CN104072243A - Full water soluble fertilizer special for grapes - Google Patents
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Abstract
The invention provides full water soluble fertilizer special for grapes, belongs to special fertilizer for grapes, and is used for topdressing from early spring when the grape bud eyes expand till the time when the grapes are picked. The fertilizer comprises the following components in parts by weight: 130 to 150 parts of urea, 50 to 70 parts of monoammonium phosphate, 110 to 140 parts of diammonium phosphate, 90 to 110 parts of ammonium sulfate, 25 to 35 parts of monopotassium phosphate, 470 to 500 parts of potassium nitrate, and 50 to 70 parts of premixed materials. The fertilizer can meet the requirements of the grapes for all nutrients, enables a grapevine to be strong and healthy in growth, strong in disease resistance, strong in early-fruit ability, good in yielding ability, and good in quality, and can improve the planting benefit of the grapes.
Description
Technical field
The invention belongs to fertilizer production technology field, be specifically related to the special-purpose full water soluble fertilizer of a kind of grape.
Background technology
Grape is a kind of look gorgeous delicious and polytrophic fruit.Meanwhile, grape also have alleviate hypoglycemia, pre-preventing thrombosis, anti-ageing, help the nourishing functions such as rehabilitation, thereby, be loved by the people.
The cultivated area of whole world grape and ultimate production all account for first place in each planting fruit-trees.Grape adaptability is very strong, at China's wide geographic area, is all planting.Viticulture two annual bearings, enter the best fruiting period on the 4th to the 6th year, and fruiting period reaches 40-60, per mu yield fresh fruit 1800-2500 kilogram, and by 10 yuan every kilogram of unit prices, every per mu yield value can reach 18000-25000 unit.According to Food and Argriculture OrganizationFAO (FAO) statistic data, there is in the world at present more than 90 country's plantation grape, the total area is about 11,250 ten thousand mu, approximately 6,500 ten thousand tons of gross annual output amounts, in all kinds of fruit, in second, developed country's vintage and area account for respectively 65.6% and 70.7% of world's total amount.Wherein vitis vinifera output and area account for half of the world, and Asia vintage and area account for nearly 1/4 of the world.Whole world vintage 70% for processing, and be mainly processed into grape wine.At present, approximately 6,000,000 mu of China's grape-growing areas, account for world's cultivated area 5.0%, approximately 4,500,000 tons of output, occupy the world the 5th (after Italy, France, the U.S., Spain), wherein Table Grape area and output ratio account for more than 70%, rank first in the world, and approximately 1,000,000 mu of Wine Grapes account for 1.5% of Gross World Product.
Grape,, starts to fruit maturation from young sprout growth the absorption of phosphorus to SPRING WHEAT BEFORE AND AFTER FLOWERING requirement maximum since rudiment in spring, Zhan Ye the absorption of nitrogen.Grape all absorbs potassium in whole vegetative period, is happiness potassium berry.The general 1000 kilograms of grape fruits of the high yield every production in vineyard of growing up need 3.8～7.8 kilograms, nitrogen (N), phosphorus (P
2o
5), 2.0～7.0 kilograms, potassium (K
2o) 4.0～8.9 kilograms.The ratio of absorbed nitrogen, phosphorus, potassium is about 1:0.6:1.2.Before Berry Growth, larger to the requirement of nitrogen, phosphorus, potassium, peak Fruit to collection period.This fertilizer not enough in stage, can produce considerable influence to vintage, especially blooms, pollinates, bears fruit, fruit expanding period is larger to the requirement of phosphorus, potassium.Grape is also relatively many to the requirement of boron.In order to prevent the deficiency disease of grape, improve the quality and yield of grape, the fertility situation according to soil, also needs the nutrient substances such as copper, zinc, manganese, iron, sulphur, molybdenum.
Fertilizer is the important substance basis of grape growth, fruit, the quality of fertilizer material quality, and whether mixing ratio is reasonable, directly affects grape growth, fruit yield and quality.Each nutritive ingredient in fertilizer, has conclusive effect to the normal growth in grape each vegetative period and fruit yield and quality, and the economic benefit of wine-growing is equally also had to very important effect.
At present, China is in grape fertilising process, and the problem of existence mainly contains:
, organic fertilizer application ratio is lower, also has part orchard worker that the fertilizer without becoming thoroughly decomposed is directly applied in ground, is not only difficult to absorb, and brings the harmful organisms such as germ, also easily causes burning root phenomenon;
, blindly the phenomenon of applying fertilizer is more serious.Vineyard excessive fertilization, the phenomenon of particularly abusing chemical fertilizer is comparatively serious, and having there is obvious fertilizer damage phenomenon in part orchard, brings loss not only to peasant household self, causes a series of environment, Climatic issues simultaneously;
, have sub-fraction orchard worker seldom to apply fertilizer, soil fertility cannot meet fruit tree normal growth;
, fertilizer structure is unreasonable, nutrients ratio is unbalance.Most of orchard worker has possessed the thought of certain balance fertilizing, but be confined to the straight fertilizers such as nitrogen, phosphorus, potassium, to moderate-elements such as calcium, sulphur, the trace elements such as copper, zinc, manganese, iron, molybdenum, boron cannot apply fertilizer, cause grape nutritive deficiency, affect output and quality;
, use traditional straight fertilizer and granular compound fertilizer, because the foreign matter content of these fertilizer is higher, often blocking dropping head, causes fertilizer efficiency to reduce, production cost increases, and has reduced the economic benefit of wine-growing.
Under the overall background of China's Developing Water-saving Agriculture, along with improving constantly of the degree such as facility, mechanize and automatization, spray fertigation technology has become the mainstream technology of modern agriculture high added value farm crop water and fertilizer management gradually.For grape nutritional needs and soil nutrient supply characteristic, carry out the principle of " overall control " and " minute period regulation ", on the basis of irrigating at micro irrigation fertilizer spreading reasonably optimizing, realize the supply fertilization mode of " on a small quantity repeatedly ", can greatly improve the utilising efficiency of liquid manure.According to the experience of foreign agriculture development and the trend of China's agricultural development, water soluble fertilizer will become the leading product of China's water soluble fertilizer completely.Therefore, be necessary to research and develop the special-purpose full water soluble fertilizer of grape.
200910095081.7, name is called the patent of invention of " a kind of high concentration drip irrigation special fertilizer for vegetative growth phase of grapes ", the main component of disclosed vegetative growth phase of grapes drip irrigation special fertilizer is (weight part): saltpetre 244-267 part, monoammonium phosphate 181-198 part, urea 357-390 part, magnesium sulfate heptahydrate 139-209 part, boric acid 0.3-0.6 part, EDTA chelated iron 3.6-5.8 part, EDTA chelated copper 0.2-0.4 part, EDTA Chelated Manganese 0.6-1.0 part, Sodium orthomolybdate 0.002-0.004 part, EDTA chelated zinc 1.0-1.6 part.In this patent formulation, the ratio of nitrogen, phosphorus, potassium (1:0.5:0.5) does not meet the characteristics of demand of grape; Magnesium sulfate (139-209 part) is higher, and the soil region of adaptation is limited, is only applicable to the area of soil magnesium deficiency; And and the ratio of EDTA chelated iron, EDTA chelated copper, EDTA Chelated Manganese, EDTA chelated zinc is uneven, the deficiency disease that can not effectively prevent grape.
200910065958.8, name is called the patent of invention of " a kind of gluconate water-soluble micronutrient fertilizer ", consists of: Ferrous Gluconate 5-10, copper gluconate 5-10, Zinc Gluconate 5-10, manganese gluconate 5-10, glucose complexing boron 1-4, ammonium molybdate 0.05-0.1, water 60-70 the material of following parts by weight.This fertilizer is only to contain water miscible gluconic acid trace element salt, and moisture 60-70, belongs to liquid fertilizer; The basic nutrition element nitrogen, phosphorus, the potassium that containing plant, do not need, more non-grape special fertilizer material.
Summary of the invention
In order to solve the problems of the technologies described above, the invention provides the special-purpose full water soluble fertilizer of a kind of grape, belong to grape special fertilizer, for grape eye in early spring, expand after picking fruit as topdressing use.This fertilizer can meet the demand of grape to all nutrients completely, can make that grape tree vigo(u)r is strong, disease resistance is strong, early fruiting character is strong, yielding ability is good, quality better, improves wine-growing benefit.
For achieving the above object, the present invention adopts following technical scheme:
The special-purpose full water soluble fertilizer of grape, it is characterized in that: by weight, comprise following component: urea 130-150 part, monoammonium phosphate 50-70 part, diammonium phosphate 110-140 part, ammonium sulfate 90-110 part, potassium primary phosphate 25-35 part, saltpetre 470-500 part, Preblend 50-70 part.
Preferably, by weight, comprise following component: urea 135-145 part, monoammonium phosphate 55-65 part, diammonium phosphate 120-130 part, ammonium sulfate 95-105 part, potassium primary phosphate 28-32 part, saltpetre 470-490 part, Preblend 55-65 part.
The basic nutrition element nitrogen, phosphorus, the potassium that in fertilizer of the present invention, contain plant needs, and the content ratio of nitrogen, phosphorus, potassium is about 1:0.6:1.2, meets the nutritional needs of grape.
Preferably, described monoammonium phosphate, diammonium phosphate and potassium primary phosphate are food grade, sanitary index fluorine, lead, arsenic, every etc. far below national standard.
Preferably, described urea is processed through attrition crushing, and granular size is 20-40 orders, is more convenient for mixing with water-soluble.
Preblend of the present invention, by weight, comprise following component: borax 320-350 part, EDTA chelating calcium 150-180 part, EDTA chelated magnesium 170-200 part, EDTA chelated copper 70-90 part, EDDHA chelated iron 70-90 part, EDTA chelated zinc 70-90 part, EDTA Chelated Manganese 32-35 part, Sodium orthomolybdate 32-35 part.
The proportional balancing method of the organic trace element using in Preblend of the present invention, the deficiency disease that can effectively prevent grape, and Organic Iron adopts EDDHA chelated iron, applicable to acid and alkalescence (PH4-10) soil.
Preferably, by weight, comprise following component: borax 330-335 part, EDTA chelating calcium 160-170 part, EDTA chelated magnesium 180-190 part, EDTA chelated copper 82-85 part, EDDHA chelated iron 82-85 part, EDTA chelated zinc 82-85 part, EDTA Chelated Manganese 33-34 part, Sodium orthomolybdate 33-34 part.
The special-purpose full water soluble fertilizer of grape of the present invention have nutrient substance comprehensively, containing a large amount of, middle amount and trace element, can meet the demand of grape to various nutrient substances completely, can not there is the advantage of deficiency disease; And can be soluble in water completely rapidly, be particularly suitable for spraying fertigation mode.
Beneficial effect is:
1, the present invention, according to the nutritional needs feature of grape and the Fertility Characteristics of soil, has added macroelement (nitrogen, phosphorus, potassium), moderate-element (calcium, magnesium, sulphur) and trace element (copper, iron, zinc, manganese, molybdenum, boron) etc. in fertilizer; Formula rationally, and proportioning is compared with prior art balance more, the component design in strict accordance with the nutritional needs of grape, as grape is about the water-soluble fertilizer 1:0.6:1.2(to the demand percentage of nitrogen, phosphorus, potassium, the ratio of nitrogen, phosphorus, potassium is about 1:0.5:1.5), conform to formula rate of the present invention, can fully meet the demand of grape to all nutrients, effectively prevent the deficiency disease of grape, meet completely and can make that grape tree vigo(u)r is strong, disease resistance is strong, early fruiting character is strong, yielding ability is good, quality better, improve wine-growing benefit.
2, the borax, EDTA chelating calcium, EDTA chelated magnesium, EDTA chelated copper, EDDHA chelated iron, EDTA chelated zinc, EDTA Chelated Manganese and the Sodium orthomolybdate that in the present invention's formula, add are humatite element, and utilization ratio improves more than 3 times than inorganic microelement.Meet grape growth, the nutritional need of bear fruit required boron, calcium, magnesium, copper, iron, zinc, manganese and molybdenum; Can effectively prevent the deficiency disease of corresponding nutritive element.
3, the chelated ferrous iron in the present invention's formula is EDDHA-Fe, with NaFeEDTA, DTPA iron, iron-amino acid chelate, the Organic Irons such as Ferrous Fumarate and inorganic ferrous sulfate are compared, its PH is applied widely, applicable to acid and alkalescence (PH4-10) soil, can effectively prevent, treat grape iron chlorosis sick (yellowtop), can effectively strengthen the photosynthesis of crop, green, photosynthetic enhancing that yellow turns, effect are lasting.
4, the urea in fertilizer formula of the present invention, adopts attrition crushing technique in process of production, has avoided having urea granules to exist in product, can fully mix, thereby guarantee the full water-soluble of product.
5, in fertilizer formula of the present invention, all monoammonium phosphate (GB 25569-2010), diammonium phosphate (GB 30613-2014), potassium primary phosphates (GB 25560-2010) are food grade, thus sanitary index fluorine in product, lead, arsenic, every etc. far below national standard.
6, the urea in formula is treated to 20-40 orders through attrition crushing, has avoided having urea granules to exist in product, can fully mix, thereby further guarantee the full water-soluble of product.
7, general water soluble fertilizer is the simple mixing of the element compounds such as nitrogenous, phosphorus, potassium, calcium, magnesium, and the raw materials such as calcium superphosphate can not be rapidly, completely water-soluble, easily stops up shower nozzle, water dropper.The urea using in the present invention is through pre-treatment, saltpetre, monoammonium phosphate, diammonium phosphate, ammonium sulfate, the potassium primary phosphate of attrition crushing, other calcium, magnesium, copper, iron, zinc, manganese are organic chelated state form, soluble in water, the compound of the elements such as boron, molybdenum is all soluble in water.Thereby realized the full water-soluble of product, can be soluble in water completely rapidly, can not stop up shower nozzle, water dropper.Therefore, be particularly suitable for spraying fertigation mode, effectively improve fertilizer utilization efficiency, play water saving, save fertile effect.
Embodiment
Below in conjunction with concrete enforcement, further describe technical solution of the present invention.
Embodiment 1
The special-purpose full water soluble fertilizer of grape, by weight, comprises following component: 135 parts, urea, 55 parts of monoammonium phosphates, 120 parts of diammonium phosphate, 92 parts, ammonium sulfate, 28 parts of potassium primary phosphates, 480 parts, saltpetre, 55 parts of Preblendes.
Embodiment 2
The special-purpose full water soluble fertilizer of grape, by weight, comprises following component: 130 parts, urea, 50 parts of monoammonium phosphates, 110 parts of diammonium phosphate, 90 parts, ammonium sulfate, 25 parts of potassium primary phosphates, 470 parts, saltpetre, 50 parts of Preblendes.
Described Preblend, by weight, comprises following component: 320 parts of boraxs, 150 parts of EDTA chelating calcium, 170 parts of EDTA chelated magnesiums, 70 parts of EDTA chelated coppers, 70 parts of EDDHA chelated irons, 70 parts of EDTA chelated zincs, 32 parts of EDTA Chelated Manganeses, 32 parts of Sodium orthomolybdates.
Embodiment 3
The special-purpose full water soluble fertilizer of grape, by weight, comprises following component: 150 parts, urea, 70 parts of monoammonium phosphates, 140 parts of diammonium phosphate, 110 parts, ammonium sulfate, 35 parts of potassium primary phosphates, 500 parts, saltpetre, 70 parts of Preblendes.
Described Preblend, by weight, comprises following component: 350 parts of boraxs, 180 parts of EDTA chelating calcium, 200 parts of EDTA chelated magnesiums, 90 parts of EDTA chelated coppers, 90 parts of EDDHA chelated irons, 90 parts of EDTA chelated zincs, 35 parts of EDTA Chelated Manganeses, 35 parts of Sodium orthomolybdates.
Embodiment 4
The special-purpose full water soluble fertilizer of grape, by weight, comprises following component: 140 parts, urea, 58 parts of monoammonium phosphates, 125 parts of diammonium phosphate, 96 parts, ammonium sulfate, 30 parts of potassium primary phosphates, 475 parts, saltpetre, 56 parts of Preblendes.
Described monoammonium phosphate, diammonium phosphate and potassium primary phosphate are food grade.
Described Preblend, by weight, comprises following component: 330 parts of boraxs, 160 parts of EDTA chelating calcium, 180 parts of EDTA chelated magnesiums, 75 parts of EDTA chelated coppers, 75 parts of EDDHA chelated irons, 80 parts of EDTA chelated zincs, 33 parts of EDTA Chelated Manganeses, 32 parts of Sodium orthomolybdates.
Embodiment 5
The special-purpose full water soluble fertilizer of grape, by weight, comprises following component: 135 parts, urea, 55 parts of monoammonium phosphates, 120 parts of diammonium phosphate, 95 parts, ammonium sulfate, 28 parts of potassium primary phosphates, 470 parts, saltpetre, 55 parts of Preblendes.
Described monoammonium phosphate, diammonium phosphate and potassium primary phosphate are food grade.
Described Preblend, by weight, comprises following component: 330 parts of boraxs, 160 parts of EDTA chelating calcium, 180 parts of EDTA chelated magnesiums, 82 parts of EDTA chelated coppers, 82 parts of EDDHA chelated irons, 82 parts of EDTA chelated zincs, 33 parts of EDTA Chelated Manganeses, 33 parts of Sodium orthomolybdates.
Described urea is processed through attrition crushing, and granular size is 20 orders.
Embodiment 6
The special-purpose full water soluble fertilizer of grape, by weight, comprises following component: 145 parts, urea, 65 parts of monoammonium phosphates, 130 parts of diammonium phosphate, 105 parts, ammonium sulfate, 32 parts of potassium primary phosphates, 490 parts, saltpetre, 65 parts of Preblendes.
Described monoammonium phosphate, diammonium phosphate and potassium primary phosphate are food grade.
Described Preblend, by weight, comprises following component: 335 parts of boraxs, 170 parts of EDTA chelating calcium, 190 parts of EDTA chelated magnesiums, 85 parts of EDTA chelated coppers, 85 parts of EDDHA chelated irons, 85 parts of EDTA chelated zincs, 34 parts of EDTA Chelated Manganeses, 34 parts of Sodium orthomolybdates.
Described urea is processed through attrition crushing, and granular size is 40 orders.
Embodiment 7
The special-purpose full water soluble fertilizer of grape, by weight, comprises following component: 140 parts, urea, 60 parts of monoammonium phosphates, 125 parts of diammonium phosphate, 100 parts, ammonium sulfate, 30 parts of potassium primary phosphates, 480 parts, saltpetre, 60 parts of Preblendes.
Described monoammonium phosphate, diammonium phosphate and potassium primary phosphate are food grade.
Described Preblend, by weight, comprises following component: 333 parts of boraxs, 165 parts of EDTA chelating calcium, 185 parts of EDTA chelated magnesiums, 83 parts of EDTA chelated coppers, 84 parts of EDDHA chelated irons, 83 parts of EDTA chelated zincs, 33.5 parts of EDTA Chelated Manganeses, 33.5 parts of Sodium orthomolybdates.
Described urea is processed through attrition crushing, and granular size is 30 orders.
Embodiment 8
The special-purpose full water soluble fertilizer of grape, by weight, comprises following component: 138 parts, urea, 58 parts of monoammonium phosphates, 126 parts of diammonium phosphate, 103 parts, ammonium sulfate, 31 parts of potassium primary phosphates, 482 parts, saltpetre, 58 parts of Preblendes.
Described monoammonium phosphate, diammonium phosphate and potassium primary phosphate are food grade.
Described Preblend, by weight, comprises following component: 332 parts of boraxs, 162 parts of EDTA chelating calcium, 186 parts of EDTA chelated magnesiums, 84 parts of EDTA chelated coppers, 83 parts of EDDHA chelated irons, 84 parts of EDTA chelated zincs, 33.6 parts of EDTA Chelated Manganeses, 33.7 parts of Sodium orthomolybdates.
Described urea is processed through attrition crushing, and granular size is 25 orders.
Embodiment 9
Produce according to the following steps fertilizer of the present invention:
The first step: production Preblend.
By proportioning raw materials, weigh borax, EDTA chelating calcium, EDTA chelated magnesium, EDTA chelated copper, EDDHA chelated iron, EDTA chelated zinc, EDTA Chelated Manganese and Sodium orthomolybdate.With the stainless steel mixing machine of 500 kilograms every batch, stir 3-4 minute, mix, by 40 kilograms/bag, with after automatic packing machine packing, be made into Preblend, put into raw material storage standby.
Second step: manufacture a finished product.
By proportioning raw materials, weigh saltpetre, urea, diammonium phosphate, ammonium sulfate, monoammonium phosphate, Preblend and potassium primary phosphate.With the stainless steel mixing machine of 2000 kilograms every batch, stir 3-4 minute, be uniformly mixed, respectively by 0.2,0.5,2,5,10,20 kilogram/bag, with after automatic packing machine packing, put into stockyard, become the special-purpose water soluble fertilizer finished product completely of grape.
In the special-purpose full water soluble fertilizer of grape of the present invention, all raw materials, product are all carried out according to NY 1107-2010 < < macroelement water-soluble fertilizer > > standard.Product is through St Chemical Fertilizer Q Supervision & Testing Center (Beijing) check, and all indexs are qualified (report number: D131410) all.
Embodiment 10
The present invention selects 3 No. 1, Portugal, Nian Sheng another name for Sichuan Province grape varieties in Yongan, Shuangliu County, Sichuan Province Hong Ti association base, every mu of plantation 200 strains.With the water-soluble fertilizer that grape full water-soluble of the present invention is fertile and general, carried out contrast test of fertilizer efficiency.
Be divided into test group and control group, 6 mu every group, 3 repetitions, each repeats 2 mu.According to conventional fertilizer application method, in the situation that executing identical base manure (account for annual fertilising approximately 15%), the water-soluble fertilizer that the grape full water-soluble of the present invention that topdresses is fertile and general specifically (accounts for annual fertilising approximately 15%) before rudiment, bloom before (accounting for annual fertilising approximately 20%), bloom after 4 periods of (accounting for annual fertilising approximately 40%), painted initial stage of grape berry (account for annual apply fertilizer approximately 10%) carry out.After picking fruit, measure respectively the output of each repetition, choose at random 5% mensuration single fruit weight, each repeats to choose soluble solid, total reducing sugar, total acid and the Vc content of 6 sample determination fruits.The results are shown in Table 1.
The impact of table 1 different fertilizer Dui Shu Portugal No. 1 vintage, fruit properties and quality
Note: have between the data of different letters with column data acceptance of the bid in table, represent statistical analysis check significant difference.
From the above results, the special-purpose full water soluble fertilizer of grape of the present invention is better than general water soluble fertilizer, more can improve the planting benefit of grape.
Claims (6)
1. the special-purpose full water soluble fertilizer of grape, it is characterized in that: by weight, comprise following component: urea 130-150 part, monoammonium phosphate 50-70 part, diammonium phosphate 110-140 part, ammonium sulfate 90-110 part, potassium primary phosphate 25-35 part, saltpetre 470-500 part, Preblend 50-70 part.
2. the special-purpose full water soluble fertilizer of grape according to claim 1, it is characterized in that: by weight, comprise following component: urea 135-145 part, monoammonium phosphate 55-65 part, diammonium phosphate 120-130 part, ammonium sulfate 95-105 part, potassium primary phosphate 28-32 part, saltpetre 470-490 part, Preblend 55-65 part.
3. the special-purpose full water soluble fertilizer of grape according to claim 1, it is characterized in that: described Preblend, by weight, comprise following component: borax 320-350 part, EDTA chelating calcium 150-180 part, EDTA chelated magnesium 170-200 part, EDTA chelated copper 70-90 part, EDDHA chelated iron 70-90 part, EDTA chelated zinc 70-90 part, EDTA Chelated Manganese 32-35 part, Sodium orthomolybdate 32-35 part.
4. the special-purpose full water soluble fertilizer of grape according to claim 3, it is characterized in that: described Preblend, by weight, comprise following component: borax 330-335 part, EDTA chelating calcium 160-170 part, EDTA chelated magnesium 180-190 part, EDTA chelated copper 82-85 part, EDDHA chelated iron 82-85 part, EDTA chelated zinc 82-85 part, EDTA Chelated Manganese 33-34 part, Sodium orthomolybdate 33-34 part.
5. according to the special-purpose full water soluble fertilizer of the grape described in claim 1-2 any one, it is characterized in that: described monoammonium phosphate, diammonium phosphate and potassium primary phosphate are food grade.
6. according to the special-purpose full water soluble fertilizer of the grape described in claim 1-2 any one, it is characterized in that: described urea is processed through attrition crushing, granular size is 20-40 orders.
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| CN104591879A (en) * | 2014-12-30 | 2015-05-06 | 成都新柯力化工科技有限公司 | Special controlled-release water soluble fertilizer for grapes and preparation method thereof |
| CN104919960A (en) * | 2015-06-12 | 2015-09-23 | 重庆市和兆山生态农业有限责任公司 | Fertilizing method improving yield of grapes |
| CN104973960A (en) * | 2015-06-26 | 2015-10-14 | 上海诺同农业科技有限公司 | Fruit tree dedicated bio-organic fertilizer, production method and application method thereof |
| CN105036876A (en) * | 2015-07-21 | 2015-11-11 | 句容市后白镇美佳多果品专业合作社 | Water and fertilizer integration special fertilizer for grapes and application method thereof |
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| CN105399551A (en) * | 2015-12-31 | 2016-03-16 | 史丹利化肥股份有限公司 | Special spray-irrigation and drip-irrigation urea-ammonium nitrate (UAN) liquid fertilizer for crops |
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| CN106631517A (en) * | 2017-01-17 | 2017-05-10 | 河北中仁化肥有限公司 | Humic-acid-containing water-soluble fertilizer capable of increasing selenium content of grapes, and preparation method and application thereof |
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