CN104109381A - Modified organic silicon resin composition - Google Patents
Modified organic silicon resin composition Download PDFInfo
- Publication number
- CN104109381A CN104109381A CN201410100288.XA CN201410100288A CN104109381A CN 104109381 A CN104109381 A CN 104109381A CN 201410100288 A CN201410100288 A CN 201410100288A CN 104109381 A CN104109381 A CN 104109381A
- Authority
- CN
- China
- Prior art keywords
- resin composition
- transparent composite
- modified organic
- epoxy resin
- organic silicone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Epoxy Resins (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a modified organic silicon resin composition. The composition comprises 30-70 parts by weight of a main resin polysilsesquioxane resin and 30-70 parts by weight of epoxy resin and/or polyallyl ester. The invention also provides a method for preparing an organic silicon resin transparent composite material by using the organic silicon resin composition, and a flexible display panel made by using the transparent composite material. The transparent composite material has a light transmittance reaching above 90% and is flexible; and compared with glass, the transparent composite material has the advantages of lightness, thinness, flexibility and portability as a display panel base material, and accords with the future development direction of electronic products.
Description
Technical field
The present invention relates to flexible display technologies field, particularly, relate to a kind of modified organic silicone resin composition, prepare the method for silicone resin transparent composite by said composition, and the flexible display panel of preparing with this transparent composite.
Background technology
Traditional display panel is all to adopt glass as baseplate material, and glass transparent and insulation, can play a supporting role, and is the baseplate material of desirable display panel, very ripe in the application in display panel field.But glass also has its shortcoming as panel substrate material, be mainly manifested in that it is comparatively thick and heavy, easily break, can not be bending etc. aspect.
Along with social development, people are more and more higher for the requirement of electronic product, wish that electronic product is more frivolous, be easy to carry.And display screen is various electronic products, as the chief component of mobile phone, notebook computer, panel computer, e-book etc., the developing direction of display screen be more frivolous, flexible, be easy to carry.Glass because it is thick and heavy, easily break, unyielding shortcoming makes it be difficult to adapt to the requirements at the higher level of following display panel, more meet the developing direction of following electronic product as the baseplate material of display panel especially flexible display panels and there is transparent composite frivolous, bendability characteristics, have a extensive future.
Summary of the invention
In order to overcome the deficiencies in the prior art, the invention provides a kind of modified organic silicone resin composition, the silicone resin transparent composite that also provides this organosilicon resin composition to prepare, and the flexible display panel of preparing with this transparent composite.The transmittance of this transparent composite can reach more than 90%, and flexible, as the base material of display panel, with glassy phase ratio, has frivolously, flexible, and the characteristic such as be easy to carry, meets the developing direction of following electronic product.
Technical scheme of the present invention is as follows: a kind of modified organic silicone resin composition, it is characterized in that, and comprise each component of following weight part, main resin: polysilsesquioxane resins, 30-70 part; Solidifying agent: epoxy resin and/or polyene propyl ester 30-70 part.
Described polysilsesquioxane resins is cage structure, ladder structure and random structure.
Described epoxy resin is one or several the composition in bisphenol A epoxide resin, novolac epoxy, isocyanate modified epoxy resin, phosphorous epoxy resin, biphenyl epoxy resin, DCPD-containing epoxy resin.
The method of the organosilicon transparent composite of preparing with described modified organic silicone resin composition, comprises the steps:
(1) get the each component of described organosilicon resin composition by formula, after mixing, add and in solvent, be configured to glue;
(2) get glasscloth and flood described one-tenth glue, in baking oven 110～160 DEG C baking 30～90 minutes solidify or through 1500mJ/cm
2uV-irradiation solidify, complete solidify after obtain described transparent composite.
Described glasscloth is selected from following model: 106,1078,1080,1086,2112,2116,2119,3313,7628.
The flexible display panels of preparing with described organosilicon transparent composite.
The present invention by described polysilsesquioxane resins as main resin,
Beneficial effect of the present invention is: its main raw of transparent composite of the present invention is polysilsesquioxane resins and solidifying agent epoxy resin and/or polyene propyl ester, and its preparation method is simple.
Embodiment
Embodiment 1:
A kind of modified organic silicone resin composition, comprising: 40 parts of polysilsesquioxane resins (waste river chemistry, HBSQ105-7), 60 parts of epoxy resin (waste river chemistry, HBSQ3008).
The method of the organosilicon transparent composite of preparing with described modified organic silicone resin composition, comprises the steps:
(1) get the each component of described organosilicon resin composition by formula, after mixing, add and in solvent, be configured to glue;
(2) get glasscloth and flood described one-tenth glue, in baking oven 135 DEG C baking 60 minutes solidify, complete solidify after obtain described transparent composite.
Described glasscloth is selected from following model: 106.
Embodiment 2:
A kind of modified organic silicone resin composition, comprising: 60 parts of polysilsesquioxane resins (waste river chemistry, HBSQ105-7), 40 parts of polyene propyl ester (waste river chemistry, HBSQ2501A).
The method of the organosilicon transparent composite of preparing with described modified organic silicone resin composition, comprises the steps:
(1) get the each component of described organosilicon resin composition by formula, after mixing, add and in solvent, be configured to glue;
(2) get glasscloth and flood described one-tenth glue, through 1500mJ/cm
2uV-irradiation solidify, complete solidify after obtain described transparent composite.
Described glasscloth is selected from following model: 1080.
Embodiment 3:
A kind of modified organic silicone resin composition, comprise: 30 parts of polysilsesquioxane resins (waste river chemistry, HBSQ105-7), 40 parts of polyene propyl ester (waste river chemistry, HBSQ2501A), 30 parts of epoxy resin (waste river chemistry, HBSQ3008).
The method of the organosilicon transparent composite of preparing with described modified organic silicone resin composition, comprises the steps:
(1) get the each component of described organosilicon resin composition by formula, after mixing, add and in solvent, be configured to glue;
(2) get glasscloth and flood described one-tenth glue, in baking oven 160 DEG C baking 30 minutes solidify, complete solidify after obtain described transparent composite.
Described glasscloth is selected from following model: 1086.
Embodiment 4:
A kind of modified organic silicone resin composition, comprising: 70 parts of polysilsesquioxane resins (waste river chemistry, HBSQ105-7), 30 parts of epoxy resin (waste river chemistry, HBSQ3008).
The method of the organosilicon transparent composite of preparing with described modified organic silicone resin composition, comprises the steps:
(1) get the each component of described organosilicon resin composition by formula, after mixing, add and in solvent, be configured to glue;
(2) get glasscloth and flood described one-tenth glue, in baking oven 110 DEG C baking 90 minutes solidify, complete solidify after obtain described transparent composite.
Described glasscloth is selected from following model: 2116.
Embodiment 5:
The flexible display panel of preparing with organosilicon transparent composite described in embodiment 1.
Above content is in conjunction with concrete preferred implementation further description made for the present invention, can not assert that specific embodiment of the invention is confined to these explanations.For general technical staff of the technical field of the invention, without departing from the inventive concept of the premise, its framework form can be flexible and changeable, can subseries product.Just make some simple deduction or replace, all should be considered as belonging to the present invention by the definite scope of patent protection of submitted to claims.
Claims (6)
1. a modified organic silicone resin composition, is characterized in that, comprises each component of following weight part, main resin: polysilsesquioxane resins, 30-70 part; Solidifying agent: epoxy resin and/or polyene propyl ester 30-70 part.
2. modified organic silicone resin composition as claimed in claim 1, is characterized in that, described polysilsesquioxane resins is cage structure, ladder structure and random structure.
3. modified organic silicone resin composition as claimed in claim 1, it is characterized in that, described epoxy resin is one or several the composition in bisphenol A epoxide resin, novolac epoxy, isocyanate modified epoxy resin, phosphorous epoxy resin, biphenyl epoxy resin, DCPD-containing epoxy resin.
4. the method for preparing organosilicon transparent composite with modified organic silicone resin composition described in claim 1-3 any one, is characterized in that, comprises the steps:
(1) get the each component of described organosilicon resin composition by formula, after mixing, add and in solvent, be configured to glue; (2) get glasscloth and flood described one-tenth glue, in baking oven 110～160 DEG C baking 30～90 minutes solidify or through 1500mJ/cm
2uV-irradiation solidify, complete solidify after obtain described transparent composite.
5. the method for preparing organosilicon transparent composite as claimed in claim 4, is characterized in that, described glasscloth is selected from following model: 106,1078,1080,1086,2112,2116,2119,3313,7628.
6. the flexible display panels of preparing with the organosilicon transparent composite described in claim 4 or 5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410100288.XA CN104109381B (en) | 2014-03-18 | 2014-03-18 | Modified organic silicone resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410100288.XA CN104109381B (en) | 2014-03-18 | 2014-03-18 | Modified organic silicone resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104109381A true CN104109381A (en) | 2014-10-22 |
| CN104109381B CN104109381B (en) | 2019-03-29 |
Family
ID=51706376
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410100288.XA Active CN104109381B (en) | 2014-03-18 | 2014-03-18 | Modified organic silicone resin composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104109381B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112759891A (en) * | 2020-12-28 | 2021-05-07 | 广东盈骅新材料科技有限公司 | Epoxy resin composition, and transparent composite material and laminate containing same |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101014644A (en) * | 2004-09-10 | 2007-08-08 | 陶氏康宁公司 | Anhydride-functional silsesquioxane resins |
| CN101089048A (en) * | 2006-06-16 | 2007-12-19 | 信越化学工业株式会社 | Epoxy-organic silicon mixed resin combination and luminous semiconductor device |
| CN101508846A (en) * | 2008-02-13 | 2009-08-19 | 东进世美肯株式会社 | Organic-inorganic composite regin combination as protective film |
| CN101525467A (en) * | 2009-04-03 | 2009-09-09 | 复旦大学 | Epoxy/organosilicon hybrid material, and preparation method and application thereof |
| CN101955666A (en) * | 2010-09-30 | 2011-01-26 | 长安大学 | Preparation method of glass fiber enhanced thermosetting resin matrix composite material |
| JP2011190402A (en) * | 2010-03-16 | 2011-09-29 | Sekisui Chem Co Ltd | Ultraviolet curable resin composition and transparent composite sheet |
| WO2013019040A2 (en) * | 2011-08-03 | 2013-02-07 | 주식회사 동진쎄미켐 | Photo-curable organic-inorganic hybrid resin composition |
-
2014
- 2014-03-18 CN CN201410100288.XA patent/CN104109381B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101014644A (en) * | 2004-09-10 | 2007-08-08 | 陶氏康宁公司 | Anhydride-functional silsesquioxane resins |
| CN101089048A (en) * | 2006-06-16 | 2007-12-19 | 信越化学工业株式会社 | Epoxy-organic silicon mixed resin combination and luminous semiconductor device |
| CN101508846A (en) * | 2008-02-13 | 2009-08-19 | 东进世美肯株式会社 | Organic-inorganic composite regin combination as protective film |
| CN101525467A (en) * | 2009-04-03 | 2009-09-09 | 复旦大学 | Epoxy/organosilicon hybrid material, and preparation method and application thereof |
| JP2011190402A (en) * | 2010-03-16 | 2011-09-29 | Sekisui Chem Co Ltd | Ultraviolet curable resin composition and transparent composite sheet |
| CN101955666A (en) * | 2010-09-30 | 2011-01-26 | 长安大学 | Preparation method of glass fiber enhanced thermosetting resin matrix composite material |
| WO2013019040A2 (en) * | 2011-08-03 | 2013-02-07 | 주식회사 동진쎄미켐 | Photo-curable organic-inorganic hybrid resin composition |
Non-Patent Citations (1)
| Title |
|---|
| 张大厚编著: "《防腐蚀复合材料及其应用》", 31 October 2006 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112759891A (en) * | 2020-12-28 | 2021-05-07 | 广东盈骅新材料科技有限公司 | Epoxy resin composition, and transparent composite material and laminate containing same |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104109381B (en) | 2019-03-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TWI622603B (en) | Surface encapsulating agent for organic el element, organic el device using the same and manufacturing method thereof, cured object and organic el panel | |
| CN104530999B (en) | Anti-blue light OCA optics two-sided tape | |
| CN103614089A (en) | Golden blue ray-resistant protection film and preparation method thereof | |
| CN103588954A (en) | OCA optical adhesive tape and making method thereof | |
| CN104356894B (en) | A kind of preparation method of high-temperature resistant silicone modified unsaturated polyester resin coating | |
| US10259979B2 (en) | Sealant composition and method for curing the same, display device and sealing method, and use thereof | |
| CN103865408B (en) | A kind of dual cure optical cement based on modified organic silicon material and application thereof | |
| CN102618195A (en) | Light shading adhesive, laminated plate, preparation method of light shading adhesive, and application of light shading adhesive | |
| CN109709693B (en) | Display screen full-lamination method and display | |
| CN104479581A (en) | Protective film with blue-light resistant function | |
| WO2009017532A3 (en) | Method of making an antireflective silica coating, resulting product, and photovoltaic device comprising same | |
| CN104449482A (en) | Formula of acrylic adhesive and preparation method of acrylic adhesive | |
| CN104109381A (en) | Modified organic silicon resin composition | |
| CN104130742B (en) | A kind of COB-LED organic silicon potting adhesive and preparation method thereof | |
| EP3550357A1 (en) | Alignment material composition and liquid crystal display panel and preparation methods therefor and display device using same | |
| CN103923439A (en) | White resin composition and method for preparing white coating by using white resin composition | |
| CN102674669B (en) | Fixing method for glass substrates | |
| CN202422050U (en) | Touch display device | |
| CN104292974A (en) | Acidproof ink for touch screen and preparation method of acidproof ink | |
| CN104538491A (en) | Solar cell backsheet repair solution | |
| CN109266300B (en) | Single-component deacidification type organic silicon sealant for bonding outdoor artware and preparation method thereof | |
| CN106653900A (en) | Dual-glass photovoltaic module | |
| CN106398557A (en) | Frame adhesive | |
| TWI623796B (en) | Liquid crystal display element, liquid crystal alignment treatment agent, and liquid crystal alignment film | |
| CN108003623B (en) | Single-component silicone rubber for acrylic bonding and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |