CN104119023A - High-efficiency delayed coagulation water reducing agent - Google Patents

High-efficiency delayed coagulation water reducing agent Download PDF

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Publication number
CN104119023A
CN104119023A CN201410293826.1A CN201410293826A CN104119023A CN 104119023 A CN104119023 A CN 104119023A CN 201410293826 A CN201410293826 A CN 201410293826A CN 104119023 A CN104119023 A CN 104119023A
Authority
CN
China
Prior art keywords
parts
water reducing
reducing agent
sodium
sulfonate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201410293826.1A
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Chinese (zh)
Other versions
CN104119023B (en
Inventor
徐松
夏晖
蔺红亮
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Linyi Tianyuan Concrete Engineering Co ltd
Original Assignee
WUHU SANXING CONCRETE ADMIXTURE Co Ltd
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Priority to CN201410293826.1A priority Critical patent/CN104119023B/en
Publication of CN104119023A publication Critical patent/CN104119023A/en
Application granted granted Critical
Publication of CN104119023B publication Critical patent/CN104119023B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Abstract

The invention discloses a high-efficiency delayed coagulation water reducing agent which is prepared by mixing the following raw materials in parts by weight: 40-60 parts of melamine sulfonate formaldehyde condensation product, 25-35 parts of poly-benzofuran resin sodium sulfonate, 10-15 parts of corn starch, 8-12 parts of sodium gluconate, 2-4 parts of xylitol, 4-8 parts of calcium superphosphate, 3-6 parts of ethylene diamine tetra (methylene phosphonic acid) sodium, 2-3 parts of glycerol ester of rosin, 3-5 parts of triethanolamine, 4-7 parts of cane molasses, 3.5-4.5 parts of sodium citrate, 4-6 parts of ferrous carbonate, 5-10 parts of fumed silica, 7-13 parts of calcium sulphoaluminate, 4-8 parts of polyvinyl alcohol, 10-15 parts of acetylene sludge and 4.5-6.5 parts of aids. The water reducing agent is high in water reducing ratio, low in slump loss, obvious in enhancement effect and excellent in working performance, the coagulation time of concrete can be obviously delayed, and after the concrete is doped, the water reducing agent is high in pumpability, high in cohesiveness, high in durability, low in gas content and low in bleeding rate and has high economic benefits and social benefits.

Description

Efficient retarding and water reducing agent
Technical field
The present invention relates to a kind of efficient retarding and water reducing agent, belong to concrete admixture field.
Background technology
Concrete admixture, is called for short admixture, refers to before mixing concrete mixing or in mix process, mixes to improve the material of concrete performance.Because admixture can improve concrete performance effectively, and have good economic benefit, be all widely used in many countries, the application in engineering more and more comes into one's own, and becomes material indispensable in concrete.Wherein retardation water reducing agent is the one in concrete admixture, and it can delay concrete coagulating time, makes the fresh concrete long period keep plasticity, convenient cast, improve operating efficiency, can not cause detrimentally affect to later concrete properties simultaneously, and have water-reduction concurrently.The retardation water reducing agent that used in the market exists the not obvious and low shortcoming of water-reducing rate of retarding effect, cannot meet the requirement of high-strength high-performance concrete.
Summary of the invention
To the object of the invention is the defect existing in prior art in order solving, a kind of slow setting time length and the high efficient retarding and water reducing agent of water-reducing rate to be provided.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of efficient retarding and water reducing agent, is mixed by the raw material of following weight part: condensate of melamine sulfonate and formaldehyde 40-60, paracoumarone resin sodium sulfonate 25-35, W-Gum 10-15, Sunmorl N 60S 8-12, Xylitol 2-4, calcium superphosphate 4-8, ethylene diamine tetra methylene phosphonic acid sodium 3-6, ester gum 2-3, trolamine 3-5, cane molasses 4-7, Trisodium Citrate 3.5-4.5, iron protocarbonate 4-6, gas-phase silica 5-10, calcium sulphoaluminate 7-13, polyvinyl alcohol 4-8, carbide slag 10-15, auxiliary agent 4.5-6.5;
Described auxiliary agent is made up of the raw material of following weight part: magnesia 10-15, Humic acid Magnesium 3-6, ammonium benzoate 2-4, α-sodium olefin sulfonate 6-12, myo-Inositol hexaphosphate 1.5-2.5, iso-butylene triethoxyl silane 3-5, poly-ferric chloride 5-10, germanite powder 12-18, titanium dioxide 5-10, myristyl glucoside 1-2, polyamide wax 4-6, lithium magnesium silicate 2-3, tea saponin 1.5-2.5;
Above-mentioned magnesia, germanite powder, titanium dioxide are mixed, then add α-sodium olefin sulfonate, iso-butylene triethoxyl silane, polyamide wax, lithium magnesium silicate, under 40-60 DEG C of bath temperature, stir 10-15min, after being cooled to normal temperature, add remaining raw material, stir, dry, obtain described auxiliary agent.
Beneficial effect of the present invention:
Water reducer water-reducing rate of the present invention is high, little loss of slump, reinforced effects is obvious, excellent working performance, can significantly delay concrete time of coagulation, mix that pumpability is good after concrete, cohesiveness strong, good endurance, air content is low, bleeding rate is little, has good economic benefit and social benefit.
Embodiment
A kind of efficient retarding and water reducing agent, is mixed by the raw material of following weight (kg): condensate of melamine sulfonate and formaldehyde 50, paracoumarone resin sodium sulfonate 30, W-Gum 12, Sunmorl N 60S 10, Xylitol 3, calcium superphosphate 6, ethylene diamine tetra methylene phosphonic acid sodium 4, ester gum 2.5, trolamine 4, cane molasses 6, Trisodium Citrate 4, iron protocarbonate 5, gas-phase silica 8, calcium sulphoaluminate 11, polyvinyl alcohol 6, carbide slag 12, auxiliary agent 5.5;
Described auxiliary agent is made up of the raw material of following weight part: magnesia 15, Humic acid Magnesium 5, ammonium benzoate 3, α-sodium olefin sulfonate 10, myo-Inositol hexaphosphate 2, iso-butylene triethoxyl silane 4, poly-ferric chloride 7, germanite powder 16, titanium dioxide 8, myristyl glucoside 1.5, polyamide wax 5, lithium magnesium silicate 3, tea saponin 2;
Above-mentioned magnesia, germanite powder, titanium dioxide are mixed, then add α-sodium olefin sulfonate, iso-butylene triethoxyl silane, polyamide wax, lithium magnesium silicate, under 60 DEG C of bath temperatures, stir 10min, after being cooled to normal temperature, add remaining raw material, stir, dry, obtain described auxiliary agent.
It is as shown in the table that the above-mentioned efficient retarding and water reducing agent making mixes salient features detected result in concrete:

Claims (1)

1. an efficient retarding and water reducing agent, it is characterized in that, mixed by the raw material of following weight part: condensate of melamine sulfonate and formaldehyde 40-60, paracoumarone resin sodium sulfonate 25-35, W-Gum 10-15, Sunmorl N 60S 8-12, Xylitol 2-4, calcium superphosphate 4-8, ethylene diamine tetra methylene phosphonic acid sodium 3-6, ester gum 2-3, trolamine 3-5, cane molasses 4-7, Trisodium Citrate 3.5-4.5, iron protocarbonate 4-6, gas-phase silica 5-10, calcium sulphoaluminate 7-13, polyvinyl alcohol 4-8, carbide slag 10-15, auxiliary agent 4.5-6.5;
Described auxiliary agent is made up of the raw material of following weight part: magnesia 10-15, Humic acid Magnesium 3-6, ammonium benzoate 2-4, α-sodium olefin sulfonate 6-12, myo-Inositol hexaphosphate 1.5-2.5, iso-butylene triethoxyl silane 3-5, poly-ferric chloride 5-10, germanite powder 12-18, titanium dioxide 5-10, myristyl glucoside 1-2, polyamide wax 4-6, lithium magnesium silicate 2-3, tea saponin 1.5-2.5;
Above-mentioned magnesia, germanite powder, titanium dioxide are mixed, then add α-sodium olefin sulfonate, iso-butylene triethoxyl silane, polyamide wax, lithium magnesium silicate, under 40-60 DEG C of bath temperature, stir 10-15min, after being cooled to normal temperature, add remaining raw material, stir, dry, obtain described auxiliary agent.
CN201410293826.1A 2014-06-25 2014-06-25 Efficient retarding and water reducing agent Expired - Fee Related CN104119023B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410293826.1A CN104119023B (en) 2014-06-25 2014-06-25 Efficient retarding and water reducing agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410293826.1A CN104119023B (en) 2014-06-25 2014-06-25 Efficient retarding and water reducing agent

Publications (2)

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CN104119023A true CN104119023A (en) 2014-10-29
CN104119023B CN104119023B (en) 2015-12-30

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104313625A (en) * 2014-11-07 2015-01-28 合肥大安印刷有限责任公司 Metal surface cleaning agent containing tea saponin and preparation method of metal surface cleaning agent
CN108314348A (en) * 2017-01-14 2018-07-24 长沙恒旺建材科技有限公司 A kind of cement water reducing agent
CN110156398A (en) * 2019-05-22 2019-08-23 陕西新意达恒众混凝土有限公司 A kind of strong concrete and preparation method thereof
CN111995310A (en) * 2020-09-02 2020-11-27 陈永霞 Super-retarding concrete and preparation method thereof
CN113636775A (en) * 2021-09-22 2021-11-12 宁波彩燕建筑材料有限公司 Preparation method of additive for concrete
CN117069415A (en) * 2023-10-16 2023-11-17 四川蜀道建筑科技有限公司 Anti-urinary polycarboxylate superplasticizer, concrete and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0891899A (en) * 1994-09-29 1996-04-09 Nissan Chem Ind Ltd Production of water reducing agent
CN102659342A (en) * 2012-05-14 2012-09-12 华北水利水电学院 Retarding superplasticizer composition for roller compacted concrete
CN103172298A (en) * 2011-12-21 2013-06-26 同济大学 Efficient water reducing agent for recycled aggregate concrete as well as preparation method and application thereof
CN103864337A (en) * 2014-02-11 2014-06-18 湖南先锋建材有限公司 Mortar plasticizer

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0891899A (en) * 1994-09-29 1996-04-09 Nissan Chem Ind Ltd Production of water reducing agent
CN103172298A (en) * 2011-12-21 2013-06-26 同济大学 Efficient water reducing agent for recycled aggregate concrete as well as preparation method and application thereof
CN102659342A (en) * 2012-05-14 2012-09-12 华北水利水电学院 Retarding superplasticizer composition for roller compacted concrete
CN103864337A (en) * 2014-02-11 2014-06-18 湖南先锋建材有限公司 Mortar plasticizer

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104313625A (en) * 2014-11-07 2015-01-28 合肥大安印刷有限责任公司 Metal surface cleaning agent containing tea saponin and preparation method of metal surface cleaning agent
CN108314348A (en) * 2017-01-14 2018-07-24 长沙恒旺建材科技有限公司 A kind of cement water reducing agent
CN110156398A (en) * 2019-05-22 2019-08-23 陕西新意达恒众混凝土有限公司 A kind of strong concrete and preparation method thereof
CN110156398B (en) * 2019-05-22 2021-06-29 陕西新意达恒众混凝土有限公司 High-strength concrete and preparation method thereof
CN111995310A (en) * 2020-09-02 2020-11-27 陈永霞 Super-retarding concrete and preparation method thereof
CN113636775A (en) * 2021-09-22 2021-11-12 宁波彩燕建筑材料有限公司 Preparation method of additive for concrete
CN117069415A (en) * 2023-10-16 2023-11-17 四川蜀道建筑科技有限公司 Anti-urinary polycarboxylate superplasticizer, concrete and preparation method thereof
CN117069415B (en) * 2023-10-16 2024-01-26 四川蜀道建筑科技有限公司 Anti-urinary polycarboxylate superplasticizer, concrete and preparation method thereof

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Effective date of registration: 20190326

Address after: 276000 Junction of Shunda Road and Zisheng Street, Hedong District, Linyi City, Shandong Province

Patentee after: LINYI TIANYUAN CONCRETE ENGINEERING Co.,Ltd.

Address before: 241100 Zhao Qiao Industrial Park, Wuhu County, Wuhu, Anhui

Patentee before: WUHU SANXING CONCRETE ADMIXTURE Co.,Ltd.

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20151230

CF01 Termination of patent right due to non-payment of annual fee