CN104119862B - 一种具有紫色荧光发射性能的配合物及其制备方法 - Google Patents
一种具有紫色荧光发射性能的配合物及其制备方法 Download PDFInfo
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- CN104119862B CN104119862B CN201410377613.7A CN201410377613A CN104119862B CN 104119862 B CN104119862 B CN 104119862B CN 201410377613 A CN201410377613 A CN 201410377613A CN 104119862 B CN104119862 B CN 104119862B
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- Prior art keywords
- cadmium
- fluorescent material
- purple
- compound
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- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- 239000000463 material Substances 0.000 claims abstract description 34
- -1 cadmium barbiturate compound Chemical class 0.000 claims abstract description 15
- 239000013078 crystal Substances 0.000 claims abstract description 13
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- HNYOPLTXPVRDBG-UHFFFAOYSA-N barbituric acid Chemical compound O=C1CC(=O)NC(=O)N1 HNYOPLTXPVRDBG-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052793 cadmium Inorganic materials 0.000 claims abstract description 8
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229940125717 barbiturate Drugs 0.000 claims abstract description 6
- WLZRMCYVCSSEQC-UHFFFAOYSA-N cadmium(2+) Chemical compound [Cd+2] WLZRMCYVCSSEQC-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003446 ligand Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 7
- LHQLJMJLROMYRN-UHFFFAOYSA-L cadmium acetate Chemical compound [Cd+2].CC([O-])=O.CC([O-])=O LHQLJMJLROMYRN-UHFFFAOYSA-L 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 5
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 5
- 229910001220 stainless steel Inorganic materials 0.000 claims description 5
- 239000010935 stainless steel Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000012153 distilled water Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 abstract description 5
- 238000010521 absorption reaction Methods 0.000 abstract description 4
- 239000012670 alkaline solution Substances 0.000 abstract description 3
- 230000005274 electronic transitions Effects 0.000 abstract description 3
- 150000002500 ions Chemical class 0.000 abstract description 3
- 238000012546 transfer Methods 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 6
- 238000004020 luminiscence type Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 229940065285 cadmium compound Drugs 0.000 description 3
- 150000002910 rare earth metals Chemical class 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical group [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 150000001662 cadmium compounds Chemical class 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 238000005424 photoluminescence Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- CBSJPCRCMBRWJT-UHFFFAOYSA-N cadmium 1,3-diazinane-2,4,6-trione Chemical compound [Cd].N1C(=O)NC(=O)CC1=O CBSJPCRCMBRWJT-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000021615 conjugation Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005281 excited state Effects 0.000 description 1
- 238000002189 fluorescence spectrum Methods 0.000 description 1
- 239000010437 gem Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- MGRWKWACZDFZJT-UHFFFAOYSA-N molybdenum tungsten Chemical compound [Mo].[W] MGRWKWACZDFZJT-UHFFFAOYSA-N 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 239000013110 organic ligand Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- IBIRZFNPWYRWOG-UHFFFAOYSA-N phosphane;phosphoric acid Chemical compound P.OP(O)(O)=O IBIRZFNPWYRWOG-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000005622 photoelectricity Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Nitrogen Condensed Heterocyclic Rings (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
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CN201410377613.7A CN104119862B (zh) | 2014-08-01 | 2014-08-01 | 一种具有紫色荧光发射性能的配合物及其制备方法 |
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CN201410377613.7A CN104119862B (zh) | 2014-08-01 | 2014-08-01 | 一种具有紫色荧光发射性能的配合物及其制备方法 |
Publications (2)
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CN104119862A CN104119862A (zh) | 2014-10-29 |
CN104119862B true CN104119862B (zh) | 2016-03-30 |
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CN201410377613.7A Expired - Fee Related CN104119862B (zh) | 2014-08-01 | 2014-08-01 | 一种具有紫色荧光发射性能的配合物及其制备方法 |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106366100B (zh) * | 2016-07-27 | 2018-06-15 | 宁波大学 | 一种5-氨基乳清酸双核镉配合物 |
CN106929007B (zh) * | 2017-03-10 | 2019-01-22 | 宁波大学 | 一种青蓝色荧光材料及其制备方法 |
CN106928259B (zh) * | 2017-03-10 | 2018-07-24 | 宁波大学 | 一种青色荧光材料及其制备方法 |
CN106905246B (zh) * | 2017-03-10 | 2019-04-16 | 宁波大学 | 一种橙黄色荧光材料及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102127426A (zh) * | 2011-01-11 | 2011-07-20 | 宁波大学 | 一种具有紫色发光性能的荧光材料及其制备方法 |
CN102241972A (zh) * | 2011-05-04 | 2011-11-16 | 宁波大学 | 一种具有紫色发光性能的荧光材料及其制备方法 |
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JP2002334786A (ja) * | 2001-03-09 | 2002-11-22 | Sony Corp | 有機電界発光素子 |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102127426A (zh) * | 2011-01-11 | 2011-07-20 | 宁波大学 | 一种具有紫色发光性能的荧光材料及其制备方法 |
CN102241972A (zh) * | 2011-05-04 | 2011-11-16 | 宁波大学 | 一种具有紫色发光性能的荧光材料及其制备方法 |
Non-Patent Citations (1)
Title |
---|
"新配合物[Cd(H20)z(phen)z](PA)z的制备及晶体结构";李大光等,;《无机化学学报》;20020228;第18卷(第2期);第209-213页 * |
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CN104119862A (zh) | 2014-10-29 |
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Effective date of registration: 20190730 Address after: 266300 Room 439, Pioneering Building, No. 1 Changjiang Road, Jiaozhou Economic and Technological Development Zone, Qingdao City, Shandong Province Patentee after: Qingdao Magic Crystal Photoelectric Co.,Ltd. Address before: 315211 Zhejiang Province, Ningbo Jiangbei District Fenghua Road No. 818 Patentee before: Ningbo University |
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Effective date of registration: 20191209 Address after: 221116 a757, East Fudong road and South Fuzhong Road (Jiayuan building), Tongshan New District, Xuzhou City, Jiangsu Province Patentee after: Jiangsu Guanggu Biotechnology Research Institute Co.,Ltd. Address before: 266300 Room 439, Pioneering Building, No. 1 Changjiang Road, Jiaozhou Economic and Technological Development Zone, Qingdao City, Shandong Province Patentee before: Qingdao Magic Crystal Photoelectric Co.,Ltd. |
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Granted publication date: 20160330 |