CN104087144A - Preparation method of waterproof and antibacterial polyurethane coating - Google Patents
Preparation method of waterproof and antibacterial polyurethane coating Download PDFInfo
- Publication number
- CN104087144A CN104087144A CN201410346616.4A CN201410346616A CN104087144A CN 104087144 A CN104087144 A CN 104087144A CN 201410346616 A CN201410346616 A CN 201410346616A CN 104087144 A CN104087144 A CN 104087144A
- Authority
- CN
- China
- Prior art keywords
- polyurethane coating
- waterproof
- preparation
- germ resistance
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011527 polyurethane coating Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 230000000844 anti-bacterial effect Effects 0.000 title abstract description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims abstract description 24
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims abstract description 17
- IYRMWMYZSQPJKC-UHFFFAOYSA-N kaempferol Chemical compound C1=CC(O)=CC=C1C1=C(O)C(=O)C2=C(O)C=C(O)C=C2O1 IYRMWMYZSQPJKC-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000005058 Isophorone diisocyanate Substances 0.000 claims abstract description 16
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- YPQLFJODEKMJEF-UHFFFAOYSA-N hydroxyflutamide Chemical compound CC(C)(O)C(=O)NC1=CC=C([N+]([O-])=O)C(C(F)(F)F)=C1 YPQLFJODEKMJEF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003054 catalyst Substances 0.000 claims abstract description 10
- NAGJZTKCGNOGPW-UHFFFAOYSA-K dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [O-]P([O-])([S-])=S NAGJZTKCGNOGPW-UHFFFAOYSA-K 0.000 claims abstract description 10
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims abstract description 8
- 239000012975 dibutyltin dilaurate Substances 0.000 claims abstract description 8
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 8
- 239000004970 Chain extender Substances 0.000 claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 16
- LCCNCVORNKJIRZ-UHFFFAOYSA-N parathion Chemical compound CCOP(=S)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 LCCNCVORNKJIRZ-UHFFFAOYSA-N 0.000 claims description 15
- 229920000642 polymer Polymers 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 14
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 12
- 241000378106 Amianthium muscitoxicum Species 0.000 claims description 11
- 229930182470 glycoside Natural products 0.000 claims description 11
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 238000004945 emulsification Methods 0.000 claims description 7
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- OLLFKUHHDPMQFR-UHFFFAOYSA-N dihydroxy(diphenyl)silane Chemical group C=1C=CC=CC=1[Si](O)(O)C1=CC=CC=C1 OLLFKUHHDPMQFR-UHFFFAOYSA-N 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 claims 2
- 239000000839 emulsion Substances 0.000 abstract description 2
- 239000004753 textile Substances 0.000 abstract description 2
- UBSCDKPKWHYZNX-UHFFFAOYSA-N Demethoxycapillarisin Natural products C1=CC(O)=CC=C1OC1=CC(=O)C2=C(O)C=C(O)C=C2O1 UBSCDKPKWHYZNX-UHFFFAOYSA-N 0.000 abstract 1
- JMFWYRWPJVEZPV-AVGVHVDKSA-N Syringetin-3-O-glucoside Chemical compound COC1=C(O)C(OC)=CC(C2=C(C(=O)C3=C(O)C=C(O)C=C3O2)O[C@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)=C1 JMFWYRWPJVEZPV-AVGVHVDKSA-N 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- BXNANOICGRISHX-UHFFFAOYSA-N coumaphos Chemical compound CC1=C(Cl)C(=O)OC2=CC(OP(=S)(OCC)OCC)=CC=C21 BXNANOICGRISHX-UHFFFAOYSA-N 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- MWDZOUNAPSSOEL-UHFFFAOYSA-N kaempferol Natural products OC1=C(C(=O)c2cc(O)cc(O)c2O1)c3ccc(O)cc3 MWDZOUNAPSSOEL-UHFFFAOYSA-N 0.000 abstract 1
- 235000008777 kaempferol Nutrition 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- UXOUKMQIEVGVLY-UHFFFAOYSA-N morin Natural products OC1=CC(O)=CC(C2=C(C(=O)C3=C(O)C=C(O)C=C3O2)O)=C1 UXOUKMQIEVGVLY-UHFFFAOYSA-N 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 5
- 238000009835 boiling Methods 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 230000003115 biocidal effect Effects 0.000 description 4
- 239000010985 leather Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 241000191967 Staphylococcus aureus Species 0.000 description 2
- DRTQHJPVMGBUCF-XVFCMESISA-N Uridine Chemical compound O[C@@H]1[C@H](O)[C@@H](CO)O[C@H]1N1C(=O)NC(=O)C=C1 DRTQHJPVMGBUCF-XVFCMESISA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000005357 flat glass Substances 0.000 description 2
- 230000000968 intestinal effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- UCTWMZQNUQWSLP-VIFPVBQESA-N (R)-adrenaline Chemical compound CNC[C@H](O)C1=CC=C(O)C(O)=C1 UCTWMZQNUQWSLP-VIFPVBQESA-N 0.000 description 1
- 229930182837 (R)-adrenaline Natural products 0.000 description 1
- YBTVSGCNBZPRBD-UHFFFAOYSA-N 4-acetamidosalicylic acid Chemical compound CC(=O)NC1=CC=C(C(O)=O)C(O)=C1 YBTVSGCNBZPRBD-UHFFFAOYSA-N 0.000 description 1
- DTUOTSLAFJCQHN-UHFFFAOYSA-N 4-bromo-1,8-naphthalic anhydride Chemical compound O=C1OC(=O)C2=CC=CC3=C2C1=CC=C3Br DTUOTSLAFJCQHN-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- DRTQHJPVMGBUCF-PSQAKQOGSA-N beta-L-uridine Natural products O[C@H]1[C@@H](O)[C@H](CO)O[C@@H]1N1C(=O)NC(=O)C=C1 DRTQHJPVMGBUCF-PSQAKQOGSA-N 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229960005139 epinephrine Drugs 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- DRTQHJPVMGBUCF-UHFFFAOYSA-N uracil arabinoside Natural products OC1C(O)C(CO)OC1N1C(=O)NC(=O)C=C1 DRTQHJPVMGBUCF-UHFFFAOYSA-N 0.000 description 1
- 229940045145 uridine Drugs 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Landscapes
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
Abstract
Description
Experimental group | Example one | Example two | Example three | Example four | Example five |
Film outward appearance (water tolerance 48h) | Transparent | Transparent | Transparent | Transparent | Transparent |
Hardness | B | B | B | B | B |
Sticking power/level | 2 | 2 | 2 | 3 | 3 |
Snappiness/mm | 2 | 2 | 2 | 2 | 2 |
Experimental group | Example one | Example two | Example three | Example four | Example five |
Elongation at break/% | 150 | 145 | 155 | 166 | 168 |
Tensile strength/MPa | 5.7 | 5.6 | 5.7 | 5.9 | 5.8 |
Abrasion resisting (level) | 3.5 | 4 | 4 | 4 | 4 |
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410346616.4A CN104087144B (en) | 2014-07-21 | 2014-07-21 | The preparation method of a kind of waterproof and Antibacterial polyurethane coating |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410346616.4A CN104087144B (en) | 2014-07-21 | 2014-07-21 | The preparation method of a kind of waterproof and Antibacterial polyurethane coating |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104087144A true CN104087144A (en) | 2014-10-08 |
CN104087144B CN104087144B (en) | 2016-03-02 |
Family
ID=51634911
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410346616.4A Expired - Fee Related CN104087144B (en) | 2014-07-21 | 2014-07-21 | The preparation method of a kind of waterproof and Antibacterial polyurethane coating |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104087144B (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105968973A (en) * | 2016-06-30 | 2016-09-28 | 河北晨阳工贸集团有限公司 | Mildew-proof, antibacterial and antiviral coating with Chinese herbal medicines and method for manufacturing mildew-proof, antibacterial and antiviral coating |
CN106221552A (en) * | 2016-08-31 | 2016-12-14 | 段宝荣 | Graphene modified flame-retardant, the preparation method of antibiotic property aqueous polyurethane coating |
CN106366896A (en) * | 2016-08-31 | 2017-02-01 | 段宝荣 | Preparation method of graphene-modified flame-retardant and light-resistant waterborne polyurethane coating |
CN108299613A (en) * | 2017-12-29 | 2018-07-20 | 合肥科天水性科技有限责任公司 | A kind of antimicrobial form anion aqueous polyurethane resin and preparation method thereof |
CN108299614A (en) * | 2017-12-29 | 2018-07-20 | 合肥科天水性科技有限责任公司 | A kind of antibacterial cation waterborne polyurethane resin and preparation method thereof |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63301251A (en) * | 1987-06-02 | 1988-12-08 | Dai Ichi Kogyo Seiyaku Co Ltd | Coating composition |
CN1931940A (en) * | 2006-09-14 | 2007-03-21 | 华明扬 | Prepn process of antibacterial poromeric paint comprising water-thinned polyurethane and silicone/acrylic acid copolymer |
JP2010077202A (en) * | 2008-09-24 | 2010-04-08 | Kaneka Corp | Moisture-permeable film, coating agent, filler for coating film, and coated sheet |
KR101247132B1 (en) * | 2011-03-25 | 2013-04-01 | 현대자동차주식회사 | Water-soluble and antibiotic paint composition for plastics and method of manufacturing coating film using the same |
KR20130137325A (en) * | 2012-06-07 | 2013-12-17 | 강석채 | Composite of paints for dew condensation and mold prevention, and manufacuring method thereof |
CN103468117A (en) * | 2013-08-16 | 2013-12-25 | 安徽快来防水防腐有限公司 | Elastic and bactericidal waterproof coating |
-
2014
- 2014-07-21 CN CN201410346616.4A patent/CN104087144B/en not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63301251A (en) * | 1987-06-02 | 1988-12-08 | Dai Ichi Kogyo Seiyaku Co Ltd | Coating composition |
CN1931940A (en) * | 2006-09-14 | 2007-03-21 | 华明扬 | Prepn process of antibacterial poromeric paint comprising water-thinned polyurethane and silicone/acrylic acid copolymer |
JP2010077202A (en) * | 2008-09-24 | 2010-04-08 | Kaneka Corp | Moisture-permeable film, coating agent, filler for coating film, and coated sheet |
KR101247132B1 (en) * | 2011-03-25 | 2013-04-01 | 현대자동차주식회사 | Water-soluble and antibiotic paint composition for plastics and method of manufacturing coating film using the same |
KR20130137325A (en) * | 2012-06-07 | 2013-12-17 | 강석채 | Composite of paints for dew condensation and mold prevention, and manufacuring method thereof |
CN103468117A (en) * | 2013-08-16 | 2013-12-25 | 安徽快来防水防腐有限公司 | Elastic and bactericidal waterproof coating |
Non-Patent Citations (2)
Title |
---|
卢敏等: "天然抗菌产物改性聚氨酯研究概述", 《聚氨酯》, no. 9, 15 September 2011 (2011-09-15), pages 74 - 77 * |
钟达飞等: "抗菌聚氨酯研究进展", 《化学推进剂与高分子材料》, vol. 5, no. 3, 25 May 2007 (2007-05-25), pages 23 - 26 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105968973A (en) * | 2016-06-30 | 2016-09-28 | 河北晨阳工贸集团有限公司 | Mildew-proof, antibacterial and antiviral coating with Chinese herbal medicines and method for manufacturing mildew-proof, antibacterial and antiviral coating |
CN105968973B (en) * | 2016-06-30 | 2018-06-08 | 河北晨阳工贸集团有限公司 | Chinese herbal medicine antimildew and antibacterial antiviral coating and preparation method thereof |
CN106221552A (en) * | 2016-08-31 | 2016-12-14 | 段宝荣 | Graphene modified flame-retardant, the preparation method of antibiotic property aqueous polyurethane coating |
CN106366896A (en) * | 2016-08-31 | 2017-02-01 | 段宝荣 | Preparation method of graphene-modified flame-retardant and light-resistant waterborne polyurethane coating |
CN108299613A (en) * | 2017-12-29 | 2018-07-20 | 合肥科天水性科技有限责任公司 | A kind of antimicrobial form anion aqueous polyurethane resin and preparation method thereof |
CN108299614A (en) * | 2017-12-29 | 2018-07-20 | 合肥科天水性科技有限责任公司 | A kind of antibacterial cation waterborne polyurethane resin and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN104087144B (en) | 2016-03-02 |
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Legal Events
Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C41 | Transfer of patent application or patent right or utility model | ||
CB03 | Change of inventor or designer information |
Inventor after: Huang Yuting Inventor before: Duan Xiaoning Inventor before: Gao Xiaolin Inventor before: Zhang Jianguo |
|
COR | Change of bibliographic data | ||
TR01 | Transfer of patent right |
Effective date of registration: 20160627 Address after: 20A, commercial building, 300 Lockhart Road, Wan Chai, Hongkong, China Patentee after: Hongkong sunny Industrial Co., Ltd. Address before: 264000 16-2, Fu Qing Street, Zhifu District, Shandong, Yantai Patentee before: Duan Xiaoning |
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C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20160705 Address after: 312000 Zhejiang province Shaoxing Paojiang Temple Street No. 20 Century Square west 2 layer -3 Patentee after: Shaoxing sunny new type building material Co., Ltd. Address before: 20A, commercial building, 300 Lockhart Road, Wan Chai, Hongkong, China Patentee before: Hongkong sunny Industrial Co., Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160302 Termination date: 20160721 |