CN104109381B - Modified organic silicone resin composition - Google Patents
Modified organic silicone resin composition Download PDFInfo
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- CN104109381B CN104109381B CN201410100288.XA CN201410100288A CN104109381B CN 104109381 B CN104109381 B CN 104109381B CN 201410100288 A CN201410100288 A CN 201410100288A CN 104109381 B CN104109381 B CN 104109381B
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- resin composition
- transparent composite
- organosilicon
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- silicone resin
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Abstract
The present invention provides a kind of modified organic silicone resin composition, each component including following parts by weight, main resin: polysilsesquioxane resins, 30-70 parts；Curing agent: epoxy resin and/or 30-70 parts of polyallyl esters.Present invention provides the methods that the organosilicon resin composition prepares organic siliconresin transparent composite, and the flexible display panel prepared with the transparent composite.The light transmittance of the transparent composite can reach 90% or more, and flexible, and as the substrate of display board, and glass phase ratio has frivolous, and flexible, the characteristics such as easy to carry meet the developing direction of future electronic product.
Description
Technical field
The present invention relates to flexible display technologies fields, and in particular, to a kind of modified organic silicone resin composition, with the group
Close the method that object prepares organic siliconresin transparent composite, and the flexible display panel prepared with the transparent composite.
Background technique
Traditional display panel is all that can be played support as baseplate material, glass transparent and insulation using glass and made
With being the baseplate material of ideal display panel, in display panel field using highly developed.But glass is as display surface
Plate baseplate material also has its disadvantage, is mainly manifested in that it is more thick and heavy, is easily broken, cannot be bent etc..
With the development of society, requirement of the people for electronic product is higher and higher, it is desirable to which electronic product is more frivolous, just
In carrying.And display screen is various electronic products, such as the main composition portion of mobile phone, laptop, tablet computer, e-book
Point, the developing direction of display screen is more frivolous, flexible, easy to carry.Glass is because its is thick and heavy, be easily broken, cannot be bent
The shortcomings that make it be difficult to adapt to the requirements at the higher level of the following display panel, and there are frivolous, bendability characteristics transparent composite woods
Material is more in line with the developing direction of future electronic product, application as the baseplate material of display panel especially flexible display panels
It has a extensive future.
Summary of the invention
For overcome the deficiencies in the prior art, it the present invention provides a kind of modified organic silicone resin composition, also provides
The organic siliconresin transparent composite of organosilicon resin composition preparation, and it is aobvious with flexibility prepared by the transparent composite
Show plate.The light transmittance of the transparent composite can reach 90% or more, and flexible, as the substrate of display board, with glass
Glass is compared, have it is frivolous, flexible, the characteristics such as easy to carry meet the developing direction of future electronic product.
Technical scheme is as follows: a kind of modified organic silicone resin composition, which is characterized in that including following weight
The each component of part, main resin: polysilsesquioxane resins, 30-70 parts；Curing agent: epoxy resin and/or polyallyl esters 30-70
Part.
The polysilsesquioxane resins are cage structure, trapezium structure and disordered structure.
The epoxy resin is bisphenol A epoxide resin, novolac epoxy resin, isocyanate modified epoxy resin, phosphorous ring
One of oxygen resin, biphenyl epoxy resin, DCPD-containing epoxy resin or several compositions.
With the method for organosilicon transparent composite prepared by the modified organic silicone resin composition, including walk as follows
It is rapid:
(1) the organosilicon resin composition each component is taken by formula, is added in solvent after mixing and is configured to glue；
(2) take glass fabric dipping described at glue, in an oven 110~160 DEG C of bakings solidification in 30~90 minutes or
Through 1500mJ/cm2Ultraviolet radiation-curable obtains the transparent composite after completing solidification.
The glass fabric is selected from following model: 106,1078,1080,1086,2112,2116,2119,3313,
7628。
The flexible display panels prepared with the organosilicon transparent composite.
The present invention uses the polysilsesquioxane resins as main resin,
The invention has the benefit that its main material of transparent composite of the present invention is polysilsesquioxane resins
With curing agent epoxy resin and/or polyallyl esters, preparation method is simple.
Specific embodiment
Embodiment 1:
A kind of modified organic silicone resin composition, comprising: polysilsesquioxane resins (waste river chemistry, HBSQ105-7) 40
Part, 60 parts of epoxy resin (waste river chemistry, HBSQ3008).
With the method for organosilicon transparent composite prepared by the modified organic silicone resin composition, including walk as follows
It is rapid:
(1) the organosilicon resin composition each component is taken by formula, is added in solvent after mixing and is configured to glue；
(2) it takes glass fabric dipping described into glue, solidifies within baking 60 minutes for 135 DEG C in an oven, after completing solidification
Obtain the transparent composite.
The glass fabric is selected from following model: 106.
Embodiment 2:
A kind of modified organic silicone resin composition, comprising: polysilsesquioxane resins (waste river chemistry, HBSQ105-7) 60
Part, 40 parts of polyallyl esters (waste river chemistry, HBSQ2501A).
With the method for organosilicon transparent composite prepared by the modified organic silicone resin composition, including walk as follows
It is rapid:
(1) the organosilicon resin composition each component is taken by formula, is added in solvent after mixing and is configured to glue；
(2) take glass fabric dipping described at glue, through 1500mJ/cm2Ultraviolet radiation-curable obtains after completing solidification
To the transparent composite.
The glass fabric is selected from following model: 1080.
Embodiment 3:
A kind of modified organic silicone resin composition, comprising: polysilsesquioxane resins (waste river chemistry, HBSQ105-7) 30
Part, 40 parts of polyallyl esters (waste river chemistry, HBSQ2501A), 30 parts of epoxy resin (waste river chemistry, HBSQ3008).
With the method for organosilicon transparent composite prepared by the modified organic silicone resin composition, including walk as follows
It is rapid:
(1) the organosilicon resin composition each component is taken by formula, is added in solvent after mixing and is configured to glue；
(2) it takes glass fabric dipping described into glue, solidifies within baking 30 minutes for 160 DEG C in an oven, after completing solidification
Obtain the transparent composite.
The glass fabric is selected from following model: 1086.
Embodiment 4:
A kind of modified organic silicone resin composition, comprising: polysilsesquioxane resins (waste river chemistry, HBSQ105-7) 70
Part, 30 parts of epoxy resin (waste river chemistry, HBSQ3008).
With the method for organosilicon transparent composite prepared by the modified organic silicone resin composition, including walk as follows
It is rapid:
(1) the organosilicon resin composition each component is taken by formula, is added in solvent after mixing and is configured to glue；
(2) it takes glass fabric dipping described into glue, solidifies within baking 90 minutes for 110 DEG C in an oven, after completing solidification
Obtain the transparent composite.
The glass fabric is selected from following model: 2116.
Embodiment 5:
The flexible display panel of the preparation of the organosilicon transparent composite described in embodiment 1.
The above content is a further detailed description of the present invention in conjunction with specific preferred embodiments, and it cannot be said that
Specific implementation of the invention is only limited to these instructions.For those of ordinary skill in the art to which the present invention belongs, exist
Under the premise of not departing from present inventive concept, architectural form cans be flexible and changeable, can be with derivative series product.It only makes several
Simple deduction or replace all shall be regarded as belonging to present invention scope of patent protection determined by the appended claims.
Claims (3)
1. a kind of method for preparing organosilicon transparent composite, which comprises the steps of:
(1) organosilicon resin composition each component is taken by formula, is added in solvent after mixing and is configured to glue；
(2) it takes glass fabric dipping described into glue, solidifies within baking 30~90 minutes for 110~160 DEG C in an oven, complete solid
The transparent composite is obtained after change,
The organosilicon resin composition, each component including following parts by weight, main resin: polysilsesquioxane resins, 30-70
Part；Curing agent: epoxy resin, 30-70 parts；Wherein, the polysilsesquioxane resins are waste river chemistry, HBSQ105-7；It is described
Epoxy resin is waste river chemistry, HBSQ3008.
1078 2. the method as described in claim 1, which is characterized in that the glass fabric is selected from following model: 106,
1080、1086、2112、2116、2119、3313、7628。
3. with the Flexible Displays for the organosilicon transparent composite preparation that any method of claim 1~2 is prepared
Panel.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410100288.XA CN104109381B (en) | 2014-03-18 | 2014-03-18 | Modified organic silicone resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410100288.XA CN104109381B (en) | 2014-03-18 | 2014-03-18 | Modified organic silicone resin composition |
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| Publication Number | Publication Date |
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| CN104109381A CN104109381A (en) | 2014-10-22 |
| CN104109381B true CN104109381B (en) | 2019-03-29 |
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| CN201410100288.XA Active CN104109381B (en) | 2014-03-18 | 2014-03-18 | Modified organic silicone resin composition |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112759891A (en) * | 2020-12-28 | 2021-05-07 | 广东盈骅新材料科技有限公司 | Epoxy resin composition, and transparent composite material and laminate containing same |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101014644A (en) * | 2004-09-10 | 2007-08-08 | 陶氏康宁公司 | Anhydride-functional silsesquioxane resins |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| KR101390087B1 (en) * | 2006-06-16 | 2014-04-28 | 신에쓰 가가꾸 고교 가부시끼가이샤 | Epoxy-silicone hybrid resin compositions and light-emitting semiconductor devices |
| KR101475780B1 (en) * | 2008-02-13 | 2014-12-23 | 주식회사 동진쎄미켐 | Organic-inorganic complex resin composition which is useful as a protecting layer |
| CN101525467A (en) * | 2009-04-03 | 2009-09-09 | 复旦大学 | Epoxy/organosilicon hybrid material, and preparation method and application thereof |
| JP2011190402A (en) * | 2010-03-16 | 2011-09-29 | Sekisui Chem Co Ltd | Ultraviolet curable resin composition and transparent composite sheet |
| CN101955666B (en) * | 2010-09-30 | 2012-04-18 | 长安大学 | Preparation method of glass fiber enhanced thermosetting resin matrix composite material |
| WO2013019040A2 (en) * | 2011-08-03 | 2013-02-07 | 주식회사 동진쎄미켐 | Photo-curable organic-inorganic hybrid resin composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101014644A (en) * | 2004-09-10 | 2007-08-08 | 陶氏康宁公司 | Anhydride-functional silsesquioxane resins |
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