CN105111911A - Single-component moisture-curable waterproof, protective and thermochromic coating and preparation method thereof - Google Patents
Single-component moisture-curable waterproof, protective and thermochromic coating and preparation method thereof Download PDFInfo
- Publication number
- CN105111911A CN105111911A CN201510613376.4A CN201510613376A CN105111911A CN 105111911 A CN105111911 A CN 105111911A CN 201510613376 A CN201510613376 A CN 201510613376A CN 105111911 A CN105111911 A CN 105111911A
- Authority
- CN
- China
- Prior art keywords
- color changing
- support
- induced color
- temperature induced
- aromatic ring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention relates to the field of preparation of waterproof and protective coatings of exterior walls of buildings, and particularly discloses a single-component moisture-curable waterproof, protective and thermochromic coating and a preparation method thereof. The single-component moisture-curable waterproof, protective and thermochromic coating comprises the following components in part by weight: 100 parts of waterproof filmogen, 0.5-25 parts of ultraviolet isolating agents, 0-15 parts of thermochromic agents, 0-3 parts of dispersing agents and 0-100 parts of diluents. By the single-component moisture-curable waterproof, protective and thermochromic coating, water can be effectively isolated from a protected inkjet decorative coat, corrosion of acid rain on the inkjet decorative coat is also avoided, and a thermochromic effect is obvious and adjustable. When the thickness of the coat of the coating ranges from 0.1-0.5 micrometers, half-life period of tensile strength and elongation at break is longer than 8 years, and rate of isolation on ultraviolet rays can reach 86%. The preparation method is simple and practicable, and can be used for industrial production.
Description
[technical field]
The present invention relates to building external wall waterproof and protective coating technical field, particularly relate to a kind of mono component wet solidifying waterproof protective and temperature induced color changing coating and preparation method thereof.
[background technology]
Along with the quickening of urbanization process, the expanding day of city size and the day by day intensive of buildings, while offering convenience for life, also make the living environment of people and visual space produce constriction, bring negative impact to the Mental health of people.
For this reason, architects make every effort to improve in engineering aesthetic structures, but these current modes all exist the defect being difficult to overcome, and such as: glass curtain wall, easily produce sunlight reflection pollute with focusing although attractive in appearance; Cover ceramic tile, although the good easily weathering of landscaping effect comes off, cause potential safety hazard.
Colo(u)r coating because its landscaping effect is flexible, nature, and receives much attention.But existing Weatherability of Exterior Wall Coatings difference and fugitive color peel off, need to repair continually, this overhauling on a large scale also can cause the huge wasting of resources.
In view of more than, need badly exploitation a kind of new waterproof protective coating, to overcome the defect of Weatherability of Exterior Wall Coatings difference of the prior art.
[summary of the invention]
The present invention is intended to the defect of the Weatherability of Exterior Wall Coatings difference overcoming prior art, provide a kind of new waterproof protective coating with and preparation method thereof.
For solving the problems of the technologies described above, the invention provides following technical scheme:
On the one hand, the invention provides a kind of mono component wet solidifying waterproof protective and temperature induced color changing coating, comprise the following component counted by weight: waterproof membrane-forming agent 100 parts; UV-screens 0.5-25 part; Temperature induced color changing agent 0-15 part; Dispersion agent 0-3 part, is preferably 0-2.0 part; Thinner 0-100 part, is preferably 5-100 part.
In some embodiments, described waterproof membrane-forming agent can be composition A and composition B mol ratio (0.8-1.2): the addition reaction product of (1.8-2.2), wherein said composition A is multiterminal amino silicones, multiterminal amino-polyether, multiterminal carboxy terminatedpolybutadiene vinyl cyanide fluid rubber, or the mixture of at least two kinds in them; Described composition B is the agent of epoxy ether alkylene organoalkoxysilane end envelope, the agent of polyisocyanates end envelope, or their mixture.
In some embodiments, described multiterminal amino silicones can have following structure:
Wherein, k>=1, R
2for hydrocarbon support, penylene, replacement penylene, aromatic ring support, replace aromatic ring support, heterocycle support or substituted heterocycle support; R
3, R
4, R
5, R
6for alkyl, phenyl, substituted-phenyl, aromatic ring yl, replacement aromatic ring yl, heterocyclic radical or substituted heterocyclic radical;
Described multiterminal amino-polyether can have following structure:
Wherein, n >=1.
In some embodiments, number-average molecular weight or the viscosity-average molecular weight of described multiterminal amino silicones, described multiterminal amino-polyether or described multiterminal carboxy terminatedpolybutadiene vinyl cyanide fluid rubber are 300-3000.
In some embodiments, the agent of described epoxy ether alkylene organoalkoxysilane end envelope has following structure:
Wherein, m>=0, n>=1, and R
1for methyl or ethyl;
Described polyisocyanates end envelope agent has following structure:
OCN-R
7-NCO
Wherein, R
7for hydrocarbon support, penylene, replacement penylene, aromatic ring support, replace aromatic ring support, heterocycle support or substituted heterocycle support.
In some embodiments, described UV-screens is metallocene, alkyl metallocene, nano transition element oxide, nano rare earth element oxide, or the mixture of at least two kinds or eutectic in them.
In some embodiments, described metallocene is ferrocene, dicyclopentadienylcobalt, nickelocene, or the mixture of at least two kinds in them; Described alkyl metallocene is containing the ferrocene of 1-3 the tertiary butyl, containing the dicyclopentadienylcobalt of 1-3 the tertiary butyl, the nickelocene containing 1-3 the tertiary butyl, or the mixture of at least two kinds in them; The median size D50 of described nano transition element oxide is 2-100nm, be preferably 2-50nm, and be yttrium oxide, vanadium oxide, titanium oxide, ferric oxide, cobalt oxide, nickel oxide, cupric oxide, zinc oxide, or the mixture of at least two kinds or eutectic in them; The median size D50 of described nano rare earth element oxide is 2-100nm, is preferably 2-50nm, and is mixture or the eutectic of a kind of in group of the lanthanides or actinide elements oxide compound or at least two kinds.
In some embodiments, described temperature induced color changing agent is the mixture of a kind of in the complex compound of Transitional element halide and xenogenesis halogenide eutectic thereof or sulfide and xenogenesis halogenide eutectic thereof, the complex compound of Transitional element halide or sulfide and oxy-compound, Transitional element halide or sulfide and amino-complex or at least two kinds; Described dispersion agent is C
8-C
36kiber alkyl amine, C
8-C
36alkyl secondary amine, C
8-C
36alkyl alcohol, C
8-C
36carboxylic acid in a kind of or mixture of at least two kinds; Described thinner is C
2-C
4primary alconol, C
2-C
4secondary alcohol, C
6-C
19alkane, benzene, substituted benzene, aromatic ring, replacement aromatic ring, heterocyclic hydrocarbon, a kind of in substituted heterocycle hydrocarbon or at least two kinds mixture.
In some embodiments, described oxy-compound has following structure:
Wherein, s is the integer of>=1; T is the integer of>=1; P+q is the integer of>=1; R
7, R
8for hydrocarbon support, penylene, replacement penylene, aromatic ring support, replace aromatic ring support, heterocycle support or substituted heterocycle support; Described amino-complex has following structure:
Wherein, s is the integer of>=1; T is the integer of>=1; P+q is the integer of>=1; R
7, R
8for hydrocarbon support, penylene, replacement penylene, aromatic ring support, replace aromatic ring support, heterocycle support or substituted heterocycle support; Described transition element is vanadium, titanium, iron, cobalt, nickel or copper; Described Transitional element halide is transition element muriate, transition element bromide or transition element iodide.
On the other hand, the invention provides a kind of method for the preparation of above-mentioned mono component wet solidifying waterproof protective and temperature induced color changing coating, comprise step: high-temperature pressure-reduction dewaters: make composition A, UV-screens, temperature induced color changing agent mixing, and below the 0.1wt% of raw material total amount is down in high-temperature pressure-reduction dehydration to moisture content, preferred below 0.07wt%, more preferably below 0.05wt%, obtains dewatered product; Addition pre-polymerization: under protective gas exists; composition B, dispersion agent and thinner are mixed with dewatered product; and carry out addition prepolymerization reaction; obtain mono component wet solidifying waterproof protective and temperature induced color changing coating, wherein the mol ratio of composition A and composition B is (0.8-1.2): (1.8-2.2).
High-temperature pressure-reduction dehydration is preferably carried out at the pressure of the temperature of 50-180 DEG C, 1/3 to 1% of normal pressure, more preferably carries out at the temperature of 80-120 DEG C, the pressure of-0.09MPa.
Addition prepolymerization reaction preferably at 25-120 DEG C of reaction 0.5-4 hour, more preferably 35-60 DEG C of reaction 3 hours, or is incubated 3 hours at 25-45 DEG C.
Compared with prior art; the present invention has following beneficial effect: mono component wet solidifying waterproof protective prepared by the present invention and temperature induced color changing coating can be crossed and effectively isolate moisture and infiltrate protected air brushing decorative coveringn; and effectively can isolate the corrosion of acid rain to air brushing decorative coveringn, its temperature is remarkable and adjustable to discoloration effect.When the coat-thickness of mono component wet solidifying waterproof protective and temperature induced color changing coating is within the scope of 0.1-0.5mm, the tensile strength of film and elongation at break transformation period, can reach 86% to ultraviolet isolation rate, temperature induced color changing effect was obvious more than 8 years.
Visible, coating of the present invention has the weathering resistance of improvement, the polychromy printing pattern of external wall can be avoided by moisture weathering, acid rain corrosion and ultraviolet damage, also have temperature induced color changing effect simultaneously, causes the effect of dazzling to alleviate sunlight reflection to eyes.Preparation method of the present invention is simple, can be applicable to suitability for industrialized production.
[embodiment]
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
first group (embodiment 1.1-1.3)
Raw material:
waterproof membrane-forming agentmiddle composition A is two Amino End Group dimethyl polysiloxanes (trade name PAM-E), and composition B is γ-glycidyl ether oxygen propyl trimethoxy silicane (trade name A-187, as the agent of end envelope).
uV-screensfor tertiary butyl ferrocene, wherein the ratio of one to tri-tert is by the control from chemical equilibrium, utilizes tertiary butyl ferrocene to collect effect to interfacial migration and forms the ultraviolet outer transparent barrier of isolation.
temperature induced color changing agentfor FeCl
3with the complex compound of tea-polyphenol mol ratio 1:3, when the content of iron trichloride and 3 moles of tea-polyphenol complex compounds is below 2%, room temperature is aobvious slightly light blue, and show as slight pink when temperature is increased to more than 60 DEG C when shining upon lower body of wall to dark brown, color can the inversion with gradient of temperature.
dispersion agentnothing, due to tertiary butyl ferrocene and iron trichloride tea-polyphenol complex compound, the self-dispersing in waterproof membrane-forming agent and thinner is good, without the need to adding extra dispersion agent.
thinnerfor raw spirit, be suitable for artificial brushing and mechanically spraying.
Preparation:
high-temperature pressure-reduction dewaters: composition A, temperature induced color changing agent are dropped in the reactor of band heating jacket, 80-120 DEG C is warming up under stirring, vacuumize and make the pressure in reactor be reduced to-0.09MPa, make raw material bring that moisture content drops to added material total amount by weight into less than 0.10%;
addition is pre- poly-: after high-temperature pressure-reduction dehydrating step completes, pass into the air through super-dry, keep 0.01MPa malleation to isolate the air of extraneous moisture content.Material is cooled to 35-60 DEG C, drops into composition B, UV-screens and thinner, in 35-60 DEG C of insulation 3 hours, finally add thinner, cool to room temperature, obtain product.
Wherein addition prepolymerization reaction formula is as follows:
second group (embodiment 2.1-2.3)
Raw material:
waterproof membrane-forming agentmiddle composition A is two Amino End Group dimethyl polysiloxane (trade name KF-8010) composition B is isoflurane chalcone diisocyanate (trade name IPDI, as the agent of end envelope).
uV-screensfor transparent nano titanium dioxide, median size D50 is between 20-50nm.
temperature causes colour-changing agentfor the eutectic of red mercury iodide Silver iodide, eutectiferous median size D50 is between 20-50nm, and it reversibly becomes slight light red when exterior wall is temperature 45-50 DEG C from slight yellowish.
dispersion agentfor stearic acid, it can impel transparent nano titanium dioxide and red mercury iodide Silver iodide eutectic good distribution.
thinnerfor toluene, finished product viscosity 10-30mPa.s, is suitable for artificial brushing and mechanically spraying.
Preparation:
high-temperature pressure-reduction dewaterscomposition A, UV-screens, temperature induced color changing agent, dispersion agent are put in the reactor of band heating jacket and high-shear decollator, under high-shear is stirred, material is warmed up to 80-120 DEG C, vacuumize and make the pressure in reactor be reduced to-0.09MPa, make raw material bring that moisture content is down to added material total amount by weight into less than 0.10%;
addition pre-polymerization, after high-temperature pressure-reduction dehydrating step completes, pass into the air through super-dry, keep 0.01MPa malleation to isolate the air of extraneous moisture content.Material is cooled to 35-65 DEG C, and drops into composition B, between 25-45 DEG C, be incubated 3 hours, finally add thinner, cool to room temperature, obtain product.
Wherein, addition prepolymerization reaction formula is as follows:
3rd group (embodiment 3.1-3.3)
Raw material:
waterproof membrane-forming agentmiddle composition A is two Amino Terminated polyether(ATPE)s (trade name PEA, molecular weight 2000), and composition B is γ-glycidyl ether oxygen propyl trimethoxy silicane (trade name A-187, as the agent of end envelope).
uV-screensfor yellow or red or green transparent nanometer ferric oxide.
temperature cause colour-changing agentnothing, because yellow or red or green transparent nanometer ferric oxide and organic amine dispersion agent have certain complexing, sunlit high temperature body of wall has slight reversible color, without the need to additionally adding temperature induced color changing agent.
dispersion agentfor the monoalkylamine of carbonatoms C18, itself and the complexing of nanometer ferric oxide have slight reversible color.
thinnerfor ethyl acetate, finished product viscosity 10-30mPa.s, is suitable for artificial brushing and mechanically spraying.
Preparation:
high-temperature pressure-reduction dewaters: composition A, UV-screens, dispersion agent are put in the reactor of band heating jacket, while stirring material is warmed up to 100-120 DEG C, vacuumize, make the pressure in reactor be reduced to-0.09MPa, make raw material bring that moisture content drops to added material total amount by weight into less than 0.05%;
addition pre-polymerization: after high-temperature pressure-reduction dehydrating step completes, material is cooled to 50-60 DEG C, and the air passed into through super-dry keeps 0.01MPa malleation, to isolate the air of extraneous moisture content, drop into composition B, between 45-50 DEG C, be incubated 3 hours, finally add thinner, cool to room temperature, obtain product.
Wherein, addition prepolymerization reaction formula is as follows:
4th group (embodiment 4.1-4.3)
Raw material:
waterproof membrane-forming agentmiddle composition A is two carboxy terminated polybutadiene vinyl cyanide fluid rubbers (trade name CTBN), and composition B is hexamethylene diisocyanate (trade name HDI, as the agent of end envelope).
uV-screensfor transparent nano cerium dioxide, median size D50 is between 20-50nm.
temperature induced color changing agentfor cobalt dichloride, it at room temperature absorbs moisture pinkiness, and under summer sunlight during exterior wall temperatures as high 45-60 DEG C, coating dries out and reversibly becomes blueness.
dispersion agentfor the mixture of sylvic acid and C18 alkanol (respectively can be 0.11% and 0.11%, 0.44% and 0.44%, 0.8% and 0.8% for embodiment 4.1,4.2 and 4.3 concentration).
thinnerfor heptane, finished product viscosity 10-30mPa.s, is suitable for artificial brushing and mechanically spraying.
Preparation:
high-temperature pressure-reduction dewaters: by composition A, UV-screens, temperature induced color changing agent, dispersion agent are put in the reactor of band heating jacket and high-shear decollator, under high-shear is stirred, material is warmed up to 80-120 DEG C, vacuumize, make the pressure in reactor be reduced to-0.09MPa, make raw material bring that moisture content drops to added material total amount by weight into less than 0.10%;
addition pre-polymerization: after high-temperature pressure-reduction dehydrating step completes, material is cooled to 35-45 DEG C, and the air be filled with through super-dry keeps 0.01MPa malleation, to isolate the air of extraneous moisture content, drop into composition B and thinner, between 25-45 DEG C, be incubated 3 hours in temperature, cool to room temperature, obtain mono component wet solidifying waterproof protective and temperature induced color changing coating.
Wherein, addition prepolymerization reaction formula is as follows:
In other embodiments, addition prepolymerization reaction formula can also be:
or
Those skilled in the art can accurately know concrete material composition and chemical reaction mechanism thereof according to formula provided by the present invention, trade name or chemical name, and therefore the film-forming principle of final finished repeats no more.
Mono component wet solidifying waterproof protective and temperature induced color changing coating that above four groups of embodiments obtain is summarized with the proportioning raw materials of parts by weight in following table 1.
Table 1: mono component wet solidifying waterproof protective and temperature induced color changing coating are with the proportioning raw materials of parts by weight
effect test
Waterproof protective ability test method reference: standard GB/T19250.
Tensile strength and elongation at break transformation period test method adopt: standard UL746A, UL746B, UL746C.
UV-light isolation rate test method adopts: standard A STMD2008.
Warm colour effect test method: sheet specimens coating being made 30 × 30 × 0.25mm, reference standard GB/T4121, test temperature is revised as-20 ,-5,10,25,40,55,70,85 DEG C respectively, spectrophotometric wavelength plate is adjusted to respectively the characteristic wavelength that naked eyes sensitivity identifies, be changed to mark with the transmitance ratio of the characteristic wavelength of 25 DEG C, the absolute value of ratio change be greater than 5% for slight, be greater than 15% for obviously, to be greater than 33% be remarkable.
Mono component wet solidifying waterproof protective and the temperature induced color changing coating effect experimental data of the acquisition of each embodiment is summarized in following table 2.
Table 2: waterproof protective and temperature induced color changing experimental data
Test-results from table 2, mono component wet solidifying waterproof protective prepared by the present invention and temperature induced color changing coating have excellent waterproof protective performance, meet the Eligibility requirements of GB/T19250, tensile strength and elongation at break transformation period are all more than 8 years, ultraviolet isolation rate is greater than 86%, and temperature induced color changing effect can be produced, meet the requirement of practical engineering application.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. mono component wet solidifying waterproof protective and a temperature induced color changing coating, is characterized in that, comprises the following component counted by weight: waterproof membrane-forming agent 100 parts; UV-screens 0.5-25 part; Temperature induced color changing agent 0-15 part; Dispersion agent 0-3 part; Thinner 0-100 part.
2. mono component wet solidifying waterproof protective according to claim 1 and temperature induced color changing coating, is characterized in that, described waterproof membrane-forming agent is composition A and composition B mol ratio (0.8-1.2): the addition reaction product of (1.8-2.2), wherein
Described composition A is multiterminal amino silicones, multiterminal amino-polyether, multiterminal carboxy terminatedpolybutadiene vinyl cyanide fluid rubber, or the mixture of at least two kinds in them;
Described composition B is the agent of epoxy ether alkylene organoalkoxysilane end envelope, the agent of polyisocyanates end envelope, or their mixture.
3. mono component wet solidifying waterproof protective according to claim 2 and temperature induced color changing coating, is characterized in that,
Described multiterminal amino silicones has following structure:
Wherein, k>=1, R
2for hydrocarbon support, penylene, replacement penylene, aromatic ring support, replace aromatic ring support, heterocycle support or substituted heterocycle support; R
3, R
4, R
5, R
6be respectively alkyl, phenyl, substituted-phenyl, aromatic ring yl, replacement aromatic ring yl, heterocyclic radical or substituted heterocyclic radical;
Described multiterminal amino-polyether has following structure:
Wherein, n >=1.
4. the mono component wet solidifying waterproof protective according to Claims 2 or 3 and temperature induced color changing coating, it is characterized in that, number-average molecular weight or the viscosity-average molecular weight of described multiterminal amino silicones, described multiterminal amino-polyether or described multiterminal carboxy terminatedpolybutadiene vinyl cyanide fluid rubber are 300-3000.
5. mono component wet solidifying waterproof protective according to claim 2 and temperature induced color changing coating, is characterized in that,
The agent of described epoxy ether alkylene organoalkoxysilane end envelope has following structure:
Wherein, m>=0, n>=1, and R
1for methyl or ethyl;
Described polyisocyanates end envelope agent has following structure:
OCN-R
7-NCO
Wherein, R
7for hydrocarbon support, penylene, replacement penylene, aromatic ring support, replace aromatic ring support, heterocycle support or substituted heterocycle support.
6. mono component wet solidifying waterproof protective according to claim 1 and temperature induced color changing coating, it is characterized in that, described UV-screens is metallocene, alkyl metallocene, nano transition element oxide, nano rare earth element oxide, or the mixture of at least two kinds or eutectic in them.
7. mono component wet solidifying waterproof protective according to claim 6 and temperature induced color changing coating, is characterized in that,
Described metallocene is ferrocene, dicyclopentadienylcobalt, nickelocene, or the mixture of at least two kinds in them;
Described alkyl metallocene is containing the ferrocene of 1-3 the tertiary butyl, containing the dicyclopentadienylcobalt of 1-3 the tertiary butyl, the nickelocene containing 1-3 the tertiary butyl, or the mixture of at least two kinds in them;
The median size D50 of described nano transition element oxide is 2-100nm, and is yttrium oxide, vanadium oxide, titanium oxide, ferric oxide, cobalt oxide, nickel oxide, cupric oxide, zinc oxide, or the mixture of at least two kinds or eutectic in them;
The median size D50 of described nano rare earth element oxide is 2-100nm, and is mixture or the eutectic of a kind of in group of the lanthanides or actinide elements oxide compound or at least two kinds.
8. mono component wet solidifying waterproof protective according to claim 1 and temperature induced color changing coating, is characterized in that,
Described temperature induced color changing agent is the mixture of a kind of in the complex compound of Transitional element halide and xenogenesis halogenide eutectic thereof or sulfide and xenogenesis sulfide eutectic thereof, the complex compound of Transitional element halide or sulfide and oxy-compound, Transitional element halide or sulfide and amino-complex or at least two kinds;
Described dispersion agent is C
8-C
36kiber alkyl amine, C
8-C
36alkyl secondary amine, C
8-C
36alkyl alcohol, C
8-C
36carboxylic acid in a kind of or mixture of at least two kinds;
Described thinner is C
2-C
4primary alconol, C
2-C
4secondary alcohol, C
6-C
19alkane, benzene, substituted benzene, aromatic ring, replacement aromatic ring, heterocyclic hydrocarbon, a kind of in substituted heterocycle hydrocarbon or at least two kinds mixture.
9. mono component wet solidifying waterproof protective according to claim 8 and temperature induced color changing coating, is characterized in that,
Described oxy-compound has following structure:
Wherein, s is the integer of>=1; T is the integer of>=1; P+q is the integer of>=1; R
7, R
8for hydrocarbon support, penylene, replacement penylene, aromatic ring support, replace aromatic ring support, heterocycle support or substituted heterocycle support;
Described amino-complex has following structure:
Wherein, s is the integer of>=1; T is the integer of>=1; P+q is the integer of>=1; R
7, R
8for hydrocarbon support, penylene, replacement penylene, aromatic ring support, replace aromatic ring support, heterocycle support or substituted heterocycle support;
Described transition element is yttrium, vanadium, titanium, iron, cobalt, nickel or copper;
Described Transitional element halide is transition element muriate, transition element bromide or transition element iodide.
10., for the preparation of a method for the mono component wet solidifying waterproof protective according to any one of claim 1-9 and temperature induced color changing coating, it is characterized in that, comprise step:
High-temperature pressure-reduction dewaters: make composition A, UV-screens, temperature induced color changing agent mixing, is down to below the 0.1wt% of raw material total amount, obtains dewatered product the high-temperature pressure-reduction dehydration of 50-180 DEG C to moisture content;
Addition pre-polymerization: under protective gas exists, in 25-120 DEG C, composition B, dispersion agent and thinner are mixed with dewatered product, and carries out addition pre-polymerization, obtain mono component wet solidifying waterproof protective and temperature induced color changing coating,
Wherein the mol ratio of composition A and composition B is (0.8-1.2): (1.8-2.2).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510613376.4A CN105111911A (en) | 2015-09-23 | 2015-09-23 | Single-component moisture-curable waterproof, protective and thermochromic coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510613376.4A CN105111911A (en) | 2015-09-23 | 2015-09-23 | Single-component moisture-curable waterproof, protective and thermochromic coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105111911A true CN105111911A (en) | 2015-12-02 |
Family
ID=54660035
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510613376.4A Pending CN105111911A (en) | 2015-09-23 | 2015-09-23 | Single-component moisture-curable waterproof, protective and thermochromic coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105111911A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109880576A (en) * | 2019-01-24 | 2019-06-14 | 深圳市锦昊辉矿业发展有限公司 | Single-component moisture curing polyurethane ceramic sealant |
| CN109880571A (en) * | 2019-01-24 | 2019-06-14 | 深圳市锦昊辉矿业发展有限公司 | Bi-component curable polyurethane ceramic sealant |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101531861A (en) * | 2009-04-17 | 2009-09-16 | 苏州中材非金属矿工业设计研究院有限公司 | Two component spray polyurea waterproof paint and preparation method and construction method of same |
| CN101608094A (en) * | 2008-06-18 | 2009-12-23 | 中冶集团建筑研究总院 | A kind of bicomponent high-strength sprayed polyurethane waterproof paint |
| CN103602249A (en) * | 2013-11-19 | 2014-02-26 | 青岛广联达精密机械有限公司 | Environmental-friendly waterproof coating material |
| CN103819647A (en) * | 2014-03-06 | 2014-05-28 | 河北宇阳泽丽防水材料有限公司 | Moisture-curable one-component exposure-type polyurethane |
-
2015
- 2015-09-23 CN CN201510613376.4A patent/CN105111911A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101608094A (en) * | 2008-06-18 | 2009-12-23 | 中冶集团建筑研究总院 | A kind of bicomponent high-strength sprayed polyurethane waterproof paint |
| CN101531861A (en) * | 2009-04-17 | 2009-09-16 | 苏州中材非金属矿工业设计研究院有限公司 | Two component spray polyurea waterproof paint and preparation method and construction method of same |
| CN103602249A (en) * | 2013-11-19 | 2014-02-26 | 青岛广联达精密机械有限公司 | Environmental-friendly waterproof coating material |
| CN103819647A (en) * | 2014-03-06 | 2014-05-28 | 河北宇阳泽丽防水材料有限公司 | Moisture-curable one-component exposure-type polyurethane |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109880576A (en) * | 2019-01-24 | 2019-06-14 | 深圳市锦昊辉矿业发展有限公司 | Single-component moisture curing polyurethane ceramic sealant |
| CN109880571A (en) * | 2019-01-24 | 2019-06-14 | 深圳市锦昊辉矿业发展有限公司 | Bi-component curable polyurethane ceramic sealant |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105131789A (en) | Cured type waterproof protective and thermochromic paint and preparation method thereof | |
| WO2018045622A1 (en) | Micro powder-reinforced, polyurethane-based, high-strength, waterproof, thermal-insulation decorative integrated material and preparation method therefor | |
| CN102690536B (en) | A kind of environmental-friendly ceramic paint for building aluminum curtain walls and preparation method thereof | |
| CN101775217B (en) | Room-temperature vulcanized organic polyorganosiloxane composition and preparation method | |
| CN102127344A (en) | Waterproof primer for buildings | |
| CN101993576B (en) | Resin emulsion for hydrophobic cathode electrophoretic coating as well as preparation method and application thereof | |
| CN102617104B (en) | Inorganic powder sandy paint and production method thereof | |
| CN102816551A (en) | Ultraviolet (UV)-moisture double-curing liquid optical transparent adhesive and preparation method thereof | |
| CN105601166A (en) | Stone-like coating resisting temperature variation construction and preparation method thereof | |
| CN103450767A (en) | Super-weather-resistant anti-fouling real stone paint | |
| CN102391778B (en) | Colored transparent heat insulation glass coating and preparation method thereof | |
| CN103468082A (en) | Nanometer anti pollution self-cleaning stone paint | |
| CN104559759A (en) | Antistatic transparent wear-resistant paint and preparation method thereof | |
| CN103740177A (en) | Development of super weather-proof marble coating rock slice paint | |
| CN102786850A (en) | Seawater-resistant anticorrosive paint and preparation method of seawater-resistant anticorrosive paint | |
| CN104995281A (en) | Photochromic curable composition | |
| CN102745966B (en) | Anti-cracking color retention VOC-free (Volatile Organic Compounds) and zero-alkali-return aqueous dry powder building colored coating | |
| CN105111911A (en) | Single-component moisture-curable waterproof, protective and thermochromic coating and preparation method thereof | |
| CN110698930A (en) | Long-acting high-weather-resistance self-cleaning water-based multicolor paint and preparation method thereof | |
| CN110183965A (en) | A kind of preparation method of novel aqueous organic silicon stone protective agent | |
| CN109575781A (en) | A kind of structure type polyurethane flame-proof antibiotic coating | |
| CN103396722B (en) | Fluorine-alcohol modified epoxypaint of a kind of water-based UV-curable and preparation method thereof | |
| CN107629683A (en) | A kind of acid-proof alkali prevention corrosion-resistant high-temperature coating easy to clean and preparation method thereof | |
| CN1328344C (en) | Colored heat insulation anti soak coating material | |
| CN106957600A (en) | A kind of clear aqueous insulating moulding coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| AD01 | Patent right deemed abandoned |
Effective date of abandoning: 20180914 |
|
| AD01 | Patent right deemed abandoned |