CN104356915B - A kind of fire-retardant preparation method with water proofing property aqueous polyurethane coating - Google Patents
A kind of fire-retardant preparation method with water proofing property aqueous polyurethane coating Download PDFInfo
- Publication number
- CN104356915B CN104356915B CN201410703140.5A CN201410703140A CN104356915B CN 104356915 B CN104356915 B CN 104356915B CN 201410703140 A CN201410703140 A CN 201410703140A CN 104356915 B CN104356915 B CN 104356915B
- Authority
- CN
- China
- Prior art keywords
- fire
- retardant
- proofing property
- add
- water proofing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 42
- 239000011527 polyurethane coating Substances 0.000 title claims abstract description 35
- 238000004078 waterproofing Methods 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims abstract description 48
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 claims abstract description 42
- 238000006243 chemical reaction Methods 0.000 claims abstract description 33
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000005058 Isophorone diisocyanate Substances 0.000 claims abstract description 15
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims abstract description 15
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 10
- 229920002635 polyurethane Polymers 0.000 claims description 16
- 239000004814 polyurethane Substances 0.000 claims description 16
- 230000001804 emulsifying effect Effects 0.000 claims description 13
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- -1 Adenosine cyclic monophosphate ester Chemical class 0.000 claims description 11
- FPGGTKZVZWFYPV-UHFFFAOYSA-M tetrabutylammonium fluoride Chemical compound [F-].CCCC[N+](CCCC)(CCCC)CCCC FPGGTKZVZWFYPV-UHFFFAOYSA-M 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- PYTMYKVIJXPNBD-OQKDUQJOSA-N 2-[4-[(z)-2-chloro-1,2-diphenylethenyl]phenoxy]-n,n-diethylethanamine;hydron;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O.C1=CC(OCCN(CC)CC)=CC=C1C(\C=1C=CC=CC=1)=C(/Cl)C1=CC=CC=C1 PYTMYKVIJXPNBD-OQKDUQJOSA-N 0.000 claims description 5
- ROQRAMYLVSOQHK-UHFFFAOYSA-N C(CC)N.[Br] Chemical compound C(CC)N.[Br] ROQRAMYLVSOQHK-UHFFFAOYSA-N 0.000 claims description 5
- XJLXINKUBYWONI-NNYOXOHSSA-N NADP zwitterion Chemical compound NC(=O)C1=CC=C[N+]([C@H]2[C@@H]([C@H](O)[C@@H](COP([O-])(=O)OP(O)(=O)OC[C@@H]3[C@H]([C@@H](OP(O)(O)=O)[C@@H](O3)N3C4=NC=NC(N)=C4N=C3)O)O2)O)=C1 XJLXINKUBYWONI-NNYOXOHSSA-N 0.000 claims description 5
- HZUKSQHMCTUZJL-UHFFFAOYSA-N P(=O)(O)(O)OCC=1C(=C(C(=NC1)C)O)C=O.P(=O)(O)(O)OC=1C(=NC=C(C1C=O)CO)C Chemical compound P(=O)(O)(O)OCC=1C(=C(C(=NC1)C)O)C=O.P(=O)(O)(O)OC=1C(=NC=C(C1C=O)CO)C HZUKSQHMCTUZJL-UHFFFAOYSA-N 0.000 claims description 5
- FOCVUCIESVLUNU-UHFFFAOYSA-N Thiotepa Chemical compound C1CN1P(N1CC1)(=S)N1CC1 FOCVUCIESVLUNU-UHFFFAOYSA-N 0.000 claims description 5
- KFSZGBHNIHLIAA-UHFFFAOYSA-M benzyl(trimethyl)azanium;fluoride Chemical compound [F-].C[N+](C)(C)CC1=CC=CC=C1 KFSZGBHNIHLIAA-UHFFFAOYSA-M 0.000 claims description 5
- ZPEIMTDSQAKGNT-UHFFFAOYSA-N chlorpromazine Chemical compound C1=C(Cl)C=C2N(CCCN(C)C)C3=CC=CC=C3SC2=C1 ZPEIMTDSQAKGNT-UHFFFAOYSA-N 0.000 claims description 5
- 229960001076 chlorpromazine Drugs 0.000 claims description 5
- 229940046989 clomiphene citrate Drugs 0.000 claims description 5
- RJMUSRYZPJIFPJ-UHFFFAOYSA-N niclosamide Chemical compound OC1=CC=C(Cl)C=C1C(=O)NC1=CC=C([N+]([O-])=O)C=C1Cl RJMUSRYZPJIFPJ-UHFFFAOYSA-N 0.000 claims description 5
- VENBJVSTINLYEU-UHFFFAOYSA-N phenol;trifluoroborane Chemical compound FB(F)F.OC1=CC=CC=C1 VENBJVSTINLYEU-UHFFFAOYSA-N 0.000 claims description 5
- 108090000765 processed proteins & peptides Proteins 0.000 claims description 5
- YLXIPWWIOISBDD-NDAAPVSOSA-N (2r,3r)-2,3-dihydroxybutanedioic acid;4-[(1r)-1-hydroxy-2-(methylamino)ethyl]benzene-1,2-diol Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O.CNC[C@H](O)C1=CC=C(O)C(O)=C1 YLXIPWWIOISBDD-NDAAPVSOSA-N 0.000 claims description 4
- TVZGACDUOSZQKY-LBPRGKRZSA-N 4-aminofolic acid Chemical compound C1=NC2=NC(N)=NC(N)=C2N=C1CNC1=CC=C(C(=O)N[C@@H](CCC(O)=O)C(O)=O)C=C1 TVZGACDUOSZQKY-LBPRGKRZSA-N 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 229960003896 aminopterin Drugs 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- OLLFKUHHDPMQFR-UHFFFAOYSA-N dihydroxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](O)(O)C1=CC=CC=C1 OLLFKUHHDPMQFR-UHFFFAOYSA-N 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical group CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims description 4
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 239000003973 paint Substances 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 2
- RZYKUPXRYIOEME-UHFFFAOYSA-N CCCCCCCCCCCC[S] Chemical compound CCCCCCCCCCCC[S] RZYKUPXRYIOEME-UHFFFAOYSA-N 0.000 claims 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N n-propyl alcohol Natural products CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 7
- 230000001070 adhesive effect Effects 0.000 abstract description 7
- 239000004970 Chain extender Substances 0.000 abstract description 3
- 239000011521 glass Substances 0.000 abstract description 3
- 150000002440 hydroxy compounds Chemical class 0.000 abstract description 3
- 238000009941 weaving Methods 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 abstract 1
- 239000000779 smoke Substances 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 7
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000010985 leather Substances 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- XENVCRGQTABGKY-ZHACJKMWSA-N chlorohydrin Chemical compound CC#CC#CC#CC#C\C=C\C(Cl)CO XENVCRGQTABGKY-ZHACJKMWSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- GATNOFPXSDHULC-UHFFFAOYSA-N ethylphosphonic acid Chemical compound CCP(O)(O)=O GATNOFPXSDHULC-UHFFFAOYSA-N 0.000 description 2
- YRXICXUINRGLJP-UHFFFAOYSA-N hydroxy(dimethyl)silicon Chemical compound C[Si](C)O YRXICXUINRGLJP-UHFFFAOYSA-N 0.000 description 2
- ZJBHFQKJEBGFNL-UHFFFAOYSA-N methylsilanetriol Chemical compound C[Si](O)(O)O ZJBHFQKJEBGFNL-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- DDSBPUYZPWNNGH-UHFFFAOYSA-N 6-n-[(4-nitrophenyl)methyl]-2-n-[[3-(trifluoromethyl)phenyl]methyl]-7h-purine-2,6-diamine Chemical compound C1=CC([N+](=O)[O-])=CC=C1CNC1=NC(NCC=2C=C(C=CC=2)C(F)(F)F)=NC2=C1NC=N2 DDSBPUYZPWNNGH-UHFFFAOYSA-N 0.000 description 1
- 229910015900 BF3 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 229960001931 ampicillin sodium Drugs 0.000 description 1
- KLOHDWPABZXLGI-YWUHCJSESA-M ampicillin sodium Chemical compound [Na+].C1([C@@H](N)C(=O)N[C@H]2[C@H]3SC([C@@H](N3C2=O)C([O-])=O)(C)C)=CC=CC=C1 KLOHDWPABZXLGI-YWUHCJSESA-M 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 1
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 1
- MZJUGRUTVANEDW-UHFFFAOYSA-N bromine fluoride Chemical compound BrF MZJUGRUTVANEDW-UHFFFAOYSA-N 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/166—Catalysts not provided for in the groups C08G18/18 - C08G18/26
- C08G18/168—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3228—Polyamines acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3246—Polyamines heterocyclic, the heteroatom being oxygen or nitrogen in the form of an amino group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3802—Low-molecular-weight compounds having heteroatoms other than oxygen having halogens
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3878—Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus
- C08G18/3882—Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus having phosphorus bound to oxygen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3878—Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus
- C08G18/3889—Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus having nitrogen in addition to phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3893—Low-molecular-weight compounds having heteroatoms other than oxygen containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/19—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
Abstract
The invention discloses a kind of fire-retardant preparation method with water proofing property aqueous polyurethane coating with adhesive, under conditions of TMAH exists, mixed with IPDI by anti-flammability hydroxy compounds, reaction obtains base polyurethane prepolymer for use as A；Chain extender is added to base polyurethane prepolymer for use as A, reaction 3 ~ 4h, add triethylamine again and be neutralized reaction, add water and dodecyl sodium sulfate emulsifies, obtain fire-retardant and water proofing property aqueous polyurethane coating and adhesive, prepared fire-retardant and waterproof polyurethane coating and adhesive environmental protection, cheap, it is widely used in body of wall, furniture, ironware surface, as plastics, glass, papermaking, the adhesive of weaving.
Description
Technical field
The present invention relates to the preparation method of polyurethane coating, particularly to fire-retardant and water proofing property aqueous polyurethane coating system
Preparation Method.
Background technology
Waterproof material main application fields includes the roofing of building construction, underground, exterior wall and indoor；Urban road bridges and
The municipal works such as the underground space；Highway and the bridge of high-speed railway, tunnel；The traffic engineering such as underground railway；Flume, water
The hydraulic engineerings such as storehouse, dam body, natural flow station and water process, it is adaptable to roofing and toilet bath room, basement, cistern, metope
Waterproof, antiseepage, protection against the tide.Fields such as can be used for papermaking, weaving, leather is divided according to application material.
Polyurethane carries out synthesizing and makees catalyst frequently with dibutyl tin laurate, but owing to Heavy Metal, Sn is along with poly-ammonia
The degraded of ester and environment is worked the mischief, the catalyst of screening high effect nontoxic is a great problem in polyurethane synthesis.
TMAH is a kind of environment friendly and pollution-free catalyst, and it can resolve into ammonia and water at 130 DEG C, as
Fruit applies some chemical materials, reduces its decomposition temperature, then in the polyurethane system generated, catalyst decomposes, and reduces and urges
The agent harm to environment.
Aqueous polyurethane (also known as water-based polyurethane) is a kind of poly-containing hydrophilic radical in the strand of polyurethane
Urethane resin, has the strongest compatibility with water, uses specific technique can be allowed to disperse and formed stable system in water.
Aqueous polyurethane is mainly used in the aspects such as leather finish, textile printing and dyeing, paper-making industry, building coating, adhesive, steel moulder's paint,
Involved is nearly all combustible material, and these materials as the most fire retardant treated, necessarily become the peace of initiation fire in use
Full hidden danger.Aqueous polyurethane flame-retarded, is one of the important directions of aqueous polyurethane functionalization.
Summary of the invention
The technical problem to be solved is to provide a kind of fire-retardant preparation side with water proofing property aqueous polyurethane coating
Method, selects TMAH to react as catalyst, anti-flammability hydroxy compounds and IPDI, fire-retardant
The clomiphene citrate of property, nicotinamide adenine dinucleotide phosphate, phosphopyridoxal pyridoxal phosphate, aminopterin, 5'-atriphos
For chain extender, bromine propylamine peptide woods, chlorpromazine, niclosamidum, centrofenoxine and triethylene thiophosphoramide neutralize and play fire-retardant
Effect, makes the boiling point of the TMAH of residual reduce and have neutralization simultaneously, boron trifluoride phenol network and thing, five
Bromine fluoride, tetrabutyl ammonium fluoride, benzyl trimethyl ammonium fluoride and BFEE, as waterproofing agent and fire retardant, make polyurethane
Anti-flammability increase substantially.
A kind of fire-retardant preparation method with water proofing property aqueous polyurethane coating, it is characterised in that:
(1) with agitator, condenser pipe, thermometer 500ml there-necked flask in add 3-aminopropyl ortho-siliformic acid
60g, IPDI 84g and TMAH 0.18g, react 1h at 70 DEG C, obtain polyurethane prepolymer
Body A is 144g；
(2) in base polyurethane prepolymer for use as A, clomiphene citrate 1.14g and Adenosine cyclic monophosphate ester 10.7g is added, in 60 DEG C of bars
React 3h under part, add triethylamine 14.2g and bromine propylamine peptide woods 0.6g and be neutralized reaction 30min, add BFEE
4.1g, carries out emulsifying 60min in 70 DEG C of reactions 1h, the 80g and dodecyl sodium sulfate 0.28g that adds water, obtains fire-retardant and water proofing property water
Property polyurethane coating.
A kind of fire-retardant preparation method with water proofing property aqueous polyurethane coating, it is characterised in that:
(1) with agitator, condenser pipe, thermometer 500ml there-necked flask in add Diphenylsilanediol 60g,
IPDI 84g and TMAH 0.72g, reacts 3h at 80 DEG C, and obtaining base polyurethane prepolymer for use as A is
144g；
(2) in base polyurethane prepolymer for use as A, nicotinamide adenine dinucleotide phosphate 4.07g, methyl trihydroxy silicon are added
Alkane 4.07g and tricresyl phosphate (2,3-bis-chloropropyl) ester 58g, reacts 4h under the conditions of 80 DEG C, adds triethylamine 20.7g and chlorpromazine
5.2g is neutralized reaction 60min, adds benzyl trimethyl ammonium fluoride 2.38g, reacts 1h in 70 DEG C, and add water 100g and 12
Sodium alkyl sulfonate 0.58g carries out emulsifying 60min, obtains fire-retardant and water proofing property aqueous polyurethane coating.
A kind of fire-retardant preparation method with water proofing property aqueous polyurethane coating, it is characterised in that:
(1) with agitator, condenser pipe, thermometer 500ml there-necked flask in add double (the dimethyl hydroxyl silicon of 4,4'-
Base) diphenyl ether 80g, IPDI 84g and TMAH 0.27g, react 3h at 75 DEG C, gathered
Urethane performed polymer A is 164g；
(2) in base polyurethane prepolymer for use as A, the chloro-1-of phosphopyridoxal pyridoxal phosphate 5.7g and 2-(2,4 dichloro benzene base) vinyl two is added
Ethyl phosphonic acid ester 35g, reacts 3.5h under the conditions of 70 DEG C, adds triethylamine 17.4g and niclosamidum 2.1g and is neutralized reaction
45min, adds tetrabutyl ammonium fluoride 2.7g, emulsifies in 70 DEG C of reactions 1h, the 110g and dodecyl sodium sulfate 0.43g that adds water
60min, obtains fire-retardant and water proofing property aqueous polyurethane coating.
A kind of fire-retardant preparation method with water proofing property aqueous polyurethane coating, it is characterised in that:
(3) with agitator, condenser pipe, temperature 500ml there-necked flask in add 1,4-double (dimethyl hydroxyl is silica-based)
Benzene 60g, IPDI 84g and TMAH 0.19g, react 1h at 70 DEG C, obtain polyurethane pre-
Aggressiveness A is 144g；
(4) in base polyurethane prepolymer for use as A, aminopterin 1.17g and Adenosine cyclic monophosphate ester 10.7g is added, under the conditions of 60 DEG C
Reaction 3h, adds triethylamine 7.1g and centrofenoxine 3.1g and is neutralized reaction 30min, add BPF 1.7g, in 70 DEG C
Reaction 1h, the 80g and dodecyl sodium sulfate 0.14g that adds water carry out emulsifying 60min, obtain fire-retardant and water proofing property aqueous polyurethane painting
Material.
A kind of fire-retardant preparation method with water proofing property aqueous polyurethane coating, it is characterised in that:
(1) with agitator, condenser pipe, temperature 500ml there-necked flask in add Adrenaline Tartrate 30g, different Buddhist
You are ketone diisocyanate 84g and TMAH 0.36g, reacts 5h at 80 DEG C, and obtaining base polyurethane prepolymer for use as A is
115g；
(2) in base polyurethane prepolymer for use as A, 5'-atriphos 2.07g, methyl ortho-siliformic acid 2.07g and 2,3-are added
Two trimethylewne chlorohydrin 3-phosphate 29g, react 4h under the conditions of 80 DEG C, add triethylamine 20.7g and triethylene thiophosphoramide
1.2g is neutralized reaction 60min, adds boron trifluoride phenol network and thing 2.38g, reacts 1h in 70 DEG C, and add water 100g and 12
Sodium alkyl sulfonate 1.28g carries out emulsifying 60min, reaction temperature 40 DEG C, reaction time 1h, obtains fire-retardant and water proofing property aqueous polyurethane
Coating.
The invention have the characteristics that:
(1) the 3-aminopropyl ortho-siliformic acid of anti-flammability hydroxy compounds, diphenyl dihydroxy silicon in base polyurethane prepolymer for use as
Double (dimethyl hydroxyl the is silica-based) benzene of double (dimethyl hydroxyl the is silica-based) diphenyl ether of alkane, 4,4'-, 1,4-, Adrenaline Tartrate and different
Isophorone diisocyanate reacts, and makes performed polymer also have anti-flammability；
(2) TMAH is a kind of environment friendly and pollution-free catalyst, its under the effect of follow-up synergist low
Resolve into ammonia and water in 70 DEG C, polyurethane system exists without catalyst, reduces dibutyl tin laurate and environment is made
The harm become.
(3) clomiphene citrate of anti-flammability, nicotinamide adenine dinucleotide phosphate, phosphopyridoxal pyridoxal phosphate, amino butterfly
Purine, 5'-atriphos are chain extender, improve fire resistance；
(4) in selecting bromine propylamine peptide woods, chlorpromazine, niclosamidum, centrofenoxine and triethylene thiophosphoramide both to have
With effect and play flame retardant effect, make the boiling point that also can make the TMAH of residual reduce, below 70 DEG C just simultaneously
Volatilizable；
(5) boron trifluoride phenol network and thing, BPF, tetrabutyl ammonium fluoride, benzyl trimethyl ammonium fluoride and three are selected
Boron fluoride ether, as waterproofing agent and fire retardant, makes the anti-flammability of polyurethane increase substantially.
Detailed description of the invention further illustrates the present invention below in conjunction with example.
Example one
(1) with agitator, condenser pipe, thermometer 500ml there-necked flask in add 3-aminopropyl ortho-siliformic acid
60g, IPDI 84g and TMAH 0.18g, react 1h at 70 DEG C, obtain polyurethane prepolymer
Body A is 144g；
(2) in base polyurethane prepolymer for use as A, clomiphene citrate 1.14g and Adenosine cyclic monophosphate ester 10.7g is added, in 60 DEG C of bars
React 3h under part, add triethylamine 14.2g and bromine propylamine peptide woods 0.6g and be neutralized reaction 30min, add BFEE
4.1g, carries out emulsifying 60min in 70 DEG C of reactions 1h, the 80g and dodecyl sodium sulfate 0.28g that adds water, obtains fire-retardant and water proofing property water
Property polyurethane coating.
Example two
(1) with agitator, condenser pipe, thermometer 500ml there-necked flask in add Diphenylsilanediol 60g,
IPDI 84g and TMAH 0.72g, reacts 3h at 80 DEG C, and obtaining base polyurethane prepolymer for use as A is
144g；
(2) in base polyurethane prepolymer for use as A, nicotinamide adenine dinucleotide phosphate 4.07g, methyl trihydroxy silicon are added
Alkane 4.07g and tricresyl phosphate (2,3-bis-chloropropyl) ester 58g, reacts 4h under the conditions of 80 DEG C, adds triethylamine 20.7g and chlorpromazine
5.2g is neutralized reaction 60min, adds benzyl trimethyl ammonium fluoride 2.38g, reacts 1h in 70 DEG C, and add water 100g and 12
Sodium alkyl sulfonate 0.58g carries out emulsifying 60min, obtains fire-retardant and water proofing property aqueous polyurethane coating.
Example three
(1) with agitator, condenser pipe, thermometer 500ml there-necked flask in add double (the dimethyl hydroxyl silicon of 4,4'-
Base) diphenyl ether 80g, IPDI 84g and TMAH 0.27g, react 3h at 75 DEG C, gathered
Urethane performed polymer A is 164g；
(2) in base polyurethane prepolymer for use as A, the chloro-1-of phosphopyridoxal pyridoxal phosphate 5.7g and 2-(2,4 dichloro benzene base) vinyl two is added
Ethyl phosphonic acid ester 35g, reacts 3.5h under the conditions of 70 DEG C, adds triethylamine 17.4g and niclosamidum 2.1g and is neutralized reaction
45min, adds tetrabutyl ammonium fluoride 2.7g and R-BHC 2.1g, reacts 1h in 70 DEG C, and add water 110g and dodecyl sodium sulfonate
Sodium 0.43g carries out emulsifying 60min, obtains fire-retardant and water proofing property aqueous polyurethane coating.
Example four
(3) with agitator, condenser pipe, temperature 500ml there-necked flask in add 1,4-double (dimethyl hydroxyl is silica-based)
Benzene 60g, IPDI 84g and TMAH 0.19g, react 1h at 70 DEG C, obtain polyurethane pre-
Aggressiveness A is 144g；
(4) in base polyurethane prepolymer for use as A, aminopterin 1.17g and Adenosine cyclic monophosphate ester 10.7g is added, under the conditions of 60 DEG C
Reaction 3h, adds triethylamine 7.1g and centrofenoxine 3.1g and is neutralized reaction 30min, adds BPF 1.7g and hydrochloric acid ground
U.S. ring element 1.2g, carries out emulsifying 60min in 70 DEG C of reactions 1h, the 80g and dodecyl sodium sulfate 0.14g that adds water, and obtains fire-retardant and anti-
Aqueous polyurethane coating.
Example five
(1) with agitator, condenser pipe, temperature 500ml there-necked flask in add Adrenaline Tartrate 30g, different Buddhist
You are ketone diisocyanate 84g and TMAH 0.36g, reacts 5h at 80 DEG C, and obtaining base polyurethane prepolymer for use as A is
115g；
(2) in base polyurethane prepolymer for use as A, 5'-atriphos 2.07g, methyl ortho-siliformic acid 2.07g and 2,3-are added
Two trimethylewne chlorohydrin 3-phosphate 29g, react 4h under the conditions of 80 DEG C, add triethylamine 20.7g and triethylene thiophosphoramide
1.2g is neutralized reaction 60min, adds boron trifluoride phenol network and thing 2.38g and ampicillin sodium 1.23g, in 70 DEG C of reactions
1h, the 100g and dodecyl sodium sulfate 1.28g that adds water carry out emulsifying 60min, reaction temperature 40 DEG C, reaction time 1h, obtain fire-retardant
With water proofing property aqueous polyurethane coating.
Beneficial effects of the present invention is further illustrated below by relevant experimental data:
Water proofing property employing takes appropriate emulsion and is evenly applied on glass plate, is put by glass plate under uniform temperature after drying and forming-film
Enter in deionized water and soak, observe film and become situation blue, that turn white, bubble, send out wrinkle, come off.
Table one is fire-retardant with waterproof polyurethane coating institute filming performance
| Experimental group | Example one | Example two | Example three | Example four | Example five |
| Film outward appearance (resistance to water 48h) | Transparent | Transparent | Transparent | Transparent | Transparent |
| Hardness | B | B | B | B | B |
| Adhesive force/level | 3 | 2 | 3 | 3 | 3 |
| Pliability/mm | 2 | 2 | 2 | 2 | 3 |
From table two it is found that from film outward appearance, hardness, adhesive force, flexibility better performances.
The fire-retardant mechanical property with waterproof polyurethane coating gained film of table two
| Experimental group | Example one | Example two | Example three | Example four | Example five |
| Elongation at break/% | 142 | 157 | 128 | 158 | 172 |
| Tensile strength/MPa | 6.7 | 6.6 | 6.7 | 5.9 | 5.8 |
| Abrasion resisting/level | 4.5 | 4 | 3.5 | 4.5 | 4.5 |
The reference of table two middle finger object detection method (Jiang Weiqi. leather finish physical and chemical inspection [M]. China Light Industry Press,
1999), coating gained film elongation at break of the present invention, tensile strength, wear-resistant all performances are preferably.
Anti-flammability is to be referred to by smoke density method (maximum smoke density, reach the maximum smoke density time), oxygen index (OI), vertical combustion
Mark (flaming combustion time, glowing time) is weighed, and elongation at break characterizes its mechanical property.
The fire-retardant anti-flammability with waterproof polyurethane coating gained film of table three
| Example one | Example two | Example three | Example four | Example five | Market PU-1 | |
| Maximum smoke density | 24 | 27 | 29 | 13 | 8 | 42 |
| Reach maximum smoke density time/s | 165 | 165 | 180 | 215 | 210 | 120 |
| Oxygen index (OI) | 27.5 | 25.7 | 25.8 | 25.8 | 26.7 | 22 |
| Flaming combustion time/s | 21.4 | 21.4 | 12.3 | 11.8 | 11.1 | 68 |
| Glowing time/s | 0 | 0 | 0 | 0 | 0 | 0 |
The detection of table three indices is respectively according to following standard: smoke density measures according to GB8323-2008, oxygen index (OI)
GB/T5454-1997 " textile combustion performance test-oxygen index method " is used to measure；When flaming combustion time and flameless combustion
Between be to be measured by GB/T 5455-1997 " textile combustion energy test-normal beam technique ".
As shown in Table 3, when the present invention is fire-retardant and waterproof polyurethane coating gained film burns, maximum smoke density significantly drops
Low, reaching the maximum smoke density time significantly extends, and oxygen index (OI) significantly improves, and burning time substantially shortens.
Claims (5)
1. a fire-retardant preparation method with water proofing property aqueous polyurethane coating, it is characterised in that:
(1) with agitator, condenser pipe, thermometer 500ml there-necked flask in add 3-aminopropyl ortho-siliformic acid 60g, different
Isophorone diisocyanate 84g and TMAH 0.18g, reacts 1h at 70 DEG C, and obtaining base polyurethane prepolymer for use as A is
144g；
(2) in base polyurethane prepolymer for use as A, clomiphene citrate 1.14g and Adenosine cyclic monophosphate ester 10.7g is added, under the conditions of 60 DEG C
Reaction 3h, adds triethylamine 14.2g and bromine propylamine peptide woods 0.6g and is neutralized reaction 30min, add BFEE 4.1g,
Carry out emulsifying 60min in 70 DEG C of reactions 1h, the 80g and dodecyl sodium sulfate 0.28g that adds water, obtain the fire-retardant and aqueous poly-ammonia of water proofing property
Ester paint.
2. a fire-retardant preparation method with water proofing property aqueous polyurethane coating, it is characterised in that:
(1) with agitator, condenser pipe, thermometer 500ml there-necked flask in add Diphenylsilanediol 60g, different Buddhist
You are ketone diisocyanate 84g and TMAH 0.72g, reacts 3h at 80 DEG C, and obtaining base polyurethane prepolymer for use as A is
144g；
(2) in base polyurethane prepolymer for use as A, nicotinamide adenine dinucleotide phosphate 4.07g, methyl ortho-siliformic acid are added
4.07g and tricresyl phosphate (2,3-bis-chloropropyl) ester 58g, reacts 4h under the conditions of 80 DEG C, adds triethylamine 20.7g and chlorpromazine
5.2g is neutralized reaction 60min, adds benzyl trimethyl ammonium fluoride 2.38g, reacts 1h in 70 DEG C, and add water 100g and 12
Sodium alkyl sulfonate 0.58g carries out emulsifying 60min, obtains fire-retardant and water proofing property aqueous polyurethane coating.
3. a fire-retardant preparation method with water proofing property aqueous polyurethane coating, it is characterised in that:
(1) with agitator, condenser pipe, thermometer 500ml there-necked flask in add double (dimethyl hydroxyl is silica-based) two of 4,4'-
Phenylate 80g, IPDI 84g and TMAH 0.27g, react 3h at 75 DEG C, obtain polyurethane
Performed polymer A is 164g；
(2) in base polyurethane prepolymer for use as A, the chloro-1-of phosphopyridoxal pyridoxal phosphate 5.7g and 2-(2,4 dichloro benzene base) vinyl diethyl is added
Phosphate 35g, reacts 3.5h under the conditions of 70 DEG C, adds triethylamine 17.4g and niclosamidum 2.1g and is neutralized reaction
45min, adds tetrabutyl ammonium fluoride 2.7g, emulsifies in 70 DEG C of reactions 1h, the 110g and dodecyl sodium sulfate 0.43g that adds water
60min, obtains fire-retardant and water proofing property aqueous polyurethane coating.
4. a fire-retardant preparation method with water proofing property aqueous polyurethane coating, it is characterised in that:
(3) with agitator, condenser pipe, temperature 500ml there-necked flask in add double (dimethyl hydroxyl the is silica-based) benzene of 1,4-
60g, IPDI 84g and TMAH 0.19g, react 1h at 70 DEG C, obtain polyurethane prepolymer
Body A is 144g；
(4) in base polyurethane prepolymer for use as A, add aminopterin 1.17g and Adenosine cyclic monophosphate ester 10.7g, react under the conditions of 60 DEG C
3h, adds triethylamine 7.1g and centrofenoxine 3.1g and is neutralized reaction 30min, add BPF 1.7g, in 70 DEG C of reactions
1h, the 80g and dodecyl sodium sulfate 0.14g that adds water carry out emulsifying 60min, obtain fire-retardant and water proofing property aqueous polyurethane coating.
5. a fire-retardant preparation method with water proofing property aqueous polyurethane coating, it is characterised in that:
(1) with agitator, condenser pipe, temperature 500ml there-necked flask in add Adrenaline Tartrate 30g, isophorone
Diisocyanate 84g and TMAH 0.36g, reacts 5h at 80 DEG C, and obtaining base polyurethane prepolymer for use as A is 115g；
(2) add 5'-atriphos 2.07g in base polyurethane prepolymer for use as A, ortho-siliformic acid 2.07g and 2,3-bis-is chloro-for methyl
1-propyl alcohol phosphate 29g, reacts 4h under the conditions of 80 DEG C, adds triethylamine 20.7g and triethylene thiophosphoramide 1.2g and enters
Row neutralizes reaction 60min, adds boron trifluoride phenol network and thing 2.38g, reacts 1h in 70 DEG C, and add water 100g and dodecyl sulphur
Acid sodium 1.28g carries out emulsifying 60min, reaction temperature 40 DEG C, reaction time 1h, obtains fire-retardant and water proofing property aqueous polyurethane coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410703140.5A CN104356915B (en) | 2014-11-29 | 2014-11-29 | A kind of fire-retardant preparation method with water proofing property aqueous polyurethane coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410703140.5A CN104356915B (en) | 2014-11-29 | 2014-11-29 | A kind of fire-retardant preparation method with water proofing property aqueous polyurethane coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104356915A CN104356915A (en) | 2015-02-18 |
| CN104356915B true CN104356915B (en) | 2016-08-17 |
Family
ID=52524237
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410703140.5A Expired - Fee Related CN104356915B (en) | 2014-11-29 | 2014-11-29 | A kind of fire-retardant preparation method with water proofing property aqueous polyurethane coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104356915B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106221551B (en) * | 2016-08-30 | 2018-03-13 | 河北晨阳工贸集团有限公司 | Fire-retardant, waterproof and low VOC polyurethane coating preparation method |
| CN107325753A (en) * | 2017-07-11 | 2017-11-07 | 合肥龙发包装有限公司 | A kind of preparation method of corrugated paper high-strength adhesive |
| EP3564285A1 (en) * | 2018-05-02 | 2019-11-06 | Henkel AG & Co. KGaA | Structural two-component adhesive |
| CN108864922B (en) * | 2018-06-18 | 2021-06-15 | 广州市雅乔化工有限公司 | Preparation method of flame-retardant, waterproof and light-resistant waterborne polyurethane coating and adhesive |
| CN109400957B (en) * | 2018-07-19 | 2020-11-27 | 中国科学院宁波材料技术与工程研究所 | Alkaloid phosphate flame retardant and preparation method thereof |
| CN111116921A (en) * | 2019-12-31 | 2020-05-08 | 广东省稀有金属研究所 | Self-flame-retardant high-hardness organic silicon resin and preparation method and application thereof |
| WO2022030748A1 (en) * | 2020-08-06 | 2022-02-10 | 성균관대학교산학협력단 | Non-halogen based, phosphorus-based flame retardant, flame retardant polymer resin using same, and production method for same |
| CN112127156B (en) * | 2020-09-25 | 2021-04-20 | 珠海华大浩宏新材料有限公司 | Environment-friendly fluorine-containing waterproof agent and preparation method thereof |
-
2014
- 2014-11-29 CN CN201410703140.5A patent/CN104356915B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN104356915A (en) | 2015-02-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104356915B (en) | A kind of fire-retardant preparation method with water proofing property aqueous polyurethane coating | |
| CN108912928B (en) | Preparation method of flame-retardant and waterproof water-based core-shell acrylate resin coating and paint | |
| CN104109457B (en) | A kind of fire-retardant with water-repellancy aqueous polyurethane coating and the preparation method of tackiness agent | |
| CN105176368B (en) | A kind of preparation method of fire-retardant and sunproof polyurethane coating and adhesive | |
| CN103666174B (en) | Heat reflection coatings and its preparation method and application | |
| CN104194607B (en) | The preparation method of fast light and water proofing property waterborne flame retardant polyurethane coating and adhesive | |
| CN103952071B (en) | A kind of fast light method with waterproof polyurethane coating and adhesive of environment-friendly type of preparing | |
| BR9912362A (en) | Compositions and methods for the protection of calcitic and / or siliceous surfaces | |
| CN102876172A (en) | Water-based fireproof paint | |
| CN109233490A (en) | A kind of fire-retardant alkali-resistant primer of aqueous environmental friendly indoor and preparation method thereof | |
| CN104830220B (en) | Aqueous flame retardant polyurethane coating and the preparation method of adhesive | |
| CN104497768A (en) | Preparation method of acrylic ester resin coatings and adhesives with flame retardance and waterproofness | |
| CN104745070B (en) | A kind of polyurethane exterior wall antiseptic fire-retardation coating and preparation method thereof | |
| CN110483708B (en) | Polymer spray film waterproof material for underground engineering and preparation method thereof | |
| CN104087144B (en) | The preparation method of a kind of waterproof and Antibacterial polyurethane coating | |
| CN106221550B (en) | Fire-retardant, light resistance and low VOC polyurethane coating preparation method | |
| CN105566968A (en) | Water-based fireproof coating and preparing method thereof | |
| CN107778419A (en) | A kind of POSS is modified self-flame-retardant acrylic emulsion and preparation method thereof | |
| CN107760089A (en) | A kind of fire proof construction coating and preparation method thereof | |
| CN104098995B (en) | A kind of preparation method of fire-retardant and water proofing property aqueous polyurethane coating | |
| CN108864922B (en) | Preparation method of flame-retardant, waterproof and light-resistant waterborne polyurethane coating and adhesive | |
| CN108192398A (en) | Blending and modifying acrylates spray film water-proofing material and preparation method thereof | |
| CN104945836A (en) | Plastic for wear-resisting interior trim panel | |
| CN108192394A (en) | Modification by copolymerization acrylates spray film water-proofing material and preparation method thereof | |
| CN109468012A (en) | A kind of alcohol-soluble Transparent expansion type fire-retardant paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Wang Wenyan Inventor after: Yu Haijiang Inventor before: Zhu Lei Inventor before: Duan Baorong |
|
| COR | Change of bibliographic data | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160718 Address after: 264006 A-44 District, Shandong, Yantai Applicant after: YANTAI SMITHDE ELECTROMECHANICAL EQUIPMENT MANUFACTURING Co.,Ltd. Address before: 264005 Shandong Province, Yantai city Laishan District Road No. 30 spring Applicant before: Zhu Lei |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Preparation method for flame-retardant waterproof aqueous polyurethane paint Effective date of registration: 20161223 Granted publication date: 20160817 Pledgee: YANTAI ZHIBEN INTELLECTUAL PROPERTY MANAGEMENT Co.,Ltd. Pledgor: YANTAI SMITHDE ELECTROMECHANICAL EQUIPMENT MANUFACTURING Co.,Ltd. Registration number: 2016990001164 |
|
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20170904 Granted publication date: 20160817 Pledgee: YANTAI ZHIBEN INTELLECTUAL PROPERTY MANAGEMENT Co.,Ltd. Pledgor: YANTAI SMITHDE ELECTROMECHANICAL EQUIPMENT MANUFACTURING Co.,Ltd. Registration number: 2016990001164 |
|
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Fu Ying Inventor after: Zhong Fusheng Inventor before: Wang Wenyan Inventor before: Yu Haijiang |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20171226 Address after: 412212 village Tianxin in Longhu Bay Village, Sunjia Wan Town, Liling City, Zhuzhou, Hunan Patentee after: Hunan Shuai flag waterproof material Co.,Ltd. Address before: 264006 A-44 District, Shandong, Yantai Patentee before: YANTAI SMITHDE ELECTROMECHANICAL EQUIPMENT MANUFACTURING Co.,Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160817 Termination date: 20211129 |