
| CN109258679A (en) * | 2018-10-09 | 2019-01-25 | 中山凯中有限公司 | A kind of insect aerosol and the preparation method and application thereof |
| CN109258679B (en) * | 2018-10-09 | 2021-05-25 | 中山凯中有限公司 | Insecticidal aerosol and preparation method and application thereof |
| CN109105383A (en) * | 2018-11-06 | 2019-01-01 | 成都彩虹电器（集团）中南有限公司 | A kind of water base microemulsion aerosol of surfactant-free and preparation method thereof |
| CN109258680A (en) * | 2018-11-06 | 2019-01-25 | 成都彩虹电器（集团）中南有限公司 | A kind of water base aerosol of homogeneous phase transparent and preparation method thereof |
| WO2022191156A1 (en) * | 2021-03-11 | 2022-09-15 | 花王株式会社 | Composition for controlling flying pest insects |
| JP7432635B2 (en) | 2021-03-11 | 2024-02-16 | 花王株式会社 | Composition for controlling flying pests |
| CN113207876A (en) * | 2021-05-19 | 2021-08-06 | 中山榄菊日化实业有限公司 | Water-based insecticidal aerosol and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN102669092B (en) | 2014-04-09 |
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