CN104119715B - 一种水性多彩花纹涂料 - Google Patents
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Abstract
一种水性多彩花纹涂料，其原料按重量份数配比如下：丙烯酸乙酯100份；过硫酸铵5‑15份；石脑油10‑20份；丙烯酸30‑40份；烷基苯磺酸钠15‑25份；异丙醇5‑25份；去离子水80‑90份；正磷酸15‑35份；颜料10‑20份；乙醇20‑40份；聚氧化乙烯15‑25份；正丁醇20‑30份；增塑剂4‑10份；月桂酸二丁基锡25‑45份；甲基丙烯酸甲酯35‑45份；六亚甲基二异氰酸酯25‑35份；产品pH值7，固含量20‑30％，耐擦洗3000‑5000次；表干时间20‑30min，最低成膜温度0‑5℃；耐水性40‑60d无变化，遮盖力300‑400g/cm2；耐碱性20‑40d无变化，80℃贮存1‑2个月，可以广泛生产并不断代替现有材料。
Description
技术领域
本申请属于涂料领域，尤其涉及一种水性多彩花纹涂料。
背景技术
涂料，在中国传统名称为油漆。所谓涂料是涂覆在被保护或被装饰的物体表面，并能与被涂物形成牢固附着的连续薄膜，通常是以树脂、或油、或乳液为主，添加或不添加颜料、填料，添加相应助剂，用有机溶剂或烷基苯磺酸钠配制而成的粘稠液体。中国涂料界比较权威的《涂料工艺》一书是这样定义的：“涂料是一种材料，这种材料可以用不同的施工工艺涂覆在物件表面，形成粘附牢固、具有一定强度、连续的固态薄膜。这样形成的膜通称涂膜，又称漆膜或涂层。”涂料涂饰于物体表面能与基体材料很好粘结并形成完整而坚韧保护膜的物料，称为涂料。涂料与油漆是同一概念。油漆是人们沿用已久的习惯名称，引进我国后，就一直利用在建筑行业。涂料的作用可以概括为三个方面：保护作用，装饰作用，特殊功能作用。涂料的一般组成：包含成膜物质、颜填料、溶剂、助剂。
涂料是指应用于物体表面而能结成坚韧保护膜的物料的总称，建筑涂料是涂料中的一个重要类别，在我国，一般将用于建筑物内墙，外墙，顶棚，地面，卫生间的涂料称为建筑涂料。丙烯酸乙酯无色液体。密度0.9405。折射率1.404。熔点-72℃，沸点99.8℃。溶于水，乙醇和乙醚。易聚合，也能与其他单体共聚。用于制备塑料、树脂等高聚物，也可用作有机合成中间体。由3-羟基丙腈与乙醇和硫酸作用，或由丙烯酸用乙醇酯化而制得。
所谓水性多彩花纹涂料是由不相容的两相成分组成，其中一相分散介质为连续相，另一相为分散相，涂装时，通过一次性喷涂，便可得到豪华、美观、水性多彩花纹的图案。高分子合成材料单体。并用于制造涂料、粘合剂、皮革加工处理剂、纺织助剂、油漆添加剂等。与乙烯的共聚物是一种热熔性粘合剂；与5％氯乙基乙烯基醚的共聚物是一种耐油、耐热性能良好的合成橡胶，某些情况下可代替丁腈橡胶。而随着人性化理念的普及，及新型和谐社会的构成，设计一种耐水性、耐擦洗性及贮存稳定性优异的水性多彩花纹涂料是非常必要的。
发明内容
解决的技术问题：
本申请针对上述技术问题，提供一种水性多彩花纹涂料，解决现有水性多彩花纹涂料耐水性和耐擦洗性差、贮存稳定性差、不碱腐蚀等技术问题。
技术方案：
一种水性多彩花纹涂料，所述水性多彩花纹涂料的原料按重量份数配比如下：丙烯酸乙酯100份；过硫酸铵5-15份；石脑油10-20份；丙烯酸30-40份；烷基苯磺酸钠15-25份；异丙醇5-25份；去离子水80-90份；正磷酸15-35份；颜料10-20份；乙醇20-40份；聚氧化乙烯15-25份；正丁醇20-30份；增塑剂4-10份；月桂酸二丁基锡25-45份；甲基丙烯酸甲酯35-45份；六亚甲基二异氰酸酯25-35份。
作为本发明的一种优选技术方案：所述水性多彩花纹涂料的原料按重量份数配比如下：丙烯酸乙酯100份；过硫酸铵10份；石脑油15份；丙烯酸35份；烷基苯磺酸钠20份；异丙醇15份；去离子水85份；正磷酸25份；颜料15份；乙醇30份；聚氧化乙烯20份；正丁醇25份；增塑剂7份；月桂酸二丁基锡35份；甲基丙烯酸甲酯40份；六亚甲基二异氰酸酯30份。
作为本发明的一种优选技术方案：所述颜料采用氧化铁红、氧化铁绿或氧化铁黄。
作为本发明的一种优选技术方案：所述增塑剂采用DBP。
有益效果：
本发明所述一种水性多彩花纹涂料采用以上技术方案与现有技术相比，具有以下技术效果：1、产品pH值7，固含量20-30％，耐擦洗3000-5000次；2、表干时间20-30min，最低成膜温度0-5℃；3、耐水性40-60d无变化，遮盖力300-400g/cm2；4、耐碱性20-40d无变化，80℃贮存1-2个月，可以广泛生产并不断代替现有材料。
具体实施方式
实施例1:
一种水性多彩花纹涂料，其原料按重量份数配比如下：丙烯酸乙酯100份；过硫酸铵5份；石脑油10份；丙烯酸30份；烷基苯磺酸钠15份；异丙醇5份；去离子水80份；正磷酸15份；氧化铁红10份；乙醇20份；聚氧化乙烯15份；正丁醇20份；DBP4份；月桂酸二丁基锡25份；甲基丙烯酸甲酯35份；六亚甲基二异氰酸酯25份。
将丙烯酸乙酯、石脑油、丙烯酸、烷基苯磺酸钠和异丙醇加入去离子水中，加热至40℃搅拌3h，加入正磷酸、乙醇、聚氧化乙烯、正丁醇、甲基丙烯酸甲酯和DBP，升温至50℃用球磨机球磨10min，加入过硫酸铵和剩余原料，升温至60℃搅拌10h后既得成品。
固含量20％，耐擦洗3000次；表干时间30min，最低成膜温度5℃；耐水性40d无变化，遮盖力300g/cm2；耐碱性20d无变化，80℃贮存1个月。
实施例2:
一种水性多彩花纹涂料，其原料按重量份数配比如下：丙烯酸乙酯100份；过硫酸铵15份；石脑油20份；丙烯酸40份；烷基苯磺酸钠25份；异丙醇25份；去离子水90份；正磷酸35份；氧化铁绿20份；乙醇40份；聚氧化乙烯25份；正丁醇30份；DBP10份；月桂酸二丁基锡45份；甲基丙烯酸甲酯45份；六亚甲基二异氰酸酯35份。
将丙烯酸乙酯、石脑油、丙烯酸、烷基苯磺酸钠和异丙醇加入去离子水中，加热至40℃搅拌3h，加入正磷酸、乙醇、聚氧化乙烯、正丁醇、甲基丙烯酸甲酯和DBP，升温至50℃用球磨机球磨10min，加入过硫酸铵和剩余原料，升温至60℃搅拌10h后既得成品。
固含量25％，耐擦洗4000次；表干时间25min，最低成膜温度3℃；耐水性50d无变化，遮盖力350g/cm2；耐碱性30d无变化，80℃贮存1.5个月。
实施例3:
一种水性多彩花纹涂料，其原料按重量份数配比如下：丙烯酸乙酯100份；过硫酸铵10份；石脑油15份；丙烯酸35份；烷基苯磺酸钠20份；异丙醇15份；去离子水85份；正磷酸25份；氧化铁黄15份；乙醇30份；聚氧化乙烯20份；正丁醇25份；DBP7份；月桂酸二丁基锡35份；甲基丙烯酸甲酯40份；六亚甲基二异氰酸酯30份。
将丙烯酸乙酯、石脑油、丙烯酸、烷基苯磺酸钠和异丙醇加入去离子水中，加热至40℃搅拌3h，加入正磷酸、乙醇、聚氧化乙烯、正丁醇、甲基丙烯酸甲酯和DBP，升温至50℃用球磨机球磨10min，加入过硫酸铵和剩余原料，升温至60℃搅拌10h后既得成品。
固含量30％，耐擦洗5000次；表干时间20min，最低成膜温度0℃；耐水性60d无变化，遮盖力400g/cm2；耐碱性40d无变化，80℃贮存2个月。
以上实施例中的组合物所有组分均可以商业购买。
上述实施例只是用于对本发明的内容进行阐述，而不是限制，因此在与本发明的权利要求书相当的含义和范围内的任何改变，都应该认为是包括在权利要求书的范围内。
Claims (2)
1.一种水性多彩花纹涂料，其特征在于所述水性多彩花纹涂料的原料按重量份数配比如下：丙烯酸乙酯100份；过硫酸铵5-15份；石脑油10-20份；丙烯酸30-40份；烷基苯磺酸钠15-25份；异丙醇5-25份；去离子水80-90份；正磷酸15-35份；颜料10-20份；乙醇20-40份；聚氧化乙烯15-25份；正丁醇20-30份；增塑剂4-10份；月桂酸二丁基锡25-45份；甲基丙烯酸甲酯35-45份；六亚甲基二异氰酸酯25-35份；
所述颜料采用氧化铁红、氧化铁绿或氧化铁黄；
所述增塑剂采用DBP。
2.根据权利要求1所述的一种水性多彩花纹涂料，其特征在于所述水性多彩花纹涂料的原料按重量份数配比如下：丙烯酸乙酯100份；过硫酸铵10份；石脑油15份；丙烯酸35份；烷基苯磺酸钠20份；异丙醇15份；去离子水85份；正磷酸25份；颜料15份；乙醇30份；聚氧化乙烯20份；正丁醇25份；增塑剂7份；月桂酸二丁基锡35份；甲基丙烯酸甲酯40份；六亚甲基二异氰酸酯30份。
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