CN104109476B - Color inhibition terrace paint and constructional method thereof - Google Patents
Color inhibition terrace paint and constructional method thereof Download PDFInfo
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- CN104109476B CN104109476B CN201410362025.6A CN201410362025A CN104109476B CN 104109476 B CN104109476 B CN 104109476B CN 201410362025 A CN201410362025 A CN 201410362025A CN 104109476 B CN104109476 B CN 104109476B
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- terrace paint
- color inhibition
- roller coat
- terrace
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- 239000003973 paint Substances 0.000 title claims abstract description 45
- 230000005764 inhibitory process Effects 0.000 title claims abstract description 37
- 238000000034 method Methods 0.000 title claims abstract description 12
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 16
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 10
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 8
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 8
- GCTFWCDSFPMHHS-UHFFFAOYSA-M Tributyltin chloride Chemical compound CCCC[Sn](Cl)(CCCC)CCCC GCTFWCDSFPMHHS-UHFFFAOYSA-M 0.000 claims abstract description 8
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical class COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims abstract description 8
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 235000019259 sodium dehydroacetate Nutrition 0.000 claims abstract description 8
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004288 Sodium dehydroacetate Substances 0.000 claims abstract description 7
- 229940079839 sodium dehydroacetate Drugs 0.000 claims abstract description 7
- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 claims abstract description 7
- 238000005498 polishing Methods 0.000 claims abstract description 6
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 6
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 5
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract description 5
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical group OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 238000006243 chemical reaction Methods 0.000 claims description 15
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 6
- 239000012965 benzophenone Substances 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 2
- 238000013019 agitation Methods 0.000 claims 3
- 238000004383 yellowing Methods 0.000 abstract description 8
- 238000003756 stirring Methods 0.000 description 12
- 238000000576 coating method Methods 0.000 description 5
- 235000010215 titanium dioxide Nutrition 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- -1 color Substances 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- WLXFQHMNMICAHI-UHFFFAOYSA-M tin;tributyl(chloro)stannane Chemical compound [Sn].CCCC[Sn](Cl)(CCCC)CCCC WLXFQHMNMICAHI-UHFFFAOYSA-M 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a kind of color inhibition terrace paint and constructional method thereof, be prepared from by the raw material of following parts by weight: urethane 50 parts ~ 60 parts, 60 parts ~ 70 parts, rosin, N-BUTYL ACETATE 15 parts ~ 25 parts, propylene glycol methyl ether acetate 15 parts ~ 20 parts, sodium polyacrylate 8 parts ~ 15 parts, titanium dioxide 5 parts ~ 10 parts, sodium dehydroacetate 5 parts ~ 10 parts, dimethylbenzene 5 parts ~ 8 parts, tributyltin chloride 5 parts ~ 10 parts, benzophenone 3 parts ~ 5 parts, nipagin esters 1 part ~ 3 parts; This terrace paint is coated with constructional method and comprises the following steps: dry sanding paper polishing → dedusting → Puttying → polish metope → roller coat thin layer color inhibition terrace paint → dry → roller coat second layer color inhibition terrace paint, roller coat arrange → dries naturally.This color inhibition terrace paint anti-yellowing property is excellent, and after application, the several years is still as before pure white.
Description
Technical field
The present invention relates to technical field of chemical paint, especially a kind of color inhibition terrace paint and constructional method thereof.
Background technology
Terrace paint is by Germany in invention in 1934 the earliest, makes primarily of oil plant, tree material, color, solvent etc.According to wanting filmogen to divide, terrace paint comprises epoxy floor coating, urethane resin terrace paint, unsaturated polyester resin terrace paint, vinylformic acid terrace paint, crystal terrace paint, polyurea elastomer terrace paint, concrete dense curing agent etc.Polyurethane floor coatings belongs to high solid thick coating, it has excellent Corrosion Protection, insulating property and acid and alkali-resistance salt performance, there are higher intensity and elasticity, polyurethane floor coatings is adopted to be coated with the bright and clean not cunning in ground of paving, good springiness, wear-resisting, withstand voltage, water-fast, elegant in appearance, walk comfortable, do not play dirt, easy cleaning, use middle nondiscoloration, do not need waxing, carpet can be replaced to use, be applicable to meeting room, Movie House, the more occasion of the stream of peoples such as Library does elastic decorative ground and industrial premises, workshop and accurate machine room wear-resisting, oil resistant, corrosion-resistant ground and vault, the water-proof decorative ground of toilet.But existing epoxypaint is in use easily by the impact of moisture in air, ozone and oxynitride, and under ultraviolet effect, the degraded of intensifier ring epoxy resins and isomerization, cause epoxypaint xanthochromia.
Summary of the invention
The object of this invention is to provide a kind of color inhibition terrace paint and constructional method thereof, this color inhibition terrace paint can solve the problem of terrace paint anti-yellowing property difference.
In order to solve the problem, the technical solution used in the present invention is:
A kind of color inhibition terrace paint, be prepared from by the raw material of following parts by weight: urethane 50 parts ~ 60 parts, 60 parts ~ 70 parts, rosin, N-BUTYL ACETATE 15 parts ~ 25 parts, propylene glycol methyl ether acetate 15 parts ~ 20 parts, sodium polyacrylate 8 parts ~ 15 parts, titanium dioxide 5 parts ~ 10 parts, sodium dehydroacetate 5 parts ~ 10 parts, dimethylbenzene 5 parts ~ 8 parts, 5 parts ~ 10 parts, tributyltin chloride tin, benzophenone 3 parts ~ 5 parts, nipagin esters 1 part ~ 3 parts.
Preparation method is: add in reaction vessel by urethane and rosin, stirs, fully dissolves; In described reaction vessel, add titanium dioxide and nipagin esters, be warming up to 80 DEG C ~ 90 DEG C, stir, react 40 minutes ~ 60 minutes; N-BUTYL ACETATE is added, propylene glycol methyl ether acetate, sodium polyacrylate, sodium dehydroacetate in described reaction vessel, dimethylbenzene, tributyltin chloride and benzophenone, be heated to 110 DEG C ~ 120 DEG C, stirs, react 3 hours ~ 4 hours, cooling, obtains color inhibition terrace paint.
The constructional method of this color inhibition terrace paint, comprises the following steps: dry sanding paper polishing → dedusting → polish metope → roller coat thin layer color inhibition terrace paint → dry → roller coat second layer color inhibition terrace paint, roller coat arrange → dries naturally.
Owing to have employed technique scheme, the present invention compared with prior art has following beneficial effect:
1, this color inhibition terrace paint with the addition of the uvioresistant such as benzophenone and tributyltin chloride additive, and delayed the xanthochromia time of epoxypaint, after application, the several years is still as before pure white.
2, this color inhibition terrace paint smooth coating, hard, bright in color, weathering resistance is strong, scratch resistance, and stain resistance is strong, and easy to clean, solid content is high, and VOC content is lower, is the terrace paint of a kind of excellent property, environmental protection.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
Embodiment 1
5 kilograms of urethane and 6.5 kilograms of rosin are added in reaction vessel, stirs, fully dissolve; In described reaction vessel, add 0.5 titanium dioxide and 0.2 kilogram of nipagin esters, be warming up to 80 DEG C, stir, react 60 minutes; 1.5 kilograms of N-BUTYL ACETATEs are added in described reaction vessel, 1.8 kilograms of propylene glycol methyl ether acetates, 0.2 kg polypropylene acid sodium, 0.75 kilogram of sodium dehydroacetate, 0.65 kilogram of dimethylbenzene, 0.5 kilogram of tributyltin chloride and 0.3 kilogram of benzophenone, be heated to 110 DEG C, stir, react 4 hours, cooling, obtains color inhibition terrace paint.
The constructional method of the present embodiment color inhibition terrace paint is: dry sanding paper polishing → dedusting → polish metope → roller coat thin layer color inhibition terrace paint → dry → roller coat second layer color inhibition terrace paint, roller coat arrange → dries naturally.
Proceeded in yellowing-resistant test box by epoxypaint prepared by the present embodiment and measure its anti-yellowing property, its color inhibition grade reaches 3.5 grades.
Embodiment 2
55 kilograms of urethane and 60 kilograms of rosin are added in reaction vessel, stirs, fully dissolve; In described reaction vessel, add 10 kilograms of titanium dioxides and 1 kilogram of nipagin esters, be warming up to 90 DEG C, stir, react 40 minutes; 20 kilograms of N-BUTYL ACETATEs are added in described reaction vessel, 15 kilograms of propylene glycol methyl ether acetates, 12 kg polypropylene acid sodium, 5 kilograms of sodium dehydroacetates, 5 kilograms of dimethylbenzene, 10 kilograms of tributyltin chlorides and 4 kilograms of benzophenone, be heated to 115 DEG C, stir, react 3.5 hours, cooling, obtains color inhibition terrace paint.
The constructional method of the present embodiment color inhibition terrace paint, comprises the following steps: dry sanding paper polishing → dedusting → polish metope → roller coat thin layer color inhibition terrace paint → dry → roller coat second layer color inhibition terrace paint, roller coat arrange → dries naturally.
Proceeded in yellowing-resistant test box by epoxypaint prepared by the present embodiment and measure its anti-yellowing property, its color inhibition grade reaches 4 grades.
Embodiment 3
600 kilograms of urethane and 700 kilograms of rosin are added in reaction vessel, stirs, fully dissolve; In described reaction vessel, add 75 kilograms of titanium dioxides and 30 kilograms of nipagin esters, be warming up to 85 DEG C, stir, react 50 minutes; 250 kilograms of N-BUTYL ACETATEs are added in described reaction vessel, 200 kilograms of propylene glycol methyl ether acetates, 150 kg polypropylene acid sodium, double centner sodium dehydroacetate, 800 kilograms of dimethylbenzene, 75 kilograms of tributyltin chlorides and 50 kilograms of benzophenone, be heated to 1120 DEG C, stir, react 3 hours, cooling, obtains color inhibition terrace paint.
The constructional method of the present embodiment color inhibition terrace paint, comprises the following steps: dry sanding paper polishing → dedusting → polish metope → roller coat thin layer color inhibition terrace paint → dry → roller coat second layer color inhibition terrace paint, roller coat arrange → dries naturally.
Proceeded in yellowing-resistant test box by epoxypaint prepared by the present embodiment and measure its anti-yellowing property, its color inhibition grade reaches 3 grades.
Claims (3)
1. a color inhibition terrace paint, is characterized in that, is prepared from by the raw material of following parts by weight: urethane 50 parts ~ 60 parts, 60 parts ~ 70 parts, rosin, N-BUTYL ACETATE 15 parts ~ 25 parts, propylene glycol methyl ether acetate 15 parts ~ 20 parts, sodium polyacrylate 8 parts ~ 15 parts, titanium dioxide 5 parts ~ 10 parts, sodium dehydroacetate 5 parts ~ 10 parts, dimethylbenzene 5 parts ~ 8 parts, tributyltin chloride 5 parts ~ 10 parts, benzophenone 3 parts ~ 5 parts, nipagin esters 1 part ~ 3 parts.
2. a preparation method for color inhibition terrace paint as claimed in claim 1, is characterized in that comprising the following steps: add in reaction vessel by urethane and rosin, magnetic agitation, fully dissolve; In described reaction vessel, add titanium dioxide and nipagin esters, be warming up to 80 DEG C ~ 90 DEG C, magnetic agitation, react 40 minutes ~ 60 minutes; N-BUTYL ACETATE is added, propylene glycol methyl ether acetate, sodium polyacrylate, sodium dehydroacetate in described reaction vessel, dimethylbenzene, tributyltin chloride and benzophenone, be heated to 110 DEG C ~ 120 DEG C, magnetic agitation, react 3 hours ~ 4 hours, cooling, obtains color inhibition terrace paint.
3. the constructional method of a color inhibition terrace paint as claimed in claim 1, it is characterized in that comprising the following steps: dry sanding paper polishing → dedusting → polish metope → roller coat thin layer color inhibition terrace paint → dry → roller coat second layer color inhibition terrace paint, roller coat arrange → dries naturally.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410362025.6A CN104109476B (en) | 2014-07-28 | 2014-07-28 | Color inhibition terrace paint and constructional method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410362025.6A CN104109476B (en) | 2014-07-28 | 2014-07-28 | Color inhibition terrace paint and constructional method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN104109476A CN104109476A (en) | 2014-10-22 |
| CN104109476B true CN104109476B (en) | 2016-04-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410362025.6A Active CN104109476B (en) | 2014-07-28 | 2014-07-28 | Color inhibition terrace paint and constructional method thereof |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104744963A (en) * | 2015-04-13 | 2015-07-01 | 哈尔滨中建璟园科技开发有限公司 | Terrace and construction method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101798483A (en) * | 2010-03-05 | 2010-08-11 | 四川大学 | Normal-temperature multiple curing organic-inorganic hybridized aqueous nano polyurethane woodware coating and preparation method thereof |
| CN103540250A (en) * | 2012-07-12 | 2014-01-29 | 关西涂料株式会社 | Coating compound for plastic |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5013582B2 (en) * | 2006-06-21 | 2012-08-29 | 学校法人明治大学 | Lacquer-based paint, its production method and lacquer coating material |
| JP5203589B2 (en) * | 2006-10-16 | 2013-06-05 | 三井化学株式会社 | Composition |
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2014
- 2014-07-28 CN CN201410362025.6A patent/CN104109476B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101798483A (en) * | 2010-03-05 | 2010-08-11 | 四川大学 | Normal-temperature multiple curing organic-inorganic hybridized aqueous nano polyurethane woodware coating and preparation method thereof |
| CN103540250A (en) * | 2012-07-12 | 2014-01-29 | 关西涂料株式会社 | Coating compound for plastic |
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| Publication number | Publication date |
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| CN104109476A (en) | 2014-10-22 |
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