CN104094074A - Capillary-pumping heat-transport device - Google Patents
Capillary-pumping heat-transport device Download PDFInfo
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- CN104094074A CN104094074A CN201280055587.5A CN201280055587A CN104094074A CN 104094074 A CN104094074 A CN 104094074A CN 201280055587 A CN201280055587 A CN 201280055587A CN 104094074 A CN104094074 A CN 104094074A
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- China
- Prior art keywords
- cistern
- fluid
- liquid
- evaporimeter
- compartment
- Prior art date
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D15/00—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies
- F28D15/02—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes
- F28D15/04—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes with tubes having a capillary structure
- F28D15/043—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes with tubes having a capillary structure forming loops, e.g. capillary pumped loops
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D15/00—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies
- F28D15/02—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes
- F28D15/04—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes with tubes having a capillary structure
- F28D15/046—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes with tubes having a capillary structure characterised by the material or the construction of the capillary structure
Abstract
The invention relates to a capillary-pumping heat-transport device, which is suitable for extracting heat from a heat source (11) and for returning said heat to a cold source (12) using a two-phase working fluid, including an evaporator (1) having a microporous body (10) suitable for ensuring the capillary pumping of a fluid in the liquid phase, a condenser (2), a tank (3) having an inlet and/or outlet (31; 31a, 31b), a vapor-communication circuit (4) connecting the outlet of the evaporator to the inlet of the condenser, and a liquid-communication circuit (5) connecting the outlet of the condenser to the tank and to the inlet of the evaporator, characterized in that the tank (3) includes a plurality of separate spaces, said separate spaces remaining in fluid communication.
Description
Technical field
The present invention relates to the heat transfer unit (HTU) of REFRIGERATION SYSTEM DRIVEN BY CAPILLARY FORCE, particularly the two phase fluid passive device that circulates.
Background technology
From file FR-A-2949642, such device is used as the equipment of cooling energy converter.
Yet, in the situation that there is higher calorific power level, the startup stage of appearance, suffer especially a plurality of problems, may there is the dry of capillary wick, cause starting unsuccessfully.
In addition, if device is accelerated, cold shock phenomenon may occur in cistern, and this phenomenon can reduce suddenly pressure degrade performance.
Therefore, need to increase the reliability of startup and the operability of this circulation.
Summary of the invention
For reaching this object, the present invention relates to the heat transfer unit (HTU) of REFRIGERATION SYSTEM DRIVEN BY CAPILLARY FORCE, it is suitable for by being included in the two-phase working fluid in common loop, from thermal source, extracts heat, and by this thermal release to low-temperature receiver, comprising:
-at least one evaporimeter, it has entrance and exit, and micropore piece, and described micropore piece is suitable for carrying out the capillary pumped of fluid liquid,
-at least one condenser, it has entrance and exit,
-cistern, it has inner chamber and at least one entrance and/or outlet port, and wherein gaseous state is partly positioned at the top of liquid part,
The-the first ac circuit, fluid is mainly gaseous state, and its outlet by evaporimeter is connected to the entrance of condenser,
The-the second ac circuit, fluid is mainly liquid, and its outlet by condenser is connected to the entrance of cistern and evaporimeter,
It is characterized in that, described cistern comprises liquid a plurality of compartments, and the described compartment keeps fluid communication,
Described cistern comprises a plurality of internal partitions, and dividing plate forms compartment, is suitable for separating liquid described a plurality of compartments,
Described a plurality of compartment is by little cross section channel AC, to produce hydraulic damping between the liquid compartment.
Thanks to these devices and so hydraulic damping of generation, when device stands to accelerate, for example, if it is arranged in the automobile of transportation, in cistern, avoided the excess flow of fluid liquid, prevent in this way the stirring in cistern, this stirring may bring cold shock effect, that is, in cistern, the rapid drawdown of the Free Surface temperature of fluid, causes the reduction of pressure drop and cycle efficieny.Similarly, fluid partitioning can be avoided stirring to a plurality of compartments, described stirring may occur due to the rapid drawdown of heat energy, particularly when starting.
In various embodiment of the present invention, following one and/or other arrangement can further alternatively be employed:
-fluid liquid is not crossed the top edge of dividing plate; This prevents the stirring of liquid when running into any acceleration;
-described a plurality of compartments are by little cross section channel AC, and described little cross section is preferentially less than 1/10 of cistern maximum cross section; Thus, a compartment can flow to another compartment, but flowing velocity is very slow;
The partition architecture of-a plurality of internal partition formation rules; Thus, all dividing plates support mutually;
-described cistern comprises macroporous structure, and described compartment does not have microcellular structure;
-described partition architecture is taked the form of alveolate texture; Like this, partition architecture is cost scheme to one's profit, because this structure is optimized;
-described device is mainly subject to the impact of terrestrial gravitation, and described partition architecture comprises inclination or vertical dividing plate; So that limit fluid flows in level acceleration situation;
-described partition architecture consists of stainless steel; Thus, its durability is highly satisfactory;
-described partition architecture consists of plastics, and it is compatible with working fluid (particularly methyl alcohol); Thus, itself and this normally used fluid compatible, be gratifying its service life, and with low cost;
-described a plurality of compartments consist of tight network structure (wire netting); The replacement scheme of separation structure has been proposed thus;
-described spacer structure is by providing the phase-change material of thermal inertia to form; Thus, cold shock effect is further reduced;
-described cistern comprises inlet flow guide plate; Thus, liquid enters the mobilization that cistern produces and is limited in the region of restriction;
-described cistern can be positioned at by evaporimeter, or cistern can be integrated with evaporimeter; Thus, the mechanical integrated of cistern can improve;
-described device also comprises check device, and it is arranged between the inner chamber of cistern and the micropore piece of evaporimeter, and the liquid backflow that is arranged to avoid evaporating in device is to the inner chamber of cistern;
-described heat-transfer arrangement does not preferentially have mechanical mercury, and reliability can increase like this;
-described device is mainly subject to the impact of gravity, and check device comprises float;
--described heat transfer unit (HTU) does not preferentially have mechanical pump, and its reliability can increase like this;
-described device also comprises the Power supply element in cistern, so that in the pressurization of startup control closed circuit processed; Like this, the startup of closed circuit can be more reliable.
Accompanying drawing explanation
By reading the following description that is provided as the several embodiments of the present invention of non-limiting example, and with reference to accompanying drawing, other aspects of the present invention, object and advantage will manifest, in accompanying drawing:
-Fig. 1 is the total figure according to embodiment of the present invention device,
-Fig. 2 is the variant of Fig. 1 device,
-Fig. 3 shows the joint more in detail of the cistern of Fig. 2 device,
-Fig. 4 a and 4b show the partition architecture in the cistern of Fig. 1 and Fig. 2 device,
-Fig. 5 is similar to Fig. 3, and shows the variant of the cistern of Fig. 2 device,
-Fig. 6 is the variant of Fig. 1 device.
In different figure, identical Reference numeral is specified same or analogous parts.
The specific embodiment
Fig. 1 shows the heat transfer unit (HTU) of the REFRIGERATION SYSTEM DRIVEN BY CAPILLARY FORCE with two phase fluid circulation.Described device comprises evaporimeter 1 and micropore piece 10, and described evaporimeter 1 has entrance 1a and outlet 1b, and described micropore piece 10 is suitable for carrying out capillary pumped.For this reason, described micropore piece 10 is around Mang Xing center longitudinal fluting 15, and in order to receive liquid working fluid 9 from cistern 3, described Mang Xing center longitudinal fluting 15 exchanges with entrance 1a.
Described evaporimeter 1, with heating power mode and thermal source 11 couplings, for example, comprises the assembly of electrical power parts or any other heater element, for example, and by Joule effect, or by any other device.
Under the impact of supplying with the calorie of contact position 16 that is full of the micropore piece of liquid, fluid changes gaseous state into from liquid state, via transmission cavity 17 and by the first ac circuit 4, shed, described the first ac circuit 4 is sent to condenser 2 by described steam, and described condenser 2 has entrance 2a and outlet 2b.
In evaporimeter 1, by micropore piece 10, from above-mentioned central recess 15, introduce liquid, be full of the cavity that discharges the steam that sheds; Well-known capillary pumped phenomenon that Here it is.
In described condenser 2, the release of fluid of heat energy by gaseous state is to low-temperature receiver 12, and this causes the cooling of gaseous fluid, with and be converted to liquid phase transformation, i.e. condensation.
In condenser 2, the temperature of working fluid 9 drops to lower than its liquid-gas equilibrium temperature, and this is also known as sub-cooled, and like this, fluid just can not revert to gaseous state when there is no large calorimetric input.
Steam pressure promotes liquid in the direction of the outlet 2b of condenser 2, and the outlet 2b of described condenser 2 opens at the second flow cycle 5 places, and the second flow cycle 5 is also connected to described cistern 3.
Cistern manifests at least one entrance and/or outlet port 31, and the situation of Fig. 1 is independent ingress port 31a and outlet port 31b here, and cistern 3 demonstration inner chambers 30, and this inner chamber 30 has been full of heat-transfer fluid 9.Working fluid 9 can be for example ammoniacal liquor, or any other suitable fluid, but methyl alcohol is preferential selection.Working fluid 9 is two phase fluids, and is partly presented as liquid 9a, and part is presented as gaseous state 9b.In the environment of Action of Gravity Field (according to Z-direction, vertically), gaseous state part 9b is positioned on liquid part 9a, and liquid-gas interface 19 is separated two states (Free Surface of liquid in cistern).
The temperature of this separation surfaces 19 has determined the pressure in loop just, and this pressure is the saturation pressure at the separation surfaces 19 general temperature in place corresponding to fluid.
At pedestal 34 places of cistern, the temperature of liquid is usually less than the general temperature at separation surfaces 19 places.
For proper operation REFRIGERATION SYSTEM DRIVEN BY CAPILLARY FORCE loop, be necessary to avoid the quick change in the separation surfaces 19 general temperature in place, and avoid especially the stirring of liquid 9a, described liquid 9a to be tending towards extracting cold liquid out to top from the bottom of cistern, and therefore making surface temperature decline, pressure also declines simultaneously.
The phenomenon that temperature and pressure declines is suddenly considered to " cold shock " conventionally, and must avoid.
The first and second fluid communication loops 4,5 are pipeline preferably, but they can be also fluid line or the alternating current path (rectangular duct, flexible pipe etc.) of other type.
Similarly, second fluid ac circuit 5 can be two separately and independently conduit 5a, the form of 5b (referring to Fig. 1), or the form (referring to Fig. 2) of the unitary catheter 5c connecting with T shape.
When several evaporimeters and/or the parallel connection of several condenser, it is relevant that these pipeline configurations keep.
In all cases, second fluid ac circuit 5 indirectly by cistern (two individual conduits in the situation that) or directly (in the situation that with the connection of T shape unitary catheter) condensator outlet 2b is connected to evaporator inlet 1a.
In view of the stirring phenomenon that may cause cold shock phenomenon that will avoid in cistern, the liquid of a plurality of compartments is provided in cistern, and the compartment is spaced, but described separated space still keeps fluid circulation.Particularly, more accurate, a plurality of internal partition 7 can be installed in cistern, they are suitable for separating described a plurality of compartment.
Yet according to alternative selection scheme, described a plurality of compartments can form tight cancellated form (not shown), for example steel wool type structure, or sponge-type structure, or macroporous structure, or the hollow ball that penetrates with aperture of a pile.
In addition, advantageously according to the present invention, cistern comprises inlet flow guide plate 8, its according to the structure of the second conduit near ingress port 31a or inlet/outlet port 31.
This inlet flow guide plate prevents that fluid from arriving generation bubble phenomenon in cistern fast, maybe may promote the current of liquid agitation.It can be downward U-shaped cross section, or the form of bowl-type or any other shape, makes the track of inlet flow produce enough skews.
Fig. 3 shows the partition architecture 71 with vertical partition plate 7, and dividing plate is directed towards gravity direction.Yet, it should be noted that dividing plate can have at an easy rate small or significantly tilt, just as shown in fig. 1.Preferably, partition architecture is regular, that is, certain geometrical pattern repeatedly repeats.It should be noted that cistern may be any shape, particularly parallelepiped or cylindrical.In addition, partition architecture can be made by stainless steel, so that good durability to be provided.In addition, partition architecture can be made of plastics, and described plastics and working fluid are compatible, particularly compatible with methyl alcohol; Partition architecture relies on and this fluid compatible being generally used in the application of land, and be gratifying its service life, and with low cost.
According to an aspect of the present invention, described a plurality of compartments are by little cross section channel AC, and this small bore is preferably less than 1/10 of cistern maximum cross section.For example, as shown in Figure 3, internal partition 7 presents the hole 70 with passage aisle cross section, to produce hydraulic damping between liquid separation space.
Passage between the compartment also can be positioned at the pedestal place of compartment, and the top of compartment does not have hole.In this case, what have a plurality of little transversal faces penetrates grid 28, allows fluid to move between compartment by transmission cavity 29, and described transmission cavity 29 is positioned at cistern base region 34.This grid 28 diffuser that is otherwise known as, it can advantageously be used as the support of partition architecture 71.
The height of dividing plate can cistern height 30% to 90% between, and need special selection, so that the upper surface 19 of liquid can not surpass the top edge of dividing plate 7.
Advantageously, can select to have honeycomb or the square net structure of hexagonal mesh, respectively as shown in Fig. 4 a and 4b.Hexagon compartment 77 (or corresponding square compartment 78) exchanges by lower opening 76 (or 79).
In addition, a plurality of dividing plates can comprise relative to each other different towards dividing plate.Especially, may have some dividing plates to be parallel to XZ plane, other be parallel to XY plane, in addition be parallel to YZ plane: in this way, can limit flowing on space in all directions, if device is used on airborne vehicle, this can be to have especially advantage.
In addition, the size of grid can not too meticulous (being less than 1 millimeter), otherwise described structure can hinder liquid by capillary, and require over filling to prevent that loop from starting under low temperature environment or desiccation during power decline.In this manner, compartment does not have multi-cellular structure, even if cistern can form macroporous structure.
According to another favourable aspect of the present invention, partition architecture comprises the phase-change material that thermal inertia is provided to described structure, and this contributes to limit unexpected variations in temperature.
Fig. 5 is similar to Fig. 3, shows the variant of the cistern of device, and described cistern has liquid inlet in one side 35 of bottom, and it can allow to simplify inlet flow deflector 8.Described input deflector 8 can be simply horizontally extending plate, or is equipped with the extension of the conduit 5 in a plurality of holes.
In addition, (be similar to Fig. 1) as shown in Figure 6, described device can also comprise check device 6, and it is arranged between the inner chamber 30 of cistern and the micropore piece 10 of evaporimeter, to prevent that liquid backflow in evaporimeter is in the inner chamber of cistern.While causing boiling startup stage of system, described check device 6 can avoid liquid to flow from evaporimeter to cistern direction.
Preferentially, described check device 6 can comprise float (not shown in the diagram), and the density of described float is slightly less than the density of fluid liquid.
In addition, described device can further comprise Power supply element 36, for example, heating element heater or pressurizing member, this Power supply element 36 is positioned at cistern place, the pressurization in loop while starting to control.The in the situation that of heating element heater, temperature information and/or pressure information that " Ctrl " control system 38 is transmitted according to sensor (not shown), manage the calorie of supplying with on described heating element heater 36, and this is the startup in order to ensure two-phase cycle.
Heating element heater can be similarly in liquid state and/or gaseous state.Preferentially, described element is in liquid state, and produces steam towards the top of cistern.Promote the adjusting of heating element heater with the low-temperature receiver of the latter's (ambient air, or other) contact.In addition, described " Ctrl " control system also can be prepared two-phase cycle for approaching and a large amount of arrival of thermal energy in evaporimeter, and this allows expection about the reaction of the required two-phase cycle of dispelling the heat.Therefore, the size of circulation can optimization so that amount of heat shed.
Advantageously, according to the present invention, described device is without using mechanical pump, although the present invention does not repel the existence of complementary mechanical pump.
Claims (14)
1. the heat transfer unit (HTU) of REFRIGERATION SYSTEM DRIVEN BY CAPILLARY FORCE, under the impact of gravity, is suitable for by means of the two-phase working fluid in common closed loop, extracts heat from thermal source (11), and by described thermal release to low-temperature receiver (12), described heat transfer unit (HTU) comprises:
-at least one evaporimeter (1), it has entrance and exit, and micropore piece (10), and described micropore piece (10) is suitable for carrying out the capillary pumped of fluid liquid,
-at least one condenser (2), it has entrance and exit,
-cistern (3), it has inner chamber (30), and at least one entrance and/or outlet port (31; 31a, 31b), wherein, it is upper that gaseous state is partly positioned at liquid part top,
The-the first ac circuit (4), wherein, fluid is mainly gaseous state, and its described outlet by described evaporimeter is connected to the described entrance of described condenser,
The-the second ac circuit (5), wherein, fluid is mainly liquid state, and its described outlet by described condenser is connected to the described entrance of described evaporimeter,
It is characterized in that, described cistern (3) comprises a plurality of compartments of fluid liquid, described a plurality of separation keeps fluid communication, described cistern comprises a plurality of internal partitions (7), described a plurality of internal partition (7) has formed compartment, described compartment is suitable for separating a plurality of compartments of described fluid liquid
Described a plurality of compartment is by little cross section channel AC, to form hydraulic damping between the described compartment of fluid liquid.
2. device according to claim 1, is characterized in that, described fluid liquid is no more than the top edge of described dividing plate (7).
3. according to the device described in any one in claim 1 to 2, it is characterized in that the partition architecture of described a plurality of internal partition formation rules.
4. according to the device described in any one in claims 1 to 3, it is characterized in that, described cistern comprises macroporous structure, and described compartment does not have microcellular structure.
5. device according to claim 4, mainly, under the impact of gravity, is characterized in that, described dividing plate forms that tilt or vertical separation baffles.
6. according to the device described in any one in claim 4 to 5, it is characterized in that, described partition architecture adopts the form of honeycomb.
7. according to the device described in any one in claim 4 to 6, it is characterized in that, described partition architecture is by providing the phase-change material of thermal inertia to form.
8. according to the device described in any one in claim 1 to 7, it is characterized in that, described cistern comprises inlet flow guide plate (8), and described inlet flow guide plate (8) is positioned near ingress port.
9. according to the device described in any one in claim 1 to 8, it is characterized in that, described cistern can be positioned at by described evaporimeter, or described cistern and described evaporimeter are integrated.
10. according to the device described in any one in claim 1 to 9, it comprises check device (6), described check device (6) is arranged between the described inner chamber (30) of described cistern and the described micropore piece (10) of described evaporimeter, and is arranged to prevent that liquid backflow in described evaporimeter is to the described inner chamber of described cistern.
11. devices according to claim 10, mainly, under the impact of gravity, is characterized in that, described check device comprises float (60).
12. according to heat transfer unit (HTU) in any one of the preceding claims wherein, it is characterized in that, it does not have mechanical pump.
13. according to device in any one of the preceding claims wherein, and it is also included in the Power supply element in described cistern, so that the described pressurization circulating described in startup control system.
14. according to device in any one of the preceding claims wherein, it is characterized in that, the described cross section of described little cross section passage is preferably less than 1/10 of described cistern maximum cross section.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1158202 | 2011-09-14 | ||
| FR1158202A FR2979981B1 (en) | 2011-09-14 | 2011-09-14 | CAPILLARY PUMP HEAT DELIVERY DEVICE |
| PCT/EP2012/067752 WO2013037784A1 (en) | 2011-09-14 | 2012-09-12 | Capillary-pumping heat-transport device |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104094074A true CN104094074A (en) | 2014-10-08 |
| CN104094074B CN104094074B (en) | 2016-08-24 |
Family
ID=46829776
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280055587.5A Active CN104094074B (en) | 2011-09-14 | 2012-09-12 | The heat transfer unit (HTU) of REFRIGERATION SYSTEM DRIVEN BY CAPILLARY FORCE |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9958214B2 (en) |
| EP (1) | EP2756251B1 (en) |
| JP (1) | JP6163490B2 (en) |
| CN (1) | CN104094074B (en) |
| ES (1) | ES2580402T3 (en) |
| FR (1) | FR2979981B1 (en) |
| WO (1) | WO2013037784A1 (en) |
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| CN109029034A (en) * | 2018-07-12 | 2018-12-18 | 南京航空航天大学 | A kind of driving heat pipe circulation heat exchanger certainly |
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| FR3006431B1 (en) * | 2013-05-29 | 2015-06-05 | Euro Heat Pipes | DEVICE FOR TRANSPORTING HEAT WITH A DIPHASIC FLUID |
| FR3009377B1 (en) * | 2013-08-01 | 2018-10-19 | Euro Heat Pipes | EVAPORATOR WITH ANTI-RETURN DEVICE FOR DIPHASIC LOOP |
| CN103987235B (en) * | 2014-04-14 | 2017-02-08 | 中国电子科技集团公司第十一研究所 | Heat dissipation method and system |
| DE102015107473A1 (en) | 2015-05-12 | 2016-11-17 | Benteler Automobiltechnik Gmbh | Automotive heat exchanger system |
| RU2665754C1 (en) * | 2017-06-22 | 2018-09-04 | Александр Михайлович Деревягин | Method and device for heat transfer |
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- 2012-09-12 US US14/344,880 patent/US9958214B2/en not_active Expired - Fee Related
- 2012-09-12 JP JP2014530188A patent/JP6163490B2/en not_active Expired - Fee Related
- 2012-09-12 ES ES12756742.8T patent/ES2580402T3/en active Active
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- 2012-09-12 EP EP12756742.8A patent/EP2756251B1/en active Active
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| CN109029034A (en) * | 2018-07-12 | 2018-12-18 | 南京航空航天大学 | A kind of driving heat pipe circulation heat exchanger certainly |
Also Published As
| Publication number | Publication date |
|---|---|
| US20150083373A1 (en) | 2015-03-26 |
| FR2979981B1 (en) | 2016-09-09 |
| FR2979981A1 (en) | 2013-03-15 |
| US9958214B2 (en) | 2018-05-01 |
| JP6163490B2 (en) | 2017-07-12 |
| WO2013037784A1 (en) | 2013-03-21 |
| CN104094074B (en) | 2016-08-24 |
| EP2756251B1 (en) | 2016-04-06 |
| EP2756251A1 (en) | 2014-07-23 |
| JP2014527153A (en) | 2014-10-09 |
| ES2580402T3 (en) | 2016-08-23 |
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