CN104108957A - Microcrystalline glass-ceramic composite panel manufacturing method and product thereof - Google Patents
Microcrystalline glass-ceramic composite panel manufacturing method and product thereof Download PDFInfo
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- CN104108957A CN104108957A CN201410377924.3A CN201410377924A CN104108957A CN 104108957 A CN104108957 A CN 104108957A CN 201410377924 A CN201410377924 A CN 201410377924A CN 104108957 A CN104108957 A CN 104108957A
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Abstract
The invention relates to a microcrystalline glass-ceramic composite panel manufacturing method and a product thereof. The method comprises the sequential steps: (A) pressing a ceramic powdery material, so as to form an unfired tile, and drying; (B) printing at least one kind of fine colored frit; (C) mixing at least two kinds of coarse colored frit, and then, carrying out material distribution; (D) spraying at least one kind of colored frit slurry; (E) spraying a fixer to fix, firing, polishing, packaging and warehousing. According to the microcrystalline glass-ceramic composite panel manufacturing method and the product thereof, line-shaped grains are formed in a manner of replacing frit powder with the frit slurry, so that the thickness and trend of lines can be controlled through adjusting the slurry spraying speed and direction of slurry spraying pipes; the number of the lines is controlled by the number of the slurry spraying pipes, line boundaries of the fired product are clear, smooth and natural and look like ice cracks generated by natural stone, and crystals are three-dimensional and natural, so that the product is a good substitute for the natural stone.
Description
Technical field
The present invention relates to ceramic tile manufacturing technology field, especially relate to manufacture method of a kind of glass-ceramic clad plate and products thereof.
Background technology
Glass-ceramic clad plate is devitrified glass to be compounded in to the composite board of ceramic brick surface one deck, and glass-ceramic clad plate has absorbed the advantage that ceramic board physical strength is large, toughness is strong, impact resistance good, resistance to chemical corrosion is high.Thereby the mechanical property that makes this composite sheet is better than the sheet material of pure devitrified glass, the performance of comprehensive acid-fast alkali-proof, chemically-resistant washings is also better than pure crystallizing glass sheet material, and this has improved the use properties of devitrified glass undoubtedly.Meanwhile, also for reducing the weight of sheet material, provide possibility with the application of widening Highrise buildings.Glass-ceramic clad plate is the high-new art product in architectural pottery field, it is with glittering and translucent, elegant and poised, self-sow and change unusual imitative bag reason, painted level, superb craftsmanship's exterior decorative effect, and not contaminated, be easy to clean, inherent good physical and chemical performance, in addition, also there is the weather proofing stronger than stone material, weathering resistance and be subject to the favor of domestic and international high-end building materials market.
In prior art, form to decorate texture and be all by cloth frit or print the mode of frit, but because frit is particulate state thereby easily delivers to vibration be dispersed in course of conveying, causing the linear Texture Boundaries that forms unintelligible.
Summary of the invention
The object of the invention is to propose a kind of manufacture method of glass-ceramic clad plate, it can solve currently available products lines and decorate the unsharp problem of Texture Boundaries.
For reaching this object, the present invention by the following technical solutions:
A manufacture method for glass-ceramic clad plate, step comprises successively:
A, ceramic powder compacting formation adobe is also dry;
B, seal are no less than a kind thin coloured frit;
C, will be no less than 2 kinds of thick coloured frits and mix rear cloth;
D, pouring are no less than a kind of coloured frit slurry;
E, spray fixing agent are fixed, and burn till, polishing.
Preferably, after described steps A, also comprise steps A 1: after water spray, execute one deck protection glaze.
Preferably, after described step D, also comprise step D1: print and be no less than a kind thin coloured frit.
Preferably, after described step D1, also comprise step D2: will be no less than 2 kinds of thick coloured frits and mix rear cloth.
Described thin its fineness of coloured frit in described step B is distributed as 20-100 order, and initial melting temperature is 1050-1080 ℃, and consumption is 0.5-1.5kg/m
2; Wherein 20-30 order accounts for 0-5%, and 30-100 order accounts for 95-100%.
It can be a kind of of screen printing or hollow out roller India and China and combination thereof that described seal in described step B is no less than a kind thin coloured frit mode.
Described thick coloured frit in described step C, its fineness is distributed as 4-30 order, and initial melting temperature is 1080-1100 ℃, and consumption is 1-2kg/m
2; Wherein 20-30 order accounts for 0-5%, and 4-20 order accounts for 95-100%.
Slurry fineness 250 mesh screen residues of the described coloured frit slurry in described step D are less than 3%, proportion 1.5-1.8.
The mode of the coloured frit slurry of described pouring in described step D is for being used the pipe of 3-10 bar diameter 5-10mm to drench slurry.
The initial melting temperature of the frit of the described coloured frit slurry in described step D is 1050-1080 ℃, and consumption is 0.5 to 1.5kg.
Described thin its fineness of coloured frit in described step D1 is distributed as 20-100 order, and initial melting temperature is 1050-1080 ℃, and consumption is 0.5-1.5kg/m
2; Wherein 20-30 order accounts for 0-5%, and 30-100 order accounts for 95-100%.
The thin coloured frit mode of described seal in described step D1 is a kind of or its combination of screen printing or hollow out roller India and China.
Described thick coloured frit in described step D2, its fineness is distributed as 4-30 order, and initial melting temperature is 1080-1100 ℃, and consumption is 2-6kg/m
2; Wherein 20-30 order accounts for 0-5%, and 4-20 order accounts for 95-100%.
Described fixing agent in described step e is the PVA solution containing 0.01%-0.1%.
Compared with prior art, the present invention uses frit slurry to replace frit powder to form linear texture, can drench the pouring slurry speed of slurry pipe and thickness and the trend that direction is controlled lines by adjusting, and by the number that pipe is starched in pouring, control the number of lines, product lines sharpness of border after firing, remarkable fluency, the ice crack producing just as lithotome, crystal stereo natural is the favorable substitutes of lithotome.And the thin coloured frit of the first cloth of the present invention, the thick coloured frit of cloth again, thick coloured frit can be suppressed thin coloured frit, vibrations occurs in transportation and disperse pattern before avoiding adobe to fire, thereby can keep printing the pattern form after thin coloured frit, make pattern globality strong.
Another object of the present invention is to propose a kind of glass-ceramic clad plate of being manufactured by aforesaid method, and it from bottom to top comprises end base layer and coloured decorative devitrified glass layer successively.
Base layer thickness of the described end is 8-15mm; Described coloured decorative devitrified glass layer thickness 1-5mm.
Described coloured decorative devitrified glass layer forms at least 2 nonplanar coloured microcrystalline coatings merge mutually to interlock.
In described coloured decorative devitrified glass layer or the wired linear marking of surface arrangement.
Accompanying drawing explanation
Fig. 1 is the structure iron of the glass-ceramic clad plate of one of them embodiment of the present invention.
Wherein: end base layer 1, coloured decorative devitrified glass layer 2, linear texture 3, thin coloured microcrystalline coating 21, thin coloured microcrystalline coating 22, thick coloured microcrystalline coating 23
Fig. 2 is the structure iron of the glass-ceramic clad plate of one of them embodiment of the present invention.
Wherein: end base layer 1, coloured decorative devitrified glass layer 2, the thin coloured microcrystalline coating 21 of linear texture 3/, thin coloured microcrystalline coating 22, thick coloured microcrystalline coating 23, thin coloured microcrystalline coating 24.
Embodiment
Below by embodiment, further illustrate technical scheme of the present invention.
Its coloured frit of embodiments of the invention all adopts the coloured frit of commercially available Dow company.
Embodiment 1
As shown in Figure 1, it from bottom to top comprises end base layer 1 and coloured decorative devitrified glass layer 2 to a kind of glass-ceramic clad plate successively, the wired linear marking 3 of surface arrangement of described coloured decorative devitrified glass layer 2.
Specification as above is the glass-ceramic clad plate manufacture method of 1000*1000mm, and step comprises successively:
A, ceramic powder compacting is formed to adobe the dry end base layer 1 that forms;
B, (wherein 20-30 order accounts for 5% first by a kind of fineness of screen printing, to be distributed as 20-100 order, 30-100 order accounts for 95%), initial melting temperature is that thin coloured frit 1.5kg of 1050 ℃ forms thin coloured microcrystalline coating 21, by hollow out roller, print a kind of fineness again and be distributed as 30-100 order, initial melting temperature is that thin coloured frit 0.5kg of 1060 ℃ forms thin coloured microcrystalline coating 22;
C, by fineness 4-20 order, (wherein 20-30 order accounts for 5% for thick coloured frit of initial melting temperature 1080 and fineness 4-30 order, 4-20 order accounts for 95%) thick coloured frit of 1100 ℃ of initial melting temperatures forms thick coloured microcrystalline coating 23 after mixing the adobe of rear cloth 4kg after step C
D, use that 3 diameters are respectively 5,8, the pipe of 10mm drenches fineness 250 mesh screen residues 2%, the frit slurry of proportion 1.5 forms linear and decorates texture 3, and the frit initial melting temperature of preparation frit slurry is 1050 ℃, and consumption is 0.5kg;
The PVA solution of E, spray content 0.01% is fixed, and burns till, polishing packing warehouse-in.
The glass-ceramic clad plate of the present embodiment after firing, its decorative devitrified glass layer 2 is merged and forms mutually by thin coloured microcrystalline coating 21, thin coloured microcrystalline coating 22, thick coloured microcrystalline coating 23, and linear is decorated the surface that texture is positioned at decorative devitrified glass layer 2.Step B forms decorative pattern after printing thin coloured frit, first melting in the process of firing, the thick coloured frit layer forming because being suppressed with step C cloth on thin coloured frit, thereby can be filled in the particle gap of thick coloured frit layer after thin coloured frit layer melting, multi-layer intercrossed decorative effect formed.
Should be noted that and adopting in coloured frit situation of same recipe, because thin coloured frit granularity is little, specific surface area is large, and surface can be large, thereby melt temperature is low; When adopting coloured frit of different ingredients, the height that can change melt temperature by the adjusting of formula is to meet the needs of technique.
The present embodiment is used frit slurry to replace frit powder to form linear texture, can drench the pouring slurry speed of slurry pipe and thickness and the trend that direction is controlled lines by adjusting, and by the number that pipe is starched in pouring, control the number of lines, product lines sharpness of border after firing, remarkable fluency, the ice crack producing just as lithotome, crystal stereo natural, is the favorable substitutes of lithotome.
Embodiment 2
Different from embodiment 1, in the present embodiment, step B is for to be distributed as 20-100 order (wherein 20-30 order accounts for 2%, and 30-100 order accounts for 98%) by a kind of fineness of screen printing, and initial melting temperature is that thin coloured frit 0.5kg of 1080 ℃ forms thin coloured microcrystalline coating 21;
Step C is by fineness 4-20 order, (wherein 20-30 order accounts for 5% for thick coloured frit that initial melting temperature is 1080 ℃, fineness 4-30 order, 4-20 order accounts for 95%) (wherein 20-30 order accounts for 2% for thick coloured frit of 1100 ℃ of initial melting temperatures and fineness 4-30 order, 4-20 order accounts for 98%) after thick coloured frit of 1090 ℃ of initial melting temperatures mixes, after the adobe of cloth 8kg after step C, form thick coloured microcrystalline coating 23;
The thin coloured frit of first cloth, the thick coloured frit of cloth again, thick coloured frit can be suppressed thin coloured frit, vibrations occurs in transportation and disperse pattern before avoiding adobe to fire, thereby can keep printing the pattern form after thin coloured frit, make pattern globality strong.
In order to use, 3 diameters are respectively 5,8 to step D, the pipe of 10mm drenches fineness 250 mesh screen residues 2%, after three kinds of color frit slurries of proportion 1.5, re-use that 2 diameters are respectively 6, the pipe of 9mm drenches fineness 250 mesh screen residues 1%, a kind of color frit slurry of proportion 1.8, the frit initial melting temperature of preparing coloured frit slurry is 1080 ℃, and consumption is 1.5kg;
Step e is fixed for spraying the PVA solution of content 0.1%;
Its end base layer 1 thickness of the glass-ceramic clad plate of the present embodiment is 8mm; Coloured decorative devitrified glass layer 2 thickness 5mm.
Embodiment 3
Different from embodiment 1, in the present embodiment, step B is distributed as 20-100 order (wherein 20-30 order accounts for 3%, and 30-100 order accounts for 97%) for printing a kind of fineness by hollow out roller, and initial melting temperature is that thin coloured frit 1kg of 1070 ℃ forms thin coloured microcrystalline coating 21;
Step C is by fineness 4-20 order, (wherein 20-30 order accounts for 5% for thick coloured frit of initial melting temperature 1080, fineness 4-30 order, 4-20 order accounts for 95%) thick coloured frit of 1080 ℃ of thick coloured frit of 1100 ℃ of initial melting temperatures and fineness 4-30 order (wherein 20-30 order accounts for 2%, 4-20 order and accounts for 98%) initial melting temperatures forms thick coloured microcrystalline coating 23 after mixing the adobe of rear cloth 6kg after step C;
In order to use, 3 diameters are respectively 5,8 to step D, the pipe of 10mm drenches fineness 250 mesh screen residues 2%, after three kinds of color frit slurries of proportion 1.5, re-use that 7 diameters are respectively 5,6,7,8,9,10, the pipe of 5mm drenches fineness 250 mesh screen residues 2.8%, seven kinds of color frit slurries of proportion 1.6,1.8,1.5,1.7,1.6,1.6,1.8, the frit initial melting temperature of preparing coloured frit slurry is 1060 ℃, and consumption is 1kg;
Step e is fixed for spraying the PVA solution of content 0.08%;
Its end base layer 1 thickness of the glass-ceramic clad plate of the present embodiment is 9mm; Coloured decorative devitrified glass layer 2 thickness 3mm.
Embodiment 4
Different from embodiment 1, in order to be distributed as 20-100 order by a kind of fineness of hollow out roller seal, (wherein 20-30 order accounts for 3% to the step B of the present embodiment, 30-100 order accounts for 97%), initial melting temperature be after thin coloured frit 1kg of 1070 ℃ again by a kind of 30-100 order of screen printing, initial melting temperature is that thin coloured frit of 1050 ℃ forms thin coloured microcrystalline coating 21,22;
After step D, also comprise that step D1 is distributed as 20-100 order (wherein 20-30 order accounts for 2%, 30-100 order and accounts for 98%) by a kind of fineness of screen printing, initial melting temperature is that thin coloured frit 0.5kg of 1080 ℃ forms thin coloured microcrystalline coating 24;
As shown in Figure 2, its end base layer 1 thickness of the glass-ceramic clad plate of the present embodiment is 10mm; Coloured decorative devitrified glass layer 2 thickness 4mm, decorative devitrified glass layer 2 is merged and forms mutually by thin coloured microcrystalline coating 21, thin coloured microcrystalline coating 22, thick coloured microcrystalline coating 23, thin coloured microcrystalline coating 24, and linear is decorated texture and is positioned at decorative devitrified glass layer 2 inside.
Embodiment 5
Different from embodiment 4, in order to be distributed as 20-100 order by a kind of fineness of screen printing, (wherein 20-30 order accounts for 5% to the step D1 of the present embodiment, 30-100 order accounts for 95%), initial melting temperature is that thin coloured frit 1.5kg of 1050 ℃ forms thin coloured microcrystalline coating 21, by hollow out roller, print a kind of fineness again and be distributed as 30-100 order, initial melting temperature is thin coloured frit 0.5kg of 1060 ℃;
After step D1, also comprise step D2: by fineness 4-20 order, (wherein 20-30 order accounts for 5% for thick coloured frit of initial melting temperature 1080, fineness 4-30 order, 4-20 order accounts for 95%) thick coloured frit of 1080 ℃ of thick coloured frit of 1100 ℃ of initial melting temperatures and fineness 4-30 order (wherein 20-30 order accounts for 2%, 4-20 order and accounts for 98%) initial melting temperatures mixes in the adobe of rear cloth 6kg after step D1.
Embodiment 6
Different from embodiment 5, the step D1 of the present embodiment is distributed as 20-100 order (wherein 20-30 order accounts for 3%, and 30-100 order accounts for 97%) for printing a kind of fineness by hollow out roller, and initial melting temperature is thin coloured frit 1kg of 1070 ℃;
Step D2 is by fineness 4-20 order, (wherein 20-30 order accounts for 5% for thick coloured frit that initial melting temperature is 1080 ℃, fineness 4-30 order, 4-20 order accounts for 95%) thick coloured frit of 1090 ℃ of thick coloured frit of 1100 ℃ of initial melting temperatures and fineness 4-30 order (wherein 20-30 order accounts for 2%, 4-20 order and accounts for 98%) initial melting temperatures mixes in the adobe of rear cloth 8kg after step D1.
Embodiment 7
Different from embodiment 6, the step D2 of the present embodiment is by fineness 4-20 order, thick coloured frit that thick coloured frit that initial melting temperature is 1080 ℃ and fineness 4-30 order (wherein 20-30 order accounts for 5%, 4-20 order and accounts for 95%) initial melting temperature is 1100 ℃ mixes in the adobe of rear cloth 4kg after step D1;
After steps A, also comprise steps A 1: after water spray, execute one deck protection glaze.The present embodiment was executed one deck protection glaze before printing frit; and execute protection glaze before trickle; pin-holing glaze bubble while having avoided drenching protection glaze; simultaneously; because protect glaze beginning fusing point lower than frit after adding one deck protection glaze, thereby first produce glassy phase in sintering procedure, suppress the gas minimizing gas that in adobe sintering process, decompositions produces and carry out the defects such as frit layer shape pin hole and small bubbles.Meanwhile, protection glaze is transparence, by design, can make to protect the decorative effect of glaze to reveal, and has not only improved quality product, has avoided the defect of pin hole, also expands the decorative effect that has enriched product.
Know-why of the present invention has below been described in conjunction with specific embodiments.These are described is in order to explain principle of the present invention, and can not be interpreted as by any way limiting the scope of the invention.Explanation based on herein, those skilled in the art does not need to pay performing creative labour can associate other embodiment of the present invention, within these modes all will fall into protection scope of the present invention.
Claims (18)
1. a manufacture method for glass-ceramic clad plate, is characterized in that: step comprises successively:
A, ceramic powder compacting formation adobe is also dry;
B, seal are no less than a kind thin coloured frit;
C, will be no less than 2 kinds of thick coloured frits and mix rear cloth;
D, pouring are no less than a kind of coloured frit slurry;
E, spray fixing agent are fixed, and burn till, polishing.
2. the manufacture method of a kind of glass-ceramic clad plate according to claim 1, is characterized in that: after described step D, also comprise step D1: print and be no less than a kind thin coloured frit.
3. the manufacture method of a kind of glass-ceramic clad plate according to claim 2, is characterized in that: after described step D1, also comprise step D2: will be no less than 2 kinds of thick coloured frits and mix rear cloth.
4. the manufacture method of a kind of glass-ceramic clad plate according to claim 1, is characterized in that: after steps A, also comprise steps A 1: after water spray, execute one deck protection glaze.
5. the manufacture method of a kind of glass-ceramic clad plate according to claim 1, is characterized in that: described thin its fineness of coloured frit in described step B is distributed as 20-100 order, and initial melting temperature is 1050-1080 ℃, and consumption is 0.5-1.5kg/m
2; Wherein 20-30 order accounts for 0-5%, and 30-100 order accounts for 95-100%.
6. the manufacture method of a kind of glass-ceramic clad plate according to claim 1, is characterized in that: the mode of the thin coloured frit of described seal in described step B is a kind of or its combination of screen printing or hollow out roller India and China.
7. the manufacture method of a kind of glass-ceramic clad plate according to claim 1, is characterized in that: the described thick coloured frit in described step C, and its fineness is distributed as 4-30 order, and initial melting temperature is 1080-1100 ℃, and consumption is 1-2kg/m
2; Wherein 20-30 order accounts for 0-5%, and 4-20 order accounts for 95-100%.
8. the manufacture method of a kind of glass-ceramic clad plate according to claim 1, is characterized in that: slurry fineness 250 mesh screen residues of the described coloured frit slurry in described step D are less than 3%, proportion 1.5-1.8.
9. the manufacture method of a kind of glass-ceramic clad plate according to claim 1, is characterized in that: the mode of the coloured frit slurry of described pouring in described step D is for being used the pipe of 3-10 bar diameter 5-10mm to drench slurry.
10. the manufacture method of a kind of glass-ceramic clad plate according to claim 1, is characterized in that: the frit initial melting temperature of the described coloured frit slurry in described step D is 1050-1080 ℃, and consumption is 0.5 to 1.5kg.
The manufacture method of 11. a kind of glass-ceramic clad plates according to claim 2, is characterized in that: described thin its fineness of coloured frit in described step D1 is distributed as 20-100 order, and initial melting temperature is 1050-1080 ℃, and consumption is 0.5-1.5kg/m
2; Wherein 20-30 order accounts for 0-5%, and 30-100 order accounts for 95-100%.
The manufacture method of 12. a kind of glass-ceramic clad plates according to claim 2, is characterized in that: the mode of the thin coloured frit of described seal in described step D1 is a kind of or its combination of screen printing or hollow out roller India and China.
The manufacture method of 13. a kind of glass-ceramic clad plates according to claim 3, is characterized in that: the described thick coloured frit in described step D2, and its fineness is distributed as 4-30 order, and initial melting temperature is 1080-1100 ℃, and consumption is 2-6kg/m
2; Wherein 20-30 order accounts for 0-5%, and 4-20 order accounts for 95-100%.
The manufacture method of 14. a kind of glass-ceramic clad plates according to claim 1, is characterized in that: the described fixing agent in described step e is the PVA solution containing 0.01%-0.1%.
15. according to the product of the manufacture method manufacturing of a kind of glass-ceramic clad plate described in any one in claim 1-14, it is characterized in that: it from bottom to top comprises end base layer and coloured decorative devitrified glass layer successively.
16. products according to claim 15 is characterized in that: base layer thickness of the described end is 8-15mm; Described coloured decorative devitrified glass layer thickness 1-5mm.
17. products according to claim 15 is characterized in that: described coloured decorative devitrified glass layer forms at least 2 nonplanar coloured microcrystalline coatings merge mutually to interlock.
18. products according to claim 15 is characterized in that: in described coloured decorative devitrified glass layer or the wired linear marking of surface arrangement.
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| CN201410377924.3A CN104108957B (en) | 2014-08-01 | 2014-08-01 | A kind of manufacture method of glass-ceramic clad plate and products thereof |
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| CN201410377924.3A CN104108957B (en) | 2014-08-01 | 2014-08-01 | A kind of manufacture method of glass-ceramic clad plate and products thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104744077A (en) * | 2015-02-06 | 2015-07-01 | 佛山石湾鹰牌陶瓷有限公司 | Flaky frit microcrystallite glass ceramic composite plate and preparation method thereof |
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| CN1382666A (en) * | 2002-05-22 | 2002-12-04 | 三水市特地陶瓷有限公司 | Process for preparing microcrystal glass-ceramic tile |
| CN103214273A (en) * | 2013-05-03 | 2013-07-24 | 广东东鹏陶瓷股份有限公司 | Polished crystal tile and preparation method thereof |
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2014
- 2014-08-01 CN CN201410377924.3A patent/CN104108957B/en active Active
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| CN1382666A (en) * | 2002-05-22 | 2002-12-04 | 三水市特地陶瓷有限公司 | Process for preparing microcrystal glass-ceramic tile |
| CN103214273A (en) * | 2013-05-03 | 2013-07-24 | 广东东鹏陶瓷股份有限公司 | Polished crystal tile and preparation method thereof |
Non-Patent Citations (1)
| Title |
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| 叶恒青 等: "微晶玻璃陶瓷复合板工艺现状及前景展望", 《广东建设报》, 28 June 2005 (2005-06-28), pages 1 - 4 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104744077A (en) * | 2015-02-06 | 2015-07-01 | 佛山石湾鹰牌陶瓷有限公司 | Flaky frit microcrystallite glass ceramic composite plate and preparation method thereof |
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| CN104108957B (en) | 2016-08-24 |
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Effective date of registration: 20170413 Address after: 528031 Chancheng, Foshan District, Jiangwan, No. three, No., layer 8, layer two Co-patentee after: Guangdong Dongpeng Holdings Co., Ltd. Patentee after: Foshan Dongpeng Ceramic Co., Ltd. Co-patentee after: Fengcheng Dongpeng Ceramic Co., Ltd. Address before: Chancheng District of Jiangwan city of Foshan province Guangdong three road 528031 No. 8 two Foshan city Eastroc Ceramics Co. Ltd Co-patentee before: Guangdong Dongpeng Holdings Co., Ltd. Patentee before: Foshan Dongpeng Ceramic Co., Ltd. Co-patentee before: Fengcheng Dongpeng Ceramic Co., Ltd. Co-patentee before: Guangdong Dongpeng Ceramic Co., Ltd. |
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