CN104108900B - Gas tracting subtractive agent - Google Patents

Gas tracting subtractive agent Download PDF

Info

Publication number
CN104108900B
CN104108900B CN201410293748.5A CN201410293748A CN104108900B CN 104108900 B CN104108900 B CN 104108900B CN 201410293748 A CN201410293748 A CN 201410293748A CN 104108900 B CN104108900 B CN 104108900B
Authority
CN
China
Prior art keywords
sodium
compound
formaldehyde
mixed
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201410293748.5A
Other languages
Chinese (zh)
Other versions
CN104108900A (en
Inventor
夏晖
徐松
蔺红亮
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hubei Tianan New Building Materials Co., Ltd.
Original Assignee
WUHU SANXING CONCRETE ADMIXTURE Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WUHU SANXING CONCRETE ADMIXTURE Co Ltd filed Critical WUHU SANXING CONCRETE ADMIXTURE Co Ltd
Priority to CN201410293748.5A priority Critical patent/CN104108900B/en
Publication of CN104108900A publication Critical patent/CN104108900A/en
Application granted granted Critical
Publication of CN104108900B publication Critical patent/CN104108900B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of gas tracting subtractive agent, it is mixed by the raw material of following weight part: sulfanilate formaldehyde condensation products 33-46, condensate of melamine sulfonate and formaldehyde 22-34, fatty acid methyl ester ethoxylate sulfonate 14-28, Sodium Nitrite? 6-12, howlite powder 12-18, mountain Yu oxygen base polydimethylsiloxane 3-5, cocounut oil acyl disodium glutamate 4-7, sodium lauroyl sareosine 3-6, condensation compound of alkyl phenol and epoxy ethane 6-9, sodium abietate? 4-7, pure third latex powder 5-10, potassium bichromate 8-14, N, N ˊ-methylene-bisacrylamide 3-6, 124 Triazole lipid acid amine salt? 5-10, auxiliary agent 4-8.Gas tracting subtractive agent of the present invention has good bleed, diminishing, enhancement, reduce concrete surface tension force significantly, improve concrete workability, improve concrete mobility, plasticity-and folding strength, reduce bleeding and segregation, improve concrete permeability resistance, freeze-thaw resistance and weather resistance etc.

Description

Gas tracting subtractive agent
Technical field
The present invention relates to a kind of gas tracting subtractive agent, belong to concrete admixture field.
Background technology
Concrete admixture, is called for short admixture, refers to before mixing concrete mixing or mixes to improve the material of concrete performance in mix process.Because admixture can improve concrete performance effectively, and have good economic benefit, be all widely used in many countries, the application in engineering more and more comes into one's own, and becomes material indispensable in concrete.Wherein gas tracting subtractive agent is the one in concrete admixture, it has bleed and diminishing function concurrently, be composited according to a certain percentage by air entrapment agent and water reducer, add in concrete and can produce uniform and stable and survivable small bubbles, to mixed material lubricate and the viscosity of slurry and surrender ability can be increased, concrete workability, plasticity and cohesion are significantly improved.Gas tracting subtractive agent over-all properties used in the market is poor, cannot be applied to freeze-thaw resistance and the high concrete of life requirement.
Summary of the invention
The object of the invention is, in order to solve the defect existed in prior art, to provide a kind of gas tracting subtractive agent, greatly improving concrete frost resistance and weather resistance.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of gas tracting subtractive agent, mixed by the raw material of following weight part: sulfanilate formaldehyde condensation products 33-46, condensate of melamine sulfonate and formaldehyde 22-34, fatty acid methyl ester ethoxylate sulfonate 14-28, Sodium Nitrite 6-12, howlite powder 12-18, mountain Yu oxygen base polydimethylsiloxane 3-5, cocounut oil acyl disodium glutamate 4-7, sodium lauroyl sareosine 3-6, condensation compound of alkyl phenol and epoxy ethane 6-9, sodium abietate 4-7, pure third latex powder 5-10, potassium bichromate 8-14, N, N'-methylene-bisacrylamide 3-6, 124 Triazole lipid acid amine salt 5-10, auxiliary agent 4-8,
The preparation method of described auxiliary agent is as follows: a, get the raw material of following weight part: activated magnesia 5-10, tuff micro mist 10-15, desulphurize fly ash 9-16, melamine urea-formaldehyde resin 12-18, microporous calcium silicate 6-12, polyisobutene 5-10, tertiary ethylene carbonate 4-6,2-methyl-2,4-pentanediol polyoxyethylene polyoxypropylene ether 2-4, sodium pentachlorophenol 1.5-2.5, Coconut Fatty Acid Monoethanolamide 3-5, bone meal 4-8, Poly Dimethyl Diallyl Ammonium Chloride 2-4, sulfonated phenylethylene-maleic anhydride copolymer 5-10; B, by sulfonated phenylethylene-maleic anhydride copolymer, Poly Dimethyl Diallyl Ammonium Chloride, 2-methyl-2,4-pentanediol polyoxyethylene polyoxypropylene ether mixes, then activated magnesia, tuff micro mist, desulphurize fly ash is added successively, 10-15min is stirred under 45-55 DEG C of bath temperature, be cooled to normal temperature, dry, obtain compound A; C, bone meal, microporous calcium silicate to be mixed, then add melamine urea-formaldehyde resin, Coconut Fatty Acid Monoethanolamide, polyisobutene, tertiary ethylene carbonate, sodium pentachlorophenol successively, high speed dispersion 5-10min, dry, obtain compound B; D, compound A and compound B to be mixed, obtain described auxiliary agent.
Beneficial effect of the present invention:
Gas tracting subtractive agent of the present invention has good bleed, diminishing, enhancement, reduce concrete surface tension force significantly, improve concrete workability, improve concrete mobility, plasticity-and folding strength, reduce bleeding and segregation, improve concrete permeability resistance, freeze-thaw resistance and weather resistance etc., be applicable to the concrete that harbour, harbour, hydro project, highway pavement, freeze-thaw-, anticorrosion, seepage control project etc. require certain air content.
Embodiment
A kind of gas tracting subtractive agent, mixed by the raw material of following weight (kg): sulfanilate formaldehyde condensation products 42, condensate of melamine sulfonate and formaldehyde 30, fatty acid methyl ester ethoxylate sulfonate 22, Sodium Nitrite 8, howlite powder 16, mountain Yu oxygen base polydimethylsiloxane 4, cocounut oil acyl disodium glutamate 6, sodium lauroyl sareosine 4, condensation compound of alkyl phenol and epoxy ethane 7, sodium abietate 5, pure third latex powder 8, potassium bichromate 12, N, N'-methylene-bisacrylamide 4,124 Triazole lipid acid amine salt 8, auxiliary agent 6;
The preparation method of described auxiliary agent is as follows: a, get the raw material of following weight (kg): activated magnesia 7, tuff micro mist 12, desulphurize fly ash 14, melamine urea-formaldehyde resin 15, microporous calcium silicate 8, polyisobutene 7, tertiary ethylene carbonate 5,2-methyl-2,4-pentanediol polyoxyethylene polyoxypropylene ether 3, sodium pentachlorophenol 2, Coconut Fatty Acid Monoethanolamide 4, bone meal 6, Poly Dimethyl Diallyl Ammonium Chloride 3, sulfonated phenylethylene-maleic anhydride copolymer 8; B, by sulfonated phenylethylene-maleic anhydride copolymer, Poly Dimethyl Diallyl Ammonium Chloride, 2-methyl-2,4-pentanediol polyoxyethylene polyoxypropylene ether mixes, then activated magnesia, tuff micro mist, desulphurize fly ash is added successively, 12min is stirred under 50 DEG C of bath temperatures, be cooled to normal temperature, dry, obtain compound A; C, bone meal, microporous calcium silicate to be mixed, then add melamine urea-formaldehyde resin, Coconut Fatty Acid Monoethanolamide, polyisobutene, tertiary ethylene carbonate, sodium pentachlorophenol successively, high speed dispersion 8min, dry, obtain compound B; D, compound A and compound B to be mixed, obtain described auxiliary agent.
The salient features detected result that above-mentioned obtained gas tracting subtractive agent mixes in concrete is as shown in the table:

Claims (1)

1. a gas tracting subtractive agent, it is characterized in that, mixed by the raw material of following weight part: sulfanilate formaldehyde condensation products 33-46, condensate of melamine sulfonate and formaldehyde 22-34, fatty acid methyl ester ethoxylate sulfonate 14-28, Sodium Nitrite 6-12, howlite powder 12-18, mountain Yu oxygen base polydimethylsiloxane 3-5, cocounut oil acyl disodium glutamate 4-7, sodium lauroyl sareosine 3-6, condensation compound of alkyl phenol and epoxy ethane 6-9, sodium abietate 4-7, pure third latex powder 5-10, potassium bichromate 8-14, N, N'-methylene-bisacrylamide 3-6, 124 Triazole lipid acid amine salt 5-10, auxiliary agent 4-8,
The preparation method of described auxiliary agent is as follows:
A, get the raw material of following weight part: activated magnesia 5-10, tuff micro mist 10-15, desulphurize fly ash 9-16, melamine urea-formaldehyde resin 12-18, microporous calcium silicate 6-12, polyisobutene 5-10, tertiary ethylene carbonate 4-6,2-methyl-2,4-pentanediol polyoxyethylene polyoxypropylene ether 2-4, sodium pentachlorophenol 1.5-2.5, Coconut Fatty Acid Monoethanolamide 3-5, bone meal 4-8, Poly Dimethyl Diallyl Ammonium Chloride 2-4, sulfonated phenylethylene-maleic anhydride copolymer 5-10;
B, by sulfonated phenylethylene-maleic anhydride copolymer, Poly Dimethyl Diallyl Ammonium Chloride, 2-methyl-2,4-pentanediol polyoxyethylene polyoxypropylene ether mixes, then activated magnesia, tuff micro mist, desulphurize fly ash is added successively, 10-15min is stirred under 45-55 DEG C of bath temperature, be cooled to normal temperature, dry, obtain compound A;
C, bone meal, microporous calcium silicate to be mixed, then add melamine urea-formaldehyde resin, Coconut Fatty Acid Monoethanolamide, polyisobutene, tertiary ethylene carbonate, sodium pentachlorophenol successively, high speed dispersion 5-10min, dry, obtain compound B; D, compound A and compound B to be mixed, obtain described auxiliary agent.
CN201410293748.5A 2014-06-25 2014-06-25 Gas tracting subtractive agent Expired - Fee Related CN104108900B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410293748.5A CN104108900B (en) 2014-06-25 2014-06-25 Gas tracting subtractive agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410293748.5A CN104108900B (en) 2014-06-25 2014-06-25 Gas tracting subtractive agent

Publications (2)

Publication Number Publication Date
CN104108900A CN104108900A (en) 2014-10-22
CN104108900B true CN104108900B (en) 2016-03-23

Family

ID=51705913

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410293748.5A Expired - Fee Related CN104108900B (en) 2014-06-25 2014-06-25 Gas tracting subtractive agent

Country Status (1)

Country Link
CN (1) CN104108900B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104386940A (en) * 2014-10-31 2015-03-04 安徽省阜南绿原化工有限公司 High-antiseptic-effect retarding water reducing agent and preparation method thereof
CN106007458B (en) * 2016-05-20 2019-01-01 江苏苏博特新材料股份有限公司 A kind of preparation method and applications of gas tracting subtractive agent
CN106630741A (en) * 2016-12-18 2017-05-10 钦州市科学技术开发中心 Resin water reducer and preparation method thereof
CN108033708A (en) * 2017-12-19 2018-05-15 萧县沃德化工科技有限公司 A kind of efficient cement water reducing agent
CN109020435B (en) * 2018-08-21 2021-04-30 福建兴纳科技有限公司 High-low temperature resistant sleeve grouting material and preparation method thereof
CN109336491A (en) * 2018-09-10 2019-02-15 张程玙 Hydraulic engineering frost-resistant concrete and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1169404A (en) * 1996-06-24 1998-01-07 张显军 Plasticizing lead gas for building mortar and concrete, lead gas water-reducer and preparation technology thereof
CN1704371A (en) * 2004-05-28 2005-12-07 班俊生 High performance water-reducing agent of sulfanilate-sulfonated acetone-formaldehyde condensate and process for making same
CN101328037A (en) * 2008-07-31 2008-12-24 华南理工大学 Alkali lignose concrete air-leading water-reducing agent, preparation and use thereof
CN102503236A (en) * 2011-10-17 2012-06-20 张家港市林达外加剂厂 Composite concrete waterproofing agent
CN102659342A (en) * 2012-05-14 2012-09-12 华北水利水电学院 Retarding superplasticizer composition for roller compacted concrete

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1169404A (en) * 1996-06-24 1998-01-07 张显军 Plasticizing lead gas for building mortar and concrete, lead gas water-reducer and preparation technology thereof
CN1704371A (en) * 2004-05-28 2005-12-07 班俊生 High performance water-reducing agent of sulfanilate-sulfonated acetone-formaldehyde condensate and process for making same
CN101328037A (en) * 2008-07-31 2008-12-24 华南理工大学 Alkali lignose concrete air-leading water-reducing agent, preparation and use thereof
CN102503236A (en) * 2011-10-17 2012-06-20 张家港市林达外加剂厂 Composite concrete waterproofing agent
CN102659342A (en) * 2012-05-14 2012-09-12 华北水利水电学院 Retarding superplasticizer composition for roller compacted concrete

Also Published As

Publication number Publication date
CN104108900A (en) 2014-10-22

Similar Documents

Publication Publication Date Title
CN104108900B (en) Gas tracting subtractive agent
CN104119026B (en) Concrete composite water reducer
CN105272042B (en) A kind of antifreeze anti-crack concrete
CN104119021B (en) High efficiency water reducing agent
CN103011662B (en) Alkali-activated high-performance water reducer and preparation method thereof
CN104119024B (en) Collapse protection type water reducer
CN104119027B (en) Retardation water reducing agent
CN104129943A (en) Wet-mixed mortar admixture as well as preparation method and application thereof
CN103086635A (en) Pumping agent and application thereof
CN104119023B (en) Efficient retarding and water reducing agent
CN104973817A (en) Concrete viscosity regulator suitable for compatible use with polycarboxylic acid water reducer and preparation method thereof
CN107473618B (en) Composite foaming agent for foam concrete and preparation method thereof
CN104030599B (en) Antifreezing polycarboxylic acid composite pumping water reducing agent and application thereof
CN104844258A (en) Aerating block with waste rubber
CN103922628A (en) Anti-freezing type polycarboxylic acid high-performance water reducer and preparation method thereof
CN103708765B (en) A kind of polycarboxylic acid series pumping agent conditioning agent
CN102173635B (en) Polycarboxylic acid high-slump-retaining zero-bleeding high-performance water reducing agent
CN104119019A (en) Water-reducing agent containing peanut shell powder
CN103613309A (en) Polycarboxylate water reducing agent for concrete
CN104119020B (en) Slow setting diminishing crack inhibitor
CN107840929A (en) The preparation method of polycarboxylate water-reducer
CN105314922A (en) Efficient pumping agent and application thereof
CN114014581B (en) Anti-seepage and anti-freezing additive for concrete in complex plateau environment and preparation method thereof
CN105948559A (en) Negative temperature concrete antifreezer
CN102503219B (en) Compound with biological materials and application thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20190326

Address after: 437000 Xian'an Economic Development Zone, Xianning City, Hubei Province

Patentee after: Hubei Tianan New Building Materials Co., Ltd.

Address before: 241100 Zhao Qiao Industrial Park, Wuhu County, Wuhu, Anhui

Patentee before: WUHU SANXING CONCRETE ADMIXTURE CO., LTD.

TR01 Transfer of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160323

Termination date: 20200625

CF01 Termination of patent right due to non-payment of annual fee